CN106883937A - It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues - Google Patents

It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues Download PDF

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Publication number
CN106883937A
CN106883937A CN201710017166.8A CN201710017166A CN106883937A CN 106883937 A CN106883937 A CN 106883937A CN 201710017166 A CN201710017166 A CN 201710017166A CN 106883937 A CN106883937 A CN 106883937A
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Prior art keywords
cleaning agent
surfactant
active component
degrading pesticide
alkali metal
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CN106883937B (en
Inventor
史瑞雪
戴彦榛
王玉路
王舒萌
李芳�
李欢欢
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of disinfection cleaning agent, it is characterised in that：The cleaning agent has the effect of disinfection and degrading pesticide residues concurrently.Including antimicrobial activity composition, degrading pesticide active component, auxiliary agent, surfactant and packing material.

Description

It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues
Technical field
It is clear the present invention relates to a kind of sterilization that can again can be used for sterilizing and cleaning washing with degrading pesticide residues Lotion.
Background technology
Residues of pesticides (Pesticide residues) problem is increasingly highlighted in China, for increasing both production and income, agricultural working Person pollutes, due to not having in latter period of Pesticide use extensively to crops injection agricultural chemicals to soil, water resource, air It is decomposed and residues in organism, cutting etc..Broadly, it is present in the trace pesticide in soil, water resource, air Substance, toxic metabolite, degradation product and impurity belong to residues of pesticides.
Especially, agricultural chemicals enters in grain, veterinary antibiotics, fish, shrimp, meat, egg, milk, causes food pollution, harm people's Health.Such as organo-chlorine pesticide, typically very slow in human body metabolism's speed, accumulated time is long.Organochlorine remains master in human body In concentrating on fat.As DDT is in the blood of people, brain, liver and content ratio is 1 in adipose tissue:4:30:300；Dieldrite It is 1:5:30:150.Because residues of pesticides are very big to people and biohazard, administration of the various countries to agricultural chemicals all carries out strict management, And Pesticide Residues tolerance is dictated.But, for various reasons, Pesticide use many times all greatly surpasses The dosage of national permission is gone out.In order to reduce harm of the people in real life Pesticide Residues to human body, water is typically all used Wash or washed with detergent.On the one hand washed using washing or with detergent can not thoroughly remove fruit and vegetable surface agricultural chemicals Residual；Still further aspect is washed the agricultural chemicals for getting off and can also flow to sewer with water, then pollutes environment.
Patent document 1 (WO2008/043638A) discloses a kind of aqueous comprising bleaching composition and activator composition Liquid cleansing composition.The bleaching composition includes KHSO5, thickening surfactant system and inorganic acid based on ammonium, institute State activator composition and include water-soluble inorganic halide such as NaCl and thickening polymer.Thickening surfactant based on ammonium Combination of the system comprising tertiary amine surfactant with amine oxide surfactant and/or quaternary surfactant.The technical side Product in case is highly effective as rinsing bleaching and disinfecting agents, but with regard to agricultural product such as its residues of pesticides neutralization and fruit It is disabled for cleaning and sterilizing.
Patent document 2 (CN103827282A) discloses a kind of many part kit systems for preparing disinfectant, makes The disinfectant prepared with many part kit systems, the disinfectant includes peroxide biocide and substitution ammonium type The combination of booster biocides.The system (is selected from KHSO comprising per-compound5、K2S2O8、Na2S2O8, single peroxide neighbour benzene Dioctyl phthalate magnesium hexahydrate, SODIUM PERCARBONATE and sodium perborate), surfactant, and the compound of the ammonium comprising substitution (is selected from two Alkyl dimethy lammonium chloride, didecyl methyl-poly- (oxygen ethyl) propionic acid ammonium, CHG, halogenation cetyl pyridinium and Hexamethylene).Wherein in a preferred embodiment, in addition to including at least one per-compound, Can also include one or more other additive, for example sodium sulphate, sodium carbonate, sodium acid carbonate, sodium acetate, potassium sulfate, potassium carbonate, Saleratus；Solid pH adjusting agent, such as malic acid, citric acid, butanedioic acid, adipic acid, maleic acid, tartaric acid；Dyestuff；And Peroxide decomposes stabilizer, such as polyvalent transition metal chelant (complexing, chelating) agent.The example bag of polyvalent transition metal intercalating agent The compound as part, such as dimethylglyoxime, especially three azacycloalkyl hydrocarbon compounds, Isosorbide-5-Nitrae with nitrogen and/or oxygen donor are included, 7- 7-triazacyclononanes (TACN) or bipyridyl amine (DPA)；Carboxylic acid derivates, such as EDTA (EDTA) and its alkali metal salt, diethylenetriamines-N, N, N ', N ', N '-pentaacetic acid (DTPA) and its alkali metal salt, nitrilo-- 2,2 ', 2 "-triacetic acid (NTA) and its alkali metal salt；Phosphonate derivative, such as 1,2- diaminos butylcyclohexyl four (methylene phosphonic acid) and Its alkali metal salt, diethylene triamine penta(methylene phosphonic acid) and its alkali metal salt, EDTMP and its alkali Slaine, polyphosphate compounds and its alkali metal salt.The technical scheme as disinfectant, have outstanding performance by its stability, but makees It is residues of pesticides nertralizer then poor effect.
Patent document 3 (CN101977658A) be the application of U.S. E-Z-EM companies can be used for remove residues of pesticides and match somebody with somebody Square patent.Toxic industrial chemicals or material (including agricultural chemicals) are applied with the composition of active composition, is thus neutralized described Toxic industrial chemicals and/or material, wherein, the active component includes 2,3- biacetyl monoximes, its alkali metal salt or alkaline earth One or more in slaine or derivatives thereof.But, the formula only can be used for neutralizing toxic industrial chemicals or thing Matter, in other words, can only remove residues of pesticides, it is impossible to which the bacterial micro-organism to fruit and vegetable surface is killed.The patent Simply solve the problems, such as to remove residues of pesticides, without in view of when actual cleaning fruit and vegetable, not only to go Except residues of pesticides, and washing removing is carried out to bacterium present on fruit and vegetable and other pollutants, the application research and development group Team is devoted to researching and developing a kind of cleaning agent, acts not only as removing the agricultural chemicals nertralizer of residues of pesticides in formula design, while Addition disinfectant and surfactant, to increase the washing sterilization function of product, are more suitable for product actually used, particularly right In the effective cleaning agent in restaurant and fruits and vegetables enterprise for being related to romaine lettuce sale.
The content of the invention
In view of above-mentioned technical problem, residues of pesticides and bacterium can either be simultaneously removed present invention aim at one kind is provided, Can realize cleaning, sterilize and removing the Trinitarian cleaning agent of residues of pesticides again.
It is not related to the neutralization both to residues of pesticides to remove in recited patent document 1~3, and to micro- life such as bacterium The killing sterilization of thing, and it is related to the technical scheme of cleaning.The present invention has taken into account cleaning, sterilization and removal residues of pesticides three simultaneously Big function.
Specifically, the present invention provides a kind of disinfection cleaning agent, it is characterised in that：The cleaning agent has disinfection and drop concurrently The effect of residues of pesticides is solved, including antimicrobial activity composition, degrading pesticide active component, auxiliary agent, surfactant and filling Material.
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：According to percentage by weight, the proportioning of the cleaning agent is：
1) disinfectant active component：0.5%-30%
2) degrading pesticide active component：0.5%-30%
3) auxiliary agent：0.1%-15%
4) surfactant：5%-15%
5) water or other packing materials：Surplus
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The antimicrobial activity composition is that can be used for cleaning and sterilizing Various quaternary ammonium salts, poly- guanidine, the mixture of one or several of biguanides and phenols, such as double decyl ammonium bromides of dimethyl, two Methyl dodecylbenzyl ammonium bromide, polyhexamethylene guanide, triclosan or chlorohexidene etc..
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The degrading pesticide active component be 2,3- dimethylglyoximes, The mixing of the alkali metal or alkali salt of the alkali metal or alkali salt and 2,3- dimethylglyoxime of 2,3- diacetyl monoximes Thing.
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The auxiliary agent is the cationic polymerization with thickening power Thing, anionic thickener or non-ionic polymers, such as cationic cellulose, carbomer, PAMC and poly- third Enol etc..
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The packing material can be according to different types of service Water or other inorganic material, such as：Silica.
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The surfactant can be anion surface active Agent, cationic surfactant, amphoteric surfactant and nonionic surfactant, such as：Lauryl sodium sulfate, hexadecane Base dimethylbenzyl ammonium bromide, dodecyl CAB, APES or alkyl polyglucosides etc..
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The consumption of the active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%
Such as above-mentioned disinfection cleaning agent of the invention, it is characterised in that：The disinfection cleaning agent can be the aqueous solution, colloid, cream Body is attached to the sterilizing article being made on the carrier of various materials, such as：Disinfected paper napkin.
According to the present invention, the antimicrobial activity composition is that can be used for various quaternary ammonium salts, poly- guanidine, the biguanides of cleaning and sterilizing It is the double decyl ammonium bromides of the mixture of one or several of class and phenols, such as dimethyl, dimethyl dodecyl base Benzylphosphonium Bromide ammonium, poly- Hexa-methylene guanidine, triclosan or chlorohexidene etc..
Wherein, polyhexamethylene guanide is into electropositive, under usual state, it is easy to by electronegative all kinds of bacteriums, virus Absorption, so as to suppress the splitting function of bacterial virus, makes bacterial virus lose fecundity, on the other hand, by with other things The matter thin polymer film to be formed that is polymerized plugs the respiration channel of microorganism, microorganism is choked to death rapidly.Therefore, poly- six is sub- Methylguanidine is widely used as being broad-spectrum antiseptic composition, to various germs, fungi and each viroid etc. effectively, compared to active ingredient For the bactericide effect of chlorine, iodine, aldehyde, alcohol, acids etc. is rapider, bactericidal effect is more firm.
Further, the guanidine radicals and long chain quaternary in polyhexamethylene guanidine compound disinfectant have activity very high, make to gather Compound is easy to generally be adsorbed in electronegative all kinds of bacteriums, virus into electropositive, so as to inhibit bacterial virus Splitting function, makes bacterial virus lose fecundity, and destroys the cell membrane and cytoplasmic membranous system of bacterium and fungi, The film formed plus polymer plugs the respiration channel of microorganism, microorganism is choked to death rapidly.According to the sterilization machine Reason, all kinds of bacteriums will not develop immunity to drugs to it.Tween is added in the system, good dividing is made it have Dissipate, emulsify and osmosis, strengthen sterilization and bacteriostasis effect.
According to the present invention, the degrading pesticide active component is 2,3- dimethylglyoximes, the alkali metal of 2,3- diacetyl monoximes Or the mixture of the alkali metal or alkali salt of alkali salt and 2,3- dimethylglyoxime.Because containing 2,3- dimethylglyoximes And its this kind combination of alkali metal salt, it has preferable neutralization to residues of pesticides, and this has more detailed in patent document 3 Thin description.Why the present invention uses is different from the degrading pesticide active component of patent document 3, described in such as patent document 3 Active component contain 2,3- biacetyl monoximes (also referred to as diacetyl monoxime (DAM)) and its alkali metal salt, such as 2,3- fourths two Ketone monoxime potassium (KBDO), but use 2,3- dimethylglyoximes, the alkali metal of 2,3- diacetyl monoximes or alkali salt and 2,3- The alkali metal of dimethylglyoxime or the mixture of alkali salt, because being obtained by after the up to ten thousand experiments of the application R＆D team To the said mixture that combines of optimal classics can effectively outside degrading pesticide active component, additionally it is possible to promote sterilization to live Property, however, the present invention is not limited in this kind of mixture, the similar mixture degradation effect to be played also is managed very much therewith Think.These mixtures should be also contained within the scope of the present invention.
According to the present invention, the auxiliary agent is the cationic polymer with thickening power, anionic thickener or nonionic Polymer, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL.These promoter effects are Thickening power, in the present invention, can also add other auxiliary agents, in addition to thickening, for example, can also be and play moisture-keeping function NMF, the flavouring agent for tarting up, and colouring agent, emulsifying agent etc..In patent document 3, preparation can be containing such as The carriers such as polyethylene glycol, mono methoxy polyethylene glycol or polyglycol ether.These compounds have formula R-O- (CH2CH2O)nCH2CH2OR, wherein, any R can be hydrogen or alkyl (including but not limited to methyl or ethyl), and " n " represents chain length.Generally, with " n " increase, compound becomes more sticky.Auxiliary agent of the present invention is using cationic polymer, anion with thickening power Thickener or non-ionic polymers, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL.Specially Thickener in sharp document 3 is used for creme, so chain length can be with value as very long.And the present invention then thickening while, change Become the ionic environment of cleaning agent, not only relative activity molecule is presented inertia, but also can preferably play the effect of active component With.
According to the present invention, the packing material according to different types of service can be water or other inorganic material, such as：Two Silica.Using water as packing material, in order to which detergent is prepared in required concentration, such as 1:100、1:200 etc. Deng to neutralize different types of pesticide residues etc..Using silica as packing material purpose then be increase creme or The viscosity of emulsion, in fact, in addition to silicon dioxide, titanium dioxide, bleaching earth, clay and bentonite etc. can also be used Deng.Different demands according to different product are prepared, as long as relative activity molecule is presented inertia, especially limit are not done It is fixed.
According to the present invention, the surfactant can be anion surfactant, cationic surfactant, both sexes Surfactant and nonionic surfactant, such as：Lauryl sodium sulfate, cetyl dimethyl benzyl ammonium bromide, 12 Alkyl CAB, APES or alkyl polyglucosides etc..The selection of these surfactants is this Invention research team prepares by classical determined by thousands of combination experiments, and it not only dramatically increases the work of cleaning agent surface Property, and the effectiveness of degrading activity composition and antimicrobial activity composition can be promoted.However, surfactant of the present invention is not limited Prepared in the classics, the degraded and Disinfection Effect to be played using similar surfactant is also highly desirable.These surfaces Activating agent should be also contained within the scope of the present invention.Can also be using in patent document 2 in disinfection cleaning agent of the present invention Surfactant, the surfactant can include the nonionic surfactant of constant weight percentage, amophoteric surface active Agent, and at least one compound comprising the ammonium for replacing, the compound is selected from dialkyl dimethy lammonium chloride, wherein each may be used At least one has 8 to 18 carbon atoms, didecyl methyl-poly- (oxygen ethyl) propionic acid in two hydrocarbyl residues of independent change Ammonium, CHG, halogenation cetyl pyridinium and hexamethylene, wherein halide refer to chloride or Bromide.As amphoteric surfactant example include based on glycine betaine-, glycinate-, aminopropionate-, both sexes acetic acid Salt-and the both sexes compound based on imidazoline, are based especially on the both sexes compound of glycine betaine.
In addition, according to the present invention, surfactant can also realize the function of cleaning by various compounding modes.Sterilization is clear Lotion can also be using other disinfectants allowed in other " food-related products catalogues ".Three kinds of oximes can also only with a kind of or Two kinds of person.
According to the present invention, due to including antimicrobial activity composition, degrading pesticide active component, so, can either remove simultaneously Residues of pesticides and bacterium, can realize cleaning, sterilize and removing the residues of pesticides Trinity again.The present invention has taken into account clear simultaneously Wash, sterilize and remove residues of pesticides three zones.
Specific embodiment
The present invention is further illustrated below by specific embodiment.
Disinfection cleaning agent of the present invention is by preparing antimicrobial activity composition, degrading pesticide active component, auxiliary agent, surfactant And packing material.
The antimicrobial activity composition is that can be used for various quaternary ammonium salts, poly- guanidine, biguanides and the phenols of cleaning and sterilizing The double decyl ammonium bromides of the mixture of one or several, such as dimethyl, dimethyl dodecyl base Benzylphosphonium Bromide ammonium, polyhexamethylene Guanidine, triclosan or chlorohexidene etc..
The degrading pesticide active component is 2,3- dimethylglyoximes, the alkali metal or alkali salt of 2,3- diacetyl monoximes And the alkali metal or the mixture of alkali salt of 2,3- dimethylglyoxime.
The auxiliary agent is the cationic polymer with thickening power, anionic thickener or non-ionic polymers, such as sun Ion fiber element, carbomer, PAMC and POLYPROPYLENE GLYCOL etc..
The packing material according to different types of service can be water or other inorganic material, such as：Silica.
The surfactant can be anion surfactant, cationic surfactant, amphoteric surfactant And nonionic surfactant, such as：Lauryl sodium sulfate, cetyl dimethyl benzyl ammonium bromide, dodecyl propyl group are sweet Dish alkali, APES or alkyl polyglucosides etc..
The consumption of the degrading pesticide active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%
In addition, surfactant can also realize the function of cleaning by various compounding modes.Disinfection cleaning agent can also Using other disinfectants allowed in other " food-related products catalogues ".Three kinds of oximes can also only use one or two kinds of.
The disinfection cleaning agent can the aqueous solution, colloid, lotion or be attached on the carrier of various materials be made Sterilizing article, such as：Disinfected paper napkin.
Embodiment 1：
Disinfection cleaning agent of the present invention is aqueous cleaning agent, is according to percentage by weight proportioning：
1, poly hexamethylene biguanide 0.5%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 2.0% of fourth 21
4, dimethylglyoxime disodium salt 1.0%
5, cationic cellulose 0.1%
6, alkyl polyglucosides (APG) 15.9%
7, deionized water surplus.
Embodiment 2：
Disinfection cleaning agent of the present invention is cation gel type cleaning agent, is according to percentage by weight proportioning：
1, double decyl dimethyl ammonium bromides 0.2%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 4.0% of fourth 21
4, dimethylglyoxime disodium salt 0.5%
5, cationic cellulose 0.5%
6, choline 0.1
7, laureth 15.0%
8, deionized water surplus.
Embodiment 3：
Disinfection cleaning agent of the present invention is pulvis cleaning agent, is according to percentage by weight proportioning：
1, sodium carbonate peroxide (coated) 5%
2, dimethylglyoxime 5.0%
3, the ketoxime monopotassium salt 15.0% of fourth 21
4, dimethylglyoxime disodium salt 5.0%
5, nano silicon 35%
6, sodium lauroyl glutamate 16%
7, sodium bentonite surplus
Embodiment 4：
Disinfection cleaning agent of the present invention is polyanionic gel type cleaning agent, is according to percentage by weight proportioning：1, triclosan 0.5%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 2.0% of fourth 21
4, dimethylglyoxime disodium salt 1.0%
5, carbomer U20 0.5%
6, pareth sulfate (AES) 15.9%
7, deionized water surplus.
Embodiment 5：
Disinfection cleaning agent of the present invention is low bubble aqueous cleaning agent, is according to percentage by weight proportioning：
1, polyhexamethylene guanide 0.5%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 2.0%
5, maleic acid-acrylic acid copolymer sodium salt 5%
6, lauroyl Sodium Glycinate 11.9%
7, acryl-based antifoaming agent 0.5%
8, deionized water surplus.
Embodiment 6：
Disinfection cleaning agent of the present invention is bubble aqueous cleaning agent high, is according to percentage by weight proportioning：
1, poly hexamethylene biguanide 0.5%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 2.0%
5, CAB 20%
6,6,501 2%
7, alkyl polyglucosides (APG) 10%
8, OB-2 10
9, deionized water surplus.
To sum up, the present invention is explained in detail according to specific embodiment, but foregoing description is exemplary, sheet Invention is not limited in these embodiments, and those skilled in the art can carry out various modifications and changes to it, it is to be understood that, Without departing from present inventive concept and spirit, these done modifications and changes all should fall protection scope of the present invention it Interior, the scope of the present invention is defined by the following claims.

Claims (9)

1. a kind of disinfection cleaning agent, it is characterised in that：The cleaning agent has the effect of disinfection and degrading pesticide residues concurrently.Its Include antimicrobial activity composition, degrading pesticide active component, auxiliary agent, surfactant and packing material.
2. cleaning agent according to claim 1, it is characterised in that：According to percentage by weight, the proportioning of the cleaning agent is：
1) disinfectant active component：0.5%-30%
2) degrading pesticide active component：0.5%-30%
3) auxiliary agent：0.1%-15%
4) surfactant：5%-15%
5) water or other packing materials：Surplus.
3. cleaning agent according to claim 1, it is characterised in that：The cleaning agent antimicrobial activity composition is according to constitutional law Rule regulation can be used for the mixture of one or several of various quaternary ammonium salts, poly- guanidine, biguanides and the phenols of cleaning and sterilizing, such as The double decyl ammonium bromides of dimethyl, dimethyl dodecyl base Benzylphosphonium Bromide ammonium, polyhexamethylene guanide, triclosan or chlorohexidene etc..
4. cleaning agent according to claim 1, it is characterised in that：The cleaning agent degrading pesticide active component is 2,3- fourths The alkali metal or alkali salt of two ketoximes, the alkali metal of 2,3- diacetyl monoximes or alkali salt and 2,3- dimethylglyoxime Mixture.
5. cleaning agent according to claim 1, it is characterised in that：The auxiliary agent of the cleaning agent is the sun with thickening power Ionomer, anionic thickener or non-ionic polymers, such as cationic cellulose, carbomer, cation polypropylene acyl Amine and POLYPROPYLENE GLYCOL etc..
6. cleaning agent according to claim 1, it is characterised in that：The packing material of the cleaning agent is according to different use shapes Formula can be water or other inorganic material, such as：Silica.
7. cleaning agent according to claim 1, it is characterised in that：The surfactant of the cleaning agent can be anion Surfactant, cationic surfactant, amphoteric surfactant and nonionic surfactant, such as：Dodecyl sulphate Sodium, cetyl dimethyl benzyl ammonium bromide, dodecyl CAB, APES or alkyl poly grape Glucosides etc..
8. degrading pesticide active component according to claim 4, it is characterised in that：The consumption of the active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%.
9. cleaning agent according to claim 1, it is characterised in that：The cleaning agent can be the aqueous solution, colloid, lotion or Person is attached to the sterilizing article being made on the carrier of various materials, such as：Disinfected paper napkin.
CN201710017166.8A 2017-01-11 2017-01-11 It is a kind of can be with the disinfection cleaning agent of degrading pesticide residues Active CN106883937B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002074090A1 (en) * 2001-03-16 2002-09-26 Univers Bio Method for the anti-pollution treatment of vegetables
CN101787334A (en) * 2010-03-09 2010-07-28 北京欧凯纳斯科技有限公司 Pesticide residue removing and sterilizing detergent
CN102250696A (en) * 2011-06-15 2011-11-23 于文 Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits
CN102618399A (en) * 2012-03-19 2012-08-01 江苏爱特福84股份有限公司 Composite capable of removing pesticide residue and disinfecting and preparation method thereof
CN105344058A (en) * 2008-01-22 2016-02-24 E-Z-Em有限公司 Method and formulation for neutralizing pesticides

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002074090A1 (en) * 2001-03-16 2002-09-26 Univers Bio Method for the anti-pollution treatment of vegetables
CN105344058A (en) * 2008-01-22 2016-02-24 E-Z-Em有限公司 Method and formulation for neutralizing pesticides
CN101787334A (en) * 2010-03-09 2010-07-28 北京欧凯纳斯科技有限公司 Pesticide residue removing and sterilizing detergent
CN102250696A (en) * 2011-06-15 2011-11-23 于文 Safe and environment-friendly concentrated special cleaning agent for vegetables and fruits
CN102618399A (en) * 2012-03-19 2012-08-01 江苏爱特福84股份有限公司 Composite capable of removing pesticide residue and disinfecting and preparation method thereof

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Denomination of invention: A kind of disinfectant and cleaner that can degrade pesticide residues

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