KR101429719B1 - Ecofriendly disinfection composition having excellent eliminating larva and spreading effect - Google Patents
Ecofriendly disinfection composition having excellent eliminating larva and spreading effect Download PDFInfo
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/02—Sulfur; Selenium; Tellurium; Compounds thereof
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- A—HUMAN NECESSITIES
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- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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Abstract
Description
본 발명은 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 관한 것으로, 더욱 상세하게는 제초제, 살충제 및 살균제 등을 첨가하지 않고도 우수한 유충구제 및 방역효과를 나타내며, 천연성분으로 이루어져, 분무확산 시에 환경오염을 유발하지 않을 뿐만 아니라 우수한 확산효과를 나타내며, 불쾌한 냄새를 유발하지 않는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 관한 것이다.
The present invention relates to an environmentally safe disinfecting composition having excellent larval remediation and electrodeposition efficiency, and more particularly, to an excellent environmentally safe disinfecting composition having excellent larval protection and antiseptic effect without addition of herbicides, insecticides and bactericides, Friendly sterilizing composition that does not cause environmental pollution, exhibits excellent diffusion effect, and has excellent larval remediation and electrodeposition efficiency that do not cause unpleasant odors.
방역살균 조성물은 연무 또는 연막을 통해 공간살포됨에 따라 효과적인 방역을 가능하게 하는 것으로, 종래에는 경유나 등유와 같은 광물유로 형성되는 기유에 살충제 또는 살균제 등이 첨가되어 제조되었으며, 열건식 연막기와 같은 연막방역기계 또는 연무방역기계를 통해 최종적으로 공간살포되었다.The antimicrobial composition of the present invention can be effectively sprayed through spraying through a mist or smoke film. Conventionally, a pesticide or a bactericide is added to a base oil formed of mineral oil such as diesel oil or kerosene, and a smoke- It was finally sprayed with a dispersing machine or spraying machine.
그러나, 방역살균 조성물은 광물유를 주성분으로 하기 때문에, 불쾌한 냄새유발은 물론 인체에 도포되면 끈적이는 현상이 발생하며, 인체에 매우 해로울 뿐만 아니라, 특히 가축의 우리, 목초, 농작물 등에 분무확산될 경우에는 동물의 사료, 동물이 섭취하는 목초, 농작물 줄기나 잎 등을 오염시킬 수 있으며, 오염성분이 자연적으로 분해되지 않아 자원을 손상시키는 문제점이 있으며, 광물유로 오염된 목초 등은 냄새에 의해 가축의 식욕을 저하시킬 수 있는 문제점이 있었다.However, since the antimicrobial composition has a mineral oil as a main component, it causes not only an unpleasant odor but also a sticky phenomenon when it is applied to a human body, and it is very harmful to the human body. Especially, when spraying on us, grasses, The animal feedstuffs, the grasses consumed by the animals, the crop stems and leaves, and the pollution components are not decomposed naturally, thereby damaging the resources, while the grasses contaminated with the mineral oil may cause the appetite of the livestock There is a problem that it can be deteriorated.
또한, 상기의 광물유는 벤젠, 톨루엔 및 크실렌 등과 같은 발암물질이 함유되어 있기 때문에, 사람이나 가축의 건강에 치명적인 문제점이 있을 뿐만 아니라 환경호르몬을 생성시킬 수 있는 위험성이 있다.In addition, since the mineral oil contains a carcinogen such as benzene, toluene, and xylene, there is a danger that the health hormone can be produced as well as a fatal problem to the health of a person or a livestock.
이러한 문제점을 해결하기 위하여 한국특허등록 제10-0456808호(2004.11.02.)에는 동식물유 46 내지 48중량%에 알콜류 20 중량%, 비이온계면활성제 또는 양성이온계면활성제 30 내지 32중량%, 파인오일 2 내지 3중량%을 순차적으로 첨가 교반하여 균질화시킨 조성물에 대하여 물 50 내지 90 중량%를 소량식 천천히 첨가 30분 이상 유화 내지는 수용화시킴을 특징으로 하는 무공해 연무확산제가 공개되어 있으며, 한국특허등록 제10-0930653호(2009.12.01.)에는 바이오디젤 67 내지 75중량%, 식물성 계면활성제 5 내지 3중량% 및 물 28 내지 22중량%로 조성하여 서로 혼합하여 이들을 유화시킨 것을 특징으로 하는 연무 확산제가 공개되어 있다.In order to solve such a problem, Korean Patent Registration No. 10-0456808 (November 2, 2004) discloses that 46 to 48 wt% of animal or vegetable oil contains 20 wt% of alcohols, 30 to 32 wt% of nonionic surfactant or amphoteric surfactant, And 2 to 3% by weight of an oil are sequentially added and stirred to homogenize the composition. 50 to 90% by weight of water is slowly added and slowly added for 30 minutes or more to emulsify or hydrate the composition. The present invention relates to a process for the production of fumed silica, which comprises mixing 67 to 75% by weight of biodiesel, 5 to 3% by weight of vegetable surfactant and 28 to 22% by weight of water, The diffuser is open.
그러나 전술한 연무 확산제들의 경우에도 동식물유나 바이오디젤 만으로는 공간살포시에 확산효과가 떨어지는 문제점이 있을 뿐만 아니라 콩기름 자체의 불쾌한 냄새와 끈적거림 현상이 발생하는 문제점이 있으며, 살충 및 살균 등과 같은 방역효과 외에 그 어떠한 부가적인 기능이 제공될 수 없는 문제점이 있다.
However, in the case of the above-mentioned fogging and dispersing agents, there is a problem that the diffusion effect is inferior at the time of spraying with space only with animal or vegetable oil or biodiesel, and the unpleasant odor and stickiness of the soybean oil itself occurs. Besides the prevention effect such as insecticide and sterilization There is a problem that any additional function can not be provided.
본 발명의 목적은 제초제, 살충제 및 살균제 등을 첨가하지 않고도 우수한 유충구제 및 방역효과를 나타내며, 천연성분으로 이루어져, 분무확산 시에 환경오염을 유발하지 않는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제공하는 것이다.It is an object of the present invention to provide an environmentally safe antimicrobial composition which is excellent in larval protection and prevention effect without addition of herbicides, insecticides and bactericides, and is composed of natural ingredients and has excellent larval remedies and electrodeposition efficiency that do not cause environmental pollution during spraying .
본 발명의 다른 목적은 분무확산시에 우수한 확산 및 전착효과를 나타내며, 불쾌한 냄새를 유발하지 않는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제공하는 것이다.
Another object of the present invention is to provide an environmentally friendly anti-fungicide composition which exhibits excellent diffusion and electrodeposition effect at the time of spray diffusion and has excellent larval remediation and electrodeposition efficiency which does not cause unpleasant odor.
본 발명의 목적은 은나노 활성수, 코코넛유, 구연산 및 액체유황으로 이루어지는 것을 특징으로하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제공함에 의해 달성된다.It is an object of the present invention to provide an environmentally friendly anti-fungicide composition having excellent larval remediation and electrodeposition efficiency, characterized by comprising silver nano-active water, coconut oil, citric acid and liquid sulfur.
본 발명의 바람직한 특징에 따르면, 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 은나노 활성수 100 중량부, 코코넛유 30 내지 60 중량부, 구연산 15 내지 30 중량부 및 액체유황 30 내지 60 중량부로 이루어지는 것으로 한다.According to a preferred aspect of the present invention, the environmentally safe antimicrobial composition having excellent larval remediation and electrodeposition efficiency comprises 100 parts by weight of silver nano-active water, 30 to 60 parts by weight of coconut oil, 15 to 30 parts by weight of citric acid and 30 to 60 parts by weight of liquid sulfur .
본 발명의 더 바람직한 특징에 따르면, 상기 은나노 활성수는 99.9%의 은나노로 활성화되는 것으로 한다.According to a further preferred feature of the present invention, the silver nano-active water is assumed to be activated with 99.9% silver nano.
본 발명의 더욱 바람직한 특징에 따르면, 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 은나노 활성수 100 중량부 대비 식물성 계면활성제 1.5 내지 3 중량부가 더 함유되는 것으로 한다.According to a further preferred feature of the present invention, the eco-friendly antiseptic composition having excellent larval remediation and electrodeposition efficiency further contains 1.5 to 3 parts by weight of the vegetable surfactant relative to 100 parts by weight of the silver nano-active water.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 계면활성제는 전분으로 이루어지는 것으로 한다.According to a further preferred feature of the present invention, the surfactant is composed of starch.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 은나노 활성수 100 중량부 대비 광물분말 5 내지 15 중량부가 더 함유되는 것으로 한다.According to a further preferred feature of the present invention, the environmentally safe antimicrobial composition having excellent larval remediation and electrodeposition efficiency further contains 5 to 15 parts by weight of mineral powder relative to 100 parts by weight of the silver nano-active water.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 광물분말은 벤토나이트, 제올라이트 및 초석으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a further preferred feature of the present invention, the mineral powder is made of at least one selected from the group consisting of bentonite, zeolite and corner stone.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 80 내지 90℃의 교반기에서 2000 내지 3000rpm의 속도로 30 내지 40분 동안 교반된 후에 20 내지 24시간 동안 숙성하여 제조되는 것으로 한다.
According to an even more preferred feature of the present invention, the environmentally safe antimicrobial composition having excellent larval remediation and electrodeposition efficiency is aged at a speed of 2000 to 3000 rpm in a stirrer at 80 to 90 캜 for 30 to 40 minutes and aged for 20 to 24 hours .
본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 제초제, 살충제 및 살균제 등을 첨가하지 않고도 우수한 유충구제 및 방역효과를 나타내며, 천연성분으로 이루어져, 분무확산 시에 환경오염을 유발하지 않는 탁월한 효과를 나타낸다.The eco-friendly anti-fungicide composition having excellent larval remediation and electrodeposition efficiency according to the present invention exhibits excellent larval remedies and preventive effects without adding herbicides, insecticides and bactericides, and is composed of natural components and does not cause environmental pollution It shows excellent effect.
또한, 분무확산시에 우수한 확산 및 전착효과를 나타내며, 불쾌한 냄새를 유발하지 않는 탁월한 효과를 나타낸다.
In addition, it exhibits excellent diffusion and electrodeposition effect at the time of spray diffusion, and exhibits an excellent effect that does not cause an unpleasant odor.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.
Hereinafter, preferred embodiments of the present invention and physical properties of the respective components will be described in detail with reference to the accompanying drawings. However, the present invention is not limited thereto, And this does not mean that the technical idea and scope of the present invention are limited.
본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 은나노 활성수, 코코넛유, 구연산 및 액체유황으로 이루어지며, 은나노 활성수 100 중량부, 코코넛유 30 내지 60 중량부, 구연산 15 내지 30 중량부 및 액체유황 30 내지 60 중량부로 이루어지는 것이 바람직하다.
The eco-friendly antiseptic composition according to the present invention is excellent in larval remediation and electrodeposition efficiency. It is composed of silver nano-active water, coconut oil, citric acid and liquid sulfur and contains 100 parts by weight of silver nano-active water, 30 to 60 parts by weight of coconut oil, And 30 to 60 parts by weight of liquid sulfur.
상기 은나노 활성수는 99.9%의 질량농도를 나타내는 은나노로 정제수를 활성화하여 제조되는데, 상기와 같은 과정을 통해 제조되는 은나노 활성수는 병원균의 세포막을 손상시키거나, 미생물의 DNA를 손상시켜 세포분열을 방해하여, 병원균이나 미생물의 증식을 억제하며, 특히, 채소류와 과수에서 주로 발생하는 흰가루병, 탄저병 및 노균병 등에 대해 효과를 나타내며, 이외에도, 악취제거나 수질정화에 효과적이다.
The silver nano-active water is prepared by activating purified water with silver nano that shows a mass concentration of 99.9%. The silver nano-active water produced through the above process damages the cell membrane of the pathogen, damages the DNA of the microorganism, Inhibits the growth of pathogens and microorganisms. In particular, it exhibits effects on powdery mildew, anthrax disease, and necrotic diseases mainly occurring in vegetables and fruit juices. In addition, it is effective in odor removal and water purification.
상기 코코넛유는 30 내지 60 중량부가 함유되며, 코코넛에서 추출된 식물성기름을 정제하여 제조되는 것이 바람직한데, 코코넛유는 생분해성이 우수하여 환경을 오염시키지 않고, 광물유와 같이 유해성분을 함유하고 있지 않기 때문에 안정적으로 사용할 수 있고, 식물성 기름으로 주로 사용되는 대두유에 비해 불쾌한 냄새를 유발하지 않는 효과를 나타낸다.The coconut oil is preferably prepared by purifying vegetable oil extracted from coconut. The coconut oil is excellent in biodegradability and does not contaminate the environment and contains harmful components such as mineral oil. It can be used stably and has an effect of not causing an unpleasant odor as compared with soybean oil mainly used as vegetable oil.
또한, 상기 코코넛유는 휘발성이나 폭발적인 연소성이 없어 광물유를 사용하는 동일 양의 공간살포 방역소독유에 비해 더 오래 방역사용을 지속시키는 역할을 하며, 특히, 해충의 알이나 유충이 번식하고 있는 물웅덩이 등에 코코넛유 성분이 함유된 방역소독용 발연제 조성물이 적용되면, 물웅덩이의 표면에 기름 막이 형성되어 산소의 공급을 차단하기 때문에, 해충의 알이나 유충이 사멸되도록 하는 역할을 한다.
In addition, the coconut oil has no volatility or explosive burning ability, and thus it plays a role of continuing the use of disinfectant for a long time compared with the same amount of disinfectant for space spraying and disinfection using mineral oil. Especially, When a composition of a disinfecting fungicide composition containing a coconut oil component is applied, an oil film is formed on the surface of the water shed to block the supply of oxygen, thereby causing the pest egg or larva to be killed.
상기 구연산은 15 내지 30 중량부가 함유되며, 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 살균성을 부여하며, 불쾌한 냄새를 제거하는 역할을 하는데, 상기 구연산의 함량이 15 중량부 미만이면, 상기의 효과가 미미하며, 상기 구연산의 함량이 30 중량부를 초과하게 되면, 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물의 분무확산 효율이 저하되며 제조비용이 증가하게 된다.
Wherein the citric acid is contained in an amount of 15 to 30 parts by weight to provide an antimicrobial and antifouling composition having excellent larval remediation and electrodeposition efficiency according to the present invention and to remove unpleasant odors. When the content of the citric acid is less than 15 parts by weight , The above effect is insignificant. When the content of citric acid is more than 30 parts by weight, the spray diffusion efficiency of the environmentally friendly disinfecting composition having excellent larval remediation and electrodeposition efficiency is lowered and the manufacturing cost is increased.
상기 액체유황은 30 내지 60 중량부가 함유되며, 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 살균성을 부여하여 제초제, 살충제 및 살균제 등을 첨가하지 않고도 우수한 방역효과를 나타내는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제공하는 역할을 한다.Wherein the liquid sulfur is contained in an amount of 30 to 60 parts by weight and the sterilizing property is imparted to the environmentally friendly antimicrobial composition having excellent larval remediation and electrodeposition efficiency according to the present invention to provide excellent antimicrobial effect without adding herbicides, And to provide an environmentally safe antimicrobial composition having an excellent electrodeposition efficiency.
본 발명에서 사용되는 액체유황은 6 내지 20%의 농도를 나타내는 것이 바람직한데, 액체유황의 농도가 6% 미만이면 살균효과가 미미하며, 상기 액체유황의 농도가 20%를 초과하게 되면, 분무효율성이 저하되며 제조비용이 증가하게 된다.The liquid sulfur used in the present invention preferably exhibits a concentration of 6 to 20%. If the concentration of the liquid sulfur is less than 6%, the sterilization effect is insignificant. If the concentration of the liquid sulfur exceeds 20% And the manufacturing cost is increased.
상기 액체유황은 유황가루를 비이온 계면활성제와 혼합한 후 온도 180 내지 250℃의 온도에서 가열 교반하고, 상기와 같은 가열 교반과정을 통해 유황가루가 비이온 계면활성제에 용해되어 20% 농도의 액체유황으로 제조된다.The liquid sulfur is prepared by mixing sulfur powder with a nonionic surfactant, heating and stirring the mixture at a temperature of 180 to 250 DEG C, and dissolving the sulfur powder in the nonionic surfactant through the heating and stirring process as described above, Sulfur.
또한, 상기와 같은 과정을 통해 얻어진 20% 농도의 액체유황은 비이온 계면활성제인 폴리옥시에틸렌 솔비탄모노올레이트(Polyoxyethylene Sorbitan Monooleate)에 혼합하고 희석함으로써 6%의 농도를 나타내는 액체유황으로 제조할 수 있다.The 20% concentration of liquid sulfur obtained through the above procedure was mixed with polyoxyethylene sorbitan monooleate, a nonionic surfactant, and diluted to produce liquid sulfur having a concentration of 6% .
이때, 상기 비이온 계면활성제는, 폴리옥시에틸렌 올레일 에테르(Polyoxyethylene oleyl ether), 폴리옥시에틸렌 지방알코올 에테르(Polyoxyethylene fatty alcohol ether), 폴리옥시에틸렌 알킬페놀 에테르(Polyoxyethylene alkyl phenol ether), 폴리에틸렌글리콜 지방산에테르(Polyoxyethylene glycol fatty acid ether) 및 지방산 디에탄올아미드(Fatty acid diethanolamide)로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직하다.The nonionic surfactant may be selected from the group consisting of polyoxyethylene oleyl ether, polyoxyethylene fatty alcohol ether, polyoxyethylene alkyl phenol ether, polyethylene glycol fatty acid A polyoxyethylene glycol fatty acid ether, and a fatty acid diethanolamide.
상기의 성분으로 이루어지는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 상기의 은나노 활성수, 코코넛유, 구연산 및 액체유황 성분을 80 내지 90℃의 온도로 가열된 교반기에 투입하고, 2000 내지 3000rpm의 속도로 30 내지 40분 동안 교반된 후에, 교반된 혼합물을 20 내지 24시간 동안 숙성하는 과정을 통해 제조된다.The environmentally safe antimicrobial composition having excellent larval remediation and electrodeposition efficiency comprising the above components is obtained by charging the above-described silver nano-active water, coconut oil, citric acid and liquid sulfur components into a stirrer heated to a temperature of 80 to 90 ° C, Stirring at a speed of 30 to 40 minutes and then aging the agitated mixture for 20 to 24 hours.
상기와 같은 교반단계를 거치면, 화학성분의 계면활성제를 사용하지 않고도, 상기의 성분들이 혼합되어 친환경적인 방역살균 조성물이 제조된다.
After the stirring step as described above, the above components are mixed without using a chemical surfactant to produce an environmentally safe disinfecting composition.
또한, 상기의 성분으로 이루어지는 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 함유되는 은나노 활성수 100 중량부 대비 식물성 계면활성제 1.5 내지 3 중량부가 더 함유되어 이루어질 수도 있는데, 상기 계면활성제는 상기 은나노 활성수, 코코넛유, 구연산 및 액체유황이 더욱 고르게 혼합되도록 하는 역할을 한다.In addition, the eco-friendly antimicrobial composition having superior anthelmia and electrodeposition efficiency according to the present invention comprising the above-described components may further contain 1.5 to 5 parts by weight of a vegetable surfactant in an amount of 100 parts by weight of the silver- 3 parts by weight of the surfactant may be added, and the surfactant serves to more evenly mix the silver nano-active water, coconut oil, citric acid and liquid sulfur.
상기 식물성 계면활성제는 전분으로 이루어지며, 더욱 상세하게는 고구마 전분, 감자 전분, 밀 전분 및 옥수수 전분 등으로 이루어지는 것이 바람직하며, 상기 전분에 함유되어 있는 글루코스 성분이 상기 코코넛유에 함유되어 있는 지방성 알코올이 반응하여 순한 비이온계 계면활성제로 제조된다.The vegetable surfactant is preferably composed of starch, more specifically, sweet potato starch, potato starch, wheat starch and corn starch, and the glucose component contained in the starch is a fatty alcohol contained in the coconut oil To produce a mild nonionic surfactant.
상기 계면활성제의 함량이 1.5 중량부 미만이면, 혼합물의 혼합효율성 향상효과가 미미하며, 상기 계면활성제의 함량이 3 중량부를 초과하게 되면 상대적으로, 은나노 활성수, 코코넛유, 구연산 및 액체유황의 혼합비율이 줄어들어 방역살균 조성물의 살균효과가 저하될 수 있다.
If the content of the surfactant is less than 1.5 parts by weight, the effect of improving the mixing efficiency of the mixture is insignificant. If the content of the surfactant exceeds 3 parts by weight, the mixing of the silver nano-active water, coconut oil, citric acid and liquid sulfur The ratio may be reduced, and the sterilizing effect of the disinfecting composition may be lowered.
또한, 상기의 성분으로 이루어지는 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에 함유되는 은나노 활성수 100 중량부 대비 광물분말 5 내지 15 중량부가 더 함유되어 이루어질 수도 있는데, 상기 광물분말은 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물의 흡착성능을 향상시켜주며, 비료성분을 공급하기 때문에, 방역살균 조성물이 토양 등에 흡착되는 경우에 토양에 비료성분을 공급하여 지력을 향상시키는 역할을 한다.In addition, the eco-friendly anti-fungicide composition having excellent larval remediation and electrodeposition efficiency according to the present invention comprising the above-described components can be applied to the environment-friendly anti-fungicidal composition having excellent larval remediation and electrodeposition efficiency, The mineral powder improves the adsorption performance of the environment-friendly anti-fungicide composition having excellent larval remediation and electrodeposition efficiency according to the present invention. Since the fertilizer component is supplied, the anti-fungicidal composition adsorbs to the soil or the like The fertilizer component is supplied to the soil to improve the intelligence.
상기 광물분말의 함량이 5 중량부 미만이면 상기의 효과가 미미하며, 상기 광물분말의 함량이 15 중량부를 초과하게 되면 제조비용이 증가된다.If the content of the mineral powder is less than 5 parts by weight, the effect is insignificant. If the content of the mineral powder exceeds 15 parts by weight, the production cost is increased.
이때, 상기 광물분말은 벤토나이트(bentonite), 제올라이트(zeolite) 및 초석(niter)으로 이루어진 그룹에서 선택된 하나로 이루어지는 것이 바람직하며, 벤토나이트, 제올라이트 및 초석이 1:1 내지 1.5:0.1 내지 0.5 중량부로 이루어지는 것이 더욱 바람직한데, 상기 벤토나이트는 운모와 같은 결정구조를 갖는 단사정계에 속하는 광물인 몬모릴로나이트가 주성분이며, 양이온을 띄는 천연미네랄이 다량 함유되어 있어 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물의 흡착성을 향상시킨다.The mineral powder preferably comprises one selected from the group consisting of bentonite, zeolite and niter. The mineral powder preferably comprises 1: 1 to 1.5: 0.1 to 0.5 part by weight of bentonite, zeolite and basic stone The bentonite is mainly composed of montmorillonite which is a mineral belonging to monoclinic having a crystal structure such as mica, and contains a large amount of natural minerals having a cation. Therefore, the environmentally safe antimicrobial composition .
또한, 상기 제올라이트는 알칼리 및 알칼리토금속의 규산알루미늄 수화물인 광물의 총칭으로 우수한 흡착성을 나타내며, 상기 초석은 감람석과 같은 결정구조를 갖는 사방정계에 속하는 광물로 질소 및 붕소와 같은 비료성분이 함유되어 있어 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물이 토양 등에 적용되었을 때, 토양의 지력을 향상시키는 역할을 한다.
The zeolite is a general term of minerals which are aluminum silicate hydrates of alkali and alkaline earth metals and exhibits excellent adsorptivity. The foundation stone is a minerals belonging to orthorhombic system having a crystal structure like olivine and contains fertilizer components such as nitrogen and boron When the eco-friendly antiseptic composition having excellent larval remediation and electrodeposition efficiency is applied to soil or the like, it plays a role of improving the intellectual strength of the soil.
이하에서는, 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물의 제조방법 및 물성을 실시예를 들어 설명하기로 한다.
Hereinafter, methods and properties of an environmentally safe anti-fungicidal composition having excellent larval remediation and electrodeposition efficiency according to the present invention will be described with reference to examples.
<실시예 1>≪ Example 1 >
은나노 활성수 100 중량부, 코코넛유 45 중량부, 구연산 22 중량부 및 액체유황 45 중량부를 85℃의 온도로 가열된 교반기에 투입하고, 2500rpm의 속도로 35분 동안 교반하고, 교반된 혼합물을 22시간 동안 숙성하여 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제조하였다.
100 parts by weight of silver nano-active water, 45 parts by weight of coconut oil, 22 parts by weight of citric acid and 45 parts by weight of liquid sulfur were fed into a stirrer heated to 85 DEG C at a speed of 2500 rpm for 35 minutes, Hours to prepare an environmentally safe antimicrobial composition having larval remediation and electrodeposition efficiency.
<실시예 2>≪ Example 2 >
은나노 활성수 100 중량부, 코코넛유 45 중량부, 구연산 22 중량부, 액체유황 45 중량부 및 전분 2.2 중량부를 85℃의 온도로 가열된 교반기에 투입하고, 2500rpm의 속도로 35분 동안 교반하고, 교반된 혼합물을 22시간 동안 숙성하여 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제조하였다.
45 parts by weight of coconut oil, 22 parts by weight of citric acid, 45 parts by weight of liquid sulfur and 2.2 parts by weight of starch were added to a stirrer heated to 85 캜 and stirred at a speed of 2500 rpm for 35 minutes, The agitated mixture was aged for 22 hours to prepare an environmentally safe antimicrobial composition having larval remediation and electrodeposition efficiency.
<실시예 3>≪ Example 3 >
은나노 활성수 100 중량부, 코코넛유 45 중량부, 구연산 22 중량부, 액체유황 45 중량부 및 광물분말 10 중량부(벤토나이트 4 중량부, 제올라이트 4 중량부 및 초석 2중량부)를 85℃의 온도로 가열된 교반기에 투입하고, 2500rpm의 속도로 35분 동안 교반하고, 교반된 혼합물을 22시간 동안 숙성하여 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제조하였다.
45 parts by weight of coconut oil, 45 parts by weight of coconut oil, 22 parts by weight of citric acid, 45 parts by weight of liquid sulfur and 10 parts by weight of mineral powder (4 parts by weight of bentonite, 4 parts by weight of zeolite and 2 parts by weight of corner stone) And the mixture was agitated at a speed of 2500 rpm for 35 minutes. The agitated mixture was aged for 22 hours to prepare an environmentally safe antimicrobial composition having larval remediation and electrodeposition efficiency.
<실시예 4><Example 4>
은나노 활성수 100 중량부, 코코넛유 45 중량부, 구연산 22 중량부, 액체유황 45 중량부, 전분 2.2 중량부 및 광물분말 10 중량부(벤토나이트 4 중량부, 제올라이트 4 중량부 및 초석 2중량부)를 85℃의 온도로 가열된 교반기에 투입하고, 2500rpm의 속도로 35분 동안 교반하고, 교반된 혼합물을 22시간 동안 숙성하여 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 제조하였다.
2.2 parts by weight of starch and 10 parts by weight of mineral powder (4 parts by weight of bentonite, 4 parts by weight of zeolite and 2 parts by weight of cornerstone), 100 parts by weight of coconut oil, 45 parts by weight of coconut oil, 22 parts by weight of citric acid, Was added to a stirrer heated to a temperature of 85 캜, stirred at a speed of 2500 rpm for 35 minutes, and the stirred mixture was aged for 22 hours to prepare an environmentally safe disinfecting composition having larval remediation and electrodeposition efficiency.
상기 실시예 1 내지 4를 통해 제조된 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물을 연막기에 투입하고, 발연하여 악취발생여부 및 노즐막힘 여부를 측정하여 아래 표 1에 나타내었다.The environmentally safe disinfecting composition prepared in Examples 1 to 4 and having excellent electrodeposition efficiency was injected into a film forming machine and fumed to determine whether or not odor was generated and whether the nozzle was clogged.
(악취발생 여부는 피시험자 10 명을 대상으로 하여 유무로 측정하였으며, 노즐막힘 현상은 방역살균 조성물 3L를 연마기로 사용한 후에 연막기의 노즐을 육안으로 확인하여 측정하였다.)
(Odor occurrence was measured with or without 10 subjects. The nozzle clogging was measured by visually checking the nozzles of the softening period after using the 3L sterilizing composition for abatement sterilization.
<표 1><Table 1>
위에 표 1에 나타낸 것처럼, 본 발명의 실시예 1 내지 4를 통해 제조된 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 연막기를 통해 사용되었을 때, 악취발생이 없고 완전히 연소되어 연막기 노즐에 막힘 현상이 발생하지 않는 것을 알 수 있다.As shown in Table 1 above, the eco-friendly antimicrobial composition having excellent larval remediation and electrodeposition efficiency, prepared through Examples 1 to 4 of the present invention, was free from odor generation and completely burned, It can be seen that the phenomenon does not occur.
또한, 본 발명에 따른 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 은나노 활성수, 코코넛유, 구연산 및 액체유황이 함유되어 제초제, 살충제 및 살균제 등을 첨가하지 않고도 우수한 유충구제 및 방역효과를 나타내며, 광물분말이 함유되어 우수한 흡착성과 지력증진 효과를 나타낸다.In addition, the eco-friendly anti-fungicidal composition having excellent larval remediation and electrodeposition efficiency according to the present invention is excellent in larval protection and prevention effect without adding herbicide, insecticide, fungicide and the like because it contains silver nano-active water, coconut oil, citric acid and liquid sulfur , Mineral powders are contained and exhibit excellent adsorptivity and an increase in the power of the earth.
Claims (8)
Cyanobacteria, citric acid, and liquid sulfur, characterized in that the active ingredient is selected from the group consisting of cocoa butter, coconut oil, citric acid, and liquid sulfur.
상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 은나노 활성수 100 중량부, 코코넛유 30 내지 60 중량부, 구연산 15 내지 30 중량부 및 액체유황 30 내지 60 중량부로 이루어지는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method according to claim 1,
The antiseptic and antimicrobial composition having excellent larval remediation and electrodeposition efficiency comprises 100 parts by weight of silver nano-active water, 30 to 60 parts by weight of coconut oil, 15 to 30 parts by weight of citric acid and 30 to 60 parts by weight of liquid sulfur. And an electrodeposition efficiency.
상기 은나노 활성수는 99.9%의 은나노로 활성화되는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method according to claim 1 or 2,
Wherein the silver nano-active water is activated with 99.9% of silver nano-particles.
상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 은나노 활성수 100 중량부 대비 식물성 계면활성제 1.5 내지 3 중량부가 더 함유되는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method according to claim 1 or 2,
The antiseptic and antimicrobial composition according to any one of claims 1 to 3, further comprising 1.5 to 3 parts by weight of a vegetable surfactant based on 100 parts by weight of the silver nano-active water.
상기 계면활성제는 전분으로 이루어지는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method of claim 4,
Wherein the surfactant is composed of starch, and is excellent in larval remediation and electrodeposition efficiency.
상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물에는 상기 은나노 활성수 100 중량부 대비 광물분말 5 내지 15 중량부가 더 함유되는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method according to claim 1 or 2,
Wherein the environmentally safe antimicrobial composition having excellent larval remediation and electrodeposition efficiency further contains 5 to 15 parts by weight of mineral powder relative to 100 parts by weight of the silver nano-active water, and exhibits excellent larval remediation and electrodeposition efficiency.
상기 광물분말은 벤토나이트, 제올라이트 및 초석으로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.
The method of claim 6,
Wherein the mineral powder is at least one selected from the group consisting of bentonite, zeolite and cornstarch, and is excellent in larval remediation and electrodeposition efficiency.
상기 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물은 80 내지 90℃의 교반기에서 2000 내지 3000rpm의 속도로 30 내지 40분 동안 교반된 후에 20 내지 24시간 동안 숙성하여 제조되는 것을 특징으로 하는 유충구제 및 전착 효율이 우수한 친환경 방역살균 조성물.The method according to claim 1,
The antiseptic and antimicrobial composition having excellent larval remediation and electrodeposition efficiency is prepared by stirring for 30 to 40 minutes at a speed of 2000 to 3000 rpm in a stirrer at 80 to 90 DEG C and then aging for 20 to 24 hours. And an electrodeposition efficiency.
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| CN109329324A (en) * | 2018-12-14 | 2019-02-15 | 福建省世纪海峡农业发展投资有限公司 | A kind of incense piece and preparation method thereof enhancing livestock immunity |
| KR20200054922A (en) | 2020-05-01 | 2020-05-20 | 정봉진 | Development of fogging additives having superior mixing solubility of substances and boosting fogging in the fogging agent usage of glycol ethers |
| CN113100255A (en) * | 2021-04-15 | 2021-07-13 | 广东力特净消毒制品有限公司 | Composite nano-silver pet deodorizing disinfectant and preparation method thereof |
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| KR20020029091A (en) * | 1999-08-05 | 2002-04-17 | 모치츠키 노부히코 | Carbamate derivatives and agricultural/horticultural bactericides |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20020029091A (en) * | 1999-08-05 | 2002-04-17 | 모치츠키 노부히코 | Carbamate derivatives and agricultural/horticultural bactericides |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109329324A (en) * | 2018-12-14 | 2019-02-15 | 福建省世纪海峡农业发展投资有限公司 | A kind of incense piece and preparation method thereof enhancing livestock immunity |
| KR20200054922A (en) | 2020-05-01 | 2020-05-20 | 정봉진 | Development of fogging additives having superior mixing solubility of substances and boosting fogging in the fogging agent usage of glycol ethers |
| CN113100255A (en) * | 2021-04-15 | 2021-07-13 | 广东力特净消毒制品有限公司 | Composite nano-silver pet deodorizing disinfectant and preparation method thereof |
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