CN106753859A - A kind of edible liquid detergent and preparation method thereof - Google Patents
A kind of edible liquid detergent and preparation method thereof Download PDFInfo
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- CN106753859A CN106753859A CN201610948485.6A CN201610948485A CN106753859A CN 106753859 A CN106753859 A CN 106753859A CN 201610948485 A CN201610948485 A CN 201610948485A CN 106753859 A CN106753859 A CN 106753859A
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- sargassum
- liquid detergent
- unstrained spirits
- vinegar unstrained
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Medicines Containing Plant Substances (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- General Preparation And Processing Of Foods (AREA)
Abstract
The present invention provides a kind of edible liquid detergent and preparation method thereof, and liquid detergent of the invention can thoroughly remove the harmful substances such as remains of pesticide and dust, greasy dirt, the worm dirt on veterinary antibiotics surface；Raw material of the present invention it is all can food grade materials, without chemical surface activity auxiliary chemicals, compound essence etc., there is no secondary pollution, not only economized on water during use, it is also very environmentally friendly；This product wipe thing when will not scratch vessel, kitchen tools or tableware to being stained with grease have rapid decontamination and water saving the features such as, it is not necessary to rinse repeatedly；With sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract reaches the effect of sterilization by the synergistic function of each component as main sterilization component；Cleaning agent low cost of the invention, preparation process is simple, easily, easy to use, nontoxic to human body non-stimulated, biological degradation rate is high, non-secondary pollution, environmental protection.
Description
Technical field
The invention belongs to articles for washing technical field, and in particular to a kind of edible liquid detergent and preparation method thereof.
Background technology
Although the detergent powder for using at present has cleaning function, it is not suitable for human body and eats, does not have after human body intake
Any benefit, excessive intake can also cause damage to human body, and the washed kitchen tools of liquid detergent always have liquid detergent residual, if not
Rinsed repeatedly, residual liquid detergent can be ingested human body, go down for a long time harmful, rinsing repeatedly can cause water resource again
Waste.
The content of the invention
In view of this, the present invention provides a kind of edible liquid detergent and preparation method thereof, to solve to mention in the prior art
Problem.
The technical scheme is that：A kind of edible liquid detergent, by following parts by weight into being grouped into：Stearoyl lemon
44-62 parts of lemon acid, deionized water 33-47 parts, sucrose fatty ester 12-23 parts, 2-5 parts of sargassum tunning, shaddock
Bark extract 3-7 parts, 14-27 parts of vinegar unstrained spirits aqueous extract.
Further, described edible liquid detergent, by following parts by weight into being grouped into：Stearoyl citric acid 51-
58 parts, deionized water 37-43 parts, sucrose fatty ester 17-21 parts, 3-4 parts of sargassum tunning, shaddock bark extract 4-
5 parts, 18-25 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
The liquid detergent that the present invention is compounded using stearoyl citric acid and sucrose fatty ester, with good hydrophily
And lipophile, the mildness of formula system is enhanced, with good decontamination, emulsification, wetting and foam performance, to skin and eye
Eyeball excitant is small, the stabilization in hard water.
The present invention provides a kind of edible liquid detergent and preparation method thereof, and liquid detergent of the invention can thoroughly remove vegetable
The harmful substance such as dish, the remains of pesticide of fruit surface and dust, greasy dirt, worm dirt；Raw material of the present invention it is all can food grade materials,
Without chemical surface activity auxiliary chemicals, compound essence etc., there is no secondary pollution, not only economized on water during use, also very
Environmental protection；This product wipe thing when will not scratch vessel, kitchen tools or tableware to being stained with grease have rapid decontamination and water saving etc.
Feature, it is not necessary to rinse repeatedly；With sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract is used as main sterilization
Composition, the effect of sterilization is reached by the synergistic function of each component；Cleaning agent low cost of the invention, preparation technology letter
Single, easy, easy to use, nontoxic to human body non-stimulated, biological degradation rate is high, non-secondary pollution, environmental protection.
The present invention is led to sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract as main sterilization component
The synergistic function of each component is crossed, pathogenic bacteria are mainly acted in terms of two：1. the cell membrane and cell of pathogenic bacteria are acted on
Film system, destroys directly and rapidly the energetic supersession and cell that depend on membrane structure integrality and organelle is depended on for existence to thing
The selective permeability of matter, makes nutriment and metabolite normally through cell membrane microorganism cannot be made to lose nutrition and cause
Its growth retardation, reaches the purpose of restraining and sterilizing bacteria；2., by suppressing the respiration of pathogenic bacteria, metabolic activity is obstructed, it is impossible to
Normal dynamic membrane structure is maintained, causes the self-dissolving of cell.By abundant hydroxyl for containing in the active component in invention etc.
Group, easily forms hydrogen bond with active site in alcohol, and then causes metabolic system disorderly, and then reaches the effect of sterilization；This hair
Bright cleaning agent low cost, preparation process is simple, easily, easy to use, nontoxic to human body non-stimulated, biological degradation rate is high, nothing
Secondary pollution, environmental protection.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
A kind of edible liquid detergent, by following parts by weight into being grouped into：54 parts of stearoyl citric acid, 39 parts of deionized water,
19 parts of sucrose fatty ester, 3 parts of sargassum tunning, 5 parts of shaddock bark extract, 21 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
Embodiment 2
A kind of edible liquid detergent, by following parts by weight into being grouped into：53 parts of stearoyl citric acid, deionized water 38
Part, 18 parts of sucrose fatty ester, 4 parts of sargassum tunning, 4 parts of shaddock bark extract, 18 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
Embodiment 3
A kind of edible liquid detergent, by following parts by weight into being grouped into：55 parts of stearoyl citric acid, 40 parts of deionized water,
29 parts of sucrose fatty ester, 4 parts of sargassum tunning, 5 parts of shaddock bark extract, 25 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
Embodiment 4
A kind of edible liquid detergent, by following parts by weight into being grouped into：51 parts of stearoyl citric acid, deionized water 37
Part, 17 parts of sucrose fatty ester, 3 parts of sargassum tunning, 4 parts of shaddock bark extract, 20 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
Embodiment 5
A kind of edible liquid detergent, by following parts by weight into being grouped into：58 parts of stearoyl citric acid, 43 parts of deionized water,
21 parts of sucrose fatty ester, 4 parts of sargassum tunning, 5 parts of shaddock bark extract, 23 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract
It is stirred until homogeneous, the feed liquid that will be stirred is de-gassed, using vacuum outgas, vacuum cavitations are divided mixed liquor in 5Mpa
Dress, you can obtain edible liquid detergent.
Comparative example 1
A kind of edible liquid detergent, by following parts by weight into being grouped into：39 parts of deionized water, sucrose fatty ester 19
Part, 3 parts of sargassum tunning, 5 parts of shaddock bark extract, 21 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, after adding deionized water to stir by weight, temperature is down to 40 DEG C, by the pH of solution
Value is adjusted to 6.9, adds sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract to be stirred until homogeneous, the material that will be stirred
Liquid is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtain edible liquid detergent.
Comparative example 2
A kind of edible liquid detergent, by following parts by weight into being grouped into：54 parts of stearoyl citric acid, 39 parts of deionized water,
3 parts of sargassum tunning, 5 parts of shaddock bark extract, 21 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, after adding stearoyl citric acid to stir by weight, temperature is down to 40 DEG C, by solution
PH values be adjusted to 6.9, add sargassum tunning, shaddock bark extract, vinegar unstrained spirits aqueous extract to be stirred until homogeneous, will stir
Good feed liquid is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtain edible
Liquid detergent.
Comparative example 3
A kind of edible liquid detergent, by following parts by weight into being grouped into：54 parts of stearoyl citric acid, 39 parts of deionized water,
19 parts of sucrose fatty ester, 3 parts of sargassum tunning, 5 parts of shaddock bark extract.
Further, the preparation method of the sargassum tunning is：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, it is fine
Dimension element enzyme Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature, pH 4.5, the h of reaction time 1.3；Cellulase water
After solution terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected supernatant and obtain sargassum cellulose hydrolyzation liquid；
Sargassum enzymolysis liquid goes out after enzyme activity, regulation pH value to 6.2-6.6, high pressure steam sterilization（121 DEG C, 20 min）, then inoculum
To sargassum enzymolysis liquid, 37 DEG C of constant incubators standings are carried out the Pediococcus pentosaceus liquid of the MRS culture mediums activation of fraction 1%
Fermentation.After fermentation ends, supernatant freeze-drying is collected in high pressure steam sterilization, 9000 r/min centrifugations, obtains sargassum hair
Ferment product, saves backup under the conditions of -20 DEG C.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, sucrose fatty ester is sequentially added by weight, after stearoyl citric acid stirs, temperature
Degree is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning, shaddock bark extract to be stirred until homogeneous, will
The feed liquid being stirred is de-gassed, and using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtaining can
Edible liquid detergent.
Comparative example 4
A kind of edible liquid detergent, by following parts by weight into being grouped into：54 parts of stearoyl citric acid, 39 parts of deionized water,
19 parts of sucrose fatty ester, 5 parts of shaddock bark extract, 21 parts of vinegar unstrained spirits aqueous extract.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
A kind of preparation method of edible liquid detergent, it is characterised in that including step in detail below：Deionized water is added
In reactor, 70 DEG C are heated to, after adding stearoyl citric acid to stir by weight, temperature is down to 40 DEG C, by solution
PH values be adjusted to 6.9, add shaddock bark extract, vinegar unstrained spirits aqueous extract to be stirred until homogeneous, the feed liquid that will be stirred is taken off
Gas, using vacuum outgas, vacuum cavitations are dispensed in 5Mpa to mixed liquor, you can obtain edible liquid detergent.
Comparative example 5
Receive the full effect enriching liquid detergent of good Mrs's brand of Li Xinxihua Co., Ltds production from Hebei, bucket limit makes the date be
20180523, as a comparison case 5.
Comparative example 6
From the lemon aloe liquid detergent of labourer's personal style and attitude board of Guangzhou Nanshun Cleaning Products Co., Ltd.'s production, bucket limit makes the date be
20180803A, as a comparison case 6.
Experimental test
1. bactericidal effect test
Using Suspension quantitative bactericidal test, the Escherichia coli after activation, salmonella, Candida albicans are taken first and is seeded to triangle
In shaking flask, 37 DEG C, the 160 r/h of min shaken cultivations 36.Then respectively inoculation 1ml above-mentioned bacteria suspensions respectively with 9
The 2% dilution mixing of the liquid detergent of ml embodiments 1-5 and comparative example 1-6,37 DEG C, 160 r/min vibration 30min,
With dilution the method for falling ware measure detergent to Escherichia coli, salmonella, Candida albicans killing logarithm value, it is parallel in triplicate
Experiment, calculates bactericidal effect such as following table.
2. detergency experiment
Press《Manual dishwashing detergent》The method of the standards of GB 9985-2000 purchase artificial dirt, 250 ppm hard water,
Instrument needed for dirt ceramics plate and foam level method test detergency.Using foam end point method, respectively Example 1-5 with
And comparative example 1-6 liquid detergent 5mL, by 1000mL concentration for the hard water of 250ppm is poured into enamel basin, separately by 1000mL concentration
For the hard water of 250ppm is put into tubualted bottle.In room temperature（25 ℃）Under, the delivery port of tubualted bottle is opened, hard water is rushed in flowing into basin
Spume.After hard water stops flowing out（The s of process about 45）, plate is scrubbed with 102 mm pigs palm fibre paintbrush, first brush clockwise
5 times, another mistake hour hands brush 5 times, after so repeating 1 time, the dirt major part being applied on plate is washed down, finally again will not
Wash lower part to scrub off, until foam is wholly absent, record the number that washes dishes, and be finally converted into deep bid subnumber, it is as a result as follows
Shown in table.
3. security toxicological test.
The main formula of Example 1 carries out toxicological test, foundation respectively《Foodsafety Toxicological Assessment program and side
Method》GB 15193-2003, using maximum tolerance metering experiment method, dosage is set to 10000 mg/kg BW, from 20
Kunming mice, male and female half and half.The h of animal fasting 16, drinking-water is not limited before experiment.The mg/mL of animal 500 is given using administration by gavage
The sample solution of concentration, gavage amount is 0.4 mL/20 g body weight.The poisoning manifestations and death condition of animal are observed after gavage,
Weigh weekly 1 time, observe 14 d, it is as a result as shown in the table.
| Sample ID | Stearoyl citric acid | Sargassum tunning | Vinegar unstrained spirits aqueous extract |
| LD50（mg/kg·BW） | 20000 | 35000 | 50000 |
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (5)
1. a kind of edible liquid detergent, it is characterised in that by following parts by weight into being grouped into：Stearoyl citric acid 44-62
Part, deionized water 33-47 parts, sucrose fatty ester 12-23 parts, 2-5 parts of sargassum tunning, shaddock bark extract 3-7
Part, 14-27 parts of vinegar unstrained spirits aqueous extract.
2. edible liquid detergent according to claim 1, it is characterised in that by following parts by weight into being grouped into：Firmly
51-58 parts of acyl citric acid, deionized water 37-43 parts, sucrose fatty ester 17-21 parts, 3-4 parts of sargassum tunning,
4-5 parts of shaddock bark extract, 18-25 parts of vinegar unstrained spirits aqueous extract.
3. edible liquid detergent according to claim 1, it is characterised in that the preparation method of the sargassum tunning
For：It is solid-liquid ratio 1: 10 to impose a condition（m/V）, cellulase Cellulase ACCF-4740 additions 2%, 55 DEG C of temperature,
PH 4.5, the h of reaction time 1.3；After cellulose hydrolyzation terminates, boiling water bath is gone out enzyme 15 min, and 9000 r/min centrifugations are collected
Supernatant obtains sargassum cellulose hydrolyzation liquid；Sargassum enzymolysis liquid is gone out after enzyme activity, and regulation pH value to 6.2-6.6, high pressure is steamed
Vapour sterilizes（121 DEG C, 20 min）, the Pediococcus pentosaceus liquid that then the MRS culture mediums of inoculation volume fraction 1% are activated to sargassum
Enzymolysis liquid, 37 DEG C of constant incubators stand, and are fermented；After fermentation ends, high pressure steam sterilization, 9000 r/min centrifugations,
Supernatant freeze-drying is collected, sargassum tunning is obtained, saved backup under the conditions of -20 DEG C.
4. edible liquid detergent according to claim 1, it is characterised in that the preparation method of the vinegar unstrained spirits aqueous extract
For：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 solid-liquid ratio（g:mL）Distilled water is added, at room temperature mistake after the h of mechanical shaking extraction 3
Filtrate is filtered to obtain, by filtrate again by 0.22 μm of sterilised membrane filter filtration sterilization, vinegar unstrained spirits aqueous extract is obtained.
5. the preparation method of a kind of edible liquid detergent as described in any one of claim 1- 4, it is characterised in that including with
Lower specific steps：By in deionized water addition reactor, 70 DEG C are heated to, sucrose fatty ester are sequentially added by weight,
After stearoyl citric acid stirs, temperature is down to 40 DEG C, and the pH values of solution are adjusted into 6.9, adds sargassum tunning,
Shaddock bark extract, vinegar unstrained spirits aqueous extract is stirred until homogeneous, and the feed liquid that will be stirred is de-gassed, using vacuum outgas, negative pressure
Control is dispensed, you can obtain edible liquid detergent in 5Mpa to mixed liquor.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955728A (en) * | 2017-12-13 | 2018-04-24 | 安徽大学 | Edible detergent containing natural plant saponin component and preparation method thereof |
| CN109135946A (en) * | 2018-10-10 | 2019-01-04 | 江南大学 | A kind of edible detergent and preparation method thereof |
| CN109735395A (en) * | 2019-02-27 | 2019-05-10 | 福建果宝生物科技有限公司 | A kind of cleaning solution of edible plant extract |
-
2016
- 2016-11-03 CN CN201610948485.6A patent/CN106753859A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107955728A (en) * | 2017-12-13 | 2018-04-24 | 安徽大学 | Edible detergent containing natural plant saponin component and preparation method thereof |
| CN109135946A (en) * | 2018-10-10 | 2019-01-04 | 江南大学 | A kind of edible detergent and preparation method thereof |
| CN109735395A (en) * | 2019-02-27 | 2019-05-10 | 福建果宝生物科技有限公司 | A kind of cleaning solution of edible plant extract |
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