CN100467390C - High efficiency sewage treating agent and its prepn process - Google Patents
High efficiency sewage treating agent and its prepn process Download PDFInfo
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- CN100467390C CN100467390C CNB2006101417741A CN200610141774A CN100467390C CN 100467390 C CN100467390 C CN 100467390C CN B2006101417741 A CNB2006101417741 A CN B2006101417741A CN 200610141774 A CN200610141774 A CN 200610141774A CN 100467390 C CN100467390 C CN 100467390C
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Abstract
The present invention relates to high efficiency sewage treating agent and its preparation process. The high efficiency sewage treating agent consists of sodium carbonate 10-20 weight portions, trisodium phosphate 50-60 weight portions, sodium silicate 30-40 weight portions, surfactant 20-30 weight portions, and water 20-30 weight portions. Its preparation process includes the following steps: dissolving sodium silicate in water inside a sandwiched reactor through stirring and introducing steam to heat at 75-80 deg.c for 1-1.5 hr to obtain sol, cooling to 30 deg.c and adding sodium carbonate and trisodium phosphate to produce exothermic reaction at 75-80 deg.c while stirring for 0.5 hr, cooling to 20-25 deg.c, adding surfactant and further stirring for 0.5 hr, discharging, cooling to solid matter, drying and crushing to obtain the product. The high efficiency sewage treating agent has no toxicity, no smell and stable performance, and is used in treating industrial and domestic sewage.
Description
One, technical field
The present invention relates to the Pollution abatement chemical field, especially a kind of high efficiency sewage treating agent and preparation method thereof.
Two, background technology
Industry, sanitary sewage are little and contain the chemistry and the material of various complicated ingredients because of particle, are difficult for precipitation, reclaim difficulty, directly are thrown into nature by great majority.Its pollutes extremely serious, can produce nonvolatil qualitative change to soil and vegetation, can cause the injury of accumulation property for people, animal and organism in water because of hard particles and various material to the basin.The various waste water controls of low cost, high benefit relate to the large construction project that country keeps benign ecological cycles and environmental pollution improvement's Sustainable development.Resource is recycled fully, has not only increased considerable economic to the people, does not bring pollution to environment again, is the good behave of benefiting the nation and the people.
At present, modes such as mechanical means fermentation, filtration are generally adopted in the sewage disposal of domestic large-lot producer, but investment is big, cost is high, and general enterprise still adopts common sewage-treating agent basically, also exist factors such as processing cost height, result be not up to standard.
Present technique is complicated ingredient and the character according to industry, sanitary sewage, and preparation comprehensively is the powdery high efficiency sewage treating agent of one with acid, alkali, calcium, and it plays sterilization, sterilization, elimination smell and rapid flocculation, precipitating action.Sewage per ton uses this agent 50～200 gram, between 0.20～0.60 yuan of the cost, throws in sewage discharge trough or pond, just takes effect at once in 3 minutes.According to No. (37), Zhang ring prison word (2006) to this agent handle build pottery, building materials, ore dressing, butcher, the papermaking wastewater monitoring, the result shows that every index all reaches national sewage discharge primary standard, the water after the processing is Clear ﹠ Transparent, reusable edible.The present invention can be brought economic benefit to enterprise, also produces huge ecological benefits and social benefit simultaneously.The main purpose of this research is based on the present situation of the present sewage disposal of China just as starting point, tries hard to develop better effects if, a series of high efficiency sewage treating agents that cost is lower, for using in practice from now on.
Three, summary of the invention
The objective of the invention is to make its combination in preparation through the control reaction process with acid, alkali, calcium, tensio-active agent etc., and in use play sterilization, sterilization, elimination smell and rapid flocculation, precipitating action, and in use cost is low, effective, can replace the new generation product of original sewage-treating agent.The present invention is achieved in that
Press 10～20 parts in yellow soda ash (weight part, down together), 50～60 parts of tertiary sodium phosphates, 30～40 parts of water glass, 20～30 parts in tensio-active agent, 20～30 parts in tap water.
Described yellow soda ash can be selected at least a from anhydrous sodium carbonate, monohydrated sodium carbonate, Sodium carbonate decahydrate.
Described tertiary sodium phosphate can be selected at least a from anhydrous, a water, ten water, ten phosphate dihydrate trisodiums.
Described water glass can be selected at least a from solids, liquids.
Described tensio-active agent can be selected a kind of from calcium dodecylbenzene sulphonate, sodium lauryl sulfate, sodium alkyl benzene sulfonate at least.
The preparation method of this high efficiency sewage treating agent joins the water of formula ratio and water glass in the reactor of strap clamp cover, stirred between 75～80 ℃ of the controlled temperature 1～1.5 hour, make water glass all be dissolved into glue, be cooled to 30 ℃ of yellow soda ash and tertiary sodium phosphates that add formula ratio while stirring, temperature control continues for 75～80 ℃ to stir 0.5 hour under the situation that temperature rises naturally, the tensio-active agent that adds formula ratio when being cooled to 20～25 ℃, continue to stir discharging while stirring after 0.5 hour again, get finished product after cooling drying, the pulverizing.
Screening formulation and method are: 20 parts in tap water, in the reactor of 30 parts of adding strap clamp covers of water glass (solid), between warming while stirring to 75～80 ℃ 1～1.5 hour, make water glass all be dissolved into jelly, be cooled to 30 ℃ again and add 10 parts in yellow soda ash (anhydrous) while stirring, 50 parts of tertiary sodium phosphates (anhydrous), 75～80 ℃ of temperature controls are 0.5 hour under its natural intensification situation, add 20 parts of calcium dodecylbenzene sulphonates when being cooled to 20～25 ℃ while stirring, continue to stir discharging 0.5 hour, cooling, dry, pulverize top grade high efficiency sewage treating agent finished product.
Four, description of drawings
Fig. 1 is preparation method's process flow sheet of the present invention.Material: 1, yellow soda ash, 2, tertiary sodium phosphate, 3, water glass, 4, tensio-active agent, 5, tap water.
Five, embodiment
Qualified high efficiency sewage treating agent technical target of the product is: outward appearance: white powdery, and pH value (2% aqueous solution) 10～11, calcium oxide (in Cao) 〉=60%, silicon oxide is (with SiO
2Meter) 〉=3%, actives composition 〉=5%, total effective ingredient 〉=98%.
Embodiment 1
Prescription: with yellow soda ash (ten water things) 10 parts, 50 parts of tertiary sodium phosphates (ten water things), 40 parts of water glass (liquids), 20 parts of sodium alkyl benzene sulfonates, 20 parts in tap water.
Technology: tap water and water glass are added in the reactor of strap clamp cover, between warming while stirring to 75～80 ℃ 1～1.5 hour, make water glass all be dissolved into jelly, be cooled to 30 ℃ again and add yellow soda ash and tertiary sodium phosphate while stirring, 75～80 ℃ of temperature controls are 0.5 hour under its situation about heating up naturally, add sodium alkyl benzene sulfonate when being cooled to 20～25 ℃ while stirring, continue to stir discharging, cooling, drying, pulverizing 0.5 hour.
The result: cooling back concentration is too rare, and the every index of product is not up to standard after drying, the pulverizing.
Embodiment 2
Prescription: with yellow soda ash (anhydride) 10 parts, 50 parts of tertiary sodium phosphates (anhydride), 30 parts of water glass (solids), 20 parts of calcium dodecylbenzene sulphonates, 20 parts in tap water.
Technology: press embodiment 1 operation unanimity.
The result: effective, every technical indicator reaches requirement.
Embodiment 3
Prescription: with yellow soda ash (anhydride) 15 parts, tertiary sodium phosphate (anhydride) 55 minutes, 35 parts of water glass (solids), 25 parts of calcium dodecylbenzene sulphonates, 25 parts in tap water.
Technology: press embodiment 1 operation unanimity.
The result: every technical indicator reaches requirement, and work in-process hardness is less for more greatly.
Embodiment 4
Prescription: with yellow soda ash (anhydride) 10 parts, 50 parts of tertiary sodium phosphates (anhydride), 30 parts of water glass (solids), 15 parts of calcium dodecylbenzene sulphonates, 20 parts in tap water.
Technology: press embodiment 1 operation unanimity.
The result: active matter content is not up to standard in the technical target of the product.
Embodiment 5
Prescription: press embodiment 2 unanimities.
Technology: disposable material with formula ratio all adds stirring in the reactor of strap clamp cover, heats up and carries out simultaneously, reacts cooling discharge between 75～80 ℃ 1～1.5 hour.
The result: caking in the still, can't discharging, use artificial discharging, the every index of product is defective.
Embodiment 6
Prescription: press embodiment 2 unanimities.
Technology: by implementing thin example 2 temperature unanimities, each few 10 minutes reaction times.
The result: every technical indicator reaches, and cooling back humidity is less for more greatly.
Embodiment 7
Prescription: press embodiment 2 unanimities.
Technology: press embodiment 2 time unanimity, each few 10 ℃ of temperature of reaction.
The result: every technical indicator reaches, and cooling back viscosity is less for more greatly.
Embodiment 8
Prescription: with yellow soda ash (anhydride) 10 parts, 50 parts of tertiary sodium phosphates (anhydride), 30 parts of water glass (solids), 20 parts of calcium dodecylbenzene sulphonates, 30 parts in tap water.
Technology: press embodiment 2 operation unanimities.
The result: every index nearly one percentage point that descends does not reach requirement.
By above embodiment as can be seen, embodiment 3,6,7 technical indicators meet the requirements, but defectiveness.Embodiment 2 every technical indicators reach requirement, and zero defect is a preferred preparation method of the present invention.
Claims (2)
1, a kind of high efficiency sewage treating agent is characterized in that getting by weight proportion raw material: 10-20 parts of anhydrous sodium carbonates, 50-60 parts of trisodium Phosphate Anhydrous, 30-40 parts of sodium silicate solids, 20-30 parts of calcium dodecylbenzene sulphonates, 20-30 parts in tap water, and be prepared with method according to the following steps:
Tap water and sodium silicate solid are joined in the reactor of strap clamp cover, stir, be warming up between 75-80 ℃ 1-1.5 hours, make water glass all be dissolved into glue, be cooled to 30 ℃ and add anhydrous sodium carbonate and trisodium Phosphate Anhydrous while stirring, rise to 75-80 ℃ naturally in temperature and continue down to stir 0.5 hour, add calcium dodecylbenzene sulphonate when being cooled to 20-25 ℃ while stirring, continue again to stir 0.5 hour, get the high efficiency sewage treating agent finished product after discharging, cooling, drying, the pulverizing.
2,, be characterised in that its raw material weight ratio is: 10 parts of anhydrous sodium carbonates, 50 parts of trisodium Phosphate Anhydrous, 30 parts of sodium silicate solids, 20 parts of calcium dodecylbenzene sulphonates, 20 parts in tap water according to the described high efficiency sewage treating agent of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101417741A CN100467390C (en) | 2006-10-02 | 2006-10-02 | High efficiency sewage treating agent and its prepn process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101417741A CN100467390C (en) | 2006-10-02 | 2006-10-02 | High efficiency sewage treating agent and its prepn process |
Publications (2)
| Publication Number | Publication Date |
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| CN1974419A CN1974419A (en) | 2007-06-06 |
| CN100467390C true CN100467390C (en) | 2009-03-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2006101417741A Expired - Fee Related CN100467390C (en) | 2006-10-02 | 2006-10-02 | High efficiency sewage treating agent and its prepn process |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101759262B (en) * | 2008-12-25 | 2012-05-09 | 山东滨州嘉源环保有限责任公司 | Manufacturing method for composite decoloration flocculant of high-concentration and high-chromaticity waste water |
| CN102502934A (en) * | 2011-11-04 | 2012-06-20 | 昆明理工大学 | Treatment chemical for lead-zinc flotation tailing wastewater |
| CN105253989A (en) * | 2015-10-16 | 2016-01-20 | 巢湖市聚源机械有限公司 | Biological fermentation treating agent for sewage |
-
2006
- 2006-10-02 CN CNB2006101417741A patent/CN100467390C/en not_active Expired - Fee Related
Non-Patent Citations (4)
| Title |
|---|
| 常温下钢铁的磷化及工艺. 陈彬等.郑州铁路职业技术学院学报，第17卷第3期. 2005 |
| 常温下钢铁的磷化及工艺. 陈彬等.郑州铁路职业技术学院学报，第17卷第3期. 2005 * |
| 聚硅酸盐类絮凝剂的研究进展. 孙剑辉等.2001年全国工业用水与废水处理技术交流会论文汇编. 2001 |
| 聚硅酸盐类絮凝剂的研究进展. 孙剑辉等.2001年全国工业用水与废水处理技术交流会论文汇编. 2001 * |
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