CN101787334A - Pesticide residue removing and sterilizing detergent - Google Patents
Pesticide residue removing and sterilizing detergent Download PDFInfo
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- CN101787334A CN101787334A CN 201010120988 CN201010120988A CN101787334A CN 101787334 A CN101787334 A CN 101787334A CN 201010120988 CN201010120988 CN 201010120988 CN 201010120988 A CN201010120988 A CN 201010120988A CN 101787334 A CN101787334 A CN 101787334A
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Abstract
The invention provides a pesticide residue removing and sterilizing detergent containing chlorine dioxide, which is mainly prepared from a surfactant, a chelating agent, a thickening agent, a bactericide precursor, a pH regulator and deionized water according to a certain proportion by weight. The pesticide residue removing and sterilizing detergent has mild property, safety, environmental protection, biological degradability and no residue after use, and not only can be used for washing melons, fruits and vegetables, but also can be used for washing tableware, thereby realizing the one-step completion of decontamination, pesticide residue removal, sterilization and disinfection. The invention has good sterilizing effect, short acting time and high sterilization ratio by selecting the chlorine dioxide as a sterilizing component, carcinogens, such as chloroform and the like can not be generated in the use process, the tolerance of bacteria to the detergent can not be generated, and the detergent takes effect when used.
Description
Technical field
The present invention relates to effect type liquid detergent, relate in particular to and a kind ofly contain dioxide peroxide, can remove the residual disinfecting scrub essence of farming, it has set up the chlorine dioxide slow-release system based on surfactant system, and select for use this green surfactant of alkyl glycoside to remove farm chemical ingredients as main decontamination, safety and environmental protection, biodegradable, with the back noresidue.
Background technology
Along with the raising of people's living standard, people's health perception is also more and more higher, and not only gourmandism must be satisfied and eaten good things, and more will say to eat safely, eat relievedly.Wanting to eat healthyly, is not simple thing so, and at first, we are still residual a large amount of agricultural chemicals above the gourd, fruit and vegetable that market buys, and the toxicity that these agricultural chemicals have is big, desinsection fast even the agricultural chemicals that has country to prohibite.Soak, wash repeatedly with tap water, also can only remove a spot of agricultural chemicals.And on a kind of product, not only use a kind of agricultural chemicals, and usually be Multiple Pesticides and usefulness, five or six kinds at least, tens kinds at most.Secondly, it is not enough that our exhausted tableware only cleans with common detergent, and common detergent only has dirt-removing functions, does not possess disinfection function.
Research about effect type detergent at present mainly concentrates on the sterilization aspect, and to removing the residual research of farming and few.The domestic in recent years patent that discloses many about sterilization meal lotion, but the stain remover of selecting for use is similar, all is some commonly used aniorfic surfactant, and difference is the sterilant difference selected for use, Chinese medicine extract, Iodophor, triclosan, garlic are for example arranged, also have biotechnological formulation etc.As disclosing a kind of meal lotion that Radix Isatidis, honeysuckle flower, the root of large-flowered skullcap, rhizome of cyrtomium, flea are stopped Chinese medicine extract that adds among the CN1085944A, intestinal bacteria, dysentery bacterium are had significantly kill and restraining effect; Disclose a kind of detergent that the chlorhexidinium iodine of iodine and chlorhexidine acetate complexing formation is made as sterilant among the CN1105385A, can kill first, hepatitis B virus; Disclose a kind ofly among the CN101508941A, can kill intestinal bacteria, Salmonellas, streptococcus aureus by the detergent of subtilis CGMCC2294 fermentation broth extract as sterilant.
No matter be triclosan, Iodophor, Chinese medicine extract, or biological bactericide, the bacterial species that they are killed all has limitation; Report according to another the American Studies data, triclosan with contact through the tap water of chlorine disinfectant after, can produce trichloromethane gas, the people can cause depression, hepatopathy if long-term contact trichloromethane can suck by skin, or even cancer, so life-time service utilizes the detergent of triclosan as sterilant, and potential danger is arranged; The complicated process of preparation of fermentation of bacillus subtilis liquid extract is not suitable for suitability for industrialized production; Prepare detergent with garlic as sterilant, more unsuitable suitability for industrialized production, single angle from cost is considered just very improper, because garlic originally is direct-edible, it is added in the detergent, if catch up with garlic days in poor harvest, the production meeting of this detergent is restricted greatly.
In addition, commercially available detergent mostly is main component with the Sodium dodecylbenzene sulfonate at present, Sodium dodecylbenzene sulfonate has good decontamination, foam performance, and degreasing power is also stronger, and not only cost is low to be used for preparation meal lotion, and effective, but it has a shortcoming is exactly big to skin irritation, also can the adversary cause degreasing when washing by hand tableware, long-time use can make pachylosis, and is dry and cracked.
On the other hand, the food of people feed except seafood mostly from agricultural-food, agricultural-food self can have a little pathogenic micro-organisms such as putrefactive bacterium, yeast, mould etc., people must note their cleaning and sterilizing when eating some gourd, fruit and vegetables raw, not so these pathogenic bacterium can enter into human body very like a cork, thereby cause various diseases.
At this, stability chlorine dioxide is best sterilant, the food preservative of excellent property, effect of generally acknowledging in the world at present, can effectively reduce food origin disease, is classified as A1 level security sterilizing agent by United Nations's health organization (WHO).Because disinfection agent of chlorine dioxide has many advantages than chlorhexidine-containing disinfectant, can not produce carcinogenic, teratogenesis, mutagenesis " three cause " effect, have the security of height, since the eighties in 20th century, be used for field of food by numerous state approvals.1996, China GB 1 listed stability chlorine dioxide in and makes sanitas in the foodstuff additive, and use range is preserving fruit and vegetable utilizing, fish processing.This standard is simultaneously with ClO
2Classify food processing aid as.
At ClO
2Molecular structure in, the outer unpaired electron that exists is so have very strong oxygenizement.Tyrosine in its oxidation rapidly, the break virus protein capsid suppresses viral specific adsorption, stops its infection to host cell.ClO
2Can with the partial amino-acid generation redox reaction in bacterium and other microproteins, amino acid decompose to be destroyed, and then controlling microbial is proteinic synthetic, causes bacterium death at last.Simultaneously, ClO
2The pair cell wall has absorption and through performance preferably, and the oxidation cell includes the enzyme of sulfydryl effectively, except that general bacterium is had the killing effect, gemma, virus, algae, fungi etc. is all had good killing effect.In addition, dioxide peroxide also has certain agricultural residual effect that removes.
Summary of the invention
In view of the foregoing, the purpose of this invention is to provide a kind ofly not only has cleaning action to tableware, and also has the meal lotion of disinfection; Another object of the present invention provides a kind of character gentleness, safe and reliable, environment friendly and pollution-free, and can remove the detergent of remains of pesticide on the gourd, fruit and vegetable.To achieve these goals, made full use of the advantage of dioxide peroxide among the present invention, selected the core of dioxide peroxide for use as product, thereby with decontamination, sterilize, go agricultural chemicals triple effect unification, it is residual except that farming not only to can be used for the fruits and vegetables sterilization, but also can carry out cleaning-sterilizing to tableware.
For realizing purpose of the present invention, a kind of farming cannibalisation bacterium liquid detergent that removes that contains dioxide peroxide provided by the present invention is made by following components in weight percentage: tensio-active agent 5-60%, sequestrant 0.01-1.0%, thickening material 0.1-10.0%, chlorine dioxide precursor 0.05-5.0%, the an amount of adjust pH of pH value conditioning agent is 6.5-8.5, complements to 100% with deionized water.
The aforesaid farming cannibalisation bacterium liquid detergent that removes, preferably make: tensio-active agent 10-55%, sequestrant 0.1-0.8%, thickening material 0.5-6.0%, chlorine dioxide precursor 0.1-4.0% by following components in weight percentage, the an amount of adjust pH of pH regulator agent is to 6.5-8.5, and deionized water complements to 100%.
The aforesaid farming cannibalisation bacterium liquid detergent that removes, more preferably make: tensio-active agent 15-50%, sequestrant 0.2-0.6%, thickening material 1.0-4.0%, chlorine dioxide precursor 0.2-3.0% by following components in weight percentage, the an amount of adjust pH of pH regulator agent is to 6.5-8.5, and deionized water complements to 100%.
Described chlorine dioxide precursor is to be selected from Textone, lithium chlorite, potassium chlorite, magnesium chlorite, the barium chlorite one or more.
Described tensio-active agent, except alkyl glycoside, also comprise, be selected from sodium lauryl sulphate, ammonium lauryl sulfate, cocounut oil sodium alcohol ether carboxylate, natural fat polyoxyethylenated alcohol, Fatty Alcohol Ether Carboxylate, cocamidopropyl propyl amide hydroxyl sulphonic acid betaine, Seconary Alkane Sulphonate Sodium, dodecyl alcohol ether sodium sulfate, dodecyl alcohol ether ammonium sulfate, AMONYL 380LC, dodecyl CAB, fatty alcohol-polyoxyethylene ether, the amine oxide one or more.
Described sequestrant is to be selected from a kind of in ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, the tetrasodium ethylenediamine tetraacetate,
Described thickening material is to be selected from the two stearates of Xylo-Mucine, sodium hydroxyethyl cellulose, polyvinylpyrrolidone, xanthan gum, card ripple, PEG-150 distearate, PEG-120 methyl glucoside ester, acrylic copolymer, polyethylene glycol 6000, polyvinylpyrrolidone, the poly-polyacrylic ester of friendship, seaweed gel, sodium-chlor, fatty acid distribution of coconut oil single ethanol amide, the fatty acid distribution of coconut oil diglycollic amide one or more
Described pH regulator agent is one or more in citric acid, Trisodium Citrate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, boric acid, the borax.
Pesticide residue removing and sterilizing detergent of the present invention has been set up the chlorine dioxide slow-release system based on surfactant system, and selects for use this green surfactant of alkyl glycoside to remove farm chemical ingredients as main decontamination, and safety and environmental protection is biodegradable, with the back noresidue.So a kind of character gentleness, safe and reliable, environment friendly and pollution-free is provided, and can have removed the detergent of remains of pesticide on the gourd, fruit and vegetable.
Pesticide residue removing and sterilizing detergent of the present invention can be killed common pathogen enterobacterias such as common intestinal bacteria, streptococcus aureus, Corynebacterium diphtheriae, dysentery bacterium, cholera bacteria, Salmonellas, Shigellae; Can also kill infective virus such as hepatitis A virus (HAV), hepatitis B virus.
The preparation method of pesticide residue removing and sterilizing detergent of the present invention is as follows:
Take by weighing an amount of purified water in proportion, be heated to 60-70 ℃, add tensio-active agent, sequestrant, thickener component, stir, be cooled to 20-30 ℃ then, add chlorine dioxide precursor, stir, transfer product pH value to get final product at last for 6.5-8.5.
The using method of pesticide residue removing and sterilizing detergent of the present invention:
Get an amount of water droplet and add several of this product (concentration is approximately 0.5-1%), adding fruits and vegetables, tableware to be cleaned soaks 5-10min behind the mixing, rinses well with flowing water then to get final product.
The prepared pesticide residue removing and sterilizing detergent of the present invention in use, the user can be as the case may be, consumption by the control product comes the Accommodation time, product concentration is high more, action time is short more, decontamination, sterilization, to remove agricultural residual effect fruit good more, and product concentration is low more, then needs relatively long action time and reaches identical effect.
Embodiment
Following examples are used to illustrate the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
At first take by weighing proper amount of deionized water, after being heated to 60-70 ℃, according to the proportioning shown in the table 1, tensio-active agent shown in the adding, sequestrant, thickener component stir, and are cooled to 20-30 ℃ then, chlorine dioxide precursor shown in the adding, stir, at last with shown in the pH regulator agent to transfer product pH value be 6.5-8.5, thereby obtained the pesticide residue removing and sterilizing detergent of embodiment 1.
Table 1: each component and consumption
| Component | Consumption (weight %) |
| Alkyl glycoside | ??10 |
| Dodecyl alcohol ether sodium sulfate | ??5 |
| AMONYL 380LC | ??5 |
| Ethylenediamine tetraacetic acid (EDTA) | ??0.1 |
| Xylo-Mucine | ??2.0 |
| Component | Consumption (weight %) |
| Polyvinylpyrrolidone | ??2.0 |
| Textone | ??0.2 |
| Trisodium Citrate | In right amount |
| Deionized water | To 100 |
Embodiment 2
Use outside each component shown in the following table 2 and the consumption, use the preparation method identical, obtained the pesticide residue removing and sterilizing detergent of embodiment 2 with embodiment 1.
Table 2: each component and consumption
| Component | Consumption (weight %) |
| Alkyl glycoside | ??15 |
| Fatty alcohol-polyoxyethylene ether | ??10 |
| Amine oxide | ??5 |
| Ethylenediamine tetraacetic acid (EDTA) | ??0.4 |
| The fatty acid distribution of coconut oil diglycollic amide | ??3.0 |
| Xanthan gum | ??1.0 |
| Potassium chlorite | ??0.6 |
| Textone | ??1.0 |
| Trisodium Citrate | In right amount |
| Deionized water | To 100 |
Embodiment 3
Use outside each component shown in the following table 3 and the consumption, use the preparation method identical, obtained the pesticide residue removing and sterilizing detergent of embodiment 3 with embodiment 1.
Table 3: each component and consumption
| Component | Consumption (weight %) |
| Alkyl glycoside | ??20 |
| The dodecyl CAB | ??10 |
| Fatty alcohol-polyoxyethylene ether | ??5 |
| Amine oxide | ??5 |
| Ethylenediamine tetraacetic acid (EDTA) | ??0.6 |
| The fatty acid distribution of coconut oil single ethanol amide | ??1.0 |
| The card ripple | ??1.0 |
| Barium chlorite | ??2.0 |
| Textone | ??2.0 |
| Citric acid | In right amount |
| Deionized water | To 100 |
Result of use;
Use the pesticide residue removing and sterilizing detergent of preparation among the embodiment 1～3, the result who carries out the result of use test shows, detergent prepared among the embodiment 1～3 is when being used to remove agricultural chemicals residual on the fruits and vegetables, working concentration 1-2%, action time 5min, can remove the agricultural chemicals more than 95%, kill microorganisms such as top all residual bacteriums, virus, yeast, fungi.Detergent prepared among the embodiment 1～3 is when being used to clean tableware, and working concentration is 1%, and action time, 5min can remove greasy dirt residual on the tableware, bacterium and various infectivity Causative virus.
Though above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements all belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (9)
1. one kind is removed farming cannibalisation bacterium liquid detergent, make by following components in weight percentage: tensio-active agent 5-60%, sequestrant 0.01-1.0%, thickening material 0.1-10.0%, chlorine dioxide precursor 0.05-5.0%, the an amount of adjust pH of pH value conditioning agent is 6.5-8.5, complements to 100% with deionized water.
2. the farming cannibalisation bacterium liquid detergent that removes according to claim 1, make by following components in weight percentage: tensio-active agent 10-55%, sequestrant 0.1-0.8%, thickening material 0.5-6.0%, chlorine dioxide precursor 0.1-4.0%, the an amount of adjust pH of pH regulator agent is to 6.5-8.5, and deionized water complements to 100%.
3. the farming cannibalisation bacterium liquid detergent that removes according to claim 1 and 2, make by following components in weight percentage: tensio-active agent 15-50%, sequestrant 0.2-0.6%, thickening material 1.0-4.0%, chlorine dioxide precursor 0.2-3.0%, the an amount of adjust pH of pH regulator agent is to 6.5-8.5, and deionized water complements to 100%.
4. according to any described farming cannibalisation bacterium liquid detergent that removes of claim 1-3, it is characterized in that, described tensio-active agent, except alkyl glycoside, also comprise, be selected from sodium lauryl sulphate, ammonium lauryl sulfate, the cocounut oil sodium alcohol ether carboxylate, the natural fat polyoxyethylenated alcohol, Fatty Alcohol Ether Carboxylate, cocamidopropyl propyl amide hydroxyl sulphonic acid betaine, Seconary Alkane Sulphonate Sodium, dodecyl alcohol ether sodium sulfate, dodecyl alcohol ether ammonium sulfate, AMONYL 380LC, the dodecyl CAB, fatty alcohol-polyoxyethylene ether, in the amine oxide one or more.
5. according to any described farming cannibalisation bacterium liquid detergent that removes of claim 1-3, it is characterized in that described chlorine dioxide precursor is to be selected from Textone, potassium chlorite, lithium chlorite, magnesium chlorite, the barium chlorite one or more.
6. according to any described farming cannibalisation bacterium liquid detergent that removes of claim 1-3, sequestrant is to be selected from a kind of in ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, the tetrasodium ethylenediamine tetraacetate.
7. according to any described farming cannibalisation bacterium liquid detergent that removes of claim 1-3, thickening material is to be selected from Xylo-Mucine, sodium hydroxyethyl cellulose, polyvinylpyrrolidone, xanthan gum, card ripple, PEG-150 distearate, PEG-120 methyl glucoside ester, acrylic copolymer, the two stearates of polyethylene glycol 6000, polyvinylpyrrolidone, the poly-polyacrylic ester of friendship, seaweed gel, sodium-chlor, fatty acid distribution of coconut oil single ethanol amide, the fatty acid distribution of coconut oil diglycollic amide one or more.
8. according to any described farming cannibalisation bacterium liquid detergent that removes of claim 1-3, the pH regulator agent is one or more in citric acid, Trisodium Citrate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, borax, the boric acid.
9. the bacterium liquid detergent is massacreed in any described farming that removes that contains dioxide peroxide according to claim 1-8, its preparation method is: take by weighing an amount of purified water in proportion, be heated to 60-70 ℃, add tensio-active agent, sequestrant, thickener component, stir, be cooled to 20-30 ℃ then, add chlorine dioxide precursor, stir, transfer product pH value to be 6.5-8.5 at last, promptly.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010101209887A CN101787334B (en) | 2010-03-09 | 2010-03-09 | Pesticide residue removing and sterilizing detergent |
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|---|---|---|---|
| CN2010101209887A CN101787334B (en) | 2010-03-09 | 2010-03-09 | Pesticide residue removing and sterilizing detergent |
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| CN101787334A true CN101787334A (en) | 2010-07-28 |
| CN101787334B CN101787334B (en) | 2012-02-01 |
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| CN2010101209887A Expired - Fee Related CN101787334B (en) | 2010-03-09 | 2010-03-09 | Pesticide residue removing and sterilizing detergent |
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| CN102250696A (en) * | 2011-06-15 | 2011-11-23 | 于文 | Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits |
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| CN103893025A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Method for preparing novel disinfectant hand cleaner |
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| CN102250696B (en) * | 2011-06-15 | 2012-12-19 | 于文 | Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits |
| CN102250696A (en) * | 2011-06-15 | 2011-11-23 | 于文 | Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits |
| CN103725444A (en) * | 2012-10-16 | 2014-04-16 | 张儒丽 | Cleanser essence |
| CN103893025A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Method for preparing novel disinfectant hand cleaner |
| CN103160386A (en) * | 2013-02-28 | 2013-06-19 | 深圳市科玺化工有限公司 | Compound cleaning agents and preparation method thereof |
| CN103205317A (en) * | 2013-03-22 | 2013-07-17 | 于文 | Rheologically modified cleanser for kitchen heavy oily dirt, and preparation method thereof |
| CN103374475A (en) * | 2013-07-08 | 2013-10-30 | 涂秦华 | Super-concentrated detergent paste |
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| CN106010823A (en) * | 2016-05-21 | 2016-10-12 | 杨勇 | General cleaning agent |
| CN105907488A (en) * | 2016-05-22 | 2016-08-31 | 俞凤鸣 | Tableware cleaning agent |
| CN106635489A (en) * | 2016-09-22 | 2017-05-10 | 长兴净安环保科技有限公司 | Machine-use tableware detergent and preparation method thereof |
| CN106590985A (en) * | 2016-12-08 | 2017-04-26 | 青岛友诚高新技术有限公司 | Disinfecting and sterilizing dishwashing liquid |
| EP3346269A1 (en) * | 2017-01-10 | 2018-07-11 | AXAGARIUS GmbH & Co. KG | Test for measurement of sulfate concentration |
| CN106883937A (en) * | 2017-01-11 | 2017-06-23 | 北京长江脉医药科技有限责任公司 | It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues |
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