CN101575185A - High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof - Google Patents

High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof Download PDF

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Publication number
CN101575185A
CN101575185A CNA2009103034333A CN200910303433A CN101575185A CN 101575185 A CN101575185 A CN 101575185A CN A2009103034333 A CNA2009103034333 A CN A2009103034333A CN 200910303433 A CN200910303433 A CN 200910303433A CN 101575185 A CN101575185 A CN 101575185A
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parts
compound
waste mash
beet waste
slag
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CNA2009103034333A
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Chinese (zh)
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CN101575185B (en
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徐彬
蔡戈
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Xinjiang Western Blue Sky New Materials Co ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/18Waste materials; Refuse organic
    • C04B18/24Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
    • C04B18/248Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork from specific plants, e.g. hemp fibres
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Environmental & Geological Engineering (AREA)
  • Civil Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to the technical field of building material manufacturing and sugar-making, and is a high-efficiency compound slag-grinding aid of beet waste mash compound and a production method thereof; the invention further comprises a using method of the high-efficiency compound slag-grinding aid of beet waste mash compound and application of beet waste mash in slag-grinding aid. The high-efficiency compound slag-grinding aid of beet waste mash compound contains beet waste mash compound, glycol, diglycol, triethanolamine and water. The invention not only uses industrial waste, reduces the cost of slag-grinding aid, but also adds 0.015-0.035% of the grinding aid in grinding process of the slag to increase the yield of slag grinder by 15%-30%; 0.015-0.035% of grinding aid is added under the condition of maintaining yield of the grinder so that the specific surface area of slag powder is increased by 7%-15%, thereby reaching to purpose of energy-saving and emission-reduction and generating economic benefit and social benefit.

Description

High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof
The present invention relates to the technical field of material of construction manufacturing and sugaring, be a kind of high-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof, also comprise the using method and the application of beet waste mash in the slag grinding aid of high-efficiency compound slag-grinding aid of beet waste mash compound.
Background technology
Slag is a large amount of a kind of industrial residues that produce in the steel manufacture process, and it is levigate back as cement mixture or the existing history for many years of concrete admixture.Be milled down to specific surface area 〉=420m behind the slag drying 2The micro mist of/kg is prepared burden, and can improve cement and concrete performance significantly.But scoriaceous grindability is very poor, and not only production efficiency is low but also energy consumption is huge to cause the production of slag powders.Therefore, it is significant for energy-saving and emission-reduction to improve scoriaceous mill efficiency.
Beet waste mash is a large amount of nontoxic harmful waste liquids based on organism that produce in the beet sugar manufacture process.The useless mash resource utilization mode of beet sugar is mainly agricultural filling method, handles alcohol slops and manufacture order cell protein and Yeast protein towards grey method, oxidation pond process, method of enrichment at present.
The beet waste mash farming is irritated back soil salinization and is increased the weight of, and suppresses the mineralising of the soil organism and total oxygen, and available phosphorus content significantly descends, and effectively zinc, manganese, iron level obviously increase.Dirty filling makes wheat yield, sewage mix filling and also makes the vegetables underproduction.
Oxidation pond process mainly utilizes microorganism and aquatic organism to come digestion of organic matter, though this method less investment, working cost is low, simple to operate, needs the pond capacity big, and floor space is big, treating processes severe contamination air and underground water.
Method of enrichment handle alcohol slops be waste liquid after neutralization, precipitation process, by evaporation concentration repeatedly, drying is made dry powder again.Dry powder is made cement water reducing agent or fertilizer raw material.This method evaporation concentration, dry steam consumption are high and product that reclaim is limited as the water reducer consumption, and it is low to make the fertilizer output value.Because investment is big, energy consumption and working cost height, the amount of circulating funds used is big, and the method for enrichment manufacturer that has built up at present mostly can't continue to produce.
Summary of the invention
The invention provides a kind of high-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof, it has overcome the deficiency of prior art, the beet waste mash that utilizes sugar industry to produce in a large number and be difficult to handle is as one of raw material, not only reduced cost but also turned waste into wealth, utilize this high-efficiency compound slag-grinding aid of beet waste mash compound that the slag mill output is significantly improved, thereby improved economic benefit and realized the effect of energy-saving and emission-reduction.
One of technical scheme of invention is achieved like this: a kind of high-efficiency compound slag-grinding aid of beet waste mash compound, and it contains by parts by weight of raw materials: 15 parts to 25 parts beet waste mash compound, 1 part to 3 parts ethylene glycol, 8 parts to 15 parts glycol ether, 23 parts to 42 parts trolamine, 15 parts to 53 parts water; Wherein: this beet waste mash compound contains by parts by weight of raw materials: 55 parts to 80 parts beet waste mash, 5 parts to 8 parts urea, 1 part to 2 parts Sodium sulfate anhydrous.min(99) and 10 parts to 39 parts water.
Be further optimization and/or selection below to one of technique scheme:
Above-mentioned beet waste mash compound obtains by following step: at first beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing back of requirement were reacted 15 hours to 17 hours under 80 ℃ to 95 ℃ temperature, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.
Beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing back of above-mentioned requirement were warmed up to 80 ℃ to 95 ℃ in 15 minutes to 30 minutes.
Above-mentioned reaction postcooling falls solid residue to normal temperature with 200 purpose screen filtrations and obtains beet waste mash compound.
Two of technical scheme of the present invention is achieved like this: the production method of above-mentioned high-efficiency compound slag-grinding aid of beet waste mash compound is undertaken by following step: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water thorough mixing of requirement are obtained high-efficiency compound slag-grinding aid of beet waste mash compound.
Three of technical scheme of the present invention is achieved like this: the using method of above-mentioned high-efficiency compound slag-grinding aid of beet waste mash compound is characterized in that the weight percent that adds the pan feeding total amount by the slag grinding machine adds 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound.
Four of technical scheme of the present invention is achieved like this: the application of beet waste mash in the slag grinding aid.
The present invention has not only made full use of trade waste, has reduced the cost of slag grinding aid, and this kind grinding aid of adding 0.015% to 0.035% in scoriaceous grinding process can make the slag mill hourly output improve 15% to 30%; This kind grinding aid of adding 0.015% to 0.035% under the situation of keeping the original unit-hour output of grinding machine can make the specific surface area of slag powders improve 7% to 15%.This had both reached the purpose of energy-saving and emission-reduction, had produced good economic benefit and social benefit again.
Embodiment
The present invention is not subjected to the restriction of following embodiment, can determine concrete embodiment according to the technical scheme and the practical situation of the invention described above.
Below in conjunction with embodiment the present invention is done further argumentation:
Embodiment 1, and this beet waste mash compound contains by parts by weight of raw materials: 55 parts beet waste mash, 5 parts urea, 1 part Sodium sulfate anhydrous.min(99) and 10 parts water.
Embodiment 2, and this beet waste mash compound contains by parts by weight of raw materials: 55 parts beet waste mash, 8 parts urea, 1 part Sodium sulfate anhydrous.min(99) and 39 parts water.
Embodiment 3, and this beet waste mash compound contains by parts by weight of raw materials: 55 parts beet waste mash, 5 parts urea, 2 parts Sodium sulfate anhydrous.min(99) and 10 parts water.
Embodiment 4, and this beet waste mash compound contains by parts by weight of raw materials: 55 parts beet waste mash, 8 parts urea, 2 parts Sodium sulfate anhydrous.min(99) and 39 parts water.
Embodiment 5, and this beet waste mash compound contains by parts by weight of raw materials: 80 parts beet waste mash, 8 parts urea, 1 part Sodium sulfate anhydrous.min(99) and 39 parts water.
Embodiment 6, and this beet waste mash compound contains by parts by weight of raw materials: 80 parts beet waste mash, 5 parts urea, 2 parts Sodium sulfate anhydrous.min(99) and 10 parts water.
Embodiment 7, and this beet waste mash compound contains by parts by weight of raw materials: 80 parts beet waste mash, 8 parts urea, 1 part Sodium sulfate anhydrous.min(99) and 39 parts water.
Embodiment 8, and this beet waste mash compound contains by parts by weight of raw materials: 80 parts beet waste mash, 8 parts urea, 2 parts Sodium sulfate anhydrous.min(99) and 39 parts water.
Embodiment 9, and this beet waste mash compound contains by parts by weight of raw materials: 68 parts beet waste mash, 7 parts urea, 1.5 parts Sodium sulfate anhydrous.min(99) and: 25 parts water.
Embodiment 10, and this beet waste mash compound contains by parts by weight of raw materials: 55 parts to 80 parts beet waste mash, 5 parts to 8 parts urea, 1 part to 2 parts Sodium sulfate anhydrous.min(99) and: 10 parts to 39 parts water.
The foregoing description 1 to 10 obtains by following production method: at first beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water of requirement is mixed back reaction 15 hours to 17 hours under 80 ℃ to 95 ℃ temperature, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.Wherein: be preferably in and be warmed up to 80 ℃ to 95 ℃ in 15 minutes to 30 minutes, be preferably in the reaction postcooling and fall solid residue to normal temperature with 200 purpose screen filtrations and obtain beet waste mash compound.
Embodiment 11, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts to 25 parts beet waste mash compound, 1 part to 3 parts ethylene glycol, 8 parts to 15 parts glycol ether, 23 parts to 42 parts trolamine, 15 parts to 53 parts water.
Embodiment 11, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts beet waste mash compound, 1 part ethylene glycol, 8 parts glycol ether, 23 parts trolamine, 15 parts water.
Embodiment 12, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts beet waste mash compound, 3 parts ethylene glycol, 8 parts glycol ether, 42 parts trolamine, 15 parts water.
Embodiment 13, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts beet waste mash compound, 1 part ethylene glycol, 15 parts glycol ether, 23 parts trolamine, 53 parts water.
Embodiment 14, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts beet waste mash compound, 3 parts ethylene glycol, 15 parts glycol ether, 42 parts trolamine, 53 parts water.
Embodiment 15, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 25 parts beet waste mash compound, 3 parts ethylene glycol, 15 parts glycol ether, 42 parts trolamine, 53 parts water.
Embodiment 16, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 25 parts beet waste mash compound, 1 part ethylene glycol, 15 parts glycol ether, 23 parts trolamine, 53 parts water.
Embodiment 17, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 25 parts beet waste mash compound, 1 part ethylene glycol, 8 parts glycol ether, 42 parts trolamine, 15 parts water.
Embodiment 18, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 25 parts beet waste mash compound, 3 parts ethylene glycol, 8 parts glycol ether, 23 parts trolamine, 15 parts water.
Embodiment 19, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 20 parts beet waste mash compound, 2 parts ethylene glycol, 11 parts glycol ether, 32 parts trolamine, 34 parts water.
Embodiment 20, and this high-efficiency compound slag-grinding aid of beet waste mash compound contains by parts by weight of raw materials: 15 parts to 25 parts beet waste mash compound, 1 part to 3 parts ethylene glycol, 8 parts to 15 parts glycol ether, 23 parts to 42 parts trolamine, 15 parts to 53 parts water.
The foregoing description 11 to 20 obtains by following production method: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water thorough mixing of requirement are obtained high-efficiency compound slag-grinding aid of beet waste mash compound.
Embodiment 21, and the using method of this high-efficiency compound slag-grinding aid of beet waste mash compound is weight percent adding 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound that adds the pan feeding total amount by the slag grinding machine.
Gained high-efficiency compound slag-grinding aid of beet waste mash compound test of the present invention is learnt: this kind grinding aid of adding 0.015% to 0.035% can make the slag mill hourly output improve 15% to 30% in scoriaceous grinding process; This kind grinding aid of adding 0.015% to 0.035% under the situation of keeping the original unit-hour output of grinding machine can make the specific surface area of slag powders improve 7% to 15%.This all reaches the purpose of energy-saving and emission-reduction, and produces good economic benefit and social benefit.
The concerned countries standard that the present invention relates to is as follows:
GB 175-1999 silicate cement, ordinary Portland cement.
The GB/T 1345-1991 cement fineness method of inspection (80 μ m sieve sieve formula).
GB/T 8074-1987 Method of determination for specific surface of cement Bo Shi method.
GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method).
JC/T 667-2004 cement grinding aid.
GB/T 18046-2008 is used for the GBFS of cement and concrete.

Claims (9)

1, a kind of high-efficiency compound slag-grinding aid of beet waste mash compound is characterized in that containing by parts by weight of raw materials: 15 parts to 25 parts beet waste mash compound, 1 part to 3 parts ethylene glycol, 8 parts to 15 parts glycol ether, 23 parts to 42 parts trolamine, 15 parts to 53 parts water; Wherein: this beet waste mash compound contains by parts by weight of raw materials: 55 parts to 80 parts beet waste mash, 5 parts to 8 parts urea, 1 part to 2 parts Sodium sulfate anhydrous.min(99) and 10 parts to 39 parts water.
2, high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 1, it is characterized in that this beet waste mash compound obtains by following step: at first beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing back of requirement were reacted 15 hours to 17 hours under 80 ℃ to 95 ℃ temperature, next obtains beet waste mash compound after being cooled to normal temperature and filtering out solid residue.
3, high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 2 is characterized in that beet waste mash, urea, Sodium sulfate anhydrous.min(99) and the water mixing back of requirement were warmed up to 80 ℃ to 95 ℃ in 15 minutes to 30 minutes.
4,, it is characterized in that reacting postcooling and fall solid residue to normal temperature with 200 purpose screen filtrations and obtain beet waste mash compound according to claim 2 or 3 described high-efficiency compound slag-grinding aid of beet waste mash compound.
5, a kind of production method according to claim 1 or 2 or 3 described high-efficiency compound slag-grinding aid of beet waste mash compound is characterized in that being undertaken by following step: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water thorough mixing of requirement are obtained high-efficiency compound slag-grinding aid of beet waste mash compound.
6, a kind of production method of high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 4 is characterized in that being undertaken by following step: beet waste mash compound, ethylene glycol, glycol ether, trolamine, the water thorough mixing of requirement are obtained high-efficiency compound slag-grinding aid of beet waste mash compound.
7, a kind of using method according to claim 1 or 2 or 3 described high-efficiency compound slag-grinding aid of beet waste mash compound is characterized in that the weight percent that adds the pan feeding total amount by the slag grinding machine adds 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound.
8, a kind of using method of high-efficiency compound slag-grinding aid of beet waste mash compound according to claim 4 is characterized in that the weight percent that adds the pan feeding total amount by the slag grinding machine adds 0.015% to 0.035% high-efficiency compound slag-grinding aid of beet waste mash compound.
9, the application of beet waste mash in the slag grinding aid.
CN2009103034333A 2009-06-19 2009-06-19 High-efficiency compound slag-grinding aid of beet waste mash compound and production method thereof Expired - Fee Related CN101575185B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249586A (en) * 2011-05-13 2011-11-23 洛阳万顺建材有限公司 Grinding-assistant reinforcing agent for mineral powder
CN104045253A (en) * 2013-03-13 2014-09-17 同济大学 Slag additive and its preparation method and use
CN106186780A (en) * 2016-07-05 2016-12-07 湖北鑫统领万象科技有限公司 A kind of grinding aid improving cement and water reducer compatibility
CN106396453B (en) * 2016-08-31 2019-01-18 武汉理工大学 A kind of modified granite powder as additive and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1011775B (en) * 1988-07-09 1991-02-27 轻工部甜菜糖业科学研究所 Simple method for making use of sugar-mill filter-residue
CN1221485C (en) * 2002-04-19 2005-10-05 尹小林 Industrial waste residue activating grinding aid

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249586A (en) * 2011-05-13 2011-11-23 洛阳万顺建材有限公司 Grinding-assistant reinforcing agent for mineral powder
CN104045253A (en) * 2013-03-13 2014-09-17 同济大学 Slag additive and its preparation method and use
CN104045253B (en) * 2013-03-13 2016-05-18 同济大学 A kind of slag additive and its production and use
CN106186780A (en) * 2016-07-05 2016-12-07 湖北鑫统领万象科技有限公司 A kind of grinding aid improving cement and water reducer compatibility
CN106186780B (en) * 2016-07-05 2020-05-05 湖北鑫统领万象科技有限公司 Grinding aid for improving compatibility of cement and water reducing agent
CN106396453B (en) * 2016-08-31 2019-01-18 武汉理工大学 A kind of modified granite powder as additive and preparation method thereof

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