CN106967514A - A kind of SODIUM PERCARBONATE powdered cleanser and its preparation method and application - Google Patents
A kind of SODIUM PERCARBONATE powdered cleanser and its preparation method and application Download PDFInfo
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- CN106967514A CN106967514A CN201710238756.3A CN201710238756A CN106967514A CN 106967514 A CN106967514 A CN 106967514A CN 201710238756 A CN201710238756 A CN 201710238756A CN 106967514 A CN106967514 A CN 106967514A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2024—Monohydric alcohols cyclic; polycyclic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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Abstract
The invention discloses a kind of SODIUM PERCARBONATE powdered cleanser, following component by weight percentage is included：SODIUM PERCARBONATE 60%~80%, neopelex 2%~5%, sodium alkyl sulfonate 1%~3%, MES 1%~4%, fat alcohol polyethylene ether sulfate 1%~5%, manganese sulfate 0.2%~1%, anhydrous sodium sulfate 10%~15%, menthol 0.5%~1%；Wherein, the carbon number of alkyl is 5~15 in sodium alkyl sulfonate, and fatty acid-based carbon number is that the carbon number of fatty alcohol radical in 5~12, fat alcohol polyethylene ether sulfate is 5~12 in MES.It is this cleaning agent disinfection effect height, environmental protection, easy to use, the organophosphorus pesticide fast degradation of fruits and vegetables foodstuff surface can be made, efficiency is eliminated up to more than 99%；There are abundant surface active function and disinfection effect simultaneously, can clean greasy residues simultaneously, fully remove wax, effectively remove the impurity and residues of pesticides of fruit surface, it is ensured that the health that the hygienic and people of fruits and vegetables food eat.
Description
Technical field
The present invention relates to a kind of SODIUM PERCARBONATE powdered cleanser and its preparation method and application, belong to cleaning agent technology neck
Domain.
Background technology
, can be by virus, bacterium, mycoplasma-like organism(MLO), fungi, algae, elder brother in the plantation and growth course of the plants such as fruits and vegetables
The harm of worm, parasite etc., and weeds nutrition contention；It then becomes necessary to suppress various pest and disease damages, elimination using agricultural chemicals
Weeds.In China, insecticide accounts for organophosphorus pesticide in 72% or so of agricultural chemicals total amount, insecticide and accounts for 70% or so.Organophosphor
Economical, efficiently, conveniently although agricultural chemicals can effectively suppress various pest and disease damages, the toxicity of organophosphorus pesticide is higher, largely makes
With can not only be polluted to environment, and it can be formed in fruits and vegetables and food in residues of pesticides, or even a kind of fruits and vegetables and have multiple
Organophosphorus pesticide, long-term consumption can cause the cumulative poison of human body, influence life and health, and may trigger a variety of chronic
Disease.
Daily people are before edible fruits vegetables, and universal cleaning mode is rinsed repeatedly using clear water, or is poured boiling water on
Scald.Although this cleaning mode can wash away the dirt of fruit and vegetable surfaces, for its remaining agricultural chemicals and bacterium, bacterium, disease
The microorganisms such as poison are but extremely difficult to thorough removing.And then, people are cleaned using fruit cleaning agent, still, conventional fruit
Cleaning agent is typically only capable to remove the wax and greasy dirt of fruit surface, and the removal effect to Organic pesticide residues is not good.
Chinese patent CN104694276A discloses a kind of releasing residues of pesticides cleaning agent and its preparation method and application, its
Main component is：1~2 gram of biology enzyme, 0.1~0.5 gram of carboxymethyl cellulose sodium, 0.2~1 gram of polypropylene glycerol aether, polyoxy second
Alkene polyoxypropylene amidogen ether, 1 gram of malic acid, 1 gram of potassium citrate, 10~15 grams of lauroylamidopropyl betaine, deionized water 87.7
~82 grams, each group composition is well mixed under certain condition colorless and transparent cleaning agent is made, gourd, fruit and vegetable, beans can be released
The remainss of pesticide such as class, five cereals, sterilizing decontamination, go heavy metal, the removing toxic substances of meat hormone, it is easy to clean, non-secondary pollution, safety
Health, category green removing toxic substances articles for washing.But, the preparation process of the patented product is cumbersome, biological enzyme preparation condition of storage is harsh,
It can not preserve for a long time, moreover, the patented product opens the epidermal cell and then degrading pesticide residues of fruits and vegetables by biology enzyme,
Need the long period to act on vegetables and fruits surface and can be only achieved preferable degradation effect, organic matter can be brought residual in fruit and vegetable surfaces on the contrary
The hidden danger stayed.
The content of the invention
To solve the above mentioned problem that prior art is present, it is an object of the invention to provide a kind of to organic phosphorus pesticide degradation
Effect is good, degradation speed is fast, being capable of effective SODIUM PERCARBONATE powdered cleanser of disinfection and its preparation method and application.
To achieve the above object, the technical solution adopted in the present invention is：
A kind of SODIUM PERCARBONATE powdered cleanser, includes following component by weight percentage：
SODIUM PERCARBONATE 60%~80%,
Neopelex 2%~5%,
Sodium alkyl sulfonate 1%~3%,
MES 1%~4%,
Fat alcohol polyethylene ether sulfate 1%~5%,
Manganese sulfate 0.2%~1%,
Anhydrous sodium sulfate 10%~15%,
Menthol 0.5%~1%.
Preferably comprise following component by weight percentage：
SODIUM PERCARBONATE 65%~78%,
Neopelex 2.5%~4%,
Sodium alkyl sulfonate 1.5%~2.5%,
MES 1.2%~2%,
Fat alcohol polyethylene ether sulfate 2%~4%,
Manganese sulfate 0.5%~0.9%,
Anhydrous sodium sulfate 12%~14%,
Menthol 0.55%~0.8%.
Most preferably comprise following component by weight percentage：
SODIUM PERCARBONATE 75%,
Neopelex 3%,
Sodium alkyl sulfonate 2%,
MES 2%,
Fat alcohol polyethylene ether sulfate 3%,
Manganese sulfate 0.8%,
Anhydrous sodium sulfate 13.6%,
Menthol 0.6%.
Further improvement of the present invention is：The carbon number of alkyl is 5~15, preferably 8 in the sodium alkyl sulfonate
~13；The carbon number of fatty alcohol radical is 5~12, preferably 6~10 in the MES；The poly alkyl alcohol
The carbon number of fatty alcohol radical is 5~12, preferably 6~10 in ethene ether sulfate.
Further improvement of the present invention is：The MES is methyl sodiosul foaliphatate, the fat
Fat alcohol polyvinylether sulfate is fat alcohol polyethylene ether zinc sulfate.
A kind of preparation method of SODIUM PERCARBONATE powdered cleanser, comprises the following steps：
A, by raw material neopelex, sodium alkyl sulfonate, MES, fat alcohol polyethylene ether sulphur
Hydrochlorate, manganese sulfate and anhydrous sodium sulfate are dried to constant weight in drying equipment respectively；
B, SODIUM PERCARBONATE, neopelex, sodium alkyl sulfonate, MES, fat are weighed by proportioning
Fat alcohol polyvinylether sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into mixing plant and are stirred mixing, and mixing is equal
Stop stirring after even；
C, compound obtained by step B is put into milling apparatus be fully ground, up to powder particles reach 80~200
Mesh, produces SODIUM PERCARBONATE powdered cleanser finished product；After powder is dispensed, sealing preserve.
In the step A, drying equipment is air dry oven, 70 DEG C~80 DEG C of drying temperature；In the step B, stirring
Equipment is stirred tank, and mixing time is 40min~60min, mixing speed 60r/min；In the step C, milling apparatus is super
Thin ball mill, each Ball-milling Time 5min, ball milling number of times is no less than 3 times.
A kind of application of SODIUM PERCARBONATE powdered cleanser, is concretely comprised the following steps：By SODIUM PERCARBONATE powdered cleanser and water
According to mass ratio 1:5 progress is dissolved, and detergent solution is made, be then sprayed directly on fruit and vegetable surfaces rub 3min~
Fruits and vegetables are immersed in detergent solution taking-up after 3min~5min by 5min, are edible after clear water is clean.
The beneficial effects of the invention are as follows：
The invention provides a kind of SODIUM PERCARBONATE powdered cleanser, good degrading effect, disinfection effect are high, green ring
Protect, it is easy to use.SODIUM PERCARBONATE cleaning agent can make the organophosphorus pesticide fast degradation of fruits and vegetables foodstuff surface be water solubility
Product, degradation efficiency is up to more than 99%；Cleaning agent has abundant surface active function and disinfection effect, energy simultaneously
Enough while cleaning greasy residues, fully removing wax, the impurity and residues of pesticides of fruit surface are effectively removed, it is ensured that fruits and vegetables
The health that the health of food and people eat.The degradation speed of product of the present invention is fast, therefore without soaking for a long time when using,
Plus raw materials used mostly water solubility, consequence vegetable foodstuff surface not residual organic matter is washed, two are brought when effectively prevent cleaning
Secondary pollution.
Product of the present invention is powder detergent, and powder granularity is small, is easy to quickly dissolve in water；Meanwhile, it is powdered clear
Clean dose is easy to long term storage and long-distance transport, easy to use.
Raw material SODIUM PERCARBONATE is a kind of efficient solid oxidizer, is the addition compound of sodium carbonate and hydrogen peroxide, tool
There is the features such as good stability, easy storage, nontoxic odorless, environmentally safe, bleaching, sterilization, its good water solubility, dissolving produces strong
The hydrogen peroxide of oxidisability, hydrogen peroxide acts on organophosphorus pesticide, is degraded to water miscible small molecule product, shows
Write reduction residues of pesticides；Meanwhile, hydrogen peroxide also has powerful bactericidal action, can be to the virus and bacteria of fruits and vegetables foodstuff surface
Effectively kill and remove.In order to improve the degraded sterilization speed of SODIUM PERCARBONATE, the present invention is specifically added appropriate manganese sulfate, passes through sulphur
The catalytic action of sour manganese, greatly improves the cleaning speed of cleaning agent.
Neopelex, sodium alkyl sulfonate, MES, fatty alcohol are also included in raw material of the present invention
Four kinds of surface active ingredients of polyvinylether sulfate, and specific species to each composition, specific consumption have carried out detailed restriction；This
After a little surface active ingredient compoundings, the elimination effect of the impurity such as greasy dirt, the wax of fruits and vegetables foodstuff surface can be made to reach most preferably.By
There is good deoiling effect in raw material of the present invention, therefore, can also be applied to kitchen utensils, car glass, building inner-outer wall, do
The cleaning of public tool, kitchen surface etc., cleaning efficiency is high, easy to use, safety and environmental protection.
Appropriate menthol is also included in raw material of the present invention, menthol adjusts the taste type of cleaning agent as odor type agent；Simultaneously
Menthol also have refrigerant effect, can as washing degree sign, i.e., cleaned after fruits and vegetables food, rinsed with water with cleaning agent
Until refrigerant sense disappears.
Anhydrous sodium sulfate is also included in raw material of the present invention, as cheap diluent.It is anhydrous in cleaning agent preparation process
Sodium sulphate increases powder density, and good fluidity prevents powder from luming.
Invention also provides the preparation method of SODIUM PERCARBONATE cleaning agent, technique is simple and convenient to operate, and is set using conventional
It is standby, and without pollutant emission, meet the requirement of clean manufacturing, be easy to industrialization promotion.
Invention also provides the application of SODIUM PERCARBONATE cleaning agent, application process is simple, is directly dissolved in water, just
Used in family；The removal of fruit and vegetable surfaces residual organic phosphorus agricultural chemicals is cannot be only used for, while being efficient cleaning agent again, it is adaptable to
The cleaning of oil stain, spot etc..
Embodiment
The present invention is described in further detail below by specific embodiment, but embodiment is not the scope of the present invention
Limitation.
In the examples below that, used raw material manufacturer and purity are as shown in the table, and remaining raw material is commercially available
Product.
| Material name | Manufacturer | Purity |
| SODIUM PERCARBONATE | Wujiang Dong Noboru Fine Chemical Co., Ltd | >13.5% |
| Neopelex | Dongying Hai Wang commerce and trade Co., Ltd | >40% |
| Manganese sulfate | Zhengzhou Yu Qiang foreign trades Co., Ltd | >98% |
| Anhydrous sodium sulfate | Zibo Hua Yan Chemical Co., Ltd.s | >99% |
In the examples below that, the detection method of fruits and vegetables foodstuff surface organophosphorus residue is gas chromatography, specific method
With reference to GB/T 14553-2003.
Embodiment 1
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 75g, neopelex 3g, penta
Alkyl sulfonic acid sodium 2g, methyl undecylate sodium sulfonate 2g, lauryl alcohol polyvinylether zinc sulfate 3g, manganese sulfate 0.8g, anhydrous sodium sulfate
13.6g, menthol 0.6g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, sodium pentanesulfonate, methyl undecylate sodium sulfonate, lauryl alcohol polyvinylether sulfuric acid
Zinc, manganese sulfate and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, sodium pentanesulfonate, methyl undecylate sodium sulfonate, ten are weighed by proportioning
Glycol polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed
Stop after 60r/min, stirring 40min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 80~100 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.After powder is dispensed, seal
Preserve.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 1, dissolves in 5g water, detergent solution is made.
Apple, grape, cucumber, the rape that same batch is bought immerse 4min in detergent solution, and then washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 1.
The cleaning agent cleaning effect tables of data of 1 embodiment of table 1
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 1, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 1 organophosphorus pesticide the most frequently used to four kinds is very notable.
Embodiment 2
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 74.8g, neopelex
3.5g, sodium pentanesulfonate 2.5g, methyl undecylate sodium sulfonate 1.5g, lauryl alcohol polyvinylether zinc sulfate 2.5g, manganese sulfate
0.75g, anhydrous sodium sulfate 13.9g, menthol 0.55g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, amyl group sodium sulfonate, methyl undecylate sulfonate, lauryl alcohol polyvinylether sulfuric acid
Zinc, manganese sulfate and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, sodium pentanesulfonate, methyl undecylate sulfonate, ten are weighed by proportioning
Glycol polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed
Stop after 60r/min, stirring 40min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 100~200 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.After powder is dispensed, it is close
Envelope is preserved.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 2, dissolves in 5g water, detergent solution is made.
Apple, grape, cucumber, the rape that same batch is bought immerse 3min in detergent solution, and then washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 2.
The cleaning agent cleaning effect tables of data of 2 embodiment of table 2
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 2, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 2 organophosphorus pesticide the most frequently used to four kinds is very notable.
Embodiment 3
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 78g, neopelex 2g, penta
Alkyl sulfonic acid sodium 1.5g, methyl undecylate sodium sulfonate 3g, ten alcohol polyvinylether zinc sulfate 2g, manganese sulfate 0.85g, anhydrous sodium sulfate
12g, menthol 0.65g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, sodium pentanesulfonate, methyl undecylate sulfonate, lauryl alcohol polyvinylether sulfuric acid
Zinc, manganese sulfate and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, sodium pentanesulfonate, methyl undecylate sulfonate, ten are weighed by proportioning
Glycol polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed
Stop after 60r/min, stirring 45min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 80-150 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.After powder is dispensed, seal
Preserve.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 1, dissolves in 5g water, detergent solution is made.
Apple, grape, cucumber, the rape that same batch is bought immerse 5min in detergent solution, and then washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 3.
The cleaning agent cleaning effect tables of data of 3 embodiment of table 3
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 3, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 3 organophosphorus pesticide the most frequently used to four kinds is very notable.
Embodiment 4
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 66g, neopelex 5g, it is pungent
Alkyl sulfonic acid sodium 3g, methyl caprate sodium sulfonate 4g, octanol polyvinylether zinc sulfate 5g, manganese sulfate 1g, anhydrous sodium sulfate 15g, peppermint
Alcohol 1g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, perfluorooctane sulfonate, methyl caprate sodium sulfonate, octanol polyvinylether zinc sulfate, sulphur
Sour manganese and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, perfluorooctane sulfonate, methyl caprate sodium sulfonate, octanol are weighed by proportioning
Polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed 60r/
Stop after min, stirring 40min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 80~100 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.
After powder is dispensed, sealing preserve.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 4, dissolves in 5g water, detergent solution is made.
Detergent solution is sprayed directly on the apple of same batch purchase, grape, cucumber, rape surface, 5min is rubbed with hand, then
Washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 4.
The cleaning agent cleaning effect tables of data of 4 embodiment of table 4
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 4, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 4 organophosphorus pesticide the most frequently used to four kinds is very notable.
Embodiment 5
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 80g, neopelex 2.5g,
Tridecane sodium sulfonate 3.5g, methyl caproate sodium sulfonate 2g, decyl alcohol polyvinylether zinc sulfate 1g, manganese sulfate 0.5g, anhydrous sodium sulfate
10g, menthol 0.5g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, tridecane sodium sulfonate, methyl caproate sodium sulfonate, decyl alcohol polyvinylether zinc sulfate,
Manganese sulfate and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, tridecane sodium sulfonate, methyl caproate sodium sulfonate, the last of the ten Heavenly stems are weighed by proportioning
Alcohol polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed
Stop after 60r/min, stirring 40min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 80~100 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.After powder is dispensed, seal
Preserve.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 5, dissolves in 5g water, detergent solution is made.
Detergent solution is sprayed directly on the apple of same batch purchase, grape, cucumber, rape surface, 3min is rubbed with hand, then
Washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 5.
The cleaning agent cleaning effect tables of data of 5 embodiment of table 5
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 5, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 5 organophosphorus pesticide the most frequently used to four kinds is very notable.
Embodiment 6
A kind of SODIUM PERCARBONATE powdered cleanser, includes following components：SODIUM PERCARBONATE 72.5g, neopelex 4g,
Sodium heptanesulfonate 2.5g, methyl valerate sodium sulfonate 1.2g, undecyl alcohol polyvinylether zinc sulfate 4g, manganese sulfate 0.9g, anhydrous slufuric acid
Sodium 14g, menthol 0.9g.
The preparation method of the SODIUM PERCARBONATE powdered cleanser is：
A, by neopelex, sodium heptanesulfonate, methyl valerate sodium sulfonate, undecyl alcohol polyvinylether zinc sulfate,
Manganese sulfate and anhydrous sodium sulfate are dried to constant weight, 70 DEG C~80 DEG C of drying temperature in air dry oven respectively；
B, SODIUM PERCARBONATE, neopelex, sodium heptanesulfonate, methyl valerate sodium sulfonate, 11 are weighed by proportioning
Alcohol polyvinylether zinc sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into stirred tank and are stirred mixing, mixing speed
Stop after 60r/min, stirring 45min, obtain uniform compound；
C, compound obtained by step B is put into ultra-fine ball mill be ground, each milling time 5min is co-mulled and made into three
Secondary, powder particles reach 80~100 mesh, produce SODIUM PERCARBONATE powdered cleanser finished product 100g.After powder is dispensed, seal
Preserve.
SODIUM PERCARBONATE powdered cleanser product 1g prepared by Example 6, dissolves in 5g water, detergent solution is made.
Detergent solution is sprayed directly on the apple of same batch purchase, grape, cucumber, rape surface, 3min is rubbed with hand, then
Washing is washed down.
The organophosphorus pesticide of fruit and vegetable surfaces before and after detection cleaning, detection data are shown in Table 6.
The cleaning agent cleaning effect tables of data of 6 embodiment of table 6
The organophosphorus pesticide clearance on four kinds of vegetables and fruits surfaces is not less than 99% it can be seen from data in table 6, and highest can
Up to 100%, it was demonstrated that the removal effect of the product of embodiment 6 organophosphorus pesticide the most frequently used to four kinds is very notable.
Above-described embodiment is used for illustrating the present invention, rather than limits the invention, in the claims in the present invention
Protection domain in, to any modifications and changes for making of the present invention, both fall within protection scope of the present invention.
Claims (9)
1. a kind of SODIUM PERCARBONATE powdered cleanser, it is characterised in that include following component by weight percentage：
SODIUM PERCARBONATE 60%~80%,
Neopelex 2%~5%,
Sodium alkyl sulfonate 1%~3%,
MES 1%~4%,
Fat alcohol polyethylene ether sulfate 1%~5%,
Manganese sulfate 0.2%~1%,
Anhydrous sodium sulfate 10%~15%,
Menthol 0.5%~1%.
2. a kind of SODIUM PERCARBONATE powdered cleanser according to claim 1, it is characterised in that comprising by weight percentage
Following component：
SODIUM PERCARBONATE 65%~78%,
Neopelex 2.5%~4%,
Sodium alkyl sulfonate 1.5%~2.5%,
MES 1.2%~2%,
Fat alcohol polyethylene ether sulfate 2%~4%,
Manganese sulfate 0.5%~0.9%,
Anhydrous sodium sulfate 12%~14%,
Menthol 0.55%~0.8%.
3. a kind of SODIUM PERCARBONATE powdered cleanser according to claim 2, it is characterised in that comprising by weight percentage
Following component：
SODIUM PERCARBONATE 75%,
Neopelex 3%,
Sodium alkyl sulfonate 2%,
MES 2%,
Fat alcohol polyethylene ether sulfate 3%,
Manganese sulfate 0.8%,
Anhydrous sodium sulfate 13.6%,
Menthol 0.6%.
4. a kind of SODIUM PERCARBONATE powdered cleanser according to any one of claims 1 to 3, it is characterised in that：The alkyl
The carbon number of alkyl is 5~15 in sodium sulfonate, in the MES fatty acid-based carbon number for 5~
12, the carbon number of fatty alcohol radical is 5~12 in the fat alcohol polyethylene ether sulfate.
5. a kind of SODIUM PERCARBONATE powdered cleanser according to claim 4, it is characterised in that：Alkane in the sodium alkyl sulfonate
The carbon number of base is 8~13, and fatty acid-based carbon number is 6~10, the fat in the MES
The carbon number of fatty alcohol radical is 6~10 in alcohol polyvinylether sulfate.
6. a kind of SODIUM PERCARBONATE powdered cleanser according to claim 5, it is characterised in that：The fatty acid methyl ester sulfonic acid
Salt is methyl sodiosul foaliphatate, and the fat alcohol polyethylene ether sulfate is fat alcohol polyethylene ether zinc sulfate.
7. a kind of preparation method of SODIUM PERCARBONATE powdered cleanser as claimed in claim 1, it is characterised in that including following step
Suddenly：
A, by raw material neopelex, sodium alkyl sulfonate, MES, fat alcohol polyethylene ether sulfuric acid
Salt, manganese sulfate and anhydrous sodium sulfate are dried to constant weight in drying equipment respectively；
B, SODIUM PERCARBONATE, neopelex, sodium alkyl sulfonate, MES, fatty alcohol are weighed by proportioning
Polyvinylether sulfate, manganese sulfate, anhydrous sodium sulfate, menthol, are put into mixing plant and are stirred mixing, after being well mixed
Stop stirring；
C, compound obtained by step B is put into milling apparatus be fully ground, up to powder particles reach 80~200 mesh,
Produce SODIUM PERCARBONATE powdered cleanser finished product；After powder is dispensed, sealing preserve.
8. a kind of preparation method of SODIUM PERCARBONATE powdered cleanser according to claim 7, it is characterised in that：The step
In A, drying equipment is air dry oven, 70 DEG C~80 DEG C of drying temperature；In the step B, mixing plant is stirred tank, stirring
Time is 40min~60min, mixing speed 60r/min；In the step C, milling apparatus is ultra-fine ball mill, each ball milling
Time 5min, ball milling number of times is no less than 3 times.
9. a kind of application of SODIUM PERCARBONATE powdered cleanser as claimed in claim 1, it is characterised in that：By SODIUM PERCARBONATE powder
Cleaning agent is with water according to mass ratio 1:5 progress is dissolved, and detergent solution is made, and is then sprayed directly on fruit and vegetable surfaces and rubbed
Rub 3min~5min with the hands or fruits and vegetables are immersed in detergent solution after 3min~5min and take out, be edible after clear water is clean.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110117913A (en) * | 2019-05-22 | 2019-08-13 | 佛山市欣比美纺织有限公司 | A kind of dyeing liquid and preparation method thereof of natural herb drug |
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| CN1597897A (en) * | 2004-08-06 | 2005-03-23 | 大连小荷化工有限公司 | Solid cleaning agent for residual pesticide on fruit and vegetable |
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