CN103205317A - Rheologically modified cleanser for kitchen heavy oily dirt, and preparation method thereof - Google Patents
Rheologically modified cleanser for kitchen heavy oily dirt, and preparation method thereof Download PDFInfo
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- CN103205317A CN103205317A CN2013100946998A CN201310094699A CN103205317A CN 103205317 A CN103205317 A CN 103205317A CN 2013100946998 A CN2013100946998 A CN 2013100946998A CN 201310094699 A CN201310094699 A CN 201310094699A CN 103205317 A CN103205317 A CN 103205317A
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- Prior art keywords
- butyl ether
- ether
- glycol butyl
- dipropylene glycol
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002904 solvent Substances 0.000 claims abstract description 36
- 239000006254 rheological additive Substances 0.000 claims abstract description 35
- 239000003513 alkali Substances 0.000 claims abstract description 33
- 229930182470 glycoside Natural products 0.000 claims abstract description 33
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 33
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 33
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 21
- 239000011734 sodium Substances 0.000 claims abstract description 21
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 21
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 26
- 239000000295 fuel oil Substances 0.000 claims description 25
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 24
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 24
- 238000000518 rheometry Methods 0.000 claims description 22
- CDNNZJLFCPFZDF-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;oxalic acid Chemical compound OC(=O)C(O)=O.OC(=O)[C@@H](N)CCC(O)=O CDNNZJLFCPFZDF-DFWYDOINSA-N 0.000 claims description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 20
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 20
- 150000005215 alkyl ethers Chemical class 0.000 claims description 20
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 18
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- 238000013019 agitation Methods 0.000 claims description 18
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 14
- 150000002191 fatty alcohols Chemical class 0.000 claims description 13
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000013531 ACULYN rheology modifier Substances 0.000 claims description 12
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 230000032683 aging Effects 0.000 claims description 10
- 239000012046 mixed solvent Substances 0.000 claims description 10
- 238000012856 packing Methods 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000001514 detection method Methods 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 9
- 238000005070 sampling Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 229960000735 docosanol Drugs 0.000 claims description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- JDRSMPFHFNXQRB-IBEHDNSVSA-N decyl glucoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JDRSMPFHFNXQRB-IBEHDNSVSA-N 0.000 claims description 7
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 7
- 229940048848 lauryl glucoside Drugs 0.000 claims description 7
- 229960004418 trolamine Drugs 0.000 claims description 7
- ORUDEUCNYHCHPB-OUUBHVDSSA-N (2r,3s,4s,5r,6r)-2-(hydroxymethyl)-6-tetradecoxyoxane-3,4,5-triol Chemical compound CCCCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ORUDEUCNYHCHPB-OUUBHVDSSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 229920006037 cross link polymer Polymers 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 6
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical group CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 claims description 6
- LBIYNOAMNIKVKF-FPLPWBNLSA-N palmitoleyl alcohol Chemical compound CCCCCC\C=C/CCCCCCCCO LBIYNOAMNIKVKF-FPLPWBNLSA-N 0.000 claims description 6
- LBIYNOAMNIKVKF-UHFFFAOYSA-N palmitoleyl alcohol Natural products CCCCCCC=CCCCCCCCCO LBIYNOAMNIKVKF-UHFFFAOYSA-N 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000443 aerosol Substances 0.000 abstract description 2
- 239000001273 butane Substances 0.000 abstract description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 2
- 239000001294 propane Substances 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000012466 permeate Substances 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 abstract 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 20
- 238000004140 cleaning Methods 0.000 description 8
- 239000012459 cleaning agent Substances 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000012706 ammonia caramel Nutrition 0.000 description 2
- 239000004125 ammonia caramel Substances 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 244000137852 Petrea volubilis Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to rheologically modified cleanser for kitchen heavy oily dirt, and a preparation method thereof. The aerosol cleanser packaged with pressure cylinders and filled with Freon, propane or butane and the like as propellant may cause dangers to the environment and may explode at high temperature. The rheologically modified cleanser for kitchen heavy oily dirt comprises, by weight percent, 0.2-3% of rheological modifier, 0.2-1% of tetrasodium glutamate diacetate, 0.5-8% of fatty alcohol-polyoxyethylene ether, 1-10% of alkyl glycoside, 0.1-6% of sodium fatty alcohol-polyoxyethylene ether sulfate, 1-8% of solvent, 0.5-5% of alkali, 0-0.5% of essence, and the balance of water. The rheologically modified cleanser for kitchen heavy oily dirt is fine in rheological property. With acrylic polymer emulsion as the rheological modifier for the rheologically modified cleanser for kitchen heavy oily dirt, the cleanser is kept to contact with the dirt for a longer time, enough time is provided for the cleanser to permeate the dirt, loss is avoided, and efficiency of the cleanser is increased.
Description
Technical field
The present invention relates to a kind of sanitising agent, be specifically related to a kind of rheology modified version kitchen heavy oil stain sanitising agent and preparation method thereof.
Background technology
Be subjected to the influence of traditional cookery mode and cooking custom, domestic kitchen fume has caused very big influence to kitchen utilities, and the cleaning difficulty is bigger.A kitchen oil stain part is that edible oil is attached on the solid surface by physics or chemical action in gastronomical process, and this part greasy dirt is removed relatively easily.Another part is owing to polymerization takes place in gastronomical process consaturated oil in the edible oil, forms the very strong film dirt of one deck adhesivity, and this type of dirt is difficult the removal.The kitchen oil stain sanitising agent is in order to reach the purpose of strong dirt-removing in the market, all use high-alkali or high solvent in the prescription, but even so, because product rheology is not good, on vertical surface, when also fully not contacting with dirt, because a little less than the adhesive power, gutter down, wasted sanitising agent, and greatly reduce cleaning efficiency.
The aerosol-type kitchen cleaning agent can effectively address this problem, but because this series products must adopt the pressure-pot packing, and fill freonll-11 or gases such as propane, butane as propelling agent, these propelling agents or belong to volatile organic matter (VOC), can work the mischief to environment, belong to combustible material, and aerosol products at high temperature there is the danger of blast.Therefore, people wish a kind of safety, environmental protection, the non-aerosol-type kitchen heavy oil stain sanitising agent that adhesive power is strong.But there is not such kitchen heavy oil stain sanitising agent with excellent properties openly to report up to now as yet.
Summary of the invention
The purpose of this invention is to provide a kind of can be attached to for a long time the article that are cleaned and gradually to the dirt internal penetration, overcome rheology modified version kitchen heavy oil stain sanitising agent of the problem that general liquid cleaner runs off in use easily and preparation method thereof.
The technical solution adopted in the present invention is:
A kind of rheology modified version kitchen heavy oil stain sanitising agent is characterized in that:
The component that includes following mass percent:
Rheology modifiers 0.2-3%;
L-glutamic acid oxalic acid four sodium 0.2-1%;
Fatty alcohol-polyoxyethylene ether 0.5-8%;
Alkyl glycoside 1-10%;
Polyoxyethylene alkyl ether sulfate sodium 0.1-6%;
Solvent 1-8%;
Alkali 0.5-5%;
Water surplus.
Be added with essence in the described prescription, the mass percent of interpolation is 0＜m ≦ 0.5%.
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC, Novethix L-10 or ACULYN 28;
Or choose acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, commodity are called ACULYN 22;
Or choose acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, commodity are called SYNTH2000;
Or choose acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, commodity are called OptasenseG82.
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9.
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside.
Described solvent is single or mixed solvent, be specially the dipropylene glycol butyl ether, the dipropylene glycol propyl ether, the propylene glycol butyl ether, the Diethylene Glycol butyl ether, a kind of in the methyl-2-pyrrolidone, or dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether, or methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether, the dipropylene glycol butyl ether, the propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone, the dipropylene glycol propyl ether, the Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether, the dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether.
Described water is deionized water or softening water.
Described alkali is selected from trolamine, monoethanolamine, water glass, sodium hydroxide, potassium hydroxide.
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent is characterized in that:
Realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 0.2-3%;
L-glutamic acid oxalic acid four sodium 0.2-1%;
Fatty alcohol-polyoxyethylene ether 0.5-8%;
Alkyl glycoside 1-10%;
Polyoxyethylene alkyl ether sulfate sodium 0.1-6%;
Solvent 1-8%;
Alkali 0.5-5%;
Essence 0-0.5%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 50-60 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 40 ± 2 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 20-30min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC, Novethix L-10 or ACULYN 28;
Or choose acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, commodity are called ACULYN 22;
Or choose acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, commodity are called SYNTH2000;
Or choose acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, commodity are called OptasenseG82;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described solvent is single or mixed solvent, be specially the dipropylene glycol butyl ether, the dipropylene glycol propyl ether, the propylene glycol butyl ether, the Diethylene Glycol butyl ether, a kind of in the methyl-2-pyrrolidone, or dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether, or methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether, the dipropylene glycol butyl ether, the propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone, the dipropylene glycol propyl ether, the Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether, the dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether;
Described water is deionized water or softening water;
Described alkali is selected from trolamine, monoethanolamine, water glass, sodium hydroxide, potassium hydroxide.
The present invention has the following advantages:
1, the present invention has good rheological, adopt acrylate polymer emulsion as kitchen heavy oil stain sanitising agent rheology modifiers, both prolonged the duration of contact of sanitising agent and dirt, make sanitising agent time enough be arranged to the dirt internal penetration, simultaneously avoid general kitchen grease sanitising agent losing issue in use again, improved clean-out system efficient.
2, sanitising agent of the present invention is the low-viscosity (mobile) liquid with good thixotropic property, adopts conventional pump just can make sanitising agent stick to the dirt surface for a long time, has saved the single usage quantity of sanitising agent.Without phosphorus in the prescription, no abrasive material can not damage the kitchen tools surface, does not contain the ethylene glycol monobutyl ether solvent, smell is pure and fresh, meet household detergent environmental labelling product technical requirements (HJ 458-2009), it is simple to have technology, easy to prepare, be easy to produce in batches, shelf-life is long, and characteristics such as product price ratio ideal can be widely used in the cleaning of the various surperficial dirts in kitchen.
Embodiment
The present invention will be described in detail below in conjunction with embodiment.
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 0.2-3%;
L-glutamic acid oxalic acid four sodium 0.2-1%;
Fatty alcohol-polyoxyethylene ether 0.5-8%;
Alkyl glycoside 1-10%;
Polyoxyethylene alkyl ether sulfate sodium 0.1-6%;
Solvent 1-8%;
Alkali 0.5-5%;
Essence 0-0.5%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 50-60 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 40 ± 2 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 20-30min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC, Novethix L-10 or ACULYN 28;
Or choose acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, commodity are called ACULYN 22;
Or choose acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, commodity are called SYNTH2000;
Or choose acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, commodity are called OptasenseG82;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described solvent is single or mixed solvent, be specially the dipropylene glycol butyl ether, the dipropylene glycol propyl ether, the propylene glycol butyl ether, the Diethylene Glycol butyl ether, a kind of in the methyl-2-pyrrolidone, or dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether, or methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether, the dipropylene glycol butyl ether, the propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone, the dipropylene glycol propyl ether, the Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether, the dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether;
Described water is deionized water or softening water;
Described alkali is selected from trolamine, monoethanolamine, water glass, sodium hydroxide, potassium hydroxide.
Embodiment 1:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 0.2%;
L-glutamic acid oxalic acid four sodium 0.2%;
Fatty alcohol-polyoxyethylene ether 0.5%;
Alkyl glycoside 1%;
Polyoxyethylene alkyl ether sulfate sodium 0.1%;
Solvent 1%;
Alkali 0.5%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 50 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 38 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, stir 20min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen octyl glucoside;
Described solvent is single solvent, is specially a kind of in dipropylene glycol butyl ether, dipropylene glycol propyl ether, propylene glycol butyl ether, Diethylene Glycol butyl ether, the methyl-2-pyrrolidone;
Described water is deionized water;
Described alkali is chosen trolamine.
Embodiment 2:
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 1%;
L-glutamic acid oxalic acid four sodium 0.4%;
Fatty alcohol-polyoxyethylene ether 2%;
Alkyl glycoside 2%;
Polyoxyethylene alkyl ether sulfate sodium 2%;
Solvent 2%;
Alkali 1%;
Essence 0.1%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 50 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 38 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 20min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Novethix L-10;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen Plantacare 818;
Described solvent is mixed solvent, is specially dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether;
Described water is deionized water;
Described alkali is chosen trolamine.
Embodiment 3:
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 1.5%;
L-glutamic acid oxalic acid four sodium 0.6%;
Fatty alcohol-polyoxyethylene ether 4%;
Alkyl glycoside 4%;
Polyoxyethylene alkyl ether sulfate sodium 3%;
Solvent 4%;
Alkali 2%;
Essence 0.2%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 55 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 40 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 25min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called ACULYN 28;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen Plantacare 818;
Described solvent is mixed solvent, is specially methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether;
Described water is deionized water;
Described alkali is chosen monoethanolamine.
Embodiment 4:
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 2%;
L-glutamic acid oxalic acid four sodium 0.8%;
Fatty alcohol-polyoxyethylene ether 6%;
Alkyl glycoside 6%;
Polyoxyethylene alkyl ether sulfate sodium 4%;
Solvent 6%;
Alkali 3%;
Essence 0.3%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 55 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 40 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 25min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, and commodity are called ACULYN 22;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen the lauryl glucoside;
Described solvent is mixed solvent, is specially dipropylene glycol butyl ether, propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone;
Described water is softening water;
Described alkali is chosen water glass.
Embodiment 5:
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 2.5%;
L-glutamic acid oxalic acid four sodium 1%;
Fatty alcohol-polyoxyethylene ether 8%;
Alkyl glycoside 8%;
Polyoxyethylene alkyl ether sulfate sodium 5%;
Solvent 8%;
Alkali 4%;
Essence 0.4%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 60 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 42 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 30min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, and commodity are called SYNTH2000;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen the lauryl glucoside;
Described solvent is mixed solvent, is specially dipropylene glycol propyl ether, Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether;
Described water is softening water;
Described alkali is chosen sodium hydroxide.
Embodiment 6:
The preparation method of a kind of rheology modified version kitchen heavy oil stain sanitising agent involved in the present invention, realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 3%;
L-glutamic acid oxalic acid four sodium 1%;
Fatty alcohol-polyoxyethylene ether 8%;
Alkyl glycoside 10%;
Polyoxyethylene alkyl ether sulfate sodium 6%;
Solvent 8%;
Alkali 5%;
Essence 0.5%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 60 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 42 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 30min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
Wherein:
Described rheology modifiers is chosen acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, and commodity are called OptasenseG82;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is chosen the myristyl glucoside;
Described solvent is mixed solvent, is specially dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether;
Described water is softening water;
Described alkali is chosen potassium hydroxide.
Rheology modifiers among the present invention is acrylate copolymer, itself is the low viscosity emulsion form, and easy handling can provide good viscosity in low surfactant and alkaline system, and this viscosity has good thixotropy.
The glucose that alkyl glycoside is transformed by natural plant starch such as corn, potatoes and derive from the Fatty Alcohol(C12-C14 and C12-C18) that Oleum Cocois, palm wet goods natural fats and oils are produced, dehydrating condensation under acid catalysis.Have good surfactivity, the performance of deoiling is strong, even still have very high solvability in highly basic, salts solution, greasy dirt is had the good emulsifying function, is a kind of nontoxic level raw material.
The branched fatty alcohol Soxylat A 25-7 has good dynamic surface tension, has good removal greasy dirt function, and safety and environmental protection.
Selected solvent has excellent dissolution greasy dirt ability, and smell is pure and fresh, and non-volatility organism (VOC) can not pollute environment.
Below be the performance test explanation of sanitising agent involved in the present invention:
Experiment 1:
This contrivance and dirt have the excellent contact time, can also can reach identical clean effect under the condition that reduces single cleaning usage quantity.
The invention cleaning agent for kitchen of identical weight is sprayed on the vertical glass surface that size is 30 * 60cm simultaneously with commercially available kitchen heavy oil stain cleaning, glass 30cm limit is placed on the desktop, requirement is sprayed on the top near vertical glass surface, and the materials flow of record liquid was dropped down to the time of glass bottom.
Conclusion (of pressure testing): the required time of this invention cleaning agent for kitchen is 180-300s, and the commercially available product of competing then gutter down in 10-40s.
Experiment 2:
The cleaning efficiency checking
1) the test preparation of kitchen grease
Test is composed as follows with the kitchen grease:
Soybean oil 64g, no ammonia caramel colorant 8g, wheat-flour 12g, lard 8g, butter 8g, glyceryl monostearate 2.4g.
Test is undertaken by following with the preparation of kitchen grease
In the 250mL plastic beaker, take by weighing soybean oil, butter, lard and glyceryl monostearate, 50 ℃ of heating for dissolving of water-bath; Stir on the limit, after the limit is cooled to 30 ℃, adds no ammonia caramel colorant, stirs 30min with the speed that is no less than 1000r/min, and emulsification evenly back adds wheat-flour, restir 10min, and ageing 24h, it is standby to put cold compartment of refrigerator, returns to 20 ℃ ~ 25 ℃ during use.
2) test is with the preparation of dirty sheet
With 240
#Sand paper is layered on the flat board, is 5 * 2.5 * 0.35cm test piece polishing light with specification, and the polishing direction is parallel to the long limit of test piece, the test piece that polishing is good is cleaned with absorbent gauze or absorbent cotton earlier, hang on S-hook, immerse in the dehydrated alcohol, clean with tweezers folder absorbent gauze or absorbent cotton again.Then test piece is moved to rinsing in acetone or (30～60) ℃ sherwood oil, behind hot blast drying, clean test piece is connected S type hook block hang on the test piece frame standby.
3) evaluation of cleaning power
Test piece after cleaning is hung in (40 ± 2) ℃ baking oven behind the dry 30min.Put into moisture eliminator, weighing m behind the 30min
0(claim accurate to ± 0.2mg), the test piece after the weighing is lain on the clean filter paper, with the greasy dirt that the pocket knife picked-up prepares, quality control is between 0.4g～0.5g.Evenly coated is at the position of test piece one side regulation.Dry and handle weighing m behind the 24h
1(claim standard extremely ± 0.2mg), test piece is vertically placed, respectively 2g cleaning agent for kitchen of the present invention and commercially available cleaning agent for kitchen are sprayed on the dirty sheet, after leaving standstill 3min, clean greasy dirt 30s with clean cotton yarn or cloth, test piece is placed on the thermostatic drying chamber baking 1h of (40 ± 2) ℃, moves in the moisture eliminator, cooling back weighing m
2(claim standard extremely ± 0.2mg), calculate detersive power.
Detersive power is calculated as follows with massfraction (f%) expression of flush away greasy dirt
In the formula:
m
0---test piece quality, g;
m
1---quality behind the test piece coating greasy dirt, g;
m
2---back quality, g are cleaned in the test piece of defiling
Conclusion (of pressure testing): the rate of deoiling of this invention cleaning agent for kitchen is all more than 95%, and the commercially available rate of deoiling of product of competing is then at 75-85%.
[0044] it is cited that content of the present invention is not limited to embodiment, and the conversion of any equivalence that those of ordinary skills take technical solution of the present invention by reading specification sheets of the present invention is claim of the present invention and contains.
Claims (10)
1. rheology modified version kitchen heavy oil stain sanitising agent is characterized in that:
The component that includes following mass percent:
Rheology modifiers 0.2-3%;
L-glutamic acid oxalic acid four sodium 0.2-1%;
Fatty alcohol-polyoxyethylene ether 0.5-8%;
Alkyl glycoside 1-10%;
Polyoxyethylene alkyl ether sulfate sodium 0.1-6%;
Solvent 1-8%;
Alkali 0.5-5%;
Water surplus.
2. a kind of rheology modified version according to claim 1 kitchen heavy oil stain sanitising agent is characterized in that:
Be added with essence in the described prescription, the mass percent of interpolation is 0＜m ≦ 0.5%.
3. a kind of rheology modified version according to claim 1 and 2 kitchen heavy oil stain sanitising agent is characterized in that:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC, Novethix L-10 or ACULYN 28;
Or choose acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, commodity are called ACULYN 22;
Or choose acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, commodity are called SYNTH2000;
Or choose acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, commodity are called OptasenseG82.
4. a kind of rheology modified version according to claim 3 kitchen heavy oil stain sanitising agent is characterized in that:
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9.
5. a kind of rheology modified version according to claim 4 kitchen heavy oil stain sanitising agent is characterized in that:
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside.
6. a kind of rheology modified version according to claim 5 kitchen heavy oil stain sanitising agent is characterized in that:
Described solvent is single or mixed solvent, be specially the dipropylene glycol butyl ether, the dipropylene glycol propyl ether, the propylene glycol butyl ether, the Diethylene Glycol butyl ether, a kind of in the methyl-2-pyrrolidone, or dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether, or methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether, the dipropylene glycol butyl ether, the propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone, the dipropylene glycol propyl ether, the Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether, the dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether.
7. a kind of rheology modified version according to claim 6 kitchen heavy oil stain sanitising agent is characterized in that:
Described water is deionized water or softening water.
8. a kind of rheology modified version according to claim 7 kitchen heavy oil stain sanitising agent is characterized in that:
Described alkali is selected from trolamine, monoethanolamine, water glass, sodium hydroxide, potassium hydroxide.
9. the preparation method of a rheology modified version kitchen heavy oil stain sanitising agent is characterized in that:
Realized by following steps:
Step 1: each component is got the raw materials ready by following mass percent:
Rheology modifiers 0.2-3%;
L-glutamic acid oxalic acid four sodium 0.2-1%;
Fatty alcohol-polyoxyethylene ether 0.5-8%;
Alkyl glycoside 1-10%;
Polyoxyethylene alkyl ether sulfate sodium 0.1-6%;
Solvent 1-8%;
Alkali 0.5-5%;
Essence 0-0.5%;
Water surplus;
Step 2: add water in batch tank, and heat, temperature is controlled to 50-60 ℃, adds rheology modifiers and L-glutamic acid oxalic acid four sodium then, stirs;
Step 3: under agitation add fatty alcohol-polyoxyethylene ether, polyoxyethylene alkyl ether sulfate sodium, be stirred to dissolving fully;
Step 4: add alkyl glycoside, be stirred to dissolving fully;
Step 5: be cooled to 40 ± 2 ℃ while stirring, add alkali, stir 510min;
Step 6: under agitation add solvent, essence stirs 20-30min;
Step 7: filter and ageing with 300 order filtering nets;
Step 8: sampling Detection, finished product packing.
10. the preparation method of a kind of rheology modified version according to claim 9 kitchen heavy oil stain sanitising agent is characterized in that:
Described rheology modifiers is chosen acrylate/behenyl alcohol polyethers-25 alkylmethacrylate polymer in the acrylate polymer emulsion, and commodity are called Tinovis GTC, Novethix L-10 or ACULYN 28;
Or choose acrylate/stearyl alcohol polyethers-20 alkylmethacrylate polymer, commodity are called ACULYN 22;
Or choose acrylate/Palmitoleyl alcohol polyethers-25 acrylate copolymer, commodity are called SYNTH2000;
Or choose acrylate/C10-30 alkylol acrylamide acid esters cross-linked polymer, commodity are called OptasenseG82;
Described fatty alcohol-polyoxyethylene ether is the branched fatty alcohol Soxylat A 25-7, and carbon chain lengths is C10 or C13, and the average adduct number of EO is 3-9;
Described alkyl glycoside is selected from octyl glucoside, Plantacare 818, lauryl glucoside, myristyl glucoside;
Described solvent is single or mixed solvent, be specially the dipropylene glycol butyl ether, the dipropylene glycol propyl ether, the propylene glycol butyl ether, the Diethylene Glycol butyl ether, a kind of in the methyl-2-pyrrolidone, or dipropylene glycol butyl ether and 1: 2 mixture of Diethylene Glycol butyl ether, or methyl-2-pyrrolidone and 1: 3 mixture of dipropylene glycol propyl ether, the dipropylene glycol butyl ether, the propylene glycol butyl ether, 1: 4: 2 mixture of methyl-2-pyrrolidone, the dipropylene glycol propyl ether, the Diethylene Glycol butyl ether, 2: 3: 1 mixture of dipropylene glycol butyl ether, the dipropylene glycol butyl ether, methyl-2-pyrrolidone, 2: 1: 4 mixture of dipropylene glycol propyl ether;
Described water is deionized water or softening water;
Described alkali is selected from trolamine, monoethanolamine, water glass, sodium hydroxide, potassium hydroxide.
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| CN103952249A (en) * | 2014-03-27 | 2014-07-30 | 侯鸣 | Kitchen oil stain cleaning agent and preparation method thereof |
| CN104194969A (en) * | 2014-09-24 | 2014-12-10 | 东元科技有限公司 | Heavy oil cleaning aerosol |
| CN104450246A (en) * | 2014-11-13 | 2015-03-25 | 王爱国 | Kitchen cleaning agent |
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| CN104194969A (en) * | 2014-09-24 | 2014-12-10 | 东元科技有限公司 | Heavy oil cleaning aerosol |
| CN104450246A (en) * | 2014-11-13 | 2015-03-25 | 王爱国 | Kitchen cleaning agent |
| CN104893838A (en) * | 2015-05-26 | 2015-09-09 | 广州立白企业集团有限公司 | Cleaning aerosol composition for household air conditioner and preparation method thereof |
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| CN105648458A (en) * | 2016-02-22 | 2016-06-08 | 苏州龙腾万里化工科技有限公司 | Stainless-steel product cleaning agent |
| CN105670826A (en) * | 2016-02-23 | 2016-06-15 | 宋德安 | Environment-friendly and efficient kitchen oil dirt detergent |
| CN106148030A (en) * | 2016-07-14 | 2016-11-23 | 广州立白企业集团有限公司 | Kitchen wet paper immersion and preparation method and application |
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| CN106833922A (en) * | 2016-12-28 | 2017-06-13 | 于文 | Cleaning agent for microwave oven and preparation method thereof |
| CN108300597A (en) * | 2018-03-01 | 2018-07-20 | 奥普家居股份有限公司 | A kind of antifouling cleaning agent |
| CN111117784A (en) * | 2019-12-21 | 2020-05-08 | 娇时日化（杭州）股份有限公司 | Bathroom cleaning agent and preparation process thereof |
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| CN103205317B (en) | 2014-11-12 |
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