CN106833945A - Biological fruit and vegetable enzyme cleaning fluid and its preparation method and application - Google Patents
Biological fruit and vegetable enzyme cleaning fluid and its preparation method and application Download PDFInfo
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- CN106833945A CN106833945A CN201510880468.9A CN201510880468A CN106833945A CN 106833945 A CN106833945 A CN 106833945A CN 201510880468 A CN201510880468 A CN 201510880468A CN 106833945 A CN106833945 A CN 106833945A
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Abstract
The invention discloses a kind of biological fruit and vegetable enzyme cleaning fluid, by weight, the biological fruit and vegetable enzyme cleaning fluid is made up of following component：Surfactant 15% ~ 25%, chelating agent 0.2% ~ 0.5%, enzyme preparation 1%~5%, enzyme stabilizers 0.1% ~ 0.5%, preservative 0.1% ~ 0.5%, glucose 1% ~ 5%, balance of deionized water.When biological fruit and vegetable enzyme cleaning fluid of the invention is used to clean fruits and vegetables, each component synergy in biological fruit and vegetable enzyme cleaning fluid, the particularly synergy of enzyme preparation and surfactant, complex enzyme can decompose or degrade organophosphorus pesticide, protein-based botanical pesticide and ester, the amide-type novel agrochemical remained on fruits and vegetables, and the product after decomposing or degrading is rapid to be removed by surfactant；Meanwhile, biological fruit and vegetable enzyme cleaning fluid of the invention can also effectively remove the various bacteriums in fruits and vegetables, surfactant noresidue, healthy and safe after cleaning fruits and vegetables.
Description
Technical field
The present invention relates to detergent technical field, more particularly to a kind of biological fruit and vegetable enzyme cleaning fluid and its preparation method and application.
Background technology
As the contaminated fruits and vegetables of institute are more and more universal on the market, people are also more and more higher to its worry, and the cleaning of fruits and vegetables just seems more and more important.Found the 6 big city Pesticide Residues in Vegetables exceeding standard rates such as the total recall rate 32% of fruit, pesticide residues in vegetables medicine, wherein total exceeding standard rate 25%, Beijing more than 50% according to Ministry of Agriculture's monitoring.Solving Pesticide Residue turns into one of key subject of raising fruit-vegetable quality.Disperse because agricultural products in China is produced, agricultural sector's difficult regulatory, Pesticide use knowledge of the peasant general lack of science, excess and nearly maturity period use, covet yield, cause the Pesticide Residue of China's fruit and vegetable food generally than more serious, wherein annual second and third residues of pesticides recall rate 40% or so in season, first, fourth season is 25% or so.
Common agricultural chemicals has organophosphor, organochlorine, pyrethroid and carbamates, and organophosphor includes demeton, parathion, thimet, malathion, Rogor, DDVP, metrifonate, Hostathion, phoxim and Profenofos；Organochlorine includes DDT, 666,889, Niran and toxaphene；Pyrethroid includes cypermethrin, Fenpropathrin, lambda-cyhalothrin, decis, fenvalerate and Permethrin；Carbamates includes arprocarb, MTMC, sevin, Aldicarb, carbofuran, isoprocarb and Aphox.The chemical constitution of agricultural chemicals is complicated, clear water typically cannot washes clean, therefore edible fruits and vegetables poisoning and the phenomenon that accumulates poisoning happen occasionally, particularly all kinds of unit dining rooms, restaurant because clean it is half-hearted caused by colony's intoxicating phenomenon occur often.At present, someone is replaced with dish washing detergent, although can wash away the part agricultural chemicals of remained on surface, but simultaneously also containing such as：The discomfort composition such as potassium permanganate, sodium hypochlorite, calcium hypochlorite, sodium tripolyphosphate, potassium pyrophosphate, tertiary sodium phosphate, because these products are only starting point from " cleaning dilutes " this purpose, and do not focus on products material toxicity in itself, its uncomfortable composition for containing, causes secondary pollution to be poisoned no less than residues of pesticides.And especially but although the remains of pesticide cleaning class product containing biology enzyme has few to be exclusively used in the product of fruit-vegetable pesticide residues cleaning class, the existing fast washing lotion of effect more complete than sub- enzyme is a kind of cleaning fluid containing biology enzyme, but the fast washing lotion of effect more complete than sub- enzyme can only effectively remove organophosphorus insecticide, and can not effectively remove organochlorine, pyrethroid and carbamate chemicals for agriculture.Therefore, a kind of complex enzyme cleaning product of all kinds of farm chemical ingredients that can effectively remove and be remained on fruits and vegetables is developed to be even more important.
The content of the invention
The present invention solves the technical problem of a kind of biological fruit and vegetable enzyme cleaning fluid of offer, when the biological fruit and vegetable enzyme cleaning fluid is used to clean fruits and vegetables, each component synergy in biological fruit and vegetable enzyme cleaning fluid, the particularly synergy of enzyme preparation and surfactant, complex enzyme can decompose or degrade organophosphorus pesticide, protein-based botanical pesticide and ester, the amide-type novel agrochemical remained on fruits and vegetables, and the product after decomposing or degrading is rapid to be removed by surfactant；Meanwhile, biological fruit and vegetable enzyme cleaning fluid of the invention can also effectively remove the various bacteriums in fruits and vegetables, surfactant noresidue, healthy and safe after cleaning fruits and vegetables.
In order to solve the above technical problems, one aspect of the present invention is：A kind of biological fruit and vegetable enzyme cleaning fluid is provided, by weight, the biological fruit and vegetable enzyme cleaning fluid is made up of following component：
Surfactant 15% ~ 25%；
Chelating agent 0.2% ~ 0.5%；
Enzyme preparation 1%~5%；
Enzyme stabilizers 0.1% ~ 0.5%；
Preservative 0.1% ~ 0.5%；
Glucose 1% ~ 5%；
Balance of deionized water.
Preferably, the surfactant be nonionic surfactant, imidazoline amophoteric surface active agent in one or two.The nonionic surfactant, imidazoline amophoteric surface active agent source are healthy and safe, with effects such as emulsification, infiltration, foamings, enzyme preparation can be helped quickly to reach the surface of fruits and vegetables, enzyme preparation is promoted to decompose remains of pesticide and spot on fruits and vegetables, meanwhile, the nonionic surfactant, imidazoline amophoteric surface active agent can also quickly remove the product produced after enzyme preparation decomposing pesticide and spot.
It is highly preferred that the nonionic surfactant be alcohol ether glucoside, APG in one or two.The alcohol ether glucoside is nontoxic, non-stimulated, be readily biodegradable, with preserving moisture and protecting skin effect, the excitant of integral formula can be significantly reduced, low-temperature water-soluble is good, resistance to hard water, has good thickening efficiency to formula system, can be compounded with all kinds of active matters, stable chemical nature, to human body and Environmental security.In addition, the cost of material of alcohol ether glucoside and product price are cheap, cost performance is high, application field is extensive, is new, multi-functional green surfactant.APG is a kind of novel green functional surfactant, is obtained by natural fatty alcohol and natural carbohydrate, no matter at aspects such as ecotoxicologicals, or is all safe in terms of dermatology.
Most preferably, the carbon number of the alkyl of the APG is 8 ~ 14.The carbon number is 8 ~ 14 APG, is processed with the other glucose of medical grade by the other palm oil of food grade or coconut oil, and moderate performance, foam appropriateness, dirt-removing power are strong, with outstanding skin-friendliness.
Preferably, the chelating agent be citric acid, sodium gluconate in one or two.The chelating agent can chelate calcium, magnesium ion in water, calcium especially in hard water, magnesium ion, make the calcium in water, magnesium ion will not the function of Surfactant have a negative impact
Preferably, the enzyme preparation is made up of esterase, protease and glucose oxidase.Esters, via hydrolysis, are cut into acids and alcohols by esterase in the presence of hydrone, ester, amide-type novel agrochemical and organophosphorus pesticide on esterase decomposition fruits and vegetables.The hydrogen peroxide that glucose oxidase is produced by oxidizing glucose is come degrading organic phosphor pesticides.Protease has stronger hydrolysis, chain rupture, stripping and degradation capability to protein-based botanical pesticide.
Preferably, the enzyme stabilizers be ethanol, glycerine, borax in one or more.The stabilizer can improve the stability of enzyme preparation, extend the period of storage of biological fruit and vegetable enzyme cleaning fluid of the present invention.Meanwhile, ethanol can improve each component solubility in deionized water in biological fruit and vegetable enzyme cleaning fluid of the present invention, while also bactericidal action also as solubilizer.
Preferably, the preservative be methyl hydroxybenzoate, propylben, sorbic acid and its salt in one or more.The preservative can extend the period of storage of biological fruit and vegetable enzyme cleaning fluid of the present invention.
In order to solve the above technical problems, another technical solution used in the present invention is：A kind of preparation method of described biological fruit and vegetable enzyme cleaning fluid is provided, is comprised the following steps：
A, to addition deionized water gross mass in ingredients pot 50% ~ 60%；
B, input chelating agent, stirring is to being completely dissolved；
C, input surfactant, are heated to 50 DEG C ~ 60 DEG C, and stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, preservative is put into；
F, input enzyme stabilizers and glucose, stir；
G, input enzyme preparation, stir；
H, regulation pH value obtain the biological fruit and vegetable enzyme cleaning fluid between 6.5 ~ 7.5.
Present invention also offers the application of described biological fruit and vegetable enzyme cleaning fluid, when directly cleaning fruits and vegetables, Jia 1 on fruits and vegetables ~ 5ml biological fruit and vegetable enzyme cleaning fluids, rinsed well after cleaning；During soaking and washing fruits and vegetables, 1 ~ 5ml biological fruit and vegetable enzyme cleaning fluids are added in a reservoir, add 500 ~ 1000ml water, fruits and vegetables are placed in after being soaked 5 ~ 10 minutes in container and rinsed well.
The beneficial effects of the invention are as follows：Secondary pollution is easily formed for the cleaning agent for being currently used for cleaning fruits and vegetables, lack the situation that can remove the complex enzyme cleaning fluid of Multiple Pesticides residual on fruits and vegetables, when biological fruit and vegetable enzyme cleaning fluid of the invention is used to clean fruits and vegetables, each component acts synergistically, the particularly synergy of complex enzyme and surfactant, complex enzyme can decompose or degrade the organophosphorus pesticide remained on fruits and vegetables, protein-based botanical pesticide and ester, amide-type novel agrochemical, i.e. esterase decomposes the ester on fruits and vegetables, amide-type novel agrochemical and organophosphorus pesticide, the organophosphorus pesticides by hydrogen peroxide that glucose oxidase glucose is produced, the protein-based botanical pesticide of proteases for decomposing, product after decomposing or degrading is rapid by surfactant removing；Meanwhile, biological fruit and vegetable enzyme cleaning fluid of the invention can also effectively remove the various bacteriums in fruits and vegetables, surfactant noresidue, healthy and safe after cleaning fruits and vegetables.
Biological fruit and vegetable enzyme cleaning fluid of the invention has further the advantage that：
1st, it is gentle non-stimulated in faintly acid or neutrality, do not hurt hands safely；
2nd, food grade materials are natural gentle；
3rd, composition is pure, without essence, pigment, safety non-toxic.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
Surfactant, chelating agent, enzyme preparation, enzyme stabilizers, preservative, glucose in embodiment can commercially, and such as enzyme preparation can be bought from Shenzhen Leveking Biology Engineering Co., Ltd.
Embodiment 1
The formula of biological fruit and vegetable enzyme cleaning fluid is as follows：By weight, APG（Atomic number of alkyl carbon is 8 ~ 14）3.5%th, APG（Atomic number of alkyl carbon is 12 ~ 14）6.5%, imidazoline amophoteric surface active agent 2.5%, alcohol ether glucoside 2.5%, sodium gluconate 0. 2%, citric acid 0.3%, enzyme preparation 5%（Esterase 3%, protease 1%, glucose oxidase 1%）, ethanol 0.3%, glycerine 0.2%, potassium sorbate 0.2%, methyl hydroxybenzoate 0.2%, propylben 0.1%, glucose 5%, deionized water 73.5%.
The preparation method of biological fruit and vegetable enzyme cleaning fluid：
Each component is weighed by above-mentioned formula, it is standby.Prepare according to the following steps：
A, to addition deionized water gross mass in ingredients pot 50% ~ 60%；
B, input chelating agent, stirring is to being completely dissolved；
C, input surfactant, are heated to 50 DEG C ~ 60 DEG C, and stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, preservative is put into；
F, input enzyme stabilizers and glucose, stir；
G, input enzyme preparation, stir；
H, regulation pH value obtain the biological fruit and vegetable enzyme cleaning fluid between 6.5 ~ 7.5.
Embodiment 2
The formula of biological fruit and vegetable enzyme cleaning fluid is as follows：By weight, APG（Atomic number of alkyl carbon is 8 ~ 14）4.5%th, APG（Atomic number of alkyl carbon is 12 ~ 14）7.5%, amphoteric imidazoline surfactant 3.5%, alcohol ether glucoside 4.5%, sodium gluconate 0.35%, enzyme preparation 3%（Esterase 1%, proteinase-10 .8%, glucose oxidase 1.2%）, borax 0.3%, potassium sorbate 0.3%, glucose 3%, deionized water 73.05%.The preparation method of biological fruit and vegetable enzyme cleaning fluid is same as Example 1.
Embodiment 3
The formula of biological fruit and vegetable enzyme cleaning fluid is as follows：By weight, APG（Atomic number of alkyl carbon is 8 ~ 14）5.5%th, APG（Atomic number of alkyl carbon is 12 ~ 14）9.5%, alcohol ether glucoside surfactant 10%, sodium gluconate 0.1%, citric acid 0.1%, enzyme preparation 1%（Esterase 0.6%, proteinase-10 .2%, glucose oxidase 0.2%）, ethanol 0.1%, methyl hydroxybenzoate 0.1%, glucose 1%, deionized water 72.6%.The preparation method of biological fruit and vegetable enzyme cleaning fluid is same as Example 1.
Embodiment 4
The Performance comparision of the performance of biological fruit and vegetable enzyme cleaning fluid of the invention and the fruits and vegetables cleaning fluid of the country.
Biological fruit and vegetable enzyme cleaning fluid of the invention does not detect fluorescent whitening agent, and the normal temperature shelf-life is 24 months.
Choose the domestic fruits and vegetables cleaning fluid sold market and be respectively the fast washing lotion of effect more complete than sub- enzyme, brave and fierce Mr.'s multipurpose liquid detergent, fast clean suitable little Huang ducks vegetables and fruits dish liquid detergent opens a meter vegetables and fruits cleaning agent.
First, pH value detection.
Regulation of the detection method with reference to GB/T6368.Test temperature is 25 DEG C, 1% sample solution concentration.Testing result is shown in Table 1：
The pH value comparative result of table 1
Reagent solution pH is in faintly acid or neutrality, on the skin of human body without influence；If reagent solution pH is in alkalescence, it is long-term or excessively using all can opponent cause certain corrosion.As shown in Table 1, biological fruit and vegetable enzyme cleaning fluid of the invention is gentle non-stimulated in faintly acid or neutrality, does not hurt hands safely.Comparatively speaking, the fast washing lotion of effect more complete than sub- enzyme and the fruits and vegetables cleaning agent of Kai meter vegetables and fruits cleaning agent two, its reagent pH value are affected using meeting opponent for a long time in alkalescence.
2nd, residues of pesticides clearance detection.
1 material and instrument
Fresh kidney beans（Purchased from the market of farm produce）, liquid chromatograph, high-speed homogenization machine, it is pure that acetonitrile, acetic acid, anhydrous calcium chloride, anhydrous magnesium sulfate are analysis；Standard sample of pesticide：Cypermethrin（Purity more than 95%）, arprocarb（Purity more than 95%）（There is provided by Changzhou Tian Ze Chemical Co., Ltd.s）；Organophosphorus pesticide（Purchased from flowers market）.
2 detection methods
Regulation of the detection method with reference to GB/T 24691-2009.
Pesticides removal rate computing formula：
Pesticides removal rate=（Sample removes persticide residue after preceding persticide residue-sample is removed）/ (sample removes preceding persticide residue) × 100%.
Testing result such as table 2：
The pesticides removal rate comparative result of table 2
As shown in Table 2, biological fruit and vegetable enzyme cleaning fluid of the invention is up to 99.99% to the clearance of cypermethrin, considerably beyond the domestic fruits and vegetables cleaning fluid that market has been sold；The clearance of arprocarb is suitable with brave and fierce Mr.'s multipurpose liquid detergent considerably beyond the fast washing lotion of effect more complete than sub- enzyme, fast clean suitable little Huang ducks fruit thinning dish liquid detergent and Kai meter vegetables and fruits cleaning agents up to 91.67% ~ 92.88%；The clearance of organophosphorus pesticide is up to 99.99%, considerably beyond the domestic fruits and vegetables cleaning fluid that market has been sold.As can be seen here, biological fruit and vegetable enzyme cleaning fluid of the invention removes the remains of pesticide effect is significant of fruits and vegetables, this is due to when biological fruit and vegetable enzyme cleaning fluid of the invention is used to clean fruits and vegetables, each component acts synergistically, the particularly synergy of enzyme preparation and surfactant, the various residues of pesticides that compound biological enzyme is directly or indirectly decomposed or degraded on fruits and vegetables, then the product after surfactant removes complex enzyme decomposition or degrading pesticide residues.
Those skilled in the art do not depart from essence of the invention and spirit, there can be various deformation scheme to realize the present invention, the foregoing is only preferably feasible embodiment of the invention, not thereby interest field of the invention is limited to, the equivalent structure change that all utilization description of the invention are made, is both contained within interest field of the invention.
Claims (10)
1. a kind of biological fruit and vegetable enzyme cleaning fluid, it is characterised in that by weight, the biological fruit and vegetable enzyme cleaning fluid is made up of following component：
Surfactant 15% ~ 25%；
Chelating agent 0.2% ~ 0.5%；
Enzyme preparation 1%~5%；
Enzyme stabilizers 0.1% ~ 0.5%；
Preservative 0.1% ~ 0.5%；
Glucose 1% ~ 5%；
Balance of deionized water.
2. biological fruit and vegetable enzyme cleaning fluid according to claim 1, it is characterised in that the surfactant is one or two in nonionic surfactant, imidazoline amophoteric surface active agent.
3. biological fruit and vegetable enzyme cleaning fluid according to claim 2, it is characterised in that the nonionic surfactant is one or two in alcohol ether glucoside, APG.
4. biological fruit and vegetable enzyme cleaning fluid according to claim 3, it is characterised in that the carbon number of the alkyl of the APG is 8 ~ 14.
5. biological fruit and vegetable enzyme cleaning fluid according to claim 1, it is characterised in that the chelating agent is one or two in citric acid, sodium gluconate.
6. biological fruit and vegetable enzyme cleaning fluid according to claim 1, it is characterised in that the enzyme preparation is made up of esterase, protease and glucose oxidase.
7. biological fruit and vegetable enzyme cleaning fluid according to claim 1, it is characterised in that the enzyme stabilizers are one or more in ethanol, glycerine, borax.
8. biological fruit and vegetable enzyme cleaning fluid according to claim 1, it is characterised in that the preservative is one or more in methyl hydroxybenzoate, propylben, sorbic acid and its salt.
9. the preparation method of the biological fruit and vegetable enzyme cleaning fluid described in any one of claim 1 ~ 8, it is characterised in that comprise the following steps：
A, to addition deionized water gross mass in ingredients pot 50% ~ 60%；
B, input chelating agent, stirring is to being completely dissolved；
C, input surfactant, are heated to 50 DEG C ~ 60 DEG C, and stirring is to being completely dissolved；
D, the remaining deionized water of addition；
When temperature of charge is less than 40 DEG C in E, pot, preservative is put into；
F, input enzyme stabilizers and glucose, stir；
G, input enzyme preparation, stir；
H, regulation pH value obtain the biological fruit and vegetable enzyme cleaning fluid between 6.5 ~ 7.5.
10. the application of the biological fruit and vegetable enzyme cleaning fluid described in any one of claim 1 ~ 8, it is characterised in that when directly cleaning fruits and vegetables, Jia 1 on fruits and vegetables ~ 5ml biological fruit and vegetable enzyme cleaning fluids, rinsed well after cleaning；During soaking and washing fruits and vegetables, 1 ~ 5ml biological fruit and vegetable enzyme cleaning fluids are added in a reservoir, add 500 ~ 1000ml water, fruits and vegetables are placed in after being soaked 5 ~ 10 minutes in container and rinsed well.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325903A (en) * | 2017-07-29 | 2017-11-07 | 安徽扬子生物科技有限公司 | A kind of fruits and vegetables preparation for removing fruit and vegetable residual pesticide and preparation method thereof |
| CN108192763A (en) * | 2018-01-23 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | One seed pod wax remover and preparation method thereof |
| CN108410851A (en) * | 2018-01-25 | 2018-08-17 | 北京森根比亚生物工程技术有限公司 | Enzyme fruits and vegetables cleaning agent and its preparation method and application |
| CN108998289A (en) * | 2018-09-26 | 2018-12-14 | 武汉新华扬生物股份有限公司 | Enzyme stabilizers, Recompounded pesticide hydrolysis enzyme solution and preparation method thereof and fruits and vegetables cleaning solution and preparation method thereof |
| CN109965189A (en) * | 2019-04-23 | 2019-07-05 | 深圳前海千水生物科技有限公司 | A kind of plant complex enzyme pesticide scavenger |
| CN111233234A (en) * | 2020-01-16 | 2020-06-05 | 广东丽臣奥威实业有限公司 | Recovery process of surfactant in wastewater and application of recovered liquid |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5728660A (en) * | 1993-04-05 | 1998-03-17 | Eet, Inc. | Extraction fluids for removal of contaminants from surfaces |
| JP2005281657A (en) * | 2004-03-29 | 2005-10-13 | Shinichiro Itoi | Detergent for vegetable/fruit |
| CN101070513A (en) * | 2006-05-11 | 2007-11-14 | 高旭 | Farm-chemical biological decomposing composition and preparing method |
| CN101380041A (en) * | 2008-10-16 | 2009-03-11 | 中国农业大学 | Method for reducing organophosphorus pesticide in soymilk |
| CN101469294A (en) * | 2007-12-30 | 2009-07-01 | 黄伟峰 | Cleaning agent for biologically removing garden stuff pesticide residue, preparation and use thereof |
| CN102618399A (en) * | 2012-03-19 | 2012-08-01 | 江苏爱特福84股份有限公司 | Composite capable of removing pesticide residue and disinfecting and preparation method thereof |
| CN102994488A (en) * | 2011-12-20 | 2013-03-27 | 辽宁中科生物工程有限公司 | Pesticide degradation enzyme preparation |
| WO2013043857A1 (en) * | 2011-09-20 | 2013-03-28 | The Procter & Gamble Company | Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants |
| CN103897876A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | A vegetable detergent |
| CN103911235A (en) * | 2014-03-25 | 2014-07-09 | 甘肃农业大学 | Effervescent tablet for removing pesticide residue |
-
2015
- 2015-12-04 CN CN201510880468.9A patent/CN106833945A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5728660A (en) * | 1993-04-05 | 1998-03-17 | Eet, Inc. | Extraction fluids for removal of contaminants from surfaces |
| JP2005281657A (en) * | 2004-03-29 | 2005-10-13 | Shinichiro Itoi | Detergent for vegetable/fruit |
| CN101070513A (en) * | 2006-05-11 | 2007-11-14 | 高旭 | Farm-chemical biological decomposing composition and preparing method |
| CN101469294A (en) * | 2007-12-30 | 2009-07-01 | 黄伟峰 | Cleaning agent for biologically removing garden stuff pesticide residue, preparation and use thereof |
| CN101380041A (en) * | 2008-10-16 | 2009-03-11 | 中国农业大学 | Method for reducing organophosphorus pesticide in soymilk |
| WO2013043857A1 (en) * | 2011-09-20 | 2013-03-28 | The Procter & Gamble Company | Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants |
| CN102994488A (en) * | 2011-12-20 | 2013-03-27 | 辽宁中科生物工程有限公司 | Pesticide degradation enzyme preparation |
| CN102618399A (en) * | 2012-03-19 | 2012-08-01 | 江苏爱特福84股份有限公司 | Composite capable of removing pesticide residue and disinfecting and preparation method thereof |
| CN103897876A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | A vegetable detergent |
| CN103911235A (en) * | 2014-03-25 | 2014-07-09 | 甘肃农业大学 | Effervescent tablet for removing pesticide residue |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325903A (en) * | 2017-07-29 | 2017-11-07 | 安徽扬子生物科技有限公司 | A kind of fruits and vegetables preparation for removing fruit and vegetable residual pesticide and preparation method thereof |
| CN108192763A (en) * | 2018-01-23 | 2018-06-22 | 深圳市芭格美生物科技有限公司 | One seed pod wax remover and preparation method thereof |
| CN108410851A (en) * | 2018-01-25 | 2018-08-17 | 北京森根比亚生物工程技术有限公司 | Enzyme fruits and vegetables cleaning agent and its preparation method and application |
| CN108998289A (en) * | 2018-09-26 | 2018-12-14 | 武汉新华扬生物股份有限公司 | Enzyme stabilizers, Recompounded pesticide hydrolysis enzyme solution and preparation method thereof and fruits and vegetables cleaning solution and preparation method thereof |
| CN109965189A (en) * | 2019-04-23 | 2019-07-05 | 深圳前海千水生物科技有限公司 | A kind of plant complex enzyme pesticide scavenger |
| CN111233234A (en) * | 2020-01-16 | 2020-06-05 | 广东丽臣奥威实业有限公司 | Recovery process of surfactant in wastewater and application of recovered liquid |
| CN111233234B (en) * | 2020-01-16 | 2022-03-22 | 广东丽臣奥威实业有限公司 | Recovery process of surfactant in wastewater |
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Application publication date: 20170613 |