CN101070513A - Farm-chemical biological decomposing composition and preparing method - Google Patents
Farm-chemical biological decomposing composition and preparing method Download PDFInfo
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- CN101070513A CN101070513A CN 200610078755 CN200610078755A CN101070513A CN 101070513 A CN101070513 A CN 101070513A CN 200610078755 CN200610078755 CN 200610078755 CN 200610078755 A CN200610078755 A CN 200610078755A CN 101070513 A CN101070513 A CN 101070513A
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Abstract
This invention has provided one kind of agricultural chemical biology decompound and its preparation method, it may be medicinal powder, pellet, tablet, liquid, young paste, it is mainly prepared by biological enzyme, stabilizer, adhesive, tax medicinal preparation, chelating agent, active agent through certain craft preparation, it may effective dissolve and decompose fruit vegetables surface and agricultural chemicals in the watery solution in a shorter time, it is one kind of home used and industrial used biological health preparation, which can be applied conveniently and security, and it is green environmental protection.
Description
Technical field
The present invention relates to farm-chemical biological decomposing composition and preparation method, the main combination of adopting modern biological enzyme technology, catalytic decomposition and emulsifying technology, produced the effect of good decomposition and removal agricultural chemicals, be mainly used in family and industry removing at the remains of pesticide in fruit, vegetables and other field.
Background technology
Along with developing rapidly of agricultural modernization, at the land for growing field crops, the orchard, the disease and pest that growing crop produces in the greenhouse etc., crop smotherings etc. adopt chemical insecticide, weedicide and sterilant are highly effective methods, it is low that it has a cost, easy to use, the obvious results characteristics, therefore the annual whole world can reduce the farm crop financial loss of over ten billion dollar, yet a large amount of agricultural chemicals use the pollution that has also brought environment and crop, especially residual on crop, can bring out multiple disease after people and animals are edible, human health has been brought direct harm, and the remains of pesticide of removing the vegetable and fruit surface is the problem of present countries in the world primary study and solution.
The washing of fruits and vegetables both at home and abroad at present mainly adopts the solution that contains tensio-active agent to dispel the dirt and the pesticide residue material on surface by the method for soaking and scrub, this method is effective to general pollutent, but the action effect to the residue of most of agricultural chemicals is very poor, pesticide molecule is strong to the adsorption of crop surface on the one hand, common solvent and promoting agent are difficult to it is dissolved, a part of on the other hand organic pesticide by strong osmosis and and the fruits and vegetables top layer in organic compound combine, remaining certain toxicity, depending merely on washing composition and be difficult to eliminate.
So can effectively dissolve remains of pesticide, decomposition agricultural chemicals that again can be real, itself is the desirability of current social people's daily life to environment and the human composition that does not have pollution, also is the main developing direction of this professional domain.
Summary of the invention
A main purpose of the present invention provides farm-chemical biological decomposing composition and preparation method, mainly adopts compositions such as biological enzyme, biological degradation activity agent, auxiliary agent, stablizer.Be mainly used in decomposition, washing and the removing of pesticide residue of the fruit and vegetable of foodstuffs industry, husbandry, PE, daily life.
The present invention mainly adopts the preparation process technology, and process processing, stablizer, dispersion agents etc. such as biological enzyme carry out compound allotment, are processed into various formulation products.Characteristics of the present invention are mainly by biological enzyme agricultural chemicals to be decomposed, and itself can natural degradation, without any pungency.
The quality percentage composition of each component of fluid composition of the present invention is:
Emulsifying agent 0.05%-15%
Calcium salt 0.01%-12%
Silicate 0.01%-8%
Fatty Alcohol(C12-C14 and C12-C18) 1%-65%
Enzyme 0.01%-15%
Boric acid and salt 0.01%-20%
Polyphosphoric acid salt 0.05%-70%
Alkali 0.01%-6%
Vitriol 0.1%-85%
Deionized water 1%-80%
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein the component emulsifying agent is as synergistic agent, it can be fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether-10, dodecyl phenol polyethenoxy ether, BS-12, tween-80, alkyl poly-dextrose acid glycosides, Oleum Cocois alkyl oxalamide or their mixture, fatty alcohol-polyoxyethylene ether preferably, its shared mass percent is 0.05%-15%, preferably 0.50%-10%.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component polyphosphoric acid salt is as chela and agent and sanitising agent, and it can be tri-polyphosphate, five poly-phosphate, pyrophosphate salt or their mixture, preferably tri-polyphosphate; Described polyphosphoric acid salt can be sylvite, sodium salt or calcium salt, sodium salt preferably, and its shared mass percent is 0.05%-70%, preferably 0.5%-60%.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained enzyme component, essential substance as the catalyticing decomposition action of agricultural chemicals, its stabilization formulations form that can be proteolytic enzyme, compound fat enzyme, amylase, cellulase, pyrethroid saccharase, permethrin enzyme, A Lcaligense SPYE11 make according to certain technology or their mixture, compound fat enzyme preferably, its shared mass percent is 0.01%-15%, preferably 0.2%-10%.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component silicic acid and salt thereof, it can be positive silicic acid and salt, metasilicic acid and salt thereof or their mixture, preferably metasilicic acid and salt thereof; Described silicate can be sylvite, sodium salt or calcium salt or their mixture, sodium salt preferably, and its shared mass percent is 0.01%-8%, preferably 0.5%-6%.As ancillary components such as liquid stabilisers, solid forming, lubricated and fillings.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component Fatty Alcohol(C12-C14 and C12-C18) can be ethylene glycol, propylene glycol, butyleneglycol, glycerol or their mixture, propylene glycol preferably, its shared mass percent is 1%-65%, preferably 5%-40%.Mainly as dissolving and ancillary component such as stable.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component boric acid and salt, as the stabilizing component of system, it can be the simple boric acid or the mixture of borate and their furnishing according to a certain percentage; Described borate can be sylvite, sodium salt, calcium salt, magnesium salts or their mixture, sodium salt preferably, and its shared mass percent is 0.01%-20%, preferably 0.1%-10%.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component vitriol is as stablizer and synergistic agent, it can be vitriolate of tartar, sal enixum, sodium sulfate, sodium pyrosulfate, Lithium Sulphate, lithium hydrogen sulfate, sal epsom or their mixture, sodium sulfate salt preferably, its shared mass percent is 0.1%-85%, preferably 0.5%-65%.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component alkali can be sodium hydroxide, potassium hydroxide, yellow soda ash, sodium bicarbonate, trolamine, diethanolamine, Sodium phosphate dibasic or their mixture, sodium bicarbonate preferably, its shared mass percent is 0.01%-6%, preferably 0.1%-4%.Mainly as the ancillary component that solution system pH value is regulated, the pH value of control solution is between 5-11, preferably between 7-10.
Farm-chemical biological decomposing composition and preparation method as mentioned above, wherein contained component calcium salt can be calcium sulfate, calcium chloride, calcium hydroxide, lime carbonate, calcium phosphate or their mixture, calcium chloride preferably, its shared mass percent is 0.01%-12%, preferably 0.1%-6%.Mainly as the medicament ancillary component, regulator solution stability and active function.
Preparation technology's method of the present composition:
Aforesaid farm-chemical biological decomposing composition and preparation method are the basic amounts according to prescription, at first add Fatty Alcohol(C12-C14 and C12-C18), put into load weighted zymin then respectively, add slowly, stirring slowly simultaneously, add calcium salt then respectively, silicate, the stirring slowly of polyphosphoric acid salt while, form uniform system, 5 ℃ of-30 ℃ of conditions add the deionized water of formula ratio again, at the uniform velocity stir, until the fluid composition that forms homogeneous.
Additional proportion and total amount by the fatty alcohol and water in the control prescription; solid materials is by mixing machine and tablets press; can produce the particulate product of certain diameter after sieving; on this basis again by the rotary medicinal tabletting machine of ZP-25; adjust pressure and dash the size of touching; the tablet product is made in compression moulding.
Embodiment
Embodiment 1
Farm-chemical biological decomposing composition and preparation method, the mass percent of its each component is:
Alkyl poly-dextrose acid glycosides 6%
Calcium sulfate 0.10%
Water glass 0.01%
Ethylene glycol 60%
Pyrethroid saccharase 10%
Boric acid 0.1%
Potassium pyrophosphate 0.5%
Sodium hydroxide 0.01%
Sodium sulfate 6%
Deionized water 17.28%
Embodiment 2
Oleum Cocois alkyl oxalamide 12%
Calcium chloride 4%
Water glass 0.1%
Propylene glycol 40%
Compound fat enzyme 11%
Boric acid 1%
Trisodium phosphate 3%
Trolamine 0.1%
Sodium sulfate 6%
Deionized water 22.8%
Embodiment 3
Tween-80 10%
Calcium chloride 5%
Water glass 0.5%
Propylene glycol 5%
Compound fat enzyme 5%
Boric acid 5%
Trisodium phosphate 25%
Sodium bicarbonate 0.1%
Sodium sulfate 40%
Deionized water 4.4%
Optimize embodiment 1
Fatty alcohol-polyoxyethylene ether 10%
Calcium chloride 5%
Water glass 1%
Propylene glycol 30%
Compound fat enzyme 1%
Boric acid 3%
Tripoly phosphate sodium STPP 5%
Sodium bicarbonate 0.1%
Sodium sulfate 10%
Deionized water 34.9%
Optimize embodiment 2
Fatty alcohol-polyoxyethylene ether 6%
Calcium chloride 8%
Water glass 0.6%
Propylene glycol 5%
Compound fat enzyme 3%
Boric acid 4%
Tripoly phosphate sodium STPP 28%
Sodium bicarbonate 0.1%
Sodium sulfate 40%
Deionized water 5.3%
The pH value of adjusting solution of the present invention is between 7-10.
About agricultural chemicals decomposes and dispels testing data 1:
Test temperature is 20-35 Celsius ℃
Annotate: adopt health ministry food Pesticides Testing qualitative, quantitative test paper, a certain amount of agricultural chemicals decomposition agent and agricultural chemicals react in container, through behind the certain hour, getting wherein, fluid drips is added to Pesticides Testing with on the qualitative, quantitative test paper, observe change in color after three minutes: red and light blue for agricultural chemicals exceeds standard, deep sapphirine is qualified.
About agricultural chemicals decomposes and dispels testing data 2:
The bacterium amount is at OD
416nmBe 0.20 o'clock, the present composition to the degradation rate of the fenvalerate of 80mg/L, Deltamethrin, lambda-cyhalothrin, Fenvalerate, Cypermethrin, Cypermethrin degraded be respectively 5.1,8.02,3.1,9.3,2.0,3.85umol/L-h; To the degraded speed of thiophos, parathion-methyl, Sumithion be respectively 16.2,29,21umol/L-h.
By to the instrumental analysis of the present composition,, also confirmed the reliability of experimental result as gas chromatographic analysis to the product of organic pesticide decomposition.
Adopt biocatalysis to decompose and the combination of drug preparation technique, produce the decomposition of more efficient, health, environmental protection and dispel the effect that remains in the fruit and vegetable surfaces agricultural chemicals, this will bring new thinking to the development and the application of the degradation technique of agricultural chemicals undoubtedly.
Claims (10)
1. farm-chemical biological decomposing composition and preparation method is characterized in that, are made up of biological enzyme, stablizer, synergistic agent etc., organically combine to produce by catalytic decomposition and emulsifying technology and decompose pesticide structure efficiently, thereby reduce toxic a kind of new formulation.
Its composition main component is constructed as follows by mass percentage:
Emulsifying agent 0.05%-15%
Calcium salt 0.01%-12%
Silicate 0.01%-8%
Fatty Alcohol(C12-C14 and C12-C18) 1%-65%
Enzyme 0.01%-15%
Boric acid and salt 0.01%-20%
Polyphosphoric acid salt 0.05%-70%
Alkali 0.01%-6%
Vitriol 0.1%-85%
Deionized water 1%-80%
2. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein the component emulsifying agent is as synergistic agent, it can be fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether-10, dodecyl phenol polyethenoxy ether, BS-12, tween-80, alkyl poly-dextrose acid glycosides, Oleum Cocois alkyl oxalamide or their mixture, fatty alcohol-polyoxyethylene ether preferably, its shared mass percent is 0.05%-15%, preferably 0.50%-10%.
3. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component polyphosphoric acid salt is as chela and agent and sanitising agent, and it can be tri-polyphosphate, five poly-phosphate, pyrophosphate salt or their mixture, preferably tri-polyphosphate; Described polyphosphoric acid salt can be sylvite, sodium salt or calcium salt, sodium salt preferably, and its shared mass percent is 0.05%-70%, preferably 0.5%-60%.
4. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained enzyme component, essential substance as the catalyticing decomposition action of agricultural chemicals, its stabilization formulations form that can be proteolytic enzyme, compound fat enzyme, amylase, cellulase, pyrethroid saccharase, permethrin enzyme, A Lcaligense SP YE11 make according to certain technology or their mixture, compound fat enzyme preferably, its shared mass percent is 0.01%-15%, preferably 0.2%-10%.
5. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component silicic acid and salt thereof, it can be positive silicic acid and salt, metasilicic acid and salt thereof or their mixture, preferably metasilicic acid and salt thereof; Described silicate can be sylvite, sodium salt or calcium salt or their mixture, sodium salt preferably, and its shared mass percent is 0.01%-8%, preferably 0.5%-6%.As ancillary components such as liquid stabilisers, solid forming, lubricated and fillings.
6. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component Fatty Alcohol(C12-C14 and C12-C18) can be ethylene glycol, propylene glycol, butyleneglycol, glycerol or their mixture, propylene glycol preferably, its shared mass percent is 1%-65%, preferably 5%-40%.Mainly as dissolving and ancillary component such as stable.
7. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component boric acid and salt, as the stabilizing component of system, it can be the simple boric acid or the mixture of borate and their furnishing according to a certain percentage; Described borate can be sylvite, sodium salt, calcium salt, magnesium salts or their mixture, sodium salt preferably, and its shared mass percent is 0.01%-20%, preferably 0.1%-10%.
8. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component alkali, can be sodium hydroxide, potassium hydroxide, yellow soda ash, sodium bicarbonate, trolamine, diethanolamine, Sodium phosphate dibasic or their mixture, sodium bicarbonate preferably, its shared mass percent is 0.01%-6%, preferably 0.1%-4%.Mainly as the ancillary component that solution system pH value is regulated, the pH value of control solution is between 5-11, preferably between 7-10.
9. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that, wherein contained component calcium salt, can be calcium sulfate, calcium chloride, calcium hydroxide, lime carbonate, calcium phosphate or their mixture, calcium chloride preferably, its shared mass percent is 0.01%-12%, preferably 0.1%-6%.Mainly as the medicament ancillary component, regulator solution stability and active function.
10. according to described farm-chemical biological decomposing composition of claim 1 and preparation method, it is characterized in that preparation technology's method of the present composition:
Aforesaid farm-chemical biological decomposing composition and preparation method are the basic amounts according to prescription, at first add Fatty Alcohol(C12-C14 and C12-C18), put into load weighted zymin then respectively, add slowly, stirring slowly simultaneously, add calcium salt then respectively, silicate, the stirring slowly of polyphosphoric acid salt while, form uniform system, 5 ℃ of-30 ℃ of conditions add the deionized water of formula ratio again, at the uniform velocity stir, until the fluid composition that forms homogeneous.
Additional proportion and total amount by the fatty alcohol and water in the control prescription; solid materials is by mixing machine and tablets press; can produce the particulate product of certain diameter after sieving; on this basis again by the rotary medicinal tabletting machine of ZP-25; adjust pressure and dash the size of touching; the tablet product is made in compression moulding.
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| CN 200610078755 CN101070513A (en) | 2006-05-11 | 2006-05-11 | Farm-chemical biological decomposing composition and preparing method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103168977A (en) * | 2013-02-05 | 2013-06-26 | 叶锦标 | Fruit and vegetable pesticide residue removing agent and preparation method thereof |
| CN103501928A (en) * | 2010-12-14 | 2014-01-08 | 友聚专利控股有限公司 | Remedial composition and treatment methods |
| CN105432607A (en) * | 2015-12-20 | 2016-03-30 | 广东中迅农科股份有限公司 | Rapidly-degradable environment-friendly type pesticide suspending agent and preparation method thereof |
| CN105586187A (en) * | 2016-03-04 | 2016-05-18 | 吕舒宏 | Melon, fruit and vegetable cleaning liquid and preparation method and application thereof |
| CN106833945A (en) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | Biological fruit and vegetable enzyme cleaning fluid and its preparation method and application |
| CN108070468A (en) * | 2016-11-17 | 2018-05-25 | 江西新华扬酵素科技有限公司 | A kind of degradation of pesticide zymophore and its application |
| CN109825382A (en) * | 2019-03-25 | 2019-05-31 | 苏州高新区浒墅关淡水草关席研究有限公司 | A kind of new formulation and preparation method thereof that degradation natural fabric middle peasant is residual |
| CN110331057A (en) * | 2019-07-30 | 2019-10-15 | 南开大学 | Compound additive and its preparation method and application, fruit and vegetable residual pesticide cleaning agent and purposes |
| CN110507947A (en) * | 2019-09-02 | 2019-11-29 | 中国人民警察大学 | A kind of chelating type metallic salt organic liquid harmful influence leakage treatment agent |
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2006
- 2006-05-11 CN CN 200610078755 patent/CN101070513A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103501928A (en) * | 2010-12-14 | 2014-01-08 | 友聚专利控股有限公司 | Remedial composition and treatment methods |
| CN103501928B (en) * | 2010-12-14 | 2015-09-30 | 友聚专利控股有限公司 | Remediation composition capable and processing method |
| CN103168977A (en) * | 2013-02-05 | 2013-06-26 | 叶锦标 | Fruit and vegetable pesticide residue removing agent and preparation method thereof |
| CN106833945A (en) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | Biological fruit and vegetable enzyme cleaning fluid and its preparation method and application |
| CN105432607A (en) * | 2015-12-20 | 2016-03-30 | 广东中迅农科股份有限公司 | Rapidly-degradable environment-friendly type pesticide suspending agent and preparation method thereof |
| CN105432607B (en) * | 2015-12-20 | 2018-08-14 | 广东中迅农科股份有限公司 | A kind of eco-friendly pesticide suspending agent capable of being fast degraded and preparation method thereof |
| CN105586187A (en) * | 2016-03-04 | 2016-05-18 | 吕舒宏 | Melon, fruit and vegetable cleaning liquid and preparation method and application thereof |
| CN108070468A (en) * | 2016-11-17 | 2018-05-25 | 江西新华扬酵素科技有限公司 | A kind of degradation of pesticide zymophore and its application |
| CN109825382A (en) * | 2019-03-25 | 2019-05-31 | 苏州高新区浒墅关淡水草关席研究有限公司 | A kind of new formulation and preparation method thereof that degradation natural fabric middle peasant is residual |
| CN109825382B (en) * | 2019-03-25 | 2021-02-09 | 苏州衣然生物科技有限公司 | Preparation for degrading pesticide residues in natural fabric and preparation method thereof |
| CN110331057A (en) * | 2019-07-30 | 2019-10-15 | 南开大学 | Compound additive and its preparation method and application, fruit and vegetable residual pesticide cleaning agent and purposes |
| CN110507947A (en) * | 2019-09-02 | 2019-11-29 | 中国人民警察大学 | A kind of chelating type metallic salt organic liquid harmful influence leakage treatment agent |
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