CN101766543B - Hand sanitizer containing chlorine dioxide - Google Patents
Hand sanitizer containing chlorine dioxide Download PDFInfo
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- CN101766543B CN101766543B CN201010110707XA CN201010110707A CN101766543B CN 101766543 B CN101766543 B CN 101766543B CN 201010110707X A CN201010110707X A CN 201010110707XA CN 201010110707 A CN201010110707 A CN 201010110707A CN 101766543 B CN101766543 B CN 101766543B
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Abstract
The invention provides a hand sanitizer containing chlorine dioxide, which is prepared by the following components according to a certain weight ratio: surfactant, chelant, humectant, thickener, water-soluble body lotion, fungicide precursor, pH regulator, essence and deionized water. The hand sanitizer provided by the invention has mild, safe and environment-friendly properties, thus cleaning, skin care and sterilization can be simultaneously finished; the chlorine dioxide is selected to serve as a component of fungicide, thereby having good sterilization effect, short action time and high sterilization ratio; the hand sanitizer can take effect as soon as being used because germs can not generate tolerance on the hand sanitizer; and in addition, during the using process of the hand sanitizer, carcinogen such as chloroform and the like can not be generated, the biodegradation rate of the surfactant is more than 90%, satisfies the national requirements, and has no toxicity and harm and environment protection, thereby people can use the product for long term trustingly.
Description
Technical field
The present invention relates to a kind of disinfection hand cleanser, specifically, relate to a kind of disinfection hand cleanser that contains chlorine dioxide.
Background technology
Along with the raising day by day of living standard, people's Personal hygiene custom also changes taking place stealthily, especially after living through SARS in 2003; People's daily sterilization consciousness strengthens gradually, especially to the understanding of hand hygiene importance progressively improving, along with the outburst of " swine flu " epidemic situation in 2009; People's daily sterilization consciousness improves once more, the problem of the cross infection that fancy soap exists when washing one's hands, and handwashing liquid has become requisite cleaning supplies in the present family life; Common handwashing liquid can only be washed oil stain, the dirt on the skin surface off; But some antibacterial, virus are difficult to washed off, so the sterilizing handwashing liquid has become best first-selection, the U.S. microbiologist charles lattice uncle say; Wash one's hands with disinfection hand cleanser, risk that can human body is ill reduces by 75% even more.
Bacteriostatic hand sanitizer in the market mainly contains droplet dew, the blue moon, opens several famous brands such as rice, Wei Lushi.The sterilization component that drips the dew handwashing liquid is PCMX (parachlorometaxylenol), and the sterilization component of blue moon handwashing liquid is BMAS-1, and the sterilization component of Wei Lushi handwashing liquid is a DMG gram bacteria factor, and the sterilization component of Kai Mibeifen handwashing liquid is ethanol and DP300.
Employed antibacterial is summarized and is mainly contained following several kinds in the domestic patent about disinfection hand cleanser: cationic surfactant, non-ionic surface active agent, extracts of Chinese herbal medicine, parachlorometaxylenol, povidone iodine, stable ClO 2 solution.Like publication number is CN1316029A; Open day is in the patent of invention in JIUYUE 12 calendar year 2001; 1227 to be antibacterial, cooperate acetylated lanolin ester, glycerol, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, hydroxyethyl-cellulose, essence, citric acid, purified water etc. to be mixed with a kind of disinfecting skin care hand-washing liquid; Publication number is CN101176700A, and open day is in the patent of invention on May 14th, 2008, is antibacterial with the povidone iodine, cooperates sodium lauryl sulphate, NPE, dodecylbenzene sodium sulfonate to be mixed with antimicrobial disinfection hand cleanser; Publication number is CN101478579A; Open day is in the patent of invention on July 8th, 2009; With the parachlorometaxylenol is antibacterial, cooperates anion surfactant, amphoteric surfactant, wetting agent, water-soluble grease, chelating agen etc. to be mixed with sterilizing skin-protective hand cleanser; Publication number is CN1097464A; Open day is in the patent of invention in January 18 nineteen ninety-five; Disclosing a kind of is antibacterial with the stability chlorine dioxide, cooperates acetylated lanolin, polysorbate60, sorbester p18, carboxymethyl cellulose, calcium carbonate, deionized water to process disinfectant skin care hand-washing agent.
But, since above-mentioned disinfection hand cleanser in sterilization component all have many shortcomings, these drawbacks limit they promotion and application in actual production.For example:
Parachlorometaxylenol (PCMX), though to most Gram-positives, negative bacterium, fungus and mycete are all killed effect; It is a kind of hypotoxicity antibacterial; But its dissolubility in water only 0.03% is prone on skin residually after washing one's hands, exist certain potential safety hazard; DP300 (having another name called triclosan, triclosan-300), according to the research of the Dr.PeterVikesland of Virginia, US Polytechnics, the chlorine reaction that remains in the water in triclosan meeting and the tap water processing procedure generates chloroform, exists the risk of indirect carcinogenesis; The antibacterial kind of surfactant series bactericidal agent is limited, and very easily produces problem of resistance; The bactericidal action of povidone iodine produces owing to decompositing free-iodine gradually, and wherein the combination iodine of 80%-90% can depolymerize to free-iodine, directly makes the intravital protein denaturation of cause of disease, deposition; So that pathogen cells is dead; Thereby reach the germ-resistant purpose of high-effective disinfecting, povidone iodine is often used in the treatment gynaecopathia, and povidone iodine is used for disinfection hand cleanser; Cost is high, unsuitable suitability for industrialized production.In addition, above-mentioned antibacterial all has a common defective, and promptly antibacterial can produce toleration to it, can not use for a long time with a kind of product.
At present, chlorine dioxide is the disinfectant that sterilizing handwashing liquid sterilization component is prepared in generally acknowledged in the world best being used for.In the molecular structure of chlorine dioxide, the outer unpaired electron that exists is so have very strong Oxidation.Tyrosine in its oxidation rapidly, the break virus protein capsid suppresses viral specific adsorption, stops its infection to host cell.Chlorine dioxide can with the partial amino-acid generation redox reaction in antibacterial and other microproteins, aminoacid decompose to be destroyed, and then controlling microbial is proteinic synthetic, causes bacterial death at last.Simultaneously, chlorine dioxide pair cell wall has absorption and through performance preferably, and the oxidation cell includes the enzyme of sulfydryl effectively, except that general antibacterial is had the killing effect, spore, virus, algae, fungus etc. is all had good killing effect.
Summary of the invention
The purpose of this invention is to provide a kind of disinfection hand cleanser chlorine dioxide, safety, efficient, environmental protection, gentle skin protection that contains.
In order to realize the object of the invention; A kind of disinfection hand cleanser that contains chlorine dioxide of the present invention; Processed by following components in weight percentage: surfactant 5%-60%, chelating agen 0.01%-1.0%, wetting agent 1.0%-10.0%, thickening agent 0.1%-10.0%, deionized water dissolubility skin moistening fat 0.1%-6.0%, chlorine dioxide bactericide precursor 0.05%-5.0%, essence 0.01%-0.5%, an amount of pH regulator agent of interpolation are regulated pH value to 6.0-7.5, complement to 100% with deionized water.
Aforesaid disinfection hand cleanser; Process by following components in weight percentage: surfactant 10%-50%, chelating agen 0.05%-0.8%, wetting agent 2.0%-8.0%, thickening agent 0.5%-8.0%, deionized water dissolubility skin moistening fat 0.2%-5.0%, chlorine dioxide bactericide precursor 0.1%-4.0%, essence 0.02%-0.4%; Add an amount of pH regulator agent and regulate pH value, complement to 100% with deionized water to 6.0-7.5.
Aforesaid disinfection hand cleanser; Process by following components in weight percentage: surfactant 15%-45%, chelating agen 0.1%-0.5%, wetting agent 3.0%-7.0%, thickening agent 1.0%-7.0%, deionized water dissolubility skin moistening fat 0.5%-4.0%, chlorine dioxide bactericide precursor 0.2%-3.5%, essence 0.05%-0.3%; Add an amount of pH regulator agent and regulate pH value, complement to 100% with deionized water to 6.0-7.5.
Aforesaid disinfection hand cleanser, wherein surfactant is several kinds in lauryl sulfosuccinate monoesters disodium, sodium lauryl sulphate, ammonium lauryl sulfate, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, coconut oil single ethanol amide sulfosuccinic acid monoesters disodium, dodecyl alcohol ether sodium sulfate, dodecyl alcohol ether ammonium sulfate, 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium, single Tryfac 5573, empgen BB, cocamido propyl betaine, lauryl amido propyl betaine, cocamidopropyl propyl amide hydroxy sulfo lycine, dodecanamide propyl amine oxide, the dimethyl dodecyl amine oxide.
Aforesaid disinfection hand cleanser, wherein chelating agen is ethylenediaminetetraacetic acid, disodiumedetate or tetrasodium ethylenediamine tetraacetate.
Aforesaid disinfection hand cleanser, wherein wetting agent is one or more in glycerol, propylene glycol, 1,3-butylene glycol, sorbitol, the Polyethylene Glycol.
Aforesaid disinfection hand cleanser, wherein thickening agent is one or more in fatty acid distribution of coconut oil single ethanol amide, fatty acid distribution of coconut oil diglycollic amide, PEG-150 distearate, PEG-120 methyl glucoside, card ripple, HANSHENGJIAO, sodium carboxymethyl cellulose, the two stearates of polyethylene glycol 6000, hydroxyethyl-cellulose, polyvinylpyrrolidone, sodium alginate, acrylic copolymer, the sodium chloride.
Aforesaid disinfection hand cleanser, wherein the chlorine dioxide bactericide precursor is one or more in sodium chlorite, potassium chlorite, barium chlorite, the magnesium chlorite.
Aforesaid disinfection hand cleanser, wherein the pH regulator agent is one or more in citric acid, sodium citrate, sodium hydrogen phosphate, potassium dihydrogen phosphate, Borax, the boric acid.
Aforesaid disinfection hand cleanser, wherein essence is apple essence, flavoring orange essence, fruit essence, Breeze essence.
The present invention also provides preparation the above-mentioned method that contains the disinfection hand cleanser of chlorine dioxide, is specially: take by weighing deionized water by above-mentioned percentage by weight, add chelating agen and wetting agent; Stir, add surfactant and thickening agent then, be heated to 70-80 ℃ and dissolve and stir; Add emollient then, stir, be cooled to 45 ℃ then; Add essence, continue to be cooled to below 30 ℃, add the chlorine dioxide bactericide precursor; Dissolving also stirs, and uses pH regulator agent regulation system pH value to be 6.0-7.5 at last, promptly gets.
The method for using of product of the present invention is following: the moistening both hands of first water; Get an amount of handwashing liquid in the palm of the hand, both hands are rubbed to abundant foam occurring each other, all will rub with the hands between the palm of the hand, the back of the hand, finger; Let foam stopping maintenance 30s-3mins on hand, totally get final product with flushing with clean water then.
By technique scheme, the present invention has advantage and beneficial effect at least:
(1) disinfection hand cleanser character gentleness, safety, the environmental protection that contains chlorine dioxide provided by the invention overcome the deficiency of existing handwashing liquid, realized that cleaning, skin protection, antibacterial accomplish synchronously.
(2) the present invention selects for use chlorine dioxide as microbiocidal composition, and bactericidal effect is good, action time is short, sterilization rate is high, and antibacterial can not produce toleration to it, instant coming into force, and people are this product of life-time service relievedly.
(3) handwashing liquid of the present invention in use can not produce carcinogens such as chloroform, and all surface activating agent biological degradation rate meets national requirements also more than 90%, and is nontoxic, harmless to environment, safety and environmental protection.
The specific embodiment
Following examples are used to explain the present invention, but are not used for limiting scope of the present invention.
Embodiment contains the disinfection hand cleanser of different component
Its component formula is shown in table 1-table 3:
Table 1
| Component | Consumption (%) |
| Dodecyl alcohol ether sodium sulfate | 10.0 |
| Dodecyl alcohol ether ammonium sulfate | 5.0 |
| Ethylenediaminetetraacetic acid | 0.1 |
| Glycerol | 4.0 |
| The fatty acid distribution of coconut oil single ethanol amide | 2.0 |
| HANSHENGJIAO | 2.0 |
| Sodium carboxymethyl cellulose | 2.0 |
| Sodium chlorite | 0.2 |
| The water solublity lanoline | 0.4 |
| Hyaluronic acid | 0.1 |
| The pH regulator agent | In right amount |
| Apple essence | 0.05 |
| Deionized water | To 100 |
Table 2
| Component | Consumption (%) |
| Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium | 10.0 |
| Sodium lauryl sulphate | 7.0 |
| 1-isobutyl-3,5-dimethylhexylphosphoric acid potassium | 7.0 |
| Empgen BB | 10.0 |
| Disodiumedetate | 0.3 |
| Glycerol | 3.0 |
| 1,3-butylene glycol | 2.0 |
| The PEG-150 distearate | 2.0 |
| The card ripple | 1.0 |
| The fatty acid distribution of coconut oil diglycollic amide | 1.0 |
| The water solublity Jojoba oil | 0.25 |
| PEG-7 cocoyl glyceride | 2.0 |
| Sodium chlorite | 1.85 |
| The pH regulator agent | In right amount |
| Flavoring orange essence | 0.18 |
| Deionized water | To 100 |
Table 3
| Component | Consumption (%) |
| Lauryl sulfosuccinate monoesters disodium | 15.0 |
| Dodecyl alcohol ether sodium sulfate | 7.0 |
| The dodecanamide propyl betanin | 10.0 |
| The dodecanamide propyl amine oxide | 6.0 |
| Coconut oil single ethanol amide sulfosuccinic acid monoesters disodium | 7.0 |
| Tetrasodium ethylenediamine tetraacetate | 0.5 |
| Sorbitol | 4.0 |
| Polyethylene Glycol | 3.0 |
| The PEG-120 methyl glucoside | ?1.0 |
| Aloe extraction solution | ?2.0 |
| PEG-7 cocoyl glyceride | ?2.0 |
| Sodium chlorite | ?2.5 |
| Barium chlorite | ?1.0 |
| The pH regulator agent | In right amount |
| Breeze essence | ?0.3 |
| Deionized water | To 100 |
The above-mentioned method for preparing that contains the disinfection hand cleanser of different component is: take by weighing deionized water by above-mentioned percentage by weight, add chelating agen and wetting agent, stir, add surfactant and thickening agent then; Be heated to 70-80 ℃ and dissolve and stir, add emollient then, stir, be cooled to 45 ℃ then; Add essence, continue to be cooled to below 30 ℃, add the chlorine dioxide bactericide precursor; Dissolving also stirs, and using pH regulator agent regulation system pH value at last is 7, promptly gets.
The bactericidal effect that contains the disinfection hand cleanser of chlorine dioxide:
(1) action time 1mins, the killing rates of common staphylococcus aureus, escherichia coli, dysentery bacterium, Bacillus typhi, fungus, mycete etc. is reached 100%;
(2) action time 3mins, to killing rates such as common virus such as hepatitis A virus, hepatitis B virus, hepatitis E virus, HIV, poliovirus, rotavirus, ECHO virus, Coxsackie viruss more than 99%;
(3) action time 3mins, to the killing rate of viruses such as respiratory infectious virus such as bird flu, foot and mouth disease, influenza A more than 99%.
Though, the present invention has been done detailed description in the preceding text with general explanation and specific embodiments, on basis of the present invention, can to some modifications of do or improvement, this will be apparent to those skilled in the art.Therefore, these modifications or the improvement on the basis of not departing from spirit of the present invention, made all belong to the scope that requirement of the present invention is protected.
Claims (3)
1. disinfection hand cleanser that contains chlorine dioxide, process by following components in weight percentage:
2. disinfection hand cleanser that contains chlorine dioxide, process by following components in weight percentage:
3. disinfection hand cleanser that contains chlorine dioxide, process by following components in weight percentage:
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| CN201010110707XA CN101766543B (en) | 2010-02-10 | 2010-02-10 | Hand sanitizer containing chlorine dioxide |
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| CN201010110707XA CN101766543B (en) | 2010-02-10 | 2010-02-10 | Hand sanitizer containing chlorine dioxide |
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| CN101766543A CN101766543A (en) | 2010-07-07 |
| CN101766543B true CN101766543B (en) | 2012-02-01 |
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Cited By (1)
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|---|---|---|---|---|
| CN111204713A (en) * | 2020-03-03 | 2020-05-29 | 金溯源(北京)科技有限公司 | Preparation method and formula of food-grade chlorine dioxide |
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| CN101176700A (en) * | 2007-10-29 | 2008-05-14 | 广东庆发药业有限公司 | Antimicrobial disinfection hand cleanser and preparation method thereof |
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| CN111204713A (en) * | 2020-03-03 | 2020-05-29 | 金溯源(北京)科技有限公司 | Preparation method and formula of food-grade chlorine dioxide |
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