CN103493847B - Environment-friendly immersing and spraying liquid and preparation method thereof - Google Patents

Abstract

The invention relates to an environment-friendly immersing and spraying liquid characterized by comprising the following components in percentage by weight: 0.5-1.2% of polyhexamethylene biguanidine, 0.15-0.25% of tea tree essential oil, 0.15-0.2% of lavender essential oil, 0.1-0.15% of mint oil, 0.1-0.5% of undecylenoyl glycine, 0.5-1.1% of solubilizer, 28-35% of acetaldehyde-free ethanol, 0.01-0.03% of sodium phytate and 61.77-70.49% of water. Compared with the conventional preparation technology of the traditional immersing and spraying liquid for a wiper, the preparation method of the environment-friendly immersing and spraying liquid has the advantages that the pharmaceutical-grade polyhexamethylene biguanidine as an approximately-nontoxic environment-friendly disinfector is selected and blended into a fully-transparent microemulsion system together with various natural essential oils by means of a nontoxic solubilizer system with relatively good surface activity, is matched with an eatable polybasic carboxylic acid and sodium phytate complexing agent to form a harmonic and synergistic system to remarkably improve the bacterium and virus inhibiting and killing performances of a composite system, has the effect of not remaining any mark during dry cleaning, and is safe, nontoxic and stable in pesticide effect; the immersing and spraying liquid is wide in application range and environment-friendly.

Description

Environment-friendly type leaching hydrojet and preparation method

Technical field

The present invention relates to a kind of thimerosal and preparation method thereof, but specifically finger is a kind of has to pathogenic microorganisms environment-friendly type leaching hydrojet and the preparation method that wide spectrum kills effect.

Background technology

Along with the raising of civilization degree and the quickening of modernization, such as get together, commercial affairs, the mankind's activity of studying abroad and travelling and so on be increasingly extensive, public implements residing for large building, the probability polluted by the harmful microorganism easily causing the diseases such as venereal disease, the ringworm of the foot, bleb, hepatitis and influenza as appliance remote control plate, computor-keyboard, mouse, game paddle, electromagnetic physiotherapeutic instrument, electric shaver, communication appliance, tea set, bedding, bathroom facilities and slippers etc. greatly increases, and becomes the major hidden danger of human health life.People expect appearing on the market early of efficient, quick, nontoxic, colourless, tasteless, non-stimulated, free from corrosion environmental type thimerosal and respective wet towel products.Technos pays arduous effort for this reason, researches and develops the thimerosal new product of successfully a great deal of and specification, but still has larger gap with the requirement that consumer advocates the new concept of environmental protection, and the weak point that product exposes can summarize following several respects:

(1) synthetic chemistry component thimerosal series

1. hypochlorite, chlorated fulminuric acid salt is comprised until classical thimerosal such as the Active Chlorine system oxidized form of dichloride chlorine etc., though stabilized process, tool wide spectrum, the advantage such as efficient, quick, but the thimerosal peculiar smell of the type heavy, stimulate human skin, corrosion implements surface, should not to store for a long time and apparent with the inferior position such as other surfactant compatibility difficulty., as the tincture of iodine, povidone iodine and chlorhexidine iodine etc., also there is the deficiencies such as dirty erosion, peculiar smell and stimulation in other metastable halogen system thimerosal;

2. the active oxygen series thimerosal for the purpose of Stabilizing Hydrogen Peroxide, comprise percarbonate, persulfate and carbamide peroxide etc., though tool wide spectrum, quick-acting, free from extraneous odour and the advantage such as not dye, but still deposit and stimulate human skin, corrosion implements surface, should not store for a long time and the defects such as other Surfactant Chemistry structure of destructible;

3. nano-disinfectant and solubility collargol kill bacteria and virus capable strong, non-residual toxicity, significant to environmental protection, but this series products stabilization technique does not reach a standard, cost of manufacture is higher, cannot large-scale promotion;

4. the chemical modifications such as heterocycle are brought to traditional disinfection agent, the new disinfectant such as oxidation glutaraldehyde, state amyldiacid peroxide, acidic oxidized electric potential water that the new disinfectant such as the imidazolone type obtained, glycolylurea class, quaternary ammonium salt and oxidation processes obtain, wide spectrum, quick-acting, low toxicity, but to the dirt erosion of tool face and the stimulation essence elimination not yet of human skin;

5. the new polyoxyethylene polyhexamethylene guanide released is low toxicity, tasteless, the better disinfectant of nonirritant, antibacterial effect that it and reacting ethylene oxide obtain by dissolubility and permeability for improving guanidine class, but in product, the risk that composition exceeds standard that is out of favour such as dioxanes still exists;

(2) biological disinfectant series

1. microbial metabolic products and for the antibiotic peptide as raw in lactobacillus etc. of food additives as the synergy component of disinfectant, but such material cost is higher and bactericidal range is narrower;

2. little, active strong, the good water solubility of genetic engineered product antibacterial peptide molecular weight, thermally-stabilised, has a broad antifungal spectrum, there is unique antibacterial mechanisms, immunogenicity is low, only act on prokaryotic and the eukaryotic of pathology occur and normal eukaryotic is almost had no side effect, have simultaneously and not easily produce the features such as drug resistance, function be extensive, can be used as high-end disinfectant, but such material cost is higher and bactericidal range is wideless, limits throughput;

3. shitosan shows antibiotic property to multiple-microorganism, there is protective effect again to human body, become the focus of disinfectant exploitation, the colourless transparent liquid be made up of shitosan, hydroxycarboxylic acid etc., slightly tart flavour, pH value is 4.7, has good killing action to bacterial propagule, saccharomycete, and anti-microbial property is stablized, little by organic substance influence, use safety, but shitosan is only applicable to the synergy component serving as disinfectant, and sterilization quick-acting is undesirable;

4. plant extracts disinfectant caters to people's fully natural green theory, and research deepens constantly, and the achievement comprising patent is more.If the volatile oil of the capsule of weeping forsythia and peppermint is for anti influenza aerosol; Seven Plants medicament extracts and the formulated preparation with bactericidal action of vegetable oil such as kuh-seng, chrysanthemum, rhizoma zingiberis; Bacterium must gram skin lotion be the compound of benzalkonium bromide of the coptis, rhizoma atractylodis, kuh-seng, frutus cnidii extract and 1000mg/L.

The Chinese invention patent application being CN201110113813.8 as application number discloses " a kind of plant essential oil bactericidal disinfectant ", it comprises following weight composition: eucalyptus oil 0.3%, tea oil 0.4%, mugwort oil 0.3%, rosemary oil 0.5%, bergamot oil 0.5%, lemon oil 0.5%, lavender oil 0.7%, caryophyllus oil 0.2%, thyme linaloe oil 0.4%, and the thinner of surplus.This application adopts Pure natural plant essential oil to make, compared with the bactericide of traditional human body skin bactericide, living-hygienic apparatus, there is natural environmental-protective, disinfection effect be good, smell is comfortable, to human body without any harm, be of value to the able-bodied feature of people.But pure plant extracts disinfectant kill bacteria and antiviral potency on the weak side, antimicrobial spectrum is wideless, need many components compatibility, color and luster is comparatively dark, easily pollutes implements surface, and self is oxidizable rotten, shelf-life is short, and certain plants essential oil and thinner are to skin irritatin comparatively greatly, cost of material is high, cannot become thimerosal main product;

(3) collaborative Compositional type thimerosal series

1. be made up of disinfectant, synergist, activator, stabilizing agent, solubilizer, surfactant, corrosion inhibiter, deodorizer, remover, adhesive and Alevaire etc., merge the collaborative Compositional type thimerosal series of synthesis chemical composition disinfectant and biological disinfectant advantage separately, because the interactive feature such as by force of its safety, low toxicity, efficient, wide spectrum and purposes is regarded as high-tech product.The research of this type of disinfectant at present enters molecular level, and its process comprises pathogenic microorganism pathogene structure clearly to be killed, the detailed process of growth and breeding metabolism; The acceptor of separation, purifying pharmaceutical effect; Be combined with genomics, proteomics, biochip, bioinformatics, determine the new target drone that special efficacy is single-minded; Develop new screening model and triage techniques, adopt according to structure-activity relationship the technology such as Computer-Aided Drug Design, computer molecular simulation, virtual drug technique, combinatorial chemistry and Combinatorial biocatalysis, high flux structure determination and screening to determine best antimicrobial collaborative compound scheme.Obviously, relate to that subject is many, requirement for experiment condition is strict, costly, cause that this type of new disinfectant development difficulty is large, the cycle is long, valuable product, the serious ability to bear departing from mass consumption.

2. with the empirical thimerosal complex preparation of traditional Chinese and western medicine classical theory for using for reference, effective fast, cost performance is high, and sensory trait is good, easy to use, and consumption increases in recent years.If application number is " polyoxy alkene guanidine disinfectant " disclosed in the Chinese invention patent application of CN00129390.7, a kind of active ingredient is disinfection sanitizer of the derivative of polyoxy alkylene guanidine (polyhexamethylene guanide) and preparation method thereof.Its component had and percentage by weight thereof are: polyoxy alkylene guanidine 0.01 ~ 0.5%, ethanol 0.002 ~ 0.05%, borneol 0.001 ~ 0.02%, purified water adds to 100%, polyoxy alkylene guanidine can be replaced by polyhexamethylene guanide, have nontoxic, colourless, tasteless, non-stimulated, corrosion-free, pollution-free, the feature of efficient, low concentration, good stability.Be suitable for the sterilization and disinfection of various occasion and various apparatus.This type of Compositional type patent with the water of cheapness for dispersion medium, but focus on bacterium to kill, need to be investigated to the effect that some easily causes dermopathic intractable fungi and virus, and because of the volatilization of moisture content medium too slow, it is inner and be not suitable for the sterilization of the public implements of the mark modernizations such as household remote plate, computor-keyboard, mouse, game paddle, electromagnetic physiotherapeutic instrument, electric shaver, communication appliance easily to infiltrate implements.

In sum, up to now, technos does not still develop wide spectrum, quick-acting, nothing dirt is lost, non-stimulated, quick-drying does not stay vestiges, storage stay-in-grade environmental type of a specified duration sterilizes the special leaching hydrojet of wiping cloth.

Summary of the invention

But technical problem to be solved by this invention be for the present situation of prior art provide a kind of to pathogenic microorganisms have wide spectrum kill effect quick-acting, without dirty erosion, nothing irritates, quick-drying does not stay vestiges, for a long time storage stay-in-grade environmental type soak hydrojet.

But another technical problem to be solved by this invention be to provide a kind of to pathogenic microorganisms have wide spectrum kill effect quick-acting, without dirty erosion, nothing irritates, quick-drying does not stay vestiges, storage stay-in-grade environmental type soaks hydrojet for a long time preparation method.

The present invention solves the problems of the technologies described above adopted technical scheme: this environment-friendly type leaching hydrojet, is characterized in that comprising following weight component:

Wherein, described poly hexamethylene biguanide is pharmaceutical grade high molecular polymer, the aqueous solution water white transparency of poly hexamethylene biguanide 18-21wt%;

Described tea tree ethereal oil, Lavender and peppermint oil are natural essential oil;

Described endecatylene acyl glycine is pharmaceutical grade white powder, the transparent state of 4-6wt% ethylene glycol solution of endecatylene acyl glycine and without cotton-shaped impurity;

The pharmaceutical grade ethanol of described full gear ethanol system full gear process, free from extraneous odour;

Described sodium phytate is pharmaceutical grade, and the 0.8-1.2wt% aqueous solution of this sodium phytate is clear state;

Described solubilizer is A or B, and wherein A is the mixture of Cremophor RH40 and cocounut oil alcohol ether-7; B is the mixture of cocounut oil alcohol ether-7, lauryl glycol ether and Cremophor RH40;

Described Cremophor RH40 and cocounut oil alcohol ether-7 are cosmetics-stage solubilizer.

As preferably, in described A, the content of described Cremophor RH40 is the 0.3-0.6% of described leaching hydrojet total amount, the content of described cocounut oil alcohol ether-7 be described leaching hydrojet total amount be 0.2-0.5%.

Described B is the EUMULGIN HPS of Kening Co., Ltd.

Preferably, described water is pure water, distilled water or deionized water.

The preparation method of above-mentioned environment-friendly type leaching hydrojet, is characterized in that comprising the steps:

L) mixed with full gear ethanol by described endecatylene acyl glycine, add solubilizer, temperature control, at 25 ~ 30 DEG C, is stirred to transparent; Then add tea tree ethereal oil, Lavender and peppermint oil, then be stirred to clear state; Obtain material A;

2) water withdrawal 4/5 water, within half an hour, at the uniform velocity drip described poly hexamethylene biguanide under 80 ~ 120rpm mixing speed, and then be warming up to 40 DEG C ~ 50 DEG C, and the transparent state of the system that is stirred to; Obtain material B;

3) separately get the water of remaining 1/5, mixing speed 80 ~ 120rpm adds whole sodium phytate, then is warming up to 40 DEG C ~ 50 DEG C, the transparent state of the system that is stirred to; Obtain material C;

4) 15-25 DEG C, under 80 ~ 100rpm mixing speed, material A is dropped in material B with the flow of 20 ~ 25 liters/min, stirs and add material C after 25-35 minute, then continue to be stirred to the transparent homogeneous state of mixed system, namely obtained environment-friendly type soaks hydrojet.

Compared with prior art, the present invention has following advantage:

But 1. rich innovatively introducing kills to virus the natural plant essential oils collaboration system be significantly made up of tea tree ethereal oil, Lavender and peppermint oil, coordinate and have effective green component endecatylene acyl glycine to intractable pathomycete, but make sterilization wiping cloth soak hydrojet kill bacterium, virus and fungi scope apparently higher than market like product, really accomplish broad-spectrum high efficacy;

2. the natural essential oil solubilizing systems that Cremophor RH40 and solubilizer cocounut oil alcohol ether-7 form is filtered out originally, under low ethanol concn, natural essential oil and water is made to form completely transparent microemulsion, give full play to the characteristics such as natural essential oil-ethanol system Thief zone, volatile and strong solubilising, make the dry-cleaning dirty removal capacities that thimerosal association is powerful, left over without solid content vestiges by scouring implements surface, therefore treat the sterilization scrubbing not being applicable to the public equipment such as electrical remote control plate, computor-keyboard, mouse, game paddle, electromagnetic physiotherapeutic instrument, electric shaver, communication appliance;

3. use the pharmaceutical grade sodium phytate with complexing and remarkable synergistic effect originally, replace traditional synthetics ethylenediamine tetra-acetic acid system complexing agent, significantly strengthen the Disinfection Effect of poly hexamethylene biguanide and endecatylene acyl glycine;

4. sterilization type leaching hydrojet provided by the present invention derives from function more than routine disinfection agent, and except the series of products such as wiping cloth leaching spray pasteurization towelette, leaching hydrojet itself also has following purposes:

A, with sprayer is supporting makes environmental type antiviral aerosol disinfectant, both can fresh air, again can sterilizing and anti-virus and flu-prevention;

The reasonable compatibility of b, endecatylene acyl glycine and natural essential oil, makes the spray obtained eliminate body odor as deodorant;

C, endecatylene acyl glycine are under the synergy of sodium phytate, effective to Staphylococcus epidermidis and propionibacterium acnes, therefore are particularly suitable for the treatment spray making the perverse tendency skin of powder;

But d, agent of killing as stupid property fungies such as the ringworm of the foot, make the anti-treating beri-beri spray of Efficient safe, detoxifying and relieving itching, foot foulness eliminating with sprayer is supporting, use rear step portion skin in refreshing clean, spray for a long time, beriberi symptom is obviously improved;

E, as disinfecting currency notes when counting liquid, rapidly and efficiently can kill the multiple pathogenic microorganismss such as the virus and bacteria that coin brings, nontoxic to human body skin, have no side effect, damage is not caused to coin and stains;

F, supporting sprayer use, and can be made into environmental type livestock and poultry cultivation sterilization aerosol, stop the propagation of zoonosis.

The preparation method of above-mentioned environment-friendly type leaching hydrojet provided by the present invention, processing step is rationally easy, and reaction easily controls, and equipment requirement is low, is applicable to suitability for industrialized production.

To sum up, instant invention overcomes the deficiencies in the prior art, provide one and both can be used for disinfecting wiping cloth leaching spray, again can decontamination separately, sterilize, the environment-friendly type of curing the disease leaching hydrojet, the high concentration essential oil all-transparent microemulsion system of its rich innovation, the height avoiding chemicals disinfectant to greatest extent irritates many drawbacks such as easily dirty erosion, to skin without irritated, effective fast, of many uses, safety and environmental protection.

Compared with soaking hydrojet conventional formulation techniques with existing wiping cloth, the present invention selects intimate nontoxic environmental protection disinfectant pharmaceutical grade poly hexamethylene biguanide, by relatively better surface-active nontoxic solubilizer system, with multiple natural essential oil furnishing all-transparent microemulsion system, and coordinate with Edible polybasic carboxylic acid sodium phytate complexing agent, form and be in harmonious proportion and synergy system, but remarkable improve compound system kill bacterial virus performance, dry-clean not trace, safety non-toxic and drug effect steady, this leaching hydrojet is of many uses, environmental protection.

Embodiment

Below in conjunction with embodiment, the present invention is described in further detail.

Embodiment 1

Charge ratio:

Preparation manipulation step:

In the reaction pot of 300 liters, vacuum sucks 140 kilograms of full gear ethanol, start the agitator that fire-proof motor drives, control mixing speed is 80rpm, temperature control is at 25 ~ 30 DEG C simultaneously, add solubilizer Cremophor RH40 1.5 kilograms and solubilizer cocounut oil alcohol ether-7 meter 1.0 kilograms, stir and within 20 minutes, make feed liquid completely transparent.Add tea tree ethereal oil 0.75 kilogram, Lavender 0.75 kilogram and peppermint oil 0.5 kilogram, stir and make feed liquid transparent state half an hour; Obtain material A;

Be in the 500 liters conventional stainless steel material pot of the stainless steel shell and tube condenser of 5 square metres at another band film-cooled heat, inject 281.96 kilograms of deionized waters, start the agitator that fire-proof motor drives, control mixing speed is 80rpm, divide within half an hour and add poly hexamethylene biguanide 2.5 kilograms for three times, be warming up to 40 DEG C ~ 50 DEG C again, stir and make feed liquid transparent state half an hour; Obtain material B;

In another 100 liter conventional stainless steel material pot, inject 70.49 kilograms of deionized waters, start agitator, control mixing speed is 80rpm, adds sodium phytate 0.05 kilogram, then is warming up to 40 DEG C ~ 50 DEG C, stirs and within 10 minutes, makes the transparent state of feed liquid; Obtain material C;

At normal temperatures, control mixing speed is 80rpm, open the high-order reaction pot bottom valve of 300 liter stainless steels of dress material A, by two pots of duct couplings, material A is dropped in the 500 liters conventional stainless steel material pot of dress material B with the flow of 20 liters/min from pot cover, stir and add material C after 30 minutes, continuing to be stirred to mixed system is complete transparent homogeneous state again, i.e. obtained environment-friendly type sterilization wiping cloth leaching hydrojet.

Embodiment 2

Charge ratio:

Preparation manipulation step:

In the conventional stainless steel reaction pot of 300 liters that band film-cooled heat is the stainless steel shell and tube condenser of 5 square metres, vacuum sucks 175 kilograms of full gear ethanol, start the agitator that fire-proof motor drives, controlling mixing speed is 80 revs/min, temperature control 25 ~ 30 DEG C (chuck leads to Steam Heating or logical cooling water temperature) simultaneously, add the peaceful solubilizer EUMULGINHPS of section and count 5.5 kilograms, stir and within 20 minutes, make feed liquid completely transparent.Add tea tree ethereal oil 1.25 kilograms, Lavender 1 kilogram and peppermint oil 0.75 kilogram, stir and make feed liquid transparent state half an hour; Obtain material A;

Be in the 500 liters conventional stainless steel material pot of the stainless steel shell and tube condenser of 5 square metres at another band film-cooled heat, injection 4/5ths i.e. 246.28 kilograms of deionized waters, start the agitator that fire-proof motor drives, control mixing speed is 80rpm, divide within half an hour and add poly hexamethylene biguanide 6 kilograms for three times, be warming up to 40 DEG C ~ 50 DEG C again, stir and make feed liquid transparent state half an hour; Obtain material B;

In another 100 liter conventional stainless steel material pot, inject remaining 1/5th i.e. 61.57 kilograms of deionized waters, start agitator, control mixing speed is 80rpm, add sodium phytate 0.15 kilogram, then be warming up to 40 DEG C ~ 50 DEG C, stir and within 10 minutes, make the transparent state of feed liquid; Obtain material C;

At normal temperatures, control mixing speed is 80rpm, starting vacuum system makes the 500 liters conventional stainless steel material pot of dress material B be in vacuum state, open the high-order reaction pot bottom valve of 300 liter stainless steels of dress material A, by two pots of duct couplings, material A is dropped in the 500 liters conventional stainless steel material pot of dress material B with the flow of 25 liters/min from pot cover, continuing to control mixing speed is 80rpm, stir and add material C after 30 minutes, continuing to be stirred to mixed system is complete transparent homogeneous state again, i.e. obtained environment-friendly type sterilization wiping cloth leaching hydrojet.

Obtained environment-friendly type sterilization wiping cloth leaching hydrojet is colourless to the micro-thick liquid of light yellow clear, and fragrant, low-temperature stability is good.

Embodiment 3 to embodiment 7

The formula composition of embodiment 3 to embodiment 7 is as shown in table 1.

Table 1

Component	Embodiment 3	Embodiment 4	Embodiment 5	Embodiment 6	Embodiment 7
						Poly hexamethylene biguanide	0.5％	0.65％	0.8％	1.0％	1.2％
Tea tree ethereal oil	0.15％	0.18％	0.20％	0.25％	0.23％
						Lavender	0.15％	0.16％	0.18％	0.2％	0.17％
Peppermint oil	0.1％	0.12％	0.15％	0.13％	0.14％
						Endecatylene acyl glycine	0.1％	0.2％	0.3％	0.4％	0.5％
Solubilizer *	0.3+0.2％	0.4+0.3％	0.5+0.4％	0.6+0.5％	HPS meter 0.5%
						Full gear ethanol	28％	30％	32％	35％	30％
Pharmaceutical grade sodium phytate	0.01％	0.018％	0.025％	0.03％	0.02％
						Water	70.49％	67.972％	65.445％	61.89％	67.24％

* the mixture that the solubilizer used in embodiment 3 to embodiment 6 is Cremophor RH40 and cocounut oil alcohol ether-7, previous numeral is the content of Cremophor RH40, and a rear numeral is the content of cocounut oil alcohol ether-7.

HPS in embodiment 7 is the EUMULGIN HPS solubilizer that Kening Co., Ltd produces.

The preparation method of embodiment 3 to embodiment 7 and the identical of embodiment 1.

Claims (5)

1. an environment-friendly type leaching hydrojet, is characterized in that being made up of following weight component:

Wherein, described poly hexamethylene biguanide is pharmaceutical grade high molecular polymer, the aqueous solution water white transparency of poly hexamethylene biguanide 18-21wt%;

Described tea tree ethereal oil, Lavender and peppermint oil are natural essential oil;

Described endecatylene acyl glycine is pharmaceutical grade white powder, the transparent state of 5wt% ethylene glycol solution of endecatylene acyl glycine and without cotton-shaped impurity;

The pharmaceutical grade ethanol of described full gear ethanol system full gear process, free from extraneous odour;

Described sodium phytate is pharmaceutical grade, and the 1wt% aqueous solution of this sodium phytate is clear state;

Described solubilizer is A or B, and wherein A is the mixture of Cremophor RH40 and cocounut oil alcohol ether-7; B is the mixture of cocounut oil alcohol ether-7, lauryl glycol ether and Cremophor RH40;

Described Cremophor RH40 and cocounut oil alcohol ether-7 are cosmetics-stage solubilizer.

2. environment-friendly type according to claim 1 leaching hydrojet, it is characterized in that in described A, the content of described Cremophor RH40 is the 0.3-0.6% of described leaching hydrojet total amount, the content of described cocounut oil alcohol ether-7 be described leaching hydrojet total amount be 0.2-0.5%.

3. environment-friendly type leaching hydrojet according to claim 1, is characterized in that described B is the EUMULGIN HPS of Kening Co., Ltd.

4. the environment-friendly type leaching hydrojet according to claim 1,2 or 3, is characterized in that described water is pure water, distilled water or deionized water.

5. the preparation method of environment-friendly type leaching hydrojet as claimed in claim 1, is characterized in that comprising the steps:

L) mixed with full gear ethanol by described endecatylene acyl glycine, add solubilizer, temperature control, at 25 ~ 30 DEG C, is stirred to transparent; Then add tea tree ethereal oil, Lavender and peppermint oil, then be stirred to clear state; Obtain material A;

2) water withdrawal 4/5 water, within half an hour, at the uniform velocity drip described poly hexamethylene biguanide under 80 ~ 120rpm mixing speed, and then be warming up to 40 DEG C ~ 50 DEG C, and the transparent state of the system that is stirred to; Obtain material B;

3) separately get the water of remaining 1/5, mixing speed 80 ~ 120rpm adds whole sodium phytate, then is warming up to 40 DEG C ~ 50 DEG C, the transparent state of the system that is stirred to; Obtain material C;

4) 15-25 DEG C, under 80 ~ 100rpm mixing speed, material A is dropped in material B with the flow of 20 ~ 25 liters/min, stirs and add material C after 25-35 minute, then continue to be stirred to the transparent homogeneous state of mixed system, namely obtained environment-friendly type soaks hydrojet.