CN113667547A - Edible cleaning emulsion and preparation method and application thereof - Google Patents
Edible cleaning emulsion and preparation method and application thereof Download PDFInfo
- Publication number
- CN113667547A CN113667547A CN202110998441.5A CN202110998441A CN113667547A CN 113667547 A CN113667547 A CN 113667547A CN 202110998441 A CN202110998441 A CN 202110998441A CN 113667547 A CN113667547 A CN 113667547A
- Authority
- CN
- China
- Prior art keywords
- parts
- edible
- cleaning
- cleaning emulsion
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 71
- 239000000839 emulsion Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000004945 emulsification Methods 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 52
- 102000004190 Enzymes Human genes 0.000 claims abstract description 27
- 108090000790 Enzymes Proteins 0.000 claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 22
- 239000003899 bactericide agent Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 229940088598 enzyme Drugs 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- 238000010008 shearing Methods 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- 239000004382 Amylase Substances 0.000 claims description 11
- 102000013142 Amylases Human genes 0.000 claims description 11
- 108010065511 Amylases Proteins 0.000 claims description 11
- 108091005804 Peptidases Proteins 0.000 claims description 11
- 239000004365 Protease Substances 0.000 claims description 11
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 11
- 235000019418 amylase Nutrition 0.000 claims description 11
- 108010059892 Cellulase Proteins 0.000 claims description 10
- 229940106157 cellulase Drugs 0.000 claims description 10
- 108090001060 Lipase Proteins 0.000 claims description 9
- 239000004367 Lipase Substances 0.000 claims description 9
- 102000004882 Lipase Human genes 0.000 claims description 9
- 229940040461 lipase Drugs 0.000 claims description 9
- 235000019421 lipase Nutrition 0.000 claims description 9
- 108010014251 Muramidase Proteins 0.000 claims description 8
- 102000016943 Muramidase Human genes 0.000 claims description 8
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims description 8
- 239000004325 lysozyme Substances 0.000 claims description 8
- 229960000274 lysozyme Drugs 0.000 claims description 8
- 235000010335 lysozyme Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 7
- 230000001804 emulsifying effect Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- HVCOBJNICQPDBP-UHFFFAOYSA-N 3-[3-[3,5-dihydroxy-6-methyl-4-(3,4,5-trihydroxy-6-methyloxan-2-yl)oxyoxan-2-yl]oxydecanoyloxy]decanoic acid;hydrate Chemical compound O.OC1C(OC(CC(=O)OC(CCCCCCC)CC(O)=O)CCCCCCC)OC(C)C(O)C1OC1C(O)C(O)C(O)C(C)O1 HVCOBJNICQPDBP-UHFFFAOYSA-N 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- 229930186217 Glycolipid Natural products 0.000 claims description 5
- 108010059820 Polygalacturonase Proteins 0.000 claims description 5
- 102000019197 Superoxide Dismutase Human genes 0.000 claims description 5
- 108010012715 Superoxide dismutase Proteins 0.000 claims description 5
- 108010093305 exopolygalacturonase Proteins 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 4
- FCBUKWWQSZQDDI-UHFFFAOYSA-N rhamnolipid Chemical compound CCCCCCCC(CC(O)=O)OC(=O)CC(CCCCCCC)OC1OC(C)C(O)C(O)C1OC1C(O)C(O)C(O)C(C)O1 FCBUKWWQSZQDDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000176 sodium gluconate Substances 0.000 claims description 4
- 229940005574 sodium gluconate Drugs 0.000 claims description 4
- 235000012207 sodium gluconate Nutrition 0.000 claims description 4
- ZTOKUMPYMPKCFX-CZNUEWPDSA-N (E)-17-[(2R,3R,4S,5S,6R)-6-(acetyloxymethyl)-3-[(2S,3R,4S,5S,6R)-6-(acetyloxymethyl)-3,4,5-trihydroxyoxan-2-yl]oxy-4,5-dihydroxyoxan-2-yl]oxyoctadec-9-enoic acid Chemical compound OC(=O)CCCCCCC/C=C/CCCCCCC(C)O[C@@H]1O[C@H](COC(C)=O)[C@@H](O)[C@H](O)[C@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](COC(C)=O)O1 ZTOKUMPYMPKCFX-CZNUEWPDSA-N 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 2
- 235000019501 Lemon oil Nutrition 0.000 claims description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- 239000010642 eucalyptus oil Substances 0.000 claims description 2
- 229940044949 eucalyptus oil Drugs 0.000 claims description 2
- 229960001031 glucose Drugs 0.000 claims description 2
- 235000001727 glucose Nutrition 0.000 claims description 2
- 239000008101 lactose Substances 0.000 claims description 2
- 229960001375 lactose Drugs 0.000 claims description 2
- 239000010501 lemon oil Substances 0.000 claims description 2
- 229960002160 maltose Drugs 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 2
- 150000003904 phospholipids Chemical class 0.000 claims description 2
- 239000010677 tea tree oil Substances 0.000 claims description 2
- 229940111630 tea tree oil Drugs 0.000 claims description 2
- 239000000811 xylitol Substances 0.000 claims description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 2
- 229960002675 xylitol Drugs 0.000 claims description 2
- 235000010447 xylitol Nutrition 0.000 claims description 2
- 238000005202 decontamination Methods 0.000 abstract description 8
- 230000003588 decontaminative effect Effects 0.000 abstract description 8
- 239000003876 biosurfactant Substances 0.000 description 7
- 239000012459 cleaning agent Substances 0.000 description 7
- 239000003599 detergent Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 229920002774 Maltodextrin Polymers 0.000 description 4
- 239000005913 Maltodextrin Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- 229940035034 maltodextrin Drugs 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 3
- 240000003553 Leptospermum scoparium Species 0.000 description 3
- 235000015459 Lycium barbarum Nutrition 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 244000166124 Eucalyptus globulus Species 0.000 description 2
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 238000003889 chemical engineering Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 238000012449 Kunming mouse Methods 0.000 description 1
- 108010028921 Lipopeptides Proteins 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000002496 gastric effect Effects 0.000 description 1
- 238000003304 gavage Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- -1 polysaccharide lipid Chemical class 0.000 description 1
- 238000011076 safety test Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 231100000041 toxicology testing Toxicity 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
An edible cleaning emulsion and its preparation method and application are provided. The invention provides edible cleaning emulsion which comprises the following preparation raw materials in parts by weight: 10-50 parts of solvent, 2-20 parts of surfactant, 20-50 parts of filler, 0.1-5 parts of bactericide and 0.5-5 parts of enzyme composition. The edible cleaning emulsion provided by the invention is reasonably matched, so that the excellent decontamination and antibacterial performance is realized, the dosage of the surfactant is obviously reduced, the provided cleaning emulsion is safe and edible, the performance is stable, the decontamination, antibacterial and safety performances are realized, the harm caused by the mistaken eating of children and pets can be effectively avoided, and the edible cleaning emulsion can be widely applied to cleaning of clothes, kitchenware, tableware, toys and the like.
Description
Technical Field
The invention belongs to the technical field of daily chemical articles, and particularly relates to edible cleaning emulsion and a preparation method thereof.
Background
The cleaning agent is a general name of cleaning products used for washing clothes, cleaning tools, cleaning furniture and the like, and becomes an indispensable daily chemical product in daily life. In order to ensure good cleaning effect, the cleaning agent used in daily life usually contains inedible components, the content of the surfactant is high, part of chemical components contained in the cleaning agent are easy to generate irritation to human skin and the like, the biodegradation degree of the cleaning agent is low, and environmental pollution is easy to cause. The safety of the existing daily chemical cleaning agent is not ideal enough, and if people or animals eat the cleaning agent by mistake, the health of the people or animals can be affected, and even the personal safety is harmed. There are reports of health accidents caused by children eating detergents by mistake without the effective supervision of guardians.
The biosurfactant is a metabolite with certain surface activity secreted by microorganisms in a metabolic process under certain conditions, such as glycolipid, polysaccharide lipid, lipopeptide or neutral lipid derivative. Although the biosurfactant product has the advantages of good performance, safety, environmental protection and easy degradation, the industrial production of the biosurfactant product is still in the initial stage, the production cost and the application cost are higher, the global dosage of the biosurfactant is less than 2 percent of the global dosage of all the biosurfactants, and the industrial application of the biosurfactant product in the daily chemical field is limited to a certain extent.
Therefore, it would be of great interest to provide an edible cleansing emulsion having a low biosurfactant content.
Disclosure of Invention
In order to solve the problems in the prior art, the inventor screens and compounds raw materials for preparing the cleaning agent through a large number of tests to screen safe and stable raw materials, and reasonably collocates the raw materials, so that the excellent decontamination and antibacterial performance is realized, the dosage of the surfactant is obviously reduced, the provided cleaning emulsion is safe, edible and stable in performance, the consideration of decontamination, bacteriostasis and safety performance is realized, the harm caused by the mistaken eating of children and pets can be effectively avoided, and the cleaning emulsion can be widely applied to cleaning clothes, tableware, toys and the like. The present invention has been completed based on the above findings.
The objects of the invention will be further apparent and elucidated by the following detailed description.
The invention provides edible cleaning emulsion which comprises the following preparation raw materials in parts by weight: 10-50 parts of solvent, 2-20 parts of surfactant, 20-50 parts of filler, 0.1-5 parts of bactericide and 0.5-5 parts of enzyme composition.
The combination and the parts by weight of the raw materials for preparation are determined by a large number of experiments, and the edible cleaning emulsion provided by the invention has excellent decontamination, bacteriostasis and safety performance.
Preferably, the edible cleaning emulsion comprises the following preparation raw materials in parts by weight: 30-50 parts of solvent, 5-10 parts of surfactant, 25-40 parts of filler, 0.2-4 parts of bactericide and 1-3 parts of enzyme composition.
Preferably, the surfactant is a biological surfactant selected from one or more of rhamnolipid, sophorolipid, algal glycolipid, phospholipid, neutral lipid, SD100 and 10075.
Preferably, the enzyme composition comprises amylase, protease, cellulase, lipase, superoxide dismutase, pectinase and lysozyme, and the mass ratio of the amylase to the protease is 0.5-2: 1-3: 1-5: 0.5-2: 0.1-1.
More preferably, the enzyme composition consists of amylase, protease, cellulase, lipase, superoxide dismutase, pectinase and lysozyme in a mass ratio of 1:2:4:1:0.5:0.5: 0.5.
The filler is selected from one or more of glucose, sodium gluconate, xylitol, maltose, lactose and pregelatinized starch.
The solvent is selected from one or more of ethanol, propylene glycol, glycerol and water. The inventor finds that the cleaning emulsion provided by the invention can exert the performance more favorably and obviously enhance the stability under the condition that the solvent contains glycerol and the filler contains sodium gluconate through a large number of experiments.
The bactericide is one or more selected from Eucalyptus oil, tea tree oil, lemon oil and herba Menthae oil.
In addition, the present invention also provides a method of preparing an edible cleansing emulsion comprising the steps of:
1) adding a solvent and a filler into an emulsifying pot, homogenizing and shearing for 20-50 min to obtain a first mixture;
2) adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 10-30 min to obtain a second mixture;
3) and adding a bactericide into the second mixture, homogenizing and shearing for 5-20 min, and uniformly stirring to obtain the edible cleaning emulsion.
In addition, the invention also provides the application of the edible cleaning emulsion in cleaning clothes, cleaning kitchenware, cleaning tableware and cleaning toys.
Compared with the prior art, the invention has the beneficial effects that: the raw materials used in the invention are natural, safe, nontoxic and nonirritating, and by combining the active ingredients of the surfactant, the ferment composition and the bactericide, the edible cleaning emulsion provided by the invention realizes excellent decontamination and bacteriostasis performance, simultaneously obviously reduces the dosage of the surfactant, is safe and edible, has stable performance, realizes the consideration of decontamination, bacteriostasis and safety performance, can effectively avoid the harm brought by the mistaken eating of children and pets, and can be widely applied to the cleaning of clothes, tableware, toys and the like. The preparation method of the edible cleaning emulsion provided by the invention is simple, and the prepared edible cleaning emulsion has stable quality. In addition, the invention also provides the application of the edible cleaning emulsion in cleaning clothes, cleaning kitchenware, cleaning tableware and cleaning toys.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
In the present invention, all the preparation raw materials are commercially available products, or can be obtained by means of conventional techniques in the field. For example: rhamnolipid is purchased from Shanghai Yingchuang chemical Co., Ltd, sophorolipid is purchased from Shanghai Yichuang chemical Co., Ltd, SD100 is purchased from Guangzhou Tunxin chemical engineering science and technology Co., Ltd, 10075 is purchased from Guangzhou Tunxin chemical engineering science and technology Co., Ltd, cellulase is purchased from Novicin Biotechnology Co., Ltd, Eucalyptus essential oil is purchased from Jiangxi Zhongxiang Co., Ltd, and tea tree essential oil is purchased from Jiangxi Zhongxiang Co., Ltd.
Example an edible cleansing emulsion
The edible cleaning emulsion comprises the following preparation raw materials in parts by weight: 48 parts of solvent, 15 parts of surfactant, 35 parts of filler, 1 part of bactericide and 1 part of enzyme composition; the more specific components and parts by weight are as follows: SD 1007 parts, 100758 parts, propylene glycol 35 parts, ethanol 5 parts, glycerol 8 parts, glucose 20 parts, maltodextrin 15 parts, eucalyptus essential oil 1 part and enzyme composition 1 part. The enzyme composition comprises amylase, protease, cellulase, lipase, superoxide dismutase, pectinase and lysozyme, and the mass ratio of the amylase to the protease to the cellulase to the lipase is 1:2:4:1:0.5:0.5: 0.5.
A method of preparing an edible cleansing emulsion comprising the steps of: adding a solvent and a filler into an emulsifying pot, homogenizing and shearing for 30min to obtain a first mixture; adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 15min to obtain a second mixture; adding a bactericide into the second mixture, homogenizing and shearing for 10min, uniformly stirring to obtain the edible cleaning emulsion, and filling after the edible cleaning emulsion is detected to be qualified.
EXAMPLE two edible cleaning emulsions
The edible cleaning emulsion comprises the following preparation raw materials in parts by weight: 48 parts of solvent, 10 parts of surfactant, 40 parts of filler, 1 part of bactericide and 1 part of enzyme composition; the more specific components and parts by weight are as follows: 5 parts of rhamnolipid, 100755 parts of propylene glycol, 10 parts of ethanol, 8 parts of glycerol, 25 parts of sodium gluconate, 15 parts of maltodextrin, 1 part of tea tree essential oil and 1 part of an enzyme composition. The enzyme composition comprises amylase, protease, cellulase, lipase and lysozyme in a mass ratio of 1.5:2:3:1:1:0.5: 0.5.
A method of preparing an edible cleansing emulsion comprising the steps of: adding a solvent and a filler into an emulsifying pot, homogenizing and shearing for 35min to obtain a first mixture; adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 15min to obtain a second mixture; adding a bactericide into the second mixture, homogenizing and shearing for 8min, uniformly stirring to obtain the edible clean emulsion, and filling after the edible clean emulsion is detected to be qualified.
EXAMPLE III edible cleaning emulsions
The edible cleaning emulsion comprises the following preparation raw materials in parts by weight: 45 parts of solvent, 10 parts of surfactant, 43 parts of filler, 1 part of bactericide and 1 part of enzyme composition; the more specific components and parts by weight are as follows: 5 parts of trehalose glycolipid, 100755 parts of propylene glycol, 30 parts of ethanol, 5 parts of glycerol, 25 parts of glucose, 18 parts of maltodextrin, 1 part of tea tree essential oil and 1 part of enzyme composition. The enzyme composition comprises amylase, protease, cellulase, lipase and lysozyme in a mass ratio of 1:2:4:1:1:0.5: 0.5.
A method of preparing an edible cleansing emulsion comprising the steps of: adding solvent and filler into emulsifying pot, homogenizing and shearing for 40min to obtain first mixture; adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 15min to obtain a second mixture; adding a bactericide into the second mixture, homogenizing and shearing for 8min, uniformly stirring to obtain the edible clean emulsion, and filling after the edible clean emulsion is detected to be qualified.
Example four edible cleaning emulsions
The edible cleaning emulsion comprises the following preparation raw materials in parts by weight: 46 parts of solvent, 15 parts of surfactant, 37 parts of filler, 1 part of bactericide and 1 part of enzyme composition; the more specific components and parts by weight are as follows: 5 parts of trehalose glycolipid, 10 parts of SD 10010 parts of ethanol, 40 parts of glycerol, 20 parts of glucose, 17 parts of maltodextrin, 1 part of lemon essential oil and 1 part of enzyme composition. The enzyme composition comprises amylase, protease, cellulase, lipase and lysozyme in a mass ratio of 1:2:4:1:1:0.5: 1.
A method of preparing an edible cleansing emulsion comprising the steps of: adding solvent and filler into emulsifying pot, homogenizing and shearing for 40min to obtain first mixture; adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 15min to obtain a second mixture; adding a bactericide into the second mixture, homogenizing and shearing for 8min, uniformly stirring to obtain the edible clean emulsion, and filling after the edible clean emulsion is detected to be qualified.
Safety test example:
get the original hair separatelyThe edible cleaning emulsions provided in the first to fourth working examples were subjected to toxicological tests according to GB15193.1-2014 "food safety toxicological evaluation procedure", using a maximum tolerance dosing test method, at a dose of 15000mg/kg BW, using 30 kunming mice randomly divided into 4 groups, male and female halves. Animals were fasted for 16h before the test, without any restriction on water. The animals were dosed with 800mg/mL samples using a gavage regimen of 0.2mL/10g body weight. Observing the behavior of the mice after gastric lavage, weighing 1 time per week, observing 14d, and calculating LD50The results are shown in Table 1.
Table 1 LD of edible cleansing emulsions provided herein50
As can be seen from the data of the implementation cases, the data disclosed so far are represented by the ethanol mouse LD 50: 5628mg/kg is standard, and the main raw material added in the patent is LD 50: 21000-32200 mg/kg; while the average result of LD50 of the patent is more than 28000mg/kg, the amount shows that the product is safe and has no toxicity after eating.
Antibacterial performance test example:
the edible cleaning emulsions provided in the first to fourth examples of the present invention and the commercial detergent were respectively used to perform the bacteriostatic performance test according to the method of GB 9985-.
Table 2 bacteriostatic test results for edible cleaning emulsions provided by the invention
| Embodiment 1 | Example II | Example three | Example four | Commercial detergent | |
| Staphylococcus aureus | 99.3％ | 99.0％ | 99.4％ | 99.0％ | 96.8％ |
| Candida albicans | 98.6％ | 98.5％ | 98.5％ | 98.6％ | 96.2％ |
| Escherichia coli | 99.5％ | 99.2％ | 99.0％ | 99.0％ | 97.3％ |
Hard object surface oil stain removal performance test example:
the edible cleaning emulsions provided in the first to fourth examples of the present invention and commercially available detergents were respectively used to perform a greasy dirt removal performance test. Using a 10cm × 10cm glass plate as a mold hard object surface before useAll glass plates were washed with chloroform and thoroughly dried, and their initial mass (m) was recorded0) About 0.1g of oil stain (to the nearest 0.0001g) was applied and used after aging in an oven at 60 ℃ overnight. Drying at room temperature for 4h, recording the weight as m1. Washing treatment: in a decontamination machine, 15 groups of washing water (tap water, containing 0.1% detergent) were prepared, one group of washing water was soaked in a group of glass plates at 30 ℃ for 1min, and after washing for 2.5min, the dishes were taken out, air dried for 4h, and the recorded weight was m2. The average stain removal per group was calculated: the removal efficiency of the oil stain was calculated by the following formula, and the results are shown in Table 3.
Table 3 oil stain removal test results for edible cleaning emulsions provided by the invention
| Embodiment 1 | Example II | Example three | Example four | Commercial detergent | |
| Oil removal rate | 99.5％ | 99.0％ | 98.7％ | 99.0％ | 98.1％ |
The test examples show that the edible cleaning emulsion provided by the invention has excellent safety, bacteriostasis and cleaning performance, the overall performance of the edible cleaning emulsion is superior to that of a commercial detergent, and the edible cleaning emulsion can meet the use requirements of cleaning clothes, cleaning kitchenware, cleaning tableware and cleaning toys in daily life.
The foregoing is a more detailed description of the invention in connection with specific preferred embodiments and it is not intended that the invention be limited to these specific details. For those skilled in the art to which the invention pertains, several simple deductions or substitutions can be made without departing from the spirit of the invention, and all shall be considered as belonging to the protection scope of the invention.
Claims (10)
1. An edible cleansing emulsion characterized by: the preparation method comprises the following preparation raw materials in parts by weight: 10-50 parts of solvent, 2-20 parts of surfactant, 20-50 parts of filler, 0.1-5 parts of bactericide and 0.5-5 parts of enzyme composition.
2. The edible cleaning emulsion of claim 1, wherein: the preparation method comprises the following preparation raw materials in parts by weight: 30-50 parts of solvent, 5-10 parts of surfactant, 25-40 parts of filler, 0.2-4 parts of bactericide and 1-3 parts of enzyme composition.
3. An edible cleaning emulsion according to claim 1 or 2 characterized in that: the surfactant is a biological surfactant, and is selected from one or more of rhamnolipid, sophorolipid, algal glycolipid, phospholipid, neutral lipid, SD100 and 10075.
4. An edible cleaning emulsion according to claim 1 or 2 characterized in that: the enzyme composition comprises amylase, protease, cellulase, lipase, superoxide dismutase, pectinase and lysozyme, and the mass ratio of the amylase to the protease is 0.5-2: 1-3: 1-5: 0.5-2: 0.1-1.
5. The edible cleaning emulsion of claim 4, wherein: the enzyme composition comprises amylase, protease, cellulase, lipase, superoxide dismutase, pectinase and lysozyme in a mass ratio of 1:2:4:1:0.5:0.5: 0.5.
6. An edible cleaning emulsion according to claim 1 or 2 characterized in that: the filler is selected from one or more of glucose, sodium gluconate, xylitol, maltose, lactose and pregelatinized starch.
7. An edible cleaning emulsion according to claim 1 or 2 characterized in that: the solvent is selected from one or more of ethanol, propylene glycol, glycerol and water.
8. An edible cleaning emulsion according to claim 1 or 2 characterized in that: the bactericide is one or more selected from Eucalyptus oil, tea tree oil, lemon oil and herba Menthae oil.
9. A process for preparing an edible cleaning emulsion according to claim 1, characterized in that: the method comprises the following steps:
1) adding a solvent and a filler into an emulsifying pot, homogenizing and shearing for 20-50 min to obtain a first mixture;
2) adding a surfactant and an enzyme composition into the first mixture, and homogenizing and shearing for 10-30 min to obtain a second mixture;
3) and adding a bactericide into the second mixture, homogenizing and shearing for 5-20 min, and uniformly stirring to obtain the edible cleaning emulsion.
10. Use of an edible cleaning emulsion according to claim 1 for cleaning laundry, cleaning kitchen ware, cleaning dishware and cleaning toys.
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