CN105039038A - Sodium-modified smectite adsorbing solution and preparation method thereof - Google Patents
Sodium-modified smectite adsorbing solution and preparation method thereof Download PDFInfo
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- CN105039038A CN105039038A CN201510534660.2A CN201510534660A CN105039038A CN 105039038 A CN105039038 A CN 105039038A CN 201510534660 A CN201510534660 A CN 201510534660A CN 105039038 A CN105039038 A CN 105039038A
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Abstract
The invention discloses a sodium-modified smectite adsorbing solution and a preparation method thereof. The sodium-modified smectite adsorbing solution is prepared by dissolving a surfactant and a natural thickener in a sodium-modified smectite microemulsion which is used as a carrier. The components of the sodium-modified smectite adsorbing solution are respectively prepared from pure natural raw materials without adding any essence, pigment, traditional chemical antimicrobial agent or the like. Thus, the sodium-modified smectite adsorbing solution has the characteristics of low foam and high stain removal power, can be easily rinsed without any softening agent, is environment-friendly, and protects the skin.
Description
Technical field
The present invention relates to a kind of articles for washing, specifically the preparation method of a kind of sodium montmorillonite adsorption liquid and this adsorption liquid, belong to the manufacturing technology field of fractionation by adsorption product.
Background technology
Along with modern living standards of the people require more and more higher, needing the requirement of articles for washing can fast decontaminating, and nontoxic, water saving, be convenient to washing, environmental protection, does not hinder hand, not damaging laundry, and after washing, clothing is dry and comfortable, submissive colour-fast.But all kinds of articless for washing in the market all contain various chemical classes preparation, life-time service there will be that hand skin is coarse, decortication, dry and cracked, produces injury the problem such as to fade to clothing.Therefore, existing market shortage is a kind of is adsorbed as main washings with natural ore plant.
Summary of the invention
The present invention seeks to: for the problems referred to above, the invention provides a kind of sodium montmorillonite adsorption liquid being main component with natural mineral and natural phant additive, also disclose the preparation method of this adsorption liquid, this adsorption liquid has fast decontaminating simultaneously, nontoxic, water saving, is convenient to washing, environmental protection, do not hinder hand, not damaging laundry, after washing, clothing is dry and comfortable, submissive non-fading feature.
In order to achieve the above object, the technical solution used in the present invention is: a kind of sodium montmorillonite adsorption liquid, with sodium montmorillonite micro emulsion for carrier, tensio-active agent and natural thickener is dissolved in sodium montmorillonite micro emulsion and makes.
This sodium montmorillonite of the present invention adsorption liquid, on the basis of technique scheme, also comprises following preferred version:
The weight percent of described tensio-active agent, natural thickener and sodium montmorillonite micro emulsion is respectively:
Tensio-active agent 2.0 ~ 20.0%;
Natural thickener 0.5% ~ 2.0%;
Surplus is sodium montmorillonite micro emulsion.
Described tensio-active agent is the mixture of natural surface active agent and non-natural surfactant, wherein, natural surface active agent is selected from any one or two or more mixtures in fatty acid methyl ester-α-sodium sulfonate, Yelkin TTS, sorbitan-fatty acid ester, sorbitan-fatty acid ester derivative, and non-natural surfactant choosing is to any one in aliphatic alcohol polyoxyethylene sodium sulfate, sodium alkyl benzene sulfonate, alkylphenol polyoxydivinyl ether, lipid acid formic acid ethoxylate or two or more mixtures.
Described natural thickener is selected from any one or two or more mixtures in Lalgine, sodium alginate, carrageenin, gum arabic, starch, pectin.
The preparation method of this sodium montmorillonite of the present invention adsorption liquid is:
Leave standstill after tensio-active agent, natural thickener and sodium montmorillonite micro emulsion mixing and stirring, and this sodium montmorillonite adsorption liquid finished product obtained.
The preparation method of this sodium montmorillonite of the present invention adsorption liquid, on the basis of technique scheme, also comprises following preferred version:
The concrete operation method of described " leaving standstill after tensio-active agent, natural thickener and sodium montmorillonite micro emulsion mixing and stirring " is: in high speed dispersor, add sodium montmorillonite micro emulsion, under stirring condition, slowly add tensio-active agent, the natural thickener be dissolved in the water is added again after disperseing completely, adjusting viscosity is to suitable, stop dispersion, static to the removal of foam.
Also carry out filling to obtained sodium montmorillonite adsorption liquid finished product, and obtain sodium montmorillonite adsorption liquid packaging final prod.
The preparation method of described sodium montmorillonite micro emulsion comprises the following steps:
Step one, first natural smectite ore deposit soil to be stirred with the pure water of 15 ~ 25 times of weight, and abundant immersion more than 50 hours, after it fully expands, make solution sieve through the above vibratory screening apparatus of 200 order while stirring;
Step 2, the emulsion that described step one obtained are in grinding machine for grinding more than 40 hours of delaminating, sodium agent water-soluble liquid is added in emulsion after grinding, in described sodium agent water-soluble liquid, the quality of sodium agent solute accounts for 2.0 ~ 7.0% of solid matter mass in described emulsion, fully stirs more than 2 hours in dispersion machine.
As preferably, also comprise step 3, the material that described step 2 obtained isolates macrobead through high speed tubular-bowl centrifuge, thus obtained sodium montmorillonite micro emulsion finished product.
As preferably, described sodium agent is selected from any one or two or more mixtures in sodium carbonate, sodium bicarbonate, trisodium phosphate, sodium phosphate, sodium sulfate.
This sodium montmorillonite of the present invention adsorption liquid, with sodium montmorillonite micro emulsion for carrier, tensio-active agent and natural thickener be dissolved in sodium montmorillonite micro emulsion and make, it has the following advantages:
1, montmorillonite is after sodium ion-exchange, and self is with electric charge, has again and carry out antistatic surface process to apparel fabrics fiber while low bubble decontamination, without the need to carrying out independent submissive process again after making clothes washing, clothing can be made a softer and smoother touch.
2, montmorillonite self has absorption property, can adsorb the foreign matter on clothing and strengthen soil removability.
3, montmorillonite molecule under the effect of water, can produce mechanical friction to the dirt in clothing again, increases soil removability.
4, the montmorillonite after sodium has slight alkalinity effectively can strengthen the ability of degreasing.
5, compared to the washing liquid prepared by various synthetic chemicals, this sodium montmorillonite of the present invention adsorption liquid has natural bacteriostatic, the feature of performance gentleness.
6, in this sodium of the present invention montmorillonite adsorption liquid, each component all adopts pure natural raw material to be prepared from, and does not add any essence and flavoring agent, pigment and traditional chemical antiseptic-germicide etc., has low bubble, strong detergency, easy rinsing, without the need to softener, and environmental protection, the feature of skin care.This sodium montmorillonite adsorption liquid coordinates small-scale ultrasonic cleaning machine to use cleaning performance better.
Embodiment
Below in conjunction with specific embodiment, such scheme is described further.Should be understood that these embodiments are not limited to for illustration of the present invention limit the scope of the invention.The implementation condition adopted in embodiment can do further adjustment according to the condition of concrete producer, and not marked implementation condition is generally the condition in normal experiment.
Embodiment one: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 93.60Kg as making raw material is got out, fatty acid methyl ester-α-sodium sulfonate and aliphatic alcohol polyoxyethylene sodium sulfate 5.00kg, Lalgine 1.40kg altogether.
Wherein fatty acid methyl ester-α-sodium sulfonate is common natural surface active agent, and Lalgine is common natural thickener, and aliphatic alcohol polyoxyethylene sodium sulfate is common non-natural surfactant.Certainly we also can adopt other natural surface active agent to substitute fatty acid methyl ester-α-sodium sulfonate in this example, such as Yelkin TTS, sorbitan-fatty acid ester or sorbitan-fatty acid ester derivative, we can also adopt mixture two or more arbitrarily in fatty acid methyl ester-α-sodium sulfonate, Yelkin TTS, sorbitan-fatty acid ester, sorbitan-fatty acid ester derivative to carry out fatty acid methyl ester-α-sodium sulfonate independent in this example alternative.We also can adopt other non-natural surfactant to substitute aliphatic alcohol polyoxyethylene sodium sulfate in this example, such as sodium alkyl benzene sulfonate, alkylphenol polyoxydivinyl ether or lipid acid formic acid ethoxylate, we can also adopt the mixture two or more arbitrarily in any one or two or more mixtures in aliphatic alcohol polyoxyethylene sodium sulfate, sodium alkyl benzene sulfonate, alkylphenol polyoxydivinyl ether, lipid acid formic acid ethoxylate to carry out aliphatic alcohol polyoxyethylene sodium sulfate independent in this example alternative.
Equally, we also can adopt other natural thickener to substitute Lalgine in this example, such as sodium alginate, carrageenin, gum arabic, starch or pectin, we can also adopt the mixture two or more arbitrarily in Lalgine, sodium alginate, carrageenin, gum arabic, starch, pectin to carry out the Lalgine be used alone in this example alternative.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 5% mass concentration, adjusting viscosity is to suitable (this suitable viscosity number is generally 2000 ~ 3000mpa.s), stop dispersion, static can filling (carrying out according to a conventional method detecting, weigh and packing) after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Embodiment two: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 91.42Kg as making raw material is got out, Yelkin TTS (it is natural surface active agent) and sodium alkyl benzene sulfonate (it is non-natural surfactant) 6.80kg, sodium alginate (it is natural thickener) 1.78kg altogether.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 6.5% mass concentration, and adjusting viscosity, to suitable, stops dispersion, static can be filling after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Embodiment three: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 90.35Kg as making raw material is got out, sorbitan-fatty acid ester (it is natural surface active agent) and sodium alkyl benzene sulfonate (it is non-natural surfactant) 9.00kg, pectin (it is natural thickener) 0.65kg altogether.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 10% mass concentration, adjusting viscosity is to suitable (appropriate viscosity mentioned here is generally 2000 ~ 3000mpa.s), stop dispersion, static can be filling after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Embodiment four: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 95.15Kg as making raw material is got out, fatty acid methyl ester-α-sodium sulfonate (it is natural surface active agent) and lipid acid formic acid ethoxylate (it is non-natural surfactant) 2.90kg, pectin (it is natural thickener) 1.95kg altogether.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 4.5% mass concentration, and adjusting viscosity, to suitable, stops dispersion, static can be filling after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Embodiment five: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 89.50Kg as making raw material is got out, sorbitan-fatty acid ester, Yelkin TTS, sorbitan-fatty acid ester and alkylphenol polyoxydivinyl ether be 10.00kg, gum arabic (it is natural thickener) 0.50kg altogether.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 4% mass concentration, and adjusting viscosity, to suitable, stops dispersion, static can be filling after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Embodiment six: the preparation of sodium montmorillonite adsorption liquid
1) raw material prepares:
First the sodium montmorillonite micro emulsion 96.00Kg as making raw material is got out, sorbitan-fatty acid ester and alkylphenol polyoxydivinyl ether 2.00kg altogether, carrageenin and starch (the two is natural thickener) 2.00kg altogether.
2) mix
In the high speed dispersor with 200L container, add ready sodium montmorillonite micro emulsion, under stirring condition, slowly add ready tensio-active agent, adding after disperseing completely has been dissolved in the water again is configured to the natural thickener of 8% mass concentration, and adjusting viscosity, to suitable, stops dispersion, static can be filling after the removal of foam, thus obtain the packaging final prod of sodium montmorillonite adsorption liquid of the present invention.
Be not difficult to find out, above-mentioned six embodiments are all with sodium montmorillonite micro emulsion for carrier, tensio-active agent (mixture for natural surface active agent and non-natural surfactant) and natural thickener are dissolved in sodium montmorillonite micro emulsion and make sodium montmorillonite adsorption liquid finished product.In obtained sodium montmorillonite adsorption liquid finished product, the weight percent of each component is:
Tensio-active agent 2.0 ~ 20.0%;
Natural thickener 0.5% ~ 2.0%;
Surplus is sodium montmorillonite micro emulsion.
Its soil removability of sodium montmorillonite adsorption liquid that above example obtains detects JB-01, JB-02, JB-03 by QB/T1224 " dress material washes agent by liquid ", is: ≈ standard washing liquid detersive power/1.0
Adopt sodium montmorillonite adsorption liquid and the comparison of traditional washing liquid bath water amount as follows
" 4 ~ 8% ", " 8 ~ 12% ", " > 12% " described in upper table, refer to the weight percent (accounting for the weight percent of tensio-active agent, natural thickener and sodium montmorillonite micro emulsion gross weight) of tensio-active agent.
In each embodiment above-mentioned, the various tensio-active agent adopted and various natural thickener are can the commodity of outsourcing.And sodium montmorillonite micro emulsion is prepared from by following method, this preparation method comprises following step:
Step one, first natural smectite ore deposit soil to be stirred with the pure water of 15 ~ 25 times of weight, and abundant immersion more than 50 hours, after it fully expands, make solution sieve through the above vibratory screening apparatus of 200 order while stirring;
Step 2, the emulsion that described step one obtained are in grinding machine for grinding more than 40 hours of delaminating, sodium agent water-soluble liquid is added in emulsion after grinding, in described sodium agent water-soluble liquid, the quality of sodium agent solute accounts for 2.0 ~ 7.0% of solid matter mass in described emulsion, the mass concentration of this sodium agent water-soluble liquid preferably 15 ~ 20%, the emulsion adding sodium agent water-soluble liquid is fully stirred more than 2 hours in dispersion machine, obtains obtained sodium montmorillonite micro emulsion;
If there is undissolved large thing in the obtained sodium montmorillonite micro emulsion that step 2 obtains, we also need the operation carrying out next step again, i.e. step 3: the material described step 2 obtained isolates macrobead (particulate matter that build is larger) through high speed tubular-bowl centrifuge.
Generally select inorganic sodium as described sodium agent, be preferably sodium carbonate, sodium bicarbonate, trisodium phosphate, sodium phosphate, any one or two or more mixtures in sodium sulfate.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to people can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalent transformations of doing according to the spirit of main technical schemes of the present invention or modification, all should be encompassed within protection scope of the present invention.
Claims (10)
1. a sodium montmorillonite adsorption liquid, is characterized in that, tensio-active agent and natural thickener for carrier with sodium montmorillonite micro emulsion, are dissolved in sodium montmorillonite micro emulsion and make by this adsorption liquid.
2. sodium montmorillonite adsorption liquid according to claim 1, is characterized in that, the weight percent of described tensio-active agent, natural thickener and sodium montmorillonite micro emulsion is respectively:
Tensio-active agent 2.0 ~ 20.0%;
Natural thickener 0.5% ~ 2.0%;
Surplus is sodium montmorillonite micro emulsion.
3. sodium montmorillonite adsorption liquid according to claim 1, it is characterized in that, described tensio-active agent is the mixture of natural surface active agent and non-natural surfactant, wherein, natural surface active agent is selected from fatty acid methyl ester-α-sodium sulfonate, Yelkin TTS, sorbitan-fatty acid ester, any one or two or more mixtures in sorbitan-fatty acid ester derivative, non-natural surfactant choosing is to aliphatic alcohol polyoxyethylene sodium sulfate, sodium alkyl benzene sulfonate, alkylphenol polyoxydivinyl ether, any one or two or more mixtures in lipid acid formic acid ethoxylate.
4. sodium montmorillonite adsorption liquid according to claim 1, is characterized in that, described natural thickener is selected from any one or two or more mixtures in Lalgine, sodium alginate, carrageenin, gum arabic, starch, pectin.
5. the preparation method of the sodium montmorillonite adsorption liquid as described in claim 1 or 2 or 3, it is characterized in that the method is: leave standstill after tensio-active agent, natural thickener and sodium montmorillonite micro emulsion mixing and stirring, and this sodium montmorillonite adsorption liquid finished product obtained.
6. the preparation method of sodium montmorillonite adsorption liquid according to claim 5, it is characterized in that, the concrete operation method of described " leaving standstill after tensio-active agent, natural thickener and sodium montmorillonite micro emulsion mixing and stirring " is: in high speed dispersor, add sodium montmorillonite micro emulsion, under stirring condition, slowly add tensio-active agent, add the natural thickener be dissolved in the water after disperseing completely again, adjusting viscosity is to suitable, stop dispersion, static to the removal of foam.
7. the preparation method of sodium montmorillonite adsorption liquid according to claim 5, is characterized in that, also carries out filling to obtained sodium montmorillonite adsorption liquid finished product, and obtains sodium montmorillonite adsorption liquid packaging final prod.
8. the preparation method of sodium montmorillonite adsorption liquid according to claim 5, is characterized in that, the preparation method of described sodium montmorillonite micro emulsion comprises the following steps:
Step one, first natural smectite ore deposit soil to be stirred with the pure water of 15 ~ 25 times of weight, and abundant immersion more than 50 hours, after it fully expands, make solution sieve through the above vibratory screening apparatus of 200 order while stirring;
Step 2, the emulsion that described step one obtained are in grinding machine for grinding more than 40 hours of delaminating, sodium agent water-soluble liquid is added in emulsion after grinding, in described sodium agent water-soluble liquid, the quality of sodium agent solute accounts for 2.0 ~ 7.0% of solid matter mass in described emulsion, fully stirs more than 2 hours in dispersion machine.
9. the preparation method of sodium montmorillonite adsorption liquid according to claim 8, is characterized in that, the preparation method of described sodium montmorillonite micro emulsion also comprises step 3: the material described step 2 obtained isolates macrobead through high speed tubular-bowl centrifuge.
10. the preparation method of sodium montmorillonite adsorption liquid according to claim 8, is characterized in that, described sodium agent is selected from any one or two or more mixtures in sodium carbonate, sodium bicarbonate, trisodium phosphate, sodium phosphate, sodium sulfate.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110003995A (en) * | 2019-04-26 | 2019-07-12 | 建平碧康家居用品有限公司 | A kind of montmorillonite natural mineral matter concentration liquid laundry detergent and preparation method thereof |
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| US20060086291A1 (en) * | 2002-10-09 | 2006-04-27 | Jardine Leslie A | Amine-containing cement processing additives |
| CN101228258A (en) * | 2005-08-01 | 2008-07-23 | 花王株式会社 | Softening detergent composition |
| CN103725454A (en) * | 2012-10-11 | 2014-04-16 | 3M创新有限公司 | Cleaning agent and application thereof to clean hard products |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060086291A1 (en) * | 2002-10-09 | 2006-04-27 | Jardine Leslie A | Amine-containing cement processing additives |
| CN101228258A (en) * | 2005-08-01 | 2008-07-23 | 花王株式会社 | Softening detergent composition |
| CN103725454A (en) * | 2012-10-11 | 2014-04-16 | 3M创新有限公司 | Cleaning agent and application thereof to clean hard products |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110003995A (en) * | 2019-04-26 | 2019-07-12 | 建平碧康家居用品有限公司 | A kind of montmorillonite natural mineral matter concentration liquid laundry detergent and preparation method thereof |
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