CN109135946B - Edible detergent and preparation method thereof - Google Patents

Edible detergent and preparation method thereof Download PDF

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CN109135946B
CN109135946B CN201811177541.6A CN201811177541A CN109135946B CN 109135946 B CN109135946 B CN 109135946B CN 201811177541 A CN201811177541 A CN 201811177541A CN 109135946 B CN109135946 B CN 109135946B
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parts
extract
content
essential oil
bactericide
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CN109135946A (en
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张丹
武玉和
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Jiangnan University
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Jiangnan University
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an edible cleaning agent and a preparation method thereof, and the edible cleaning agent comprises a solvent, a surfactant, a humectant, a decontamination auxiliary agent and a bactericide, wherein the solvent consists of water, ethanol and glycerol, the surfactant consists of rhamnolipid, tea saponin and sucrose fatty acid ester SE-16, the humectant consists of tea seed oil, chitosan oligosaccharide and an ophiopogon root extract, the decontamination auxiliary agent consists of vetiver essential oil, konjac refined powder and a ginkgo leaf extract, and the bactericide consists of lavender essential oil, a scutellaria baicalensis extract and a cactus extract; the cleaning agent comprises, by mass, 860-865 parts of a solvent, 68-72 parts of a surfactant, 22-26 parts of a humectant, 26-30 parts of a decontamination auxiliary agent and 14-18 parts of a bactericide. The invention has obvious sterilization effect, excellent capability of removing pesticide residue and decontamination, environmental protection, safety and sustainability.

Description

Edible detergent and preparation method thereof
Technical Field
The invention belongs to the technical field of detergents, and particularly relates to an edible detergent and a preparation method thereof.
Background
With the development of industries such as petrochemical industry and the like, people begin to be flooded with various petroleum products in daily life, in particular, surfactants and the like applied in the field of cleaning and decontamination, represented by liquid detergents and the like for cleaning kitchen ware, are easy to pollute water quality, have residues and the like in the using process, then enter an ecological circulation system or are directly eaten by people by mistake, not only influence the health of human beings, but also threaten the balance of ecological environment.
Therefore, the harmless and degradable cleanser product for developing the novel biological matrix has the advantages of environmental protection and health and bright prospect, and how to prepare the multifunctional and edible cleanser can be applied to various occasions such as cleaning kitchen ware, vegetables and fruits, meat, flowers, bonsai and even facial skin, and the like, and even if the cleanser is eaten by mistake, the cleanser cannot influence the health of human bodies, and the cleanser which is green, environment-friendly, safe and sustainable is the technical problem to be solved in the field.
Disclosure of Invention
This section is for the purpose of summarizing some aspects of embodiments of the invention and to briefly introduce some preferred embodiments. In this section, as well as in the abstract and the title of the invention of this application, simplifications or omissions may be made to avoid obscuring the purpose of the section, the abstract and the title, and such simplifications or omissions are not intended to limit the scope of the invention.
In one aspect of the present invention, the present invention overcomes the deficiencies of the prior art by providing an edible cleanser.
In order to solve the technical problems, the invention provides the following technical scheme: an edible cleanser comprises a solvent, a surfactant, a humectant, a decontamination auxiliary agent and a bactericide, wherein the solvent consists of water, ethanol and glycerol, the surfactant consists of rhamnolipid, tea saponin and sucrose fatty acid ester SE-16, the humectant consists of tea seed oil, chitosan oligosaccharide and an extract of radix ophiopogonis, the decontamination auxiliary agent consists of vetiver essential oil, konjac refined powder and an extract of ginkgo leaves, and the bactericide consists of lavender essential oil, an extract of scutellaria baicalensis and an extract of cactus;
the cleaning agent comprises, by mass, 860-865 parts of a solvent, 68-72 parts of a surfactant, 22-26 parts of a humectant, 26-30 parts of a decontamination auxiliary agent and 14-18 parts of a bactericide.
As a preferred embodiment of the edible cleaning agent of the present invention: the water content is 752 parts, the ethanol content is 85 parts, and the glycerol content is 25 parts by mass.
As a preferred embodiment of the edible cleaning agent of the present invention: the rhamnolipid content is 24.5-25 parts, the tea saponin content is 17.5-18 parts, and the sucrose fatty acid ester SE-16 content is 27-28 parts by mass.
As a preferred embodiment of the edible cleaning agent of the present invention: the tea seed oil comprises, by mass, 6-6.5 parts of tea seed oil, 8-8.5 parts of chitosan oligosaccharide and 9.5-10 parts of radix ophiopogonis extract.
As a preferred embodiment of the edible cleaning agent of the present invention: the weight parts of the vetiver essential oil are 2.5-3 parts, the konjac powder is 16-16.5 parts, and the ginkgo leaf extract is 8.5-9.5 parts.
As a preferred embodiment of the edible cleaning agent of the present invention: the lavender essential oil content is 2-2.5 parts, the scutellaria baicalensis extract content is 5.5-6 parts, and the cactus extract content is 8-8.5 parts by mass.
As another aspect of the invention, the invention overcomes the defects in the prior art and provides a preparation method of the edible cleanser.
In order to solve the technical problems, the invention provides the following technical scheme: the preparation method of the edible cleanser comprises the following steps,
sequentially adding the humectant, the decontamination auxiliary agent and the bactericide, adding the solvent, uniformly stirring, adding the surfactant, and homogenizing.
As a preferred embodiment of the preparation method of the edible cleaning agent, the following steps are carried out: the homogenizing comprises homogenizing at 2800-3600 rpm for 5-8 min.
The invention has the beneficial effects that: the multifunctional edible cleaning agent provided by the invention adopts the pure bio-based edible surfactant and other edible auxiliary decontamination components, so that the problem of residue is not worried about, and the health of a human body is not influenced even if the multifunctional edible cleaning agent is eaten by mistake. The components in the flower pot are edible but low in nutrition, and are not rich in elements such as phosphorus, sulfur and the like, so that the sewage after cleaning does not pollute the environment, and the sewage after cleaning flowers and bonsais can flow into the pot without burning out plants due to overhigh nutrition content.
The multifunctional edible detergent contains edible natural humectant and bactericide, and has certain fresh-keeping and brightening effects. If the vegetables and fruits are washed, the vegetables and fruits can not lose water or deteriorate prematurely and can be stored for a long time; after the plants are cleaned, the leaves and the flowers are cleaner and brighter and are kept for a longer time; after the hand and face skins are cleaned, the moisture content of the skins can be properly improved, germs such as mites and the like can be effectively killed, the surfaces of the skins are moistened and pollution-resistant, and the skin problems such as acne, darkness, rhagadia and the like are reduced.
The film formed by the residues after washing reaches the nanometer level, so that the air permeability, the touch feeling, the mouthfeel and the like are not influenced, namely the washed food can be eaten at ease, and the mouthfeel is not different; the cleaned flower has dry and comfortable surface touch and is not greasy, and the normal photosynthesis, transpiration and the like of the plant cannot be influenced.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with examples are described in detail below.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, but the present invention may be practiced in other ways than those specifically described and will be readily apparent to those of ordinary skill in the art without departing from the spirit of the present invention, and therefore the present invention is not limited to the specific embodiments disclosed below.
Furthermore, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
Example 1:
adding 6 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 10 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16 parts of konjac fine powder, 9 parts of ginkgo leaf extract, 2 parts of lavender essential oil, 6 parts of scutellaria baicalensis extract and 8 parts of cactus extract into a container in sequence, adding 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol, stirring uniformly, adding 25 parts of rhamnolipid, 18 parts of tea saponin and 27 parts of sucrose fatty acid ester SE-16, homogenizing at the rotating speed of 3200rpm for 6.5min, and sealing and packaging.
Example 2:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after stirring uniformly, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after stirring uniformly, and the mixture is sealed and packaged after being homogenized for 6.5min at the rotating speed of 3200 rpm.
Example 3:
adding 6 parts of tea seed oil, 8.5 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 2.5 parts of vetiver essential oil, 16 parts of konjac powder, 9.5 parts of ginkgo leaf extract, 2 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8.5 parts of cactus extract into a container in sequence, adding 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol, stirring uniformly, adding 25 parts of rhamnolipid, 17.5 parts of tea saponin and 27.5 parts of sucrose fatty acid ester SE-16, homogenizing at the rotating speed of 3200rpm for 6.5min, and sealing and packaging.
Comparative example 1:
6.5 parts of tea seed oil, 8 parts of soybean extract, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after being homogenized at the rotating speed of 3200rpm for 6.5min, and then the mixture is sealed and packaged (the chitosan oligosaccharide is replaced by the soybean extract, and the rest is the same as the embodiment 2).
Comparative example 2:
13 parts of tea seed oil, 6 parts of chitosan oligosaccharide, 5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after being homogenized at the rotating speed of 3200rpm for 6.5min, and the mixture is sealed and packaged (the proportion of the humectant is different, and the rest is the same as that in example 2).
Comparative example 3:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 11 parts of vetiver essential oil, 6.5 parts of konjac powder, 10.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after being homogenized at the rotating speed of 3200rpm for 6.5min, and then the mixture is sealed and packaged (the proportion of the decontamination auxiliary agent is different, and the rest is the same as the embodiment 2).
Comparative example 4:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of corn starch, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added into the container, and after the mixture is homogenized at the rotating speed of 3200rpm for 6.5min, the mixture is sealed and packaged (the konjac powder is changed into the corn starch, and the rest is the same as the embodiment 2).
Comparative example 5:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of honeysuckle extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added, and after homogenizing at the rotating speed of 3200rpm for 6.5min, the mixture is sealed and packaged (the cactus extract is changed into the honeysuckle extract, and the rest is the same as the embodiment 2).
Comparative example 6:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 7.5 parts of lavender essential oil, 3.5 parts of scutellaria baicalensis extract and 5 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after stirring uniformly, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after stirring uniformly at the rotating speed of 3200rpm for 6.5min, and then sealing and packaging are carried out (the proportion of bactericides is different, and the other parts are the same as in example 2).
Comparative example 7:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after being homogenized at the rotating speed of 3200rpm for 6.5min, and then the mixture is sealed and packaged (the glycerol is changed into butanediol, and the rest is the same as in example 2).
Comparative example 8:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 582 parts of deionized water, 230 parts of ethanol and 50 parts of glycerol are added after stirring uniformly, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-16 are added after stirring uniformly, and after homogenizing at 3200rpm for 6.5min, sealing and packaging are carried out (the solvent ratio is different, and the rest are the same as in example 2).
Comparative example 9:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 24.5 parts of rhamnolipid, 17.5 parts of tea saponin and 28 parts of sucrose fatty acid ester SE-8 are added after being homogenized for 6.5min at the rotating speed of 3200rpm, and then the mixture is sealed and packaged (the sucrose fatty acid ester SE-16 is changed into the sucrose fatty acid ester SE-8, and the rest is the same as the embodiment 2).
Comparative example 10:
6.5 parts of tea seed oil, 8 parts of chitosan oligosaccharide, 9.5 parts of radix ophiopogonis extract, 3 parts of vetiver essential oil, 16.5 parts of konjac powder, 8.5 parts of ginkgo leaf extract, 2.5 parts of lavender essential oil, 5.5 parts of scutellaria baicalensis extract and 8 parts of cactus extract are sequentially added into a container, 752 parts of deionized water, 85 parts of ethanol and 25 parts of glycerol are added after being uniformly stirred, 19.5 parts of rhamnolipid, 32.5 parts of tea saponin and 18 parts of sucrose fatty acid ester SE-16 are added after being homogenized at the rotating speed of 3200rpm for 6.5min, and then the mixture is sealed and packaged (the proportion of the surfactant is different, and the rest is the same as the embodiment 2).
Comparative example 11:
some commercially available lemon cleanser essence.
Detergent performance testing:
1. and (3) testing the sterilizing effect:
a suspension quantitative sterilization test is adopted, firstly activated staphylococcus aureus, escherichia coli, salmonella and candida albicans are inoculated into a triangular shake flask, and shake culture is carried out for 36 hours at 37 ℃ and 160 r/min. Then respectively inoculating 1mL of the bacterial suspension and 2mL of 2.5% diluent of the cleaning agent of the embodiments 1-3 and the comparison examples 1-10, mixing, oscillating for 30min at 37 ℃ and 160r/min, measuring the killing logarithm value of the cleaning agent on staphylococcus aureus, escherichia coli, salmonella and candida albicans by using a dilution pour-pan method, repeating three times of parallel tests, and calculating the sterilization effect (killing rate) as shown in the following table.
Figure BDA0001824141740000071
As can be seen from the above table, the bactericidal effect of each example and each comparative example of the present invention is better than that of the commercially available detergent. In addition, the proportion of the bactericide has great influence on the sterilization effect of the detergent, the type of the bactericide has great influence on the sterilization broad spectrum of the detergent, and other components also have synergistic effect, namely the bactericide has certain influence on the sterilization effect.
2. And (4) safety toxicology testing:
the main formula of example 1 was used for toxicological tests, and according to the food safety toxicological evaluation procedure and method GB 15193-2003, the maximum tolerance was measured at 15000mg/kg BW, and 20 Kunming mice, male and female halves, were selected. Animals were fasted for 16h before the test, without any restriction on water. The sample solution with the concentration of 800mg/mL is given to the animals by a gastric lavage method, and the gastric lavage amount is 0.2mL/10g of body weight. Animals were observed for signs of intoxication and mortality after gavage by weighing 1 time per week for 14 days and the results are shown in the following table.
Figure BDA0001824141740000081
LD with reference to ethanol50Is 7060mg/kg BW, LD of sucrose fatty acid ester5039000mg/kg, LD of each example and comparative example of the present invention, as can be seen from the above table50All above 45000mg/kg, so the examples and comparative examples of the present invention have almost no toxicity, but LD of common commercial detergent503850mg/kg, which is mild toxicity.
3. Pesticide residue removal test:
soaking fresh pakchoi in mixed pesticide aqueous solution (each pesticide concentration is 250ppm) of methyl parathion, cypermethrin and propoxur, taking out after 20min, and hanging in a shady place at room temperature for air drying; dividing the prepared vegetable samples into 3 groups, washing 1 group respectively by unwashed water, water and 0.25% detergent (examples 1-3 and comparative examples 1-11), namely 16 groups in total, and each group comprises 2 parts, and each part is 75 g; the above pre-treatments were repeated 3 times in parallel. The subsequent test method is carried out according to the standard NY/T761-2008 of determination of organophosphorus, organochlorine, pyrethroid and carbamate pesticide residues in vegetables and fruits. The test results are shown in the following table.
Figure BDA0001824141740000091
As can be seen from the above table, the removal rate of the embodiments of the present invention for various pesticides can reach more than 99%, the removal rate of the comparative examples of the present invention for various pesticides can also reach more than 95%, and the removal rate of the commercially available detergent of comparative example 11 for various pesticides is less than 60%, so that the present invention has excellent performance of removing pesticide residues.
4. And (3) testing detergency:
adding beef tallow: lard oil: vegetable oil is mixed at a ratio of 0.5: 0.5: 1, and vaseline accounting for 8 percent of the total mass of the artificial dirt is added, namely the artificial dirt. Heating the artificial dirt to 120 ℃, stirring and keeping the temperature for 10min, and naturally cooling to the required temperature for later use. Cooling to 85 deg.C at room temperature of 20 deg.C.
75 clean dishes of uniform size are prepared and divided into 15 groups, and the initial weight of each dish is recorded as m0.2mL of artificial dirt is taken and poured into the dish and is evenly coated on the bottom in the dish. Drying at room temperature for 4h, recording the weight as m1. Washing treatment: in a decontamination machine, 15 sets of washing water (tap water, tap water solution containing 0.1% detergent (examples 1 to 3, comparative examples 1 to 11)) were prepared, one set of washing water corresponded to one set of 5 dirty dishes, the dirty dishes were immersed in washing water at 30 ℃ for 1min and washed for 2.5min, the dishes were taken out, air-dried for 4h, and the recorded weight was m2. The average stain removal per group was calculated:
stain removal ratio (%) - (m)1-m2)/(m1-m0)*100％。
The average detergency ratio finally obtained is shown in the following table.
Figure BDA0001824141740000101
As is clear from the above table, the detergency ratios in the examples of the present invention are all 99% or more, the detergency ratios in the comparative examples of the present invention are all 92% or more, and the detergency ratio of the commercially available detergent is only about 70%, and it is seen that the present invention is excellent in detergency against kitchen stains and the like.
The multifunctional edible detergent can be used in different ways according to different application occasions. When cleaning kitchenware, vegetables, melons and fruits and fresh foods, 2.5 per mill of diluent is sprayed, then physical washing functions such as brushing, rubbing and the like are properly applied, and then dirt is washed away by water; when small-volume fruits such as flowers, potted landscape leaves or grapes are washed, 2.5 thousandth of diluent is uniformly sprayed, so that the surface of the small-volume fruits is fully wetted by the detergent, the small-volume fruits can be removed by spraying or washing the small-volume fruits with clear water after 10 seconds, the small-volume fruits do not need to be wiped or rubbed one by means of external force, and the washing machine is time-saving, labor-saving, flexible and changeable.
The multifunctional edible cleaning agent provided by the invention has an obvious synergistic interaction effect among solvents (deionized water, ethanol and glycerol), surfactants (rhamnolipid, tea saponin and sucrose fatty acid ester SE-16), decontamination aids (vetiver essential oil, konjac powder and ginkgo leaf extract), bactericides (lavender essential oil, scutellaria baicalensis extract and cactus extract) and humectants (tea seed oil, chitosan oligosaccharide and ophiopogon root extract).
Specifically, the solvents are safe and non-irritant aqueous solvents, provide a good uniform and stable environment for other components, and the glycerol has a moisturizing effect. The rhamnolipid molecules are spread on the surfaces of crops, vegetables, fruits and flowers to play roles in stimulating growth and assisting in absorbing nutrition; the tea saponin macromolecules can be automatically degraded, the integral permeability of the cleaning agent is improved, and particularly the peeling effect on pesticide molecules is improved, so that the exertion of the detergency and the pesticide residue removing capability of the cleaning agent is promoted.
The compound combination of the vetiver essential oil, the lavender essential oil, the konjac powder, the ginkgo leaf extract, the scutellaria baicalensis extract and the cactus extract further improves the range and the effect of decontamination and sterilization. The fine particles of the konjac fine powder can be slowly precipitated in the using process, so that the physical and mechanical effects are intensified, and the decontamination effect is enhanced; the ginkgo flavone-glycoside component in the ginkgo leaf extract has strong oxidation resistance and free radical scavenging capacity, so that the function of cleaning the skin is further expanded; the broad-spectrum sterilization capability and the heat-clearing and detoxifying effects of the scutellaria baicalensis extract are more fully exerted under the coordination of the tartronic acid, the triterpenoid saponin and various flavonoid micromolecule substances in the cactus extract, and the bacteriostatic and anti-inflammatory effects of the cactus extract complement each other, so that the cleanser can still achieve excellent bacteriostatic and disinfectant, safe and stable long-acting functions without adding any chemical preservative. In the humectant, the tea seed oil is rich in unsaturated fatty acid and linolenic acid, so that excellent moisturizing and moistening functions are provided; the chitosan oligosaccharide has incomparable superiority with chitosan, can be completely dissolved in water as free molecules, has good biological activity, is easier to be absorbed by plants and human bodies, and plays a role in absorbing water, enhancing immunity and resisting infection; the ophiopogonin, ophiopogonone, methyl ophiopogonone and other components in the ophiopogon root have obvious moistening effect, and the natural property of the ophiopogonone, the ophiopogonone and the methyl ophiopogonone also ensures the adaptability and affinity of organisms to the ophiopogonone.
The decontamination auxiliary agent, the bactericide and the humectant are mainly formed in the forms of 'essential oil + soluble powder particles + natural extracts', and experiments prove that the decontamination auxiliary agent, the bactericide and the humectant have remarkable synergistic performance, so that the stable performance and the cooperation of respective functions are ensured, different use environments can be more hierarchically responded, and the effects of decontamination, sterilization and pesticide removal are enhanced.
The multifunctional edible cleaning agent has edible components but low nutrition, and does not contain elements such as phosphorus, sulfur and the like, so that the sewage after cleaning does not pollute the environment, and the sewage after cleaning flowers and bonsais can also flow into a pot without burning the plants due to overhigh nutrition content.
The multifunctional edible detergent contains edible natural humectant and bactericide, and has certain fresh-keeping and brightening effects. If the vegetables and fruits are washed, the vegetables and fruits can not lose water or deteriorate prematurely and can be stored for a long time; after the plants are cleaned, the leaves and the flowers are cleaner and brighter and are kept for a longer time; after the hand and face skins are cleaned, the moisture content of the skins can be properly improved, germs such as mites and the like can be effectively killed, the surfaces of the skins are moistened and pollution-resistant, and the skin problems such as acne, darkness, rhagadia and the like are reduced.
The film formed by the residues after washing reaches the nanometer level, so that the air permeability, the touch feeling, the mouthfeel and the like are not influenced, namely the washed food can be eaten at ease, and the mouthfeel is not different; the cleaned flower has dry and comfortable surface touch and is not greasy, and the normal photosynthesis, transpiration and the like of the plant cannot be influenced.
It should be noted that the above-mentioned embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.

Claims (3)

1. An edible cleanser, comprising: the cleaning agent comprises a solvent, a surfactant, a humectant, a decontamination auxiliary agent and a bactericide, wherein the solvent consists of deionized water, ethanol and glycerol, the surfactant consists of rhamnolipid, tea saponin and sucrose fatty acid ester SE-16, the humectant consists of tea seed oil, chitosan oligosaccharide and an extract of radix ophiopogonis, the decontamination auxiliary agent consists of vetiver essential oil, konjac powder and an extract of ginkgo biloba, and the bactericide consists of lavender essential oil, an extract of scutellaria baicalensis and an extract of cactus;
wherein the content of the solvent is 860-865 parts, the content of the surfactant is 68-72 parts, the content of the humectant is 22-26 parts, the content of the decontamination auxiliary agent is 26-30 parts, and the content of the bactericide is 14-18 parts by mass;
24.5-25 parts of rhamnolipid, 17.5-18 parts of tea saponin and 27-28 parts of sucrose fatty acid ester SE-16; the tea seed oil content is 6-6.5 parts, the chitosan oligosaccharide content is 8-8.5 parts, and the radix ophiopogonis extract content is 9.5-10 parts; 2.5-3 parts of vetiver essential oil, 16-16.5 parts of konjac fine powder and 8.5-9.5 parts of ginkgo leaf extract; 2-2.5 parts of lavender essential oil, 5.5-6 parts of scutellaria baicalensis extract and 8-8.5 parts of cactus extract; the water content is 752 parts, the ethanol content is 85 parts, and the glycerol content is 25 parts.
2. A process for preparing an edible cleanser according to claim 1, wherein: comprises sequentially adding humectant, decontamination auxiliary agent, bactericide, solvent, surfactant after stirring, and homogenizing.
3. A process for preparing an edible cleanser according to claim 2, wherein: the homogenizing comprises homogenizing at 2800-3600 rpm for 5-8 min.
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CN111676098A (en) * 2019-12-02 2020-09-18 河南海利未来科技有限公司 Natural plant-derived antibacterial fruit and vegetable cleaning agent and preparation method thereof
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