CN106857628A - A kind of disinfectant including sterilization and degrading pesticide active component - Google Patents

A kind of disinfectant including sterilization and degrading pesticide active component Download PDF

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Publication number
CN106857628A
CN106857628A CN201710017158.3A CN201710017158A CN106857628A CN 106857628 A CN106857628 A CN 106857628A CN 201710017158 A CN201710017158 A CN 201710017158A CN 106857628 A CN106857628 A CN 106857628A
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China
Prior art keywords
disinfectant
active component
mentioned
alkali metal
degrading pesticide
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CN201710017158.3A
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Chinese (zh)
Inventor
史瑞雪
戴彦榛
王舒萌
王玉路
李芳�
李欢欢
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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Changjiangmai Medicine Science & Technology Co Ltd Beijing
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Priority to CN201710017158.3A priority Critical patent/CN106857628A/en
Publication of CN106857628A publication Critical patent/CN106857628A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
    • A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/268—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
    • A62D2101/04—Pesticides, e.g. insecticides, herbicides, fungicides or nematocides

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Emergency Medicine (AREA)
  • Zoology (AREA)
  • Molecular Biology (AREA)
  • Agronomy & Crop Science (AREA)
  • Emergency Management (AREA)
  • Business, Economics & Management (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A kind of disinfectant, 4 have the effect of disinfection and degrading pesticide residues concurrently, including antimicrobial activity composition, degrading pesticide active component, auxiliary agent and packing material.

Description

A kind of disinfectant including sterilization and degrading pesticide active component
Technical field
The present invention relates to it is a kind of can again be can be used for degrading pesticide residues sterilizing without surfactant Disinfectant.
Background technology
Residues of pesticides (Pesticide residues) problem is increasingly highlighted in China, for increasing both production and income, agricultural working Person pollutes, due to not having in latter period of Pesticide use extensively to crops injection agricultural chemicals to soil, water resource, air It is decomposed and residues in organism, cutting etc..Broadly, it is present in the trace pesticide in soil, water resource, air Substance, toxic metabolite, degradation product and impurity belong to residues of pesticides.
Especially, agricultural chemicals enters in grain, veterinary antibiotics, fish, shrimp, meat, egg, milk, causes food pollution, harm people's Health.Such as organo-chlorine pesticide, typically very slow in human body metabolism's speed, accumulated time is long.Organochlorine remains master in human body In concentrating on fat.As DDT is in the blood of people, brain, liver and content ratio is 1 in adipose tissue:4:30:300；Dieldrite It is 1:5:30:150.Because residues of pesticides are very big to people and biohazard, administration of the various countries to agricultural chemicals all carries out strict management, And Pesticide Residues tolerance is dictated.But, for various reasons, Pesticide use many times all greatly surpasses The dosage of national permission is gone out.In order to reduce harm of the people in real life Pesticide Residues to human body, water is typically all used Wash or washed with detergent.On the one hand washed using washing or with detergent can not thoroughly remove fruit and vegetable surface agricultural chemicals Residual；Still further aspect is washed the agricultural chemicals for getting off and can also flow to sewer with water, then pollutes environment.
Patent document 1 (WO2008/043638A) discloses a kind of aqueous comprising bleaching composition and activator composition Liquid cleansing composition.The bleaching composition includes KHSO5, thickening surfactant system and inorganic acid based on ammonium, institute State activator composition and include water-soluble inorganic halide such as NaCl and thickening polymer.Thickening surfactant based on ammonium Combination of the system comprising tertiary amine surfactant with amine oxide surfactant and/or quaternary surfactant.The technical side Product in case is highly effective as rinsing bleaching and disinfecting agents, but with regard to agricultural product such as its residues of pesticides neutralization and fruit It is disabled for cleaning and sterilizing.
Patent document 2 (CN103827282A) discloses a kind of many part kit systems for preparing disinfectant, makes The disinfectant prepared with many part kit systems, the disinfectant includes peroxide biocide and substitution ammonium type The combination of booster biocides.The system (is selected from KHSO comprising per-compound5、K2S2O8、Na2S2O8, single peroxide neighbour benzene Dioctyl phthalate magnesium hexahydrate, SODIUM PERCARBONATE and sodium perborate), surfactant, and the compound of the ammonium comprising substitution (is selected from two Alkyl dimethy lammonium chloride, didecyl methyl-poly- (oxygen ethyl) propionic acid ammonium, CHG, halogenation cetyl pyridinium and Hexamethylene).Wherein in a preferred embodiment, in addition to including at least one per-compound, Can also include one or more other additive, for example sodium sulphate, sodium carbonate, sodium acid carbonate, sodium acetate, potassium sulfate, potassium carbonate, Saleratus；Solid pH adjusting agent, such as malic acid, citric acid, butanedioic acid, adipic acid, maleic acid, tartaric acid；Dyestuff；And Peroxide decomposes stabilizer, such as polyvalent transition metal chelant (complexing, chelating) agent.The example bag of polyvalent transition metal intercalating agent The compound as part, such as dimethylglyoxime, especially three azacycloalkyl hydrocarbon compounds, Isosorbide-5-Nitrae with nitrogen and/or oxygen donor are included, 7- 7-triazacyclononanes (TACN) or bipyridyl amine (DPA)；Carboxylic acid derivates, such as EDTA (EDTA) and its alkali metal salt, diethylenetriamines-N, N, N ', N ', N '-pentaacetic acid (DTPA) and its alkali metal salt, nitrilo-- 2,2 ', 2 "-triacetic acid (NTA) and its alkali metal salt；Phosphonate derivative, such as 1,2- diaminos butylcyclohexyl four (methylene phosphonic acid) and Its alkali metal salt, diethylene triamine penta(methylene phosphonic acid) and its alkali metal salt, EDTMP and its alkali Slaine, polyphosphate compounds and its alkali metal salt.The technical scheme as disinfectant, have outstanding performance by its stability, but makees It is residues of pesticides nertralizer then poor effect.
Patent document 3 (CN101977658A) be the application of U.S. E-Z-EM companies can be used for remove residues of pesticides and match somebody with somebody Square patent.Toxic industrial chemicals or material (including agricultural chemicals) are applied with the composition of active composition, is thus neutralized described Toxic industrial chemicals and/or material, wherein, the active component includes 2,3- biacetyl monoximes, its alkali metal salt or alkaline earth One or more in slaine or derivatives thereof.But, the formula only can be used for neutralizing toxic industrial chemicals or thing Matter, in other words, can only remove residues of pesticides, it is impossible to which the bacterial micro-organism to fruit and vegetable surface is killed.The patent Simply solve the problems, such as to remove residues of pesticides, without in view of when actual cleaning fruit and vegetable, not only to go Except residues of pesticides, and washing removing is carried out to bacterium present on fruit and vegetable and other pollutants, the application research and development group Team is devoted to researching and developing a kind of disinfectant, acts not only as removing the agricultural chemicals nertralizer of residues of pesticides in formula design, while Addition disinfectant, to increase the sterilizing function of product in the case of without surfactant, makes product be more suitable for actually making With especially for the effective disinfectant in restaurant and fruits and vegetables enterprise for being related to romaine lettuce sale.
The content of the invention
In view of above-mentioned technical problem, residues of pesticides and bacterium can either be simultaneously removed present invention aim at one kind is provided, The disinfectant of sterilization can be realized again.
It is not related to the neutralization both to residues of pesticides to remove in recited patent document 1~3, and to micro- life such as bacterium The technical scheme of the killing sterilization of thing.The present invention has taken into account sterilization and removal residues of pesticides function simultaneously.On the other hand, patent text Surfactant is added in offering 1~3, although the surfactant increased the activity of antimicrobial activity agent, enhance cleaning Function, but, the present invention can need not add surfactant in the mixture, it is also possible to realize that sterilization and removal agricultural chemicals are residual Stay, and can be good at realizing the function of cleaning.It is pointed out that on not only adding surfactant but also can realize Except agricultural chemicals, sterilize, wash Trinitarian technical scheme applicant it is other one series application in have a detailed description, herein Its particular content is repeated no more.
Specifically, the present invention provides a kind of disinfectant, it is characterised in that：The cleaning agent has disinfection and degraded agriculture concurrently The effect of medicine residual, including antimicrobial activity composition, degrading pesticide active component, auxiliary agent and packing material.
Such as above-mentioned disinfectant of the invention, it is characterised in that：According to mass percent, the proportioning of the cleaning agent is：
1) disinfectant active component：0.5%-30%
2) degrading pesticide active component：0.5%-30%
3) auxiliary agent：0.1%-15%
4) water or other packing materials：Surplus
According to the present invention, unless otherwise instructed, what all of proportioning referred in the application is matching somebody with somebody according to mass percent Than.
Such as above-mentioned disinfectant of the invention, it is characterised in that：The antimicrobial activity composition is can be used for cleaning and sterilizing each Plant the mixture of one or several of quaternary ammonium salt, poly- guanidine, biguanides and phenols, such as double decyl ammonium bromides of dimethyl, dimethyl Dodecylbenzyl ammonium bromide, polyhexamethylene guanide, triclosan or chlorohexidene etc..
The cleaning agent antimicrobial activity composition is to can be used for the various activity of cleaning and sterilizing in strict accordance with state's laws regulation Composition.Above-named antimicrobial activity composition is that R＆D team of the present invention is considered that obvious technical effects are carried in testing Composition high, but as long as those skilled in the art will appreciate that meet state's laws regulation and can make in the present invention The active component that disinfective action is played under conditions of can be applied in the present invention.
Such as above-mentioned disinfectant of the invention, it is characterised in that：The degrading pesticide active component is 2,3- dimethylglyoximes, 2,3- The alkali metal or alkali salt of diacetyl monoxime and the alkali metal of 2,3- dimethylglyoxime or the mixture of alkali salt.
Such as above-mentioned disinfectant of the invention, it is characterised in that：The auxiliary agent is the cationic polymer with thickening power, the moon Ionic thickners or non-ionic polymers, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL Deng.
Such as above-mentioned disinfectant of the invention, it is characterised in that：The packing material according to different types of service can for water or Person other inorganic material, such as：Silica.
Such as above-mentioned disinfectant of the invention, it is characterised in that：The consumption of the active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%
Such as above-mentioned disinfectant of the invention, it is characterised in that：The disinfection cleaning agent can be the aqueous solution, colloid, lotion or Person is attached to the sterilizing article being made on the carrier of various materials, such as：Disinfected paper napkin.
According to the present invention, the antimicrobial activity composition is that can be used for various quaternary ammonium salts, poly- guanidine, the biguanides of cleaning and sterilizing It is the double decyl ammonium bromides of the mixture of one or several of class and phenols, such as dimethyl, dimethyl dodecyl base Benzylphosphonium Bromide ammonium, poly- Hexa-methylene guanidine, triclosan or chlorohexidene etc..
Wherein, polyhexamethylene guanide is into electropositive, under usual state, it is easy to by electronegative all kinds of bacteriums, virus Absorption, so as to suppress the splitting function of bacterial virus, makes bacterial virus lose fecundity, on the other hand, by with other things The matter thin polymer film to be formed that is polymerized plugs the respiration channel of microorganism, microorganism is choked to death rapidly.Therefore, poly- six is sub- Methylguanidine is widely used as being broad-spectrum antiseptic composition, to various germs, fungi and each viroid etc. effectively, compared to active ingredient For the bactericide effect of chlorine, iodine, aldehyde, alcohol, acids etc. is rapider, bactericidal effect is more firm.
Further, the guanidine radicals and long chain quaternary in polyhexamethylene guanidine compound disinfectant have activity very high, make to gather Compound is easy to generally be adsorbed in electronegative all kinds of bacteriums, virus into electropositive, so as to inhibit bacterial virus Splitting function, makes bacterial virus lose fecundity, and destroys the cell membrane and cytoplasmic membranous system of bacterium and fungi, The film formed plus polymer plugs the respiration channel of microorganism, microorganism is choked to death rapidly.According to the sterilization machine Reason, all kinds of bacteriums will not develop immunity to drugs to it.Tween is added in the system, good dividing is made it have Dissipate, emulsify and osmosis, strengthen sterilization and bacteriostasis effect.
According to the present invention, the degrading pesticide active component is 2,3- dimethylglyoximes, the alkali metal of 2,3- diacetyl monoximes Or the mixture of the alkali metal or alkali salt of alkali salt and 2,3- dimethylglyoxime.Because containing 2,3- dimethylglyoximes And its this kind combination of alkali metal salt, it has preferable neutralization to residues of pesticides, and this has more detailed in patent document 3 Thin description.Why the present invention uses is different from the degrading pesticide active component of patent document 3, described in such as patent document 3 Active component contain 2,3- biacetyl monoximes (also referred to as diacetyl monoxime (DAM)) and its alkali metal salt, such as 2,3- fourths two Ketone monoxime potassium (KBDO), but use 2,3- dimethylglyoximes, the alkali metal of 2,3- diacetyl monoximes or alkali salt and 2,3- The alkali metal of dimethylglyoxime or the mixture of alkali salt, because being obtained by after the up to ten thousand experiments of the application R＆D team To the said mixture that combines of optimal classics can effectively outside degrading pesticide active component, additionally it is possible to promote sterilization to live Property, however, the present invention is not limited in this kind of mixture, the similar mixture degradation effect to be played also is managed very much therewith Think.These mixtures should be also contained within the scope of the present invention.
According to the present invention, the auxiliary agent is the cationic polymer with thickening power, anionic thickener or nonionic Polymer, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL.These promoter effects are Thickening power, in the present invention, can also add other auxiliary agents, in addition to thickening, for example, can also be and play moisture-keeping function NMF, the flavouring agent for tarting up, and colouring agent, emulsifying agent etc..In patent document 3, preparation can be containing such as The carriers such as polyethylene glycol, mono methoxy polyethylene glycol or polyglycol ether.These compounds have formula R-O- (CH2CH2O)nCH2CH2OR, wherein, any R can be hydrogen or alkyl (including but not limited to methyl or ethyl), and " n " represents chain length.Generally, with " n " increase, compound becomes more sticky.Auxiliary agent of the present invention is using cationic polymer, anion with thickening power Thickener or non-ionic polymers, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL.Specially Thickener in sharp document 3 is used for creme, so chain length can be with value as very long.And the present invention then thickening while, change Become the ionic environment of cleaning agent, not only relative activity molecule is presented inertia, but also can preferably play the effect of active component With.
According to the present invention, the packing material according to different types of service can be water or other inorganic material, such as：Two Silica.Using water as packing material, in order to which detergent is prepared in required concentration, such as 1:100、1:200 etc. Deng to neutralize different types of pesticide residues etc..Using silica as packing material purpose then be increase creme or The viscosity of emulsion, in fact, in addition to silicon dioxide, titanium dioxide, bleaching earth, clay and bentonite etc. can also be used Deng.Different demands according to different product are prepared, as long as relative activity molecule is presented inertia, especially limit are not done It is fixed.
In addition, according to the present invention, three kinds of oximes can also only use one or two kinds of.
According to the present invention, due to including antimicrobial activity composition, degrading pesticide active component, so, can either remove simultaneously Residues of pesticides and bacterium, can realize sterilization again, be a kind of multifunctional disinfectant.
Specific embodiment
The present invention is further illustrated below by specific embodiment.
Disinfection cleaning agent of the present invention is by preparing antimicrobial activity composition, degrading pesticide active component, auxiliary agent and packing material.
In the present invention, the antimicrobial activity composition is that can be used for various quaternary ammonium salts, poly- guanidine, the biguanides of cleaning and sterilizing It is the double decyl ammonium bromides of the mixture of one or several of class and phenols, such as dimethyl, dimethyl dodecyl base Benzylphosphonium Bromide ammonium, poly- Hexa-methylene guanidine, triclosan or chlorohexidene etc..
In the present invention, the degrading pesticide active component is 2,3- dimethylglyoximes, the alkali metal of 2,3- diacetyl monoximes Or the mixture of the alkali metal or alkali salt of alkali salt and 2,3- dimethylglyoxime.
In the present invention, the auxiliary agent is the cationic polymer with thickening power, anionic thickener or nonionic Polymer, such as cationic cellulose, carbomer, PAMC and POLYPROPYLENE GLYCOL.
In the present invention, the packing material according to different types of service can be water or other inorganic material, such as：Two Silica.
In the present invention, the consumption of the degrading pesticide active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%
Three kinds of oximes can also only use one or two kinds of.
In the present invention, antimicrobial activity composition and degrading pesticide active component are the work specified in strict conformity with state's laws Property composition.
In the present invention, the disinfection cleaning agent can be the aqueous solution, colloid, lotion or the load for being attached to various materials The sterilizing article being made on body, such as：Disinfected paper napkin.
According to the present invention, due to including antimicrobial activity composition, degrading pesticide active component, so, can either remove simultaneously Residues of pesticides and bacterium, can realize sterilization again, be a kind of multifunctional disinfectant, meanwhile, to person poultry harmless, cleaning method is wide It is general, the especially preferable disinfection cleaning agent in daily life such as fruit and vegetable cleaning.
Embodiment 1
Disinfection cleaning agent of the present invention is aqueous cleaning agent, is according to percentage by weight proportioning：
1, poly hexamethylene biguanide 0.5%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 2.0% of fourth 21
4, dimethylglyoxime disodium salt 1.0%
5, cationic cellulose 0.5%
6, deionized water surplus.
Embodiment 2
Disinfection cleaning agent of the present invention is cation gel type cleaning agent, is according to percentage by weight proportioning：
Double decyl dimethyl ammonium bromides 0.2%
Dimethylglyoxime 0.1%
The ketoxime monopotassium salt 4.0% of fourth 21
Dimethylglyoxime disodium salt 0.5%
Cationic cellulose 0.5%
Choline Chloride 1.0%
Deionized water surplus.
Embodiment 3
Disinfection cleaning agent of the present invention be without aqueous cleaning agent, according to percentage by weight proportioning be：
1, polyhexamethylene guanide 0.5%
2, dimethylglyoxime 0.1%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 2.0%
5, maleic acid-acrylic acid copolymer sodium salt 5%
6, deionized water surplus.
Embodiment 4
Disinfection cleaning agent pasteurization towelette stoste of the present invention, be according to percentage by weight proportioning：
1, double-track suspended self-propelled conveyor 0.2%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 2.0%
5, deionized water surplus.
Embodiment 5
Disinfection cleaning agent granule of the present invention, be according to percentage by weight proportioning：
1, double decyl dimethyl ammonium bromides 0.2%
2, dimethylglyoxime 0.5%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 2.0%
5, nano silicon surplus.
Embodiment 6
Disinfection cleaning agent of the present invention is cation disinfection cleaning agent, is according to percentage by weight proportioning：
1, poly hexamethylene biguanide 0.5%
2, dimethylglyoxime 0.1%
3, the ketoxime monopotassium salt 5.0% of fourth 21
4, dimethylglyoxime disodium salt 0.5%
5, PAMC 5%
To sum up, the present invention is explained in detail according to specific embodiment, but foregoing description is exemplary, sheet Invention is not limited in these embodiments, and those skilled in the art can carry out various modifications and changes to it, it is to be understood that, Without departing from present inventive concept and spirit, these done modifications and changes all should fall protection scope of the present invention it Interior, the scope of the present invention is defined by the following claims.

Claims (8)

1. a kind of disinfectant, it is characterised in that：The cleaning agent has the effect of disinfection and degrading pesticide residues concurrently, wherein wrapping Include antimicrobial activity composition, degrading pesticide active component, auxiliary agent and packing material.
2. the disinfectant as described in above-mentioned claim 1, it is characterised in that：According to mass percent, the proportioning of the cleaning agent is：
1) disinfectant active component：0.5%-30%
2) degrading pesticide active component：0.5%-30%
3) auxiliary agent：0.1%-15%
4) water or other packing materials：Surplus.
3. the disinfectant as described in above-mentioned claim 1, it is characterised in that：The antimicrobial activity composition is that can be used for cleaning and sterilizing Various quaternary ammonium salts, poly- guanidine, the mixture of one or several of biguanides and phenols, such as double decyl ammonium bromides of dimethyl, two Methyl dodecylbenzyl ammonium bromide, polyhexamethylene guanide, triclosan or chlorohexidene etc..
4. the disinfectant as described in above-mentioned claim 1, it is characterised in that：The degrading pesticide active component is 2,3- diacetyl The alkali metal or alkali salt of oxime, the alkali metal of 2,3- diacetyl monoximes or alkali salt and 2,3- dimethylglyoxime it is mixed Compound.
5. the disinfectant as described in above-mentioned claim 1, it is characterised in that：The auxiliary agent is the cationic polymerization with thickening power Thing, anionic thickener or non-ionic polymers, such as cationic cellulose, carbomer, PAMC and poly- third Enol etc..
6. the disinfectant as described in above-mentioned claim 1, it is characterised in that：The packing material can be according to different types of service Water or other inorganic material, such as：Silica.
7. the disinfectant as described in above-mentioned claim 4, it is characterised in that：The consumption of the active component is：
1) 2,3- dimethylglyoximes：0.5%-5%,
2) alkali metal or alkali salt of 2,3- diacetyl monoxime：1%-15%,
3) alkali metal or alkali salt of 2,3- dimethylglyoximes：1%-10%.
8. the disinfectant as described in above-mentioned claim 1, it is characterised in that：The disinfection cleaning agent can be the aqueous solution, colloid, cream Body is attached to the sterilizing article being made on the carrier of various materials, such as：Disinfected paper napkin.
CN201710017158.3A 2017-01-11 2017-01-11 A kind of disinfectant including sterilization and degrading pesticide active component Pending CN106857628A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101977658A (en) * 2008-01-22 2011-02-16 E-Z-Em有限公司 Method and formulation for neutralizing toxic chemicals and materials
CN104450339A (en) * 2014-12-04 2015-03-25 成都顺发消洗科技有限公司 Washing agent for removing pesticide residues on vegetables and fruits
CN104479931A (en) * 2014-12-04 2015-04-01 成都顺发消洗科技有限公司 Preparation method of vegetable and fruit washing agent for removing pesticide residues

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101977658A (en) * 2008-01-22 2011-02-16 E-Z-Em有限公司 Method and formulation for neutralizing toxic chemicals and materials
CN104450339A (en) * 2014-12-04 2015-03-25 成都顺发消洗科技有限公司 Washing agent for removing pesticide residues on vegetables and fruits
CN104479931A (en) * 2014-12-04 2015-04-01 成都顺发消洗科技有限公司 Preparation method of vegetable and fruit washing agent for removing pesticide residues

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