CN103981039A - Detergent and preparation method thereof - Google Patents
Detergent and preparation method thereof Download PDFInfo
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- CN103981039A CN103981039A CN201410206739.8A CN201410206739A CN103981039A CN 103981039 A CN103981039 A CN 103981039A CN 201410206739 A CN201410206739 A CN 201410206739A CN 103981039 A CN103981039 A CN 103981039A
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Abstract
The invention provides a detergent, comprising the following components in parts by weight: 0.4-8 parts of thickener, 0.06-2 parts of cross linker, 2-30 parts of active matter and 60-97.54 parts of water, wherein the thickener is selected from at least one of galactomannan and glucomannan; the cross linker is selected from at least one of boric acid, metaboric acid, metaborate and borate; the active matter is a surfactant of which the hydrophile-lipophile balance value is more than or equal to 12. The detergent is not bonded to packages or hands. Moreover, the invention further provides a preparation method for the detergent.
Description
Technical field
The invention belongs to cleaning supplies field, relate in particular to a kind of cleaning agent and preparation method thereof.
Background technology
Cleaning agent is almost indispensable a kind of cleaning supplies in people's daily life, cleaning agent is generally liquid or paste body shape, after cleaning agent uses, still have the inside that part cleaning agent sticks to packing material, now must can be removed by water, and traditional cleaning agent also must make water remove after sticking on hand, trouble very.
Summary of the invention
Given this, be necessary to provide a kind of packing material or cleaning agent on hand of can not sticking to.
The preparation method of above-mentioned cleaning agent also will be provided in addition.
A cleaning agent, according to parts by weight, comprises following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water; Wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.
In an embodiment, described polygalactomannan is selected from least one in guar gum, Viscogum BE, fenugreek gum, sesbania gum, Chinese honey locust bean gum, thorn kidney bean glue and Cassia bean gum therein; Described glucomannan is konjak gum.
In an embodiment, described metaborate is selected from least one in sodium metaborate and potassium metaborate therein; Described borate is selected from least one in sodium tetraborate and potassium tetraborate.
In an embodiment, described active substance is that hydrophile-lipophile balance value is more than or equal to 16 tensio-active agent therein.
In an embodiment, also comprise that parts by weight are the sequestrant of 0.02 part～0.5 part therein.
In an embodiment, also comprise that parts by weight are the amendment of 0.05 part～3 parts therein.
In an embodiment, also comprise that parts by weight are the wetting Agent for Printing Inks of 1 part～16 parts therein.
In an embodiment, also comprise that parts by weight are the buffer reagent of 0.2 part～3 parts therein.
A preparation method for cleaning agent, comprises the steps:
According to parts by weight, take following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water, wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent; And
Described active substance, described thickening material are mixed with described water, and then add described linking agent to be mixed to form gel.
A preparation method for cleaning agent, comprises the steps:
According to parts by weight, take following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts, tensio-active agent and water, wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent; And
Described thickening material is dissolved in described water, then adds described linking agent to form gel, more described gel is mixed with described active substance.
Above-mentioned cleaning agent is by being used at least one in polygalactomannan and glucomannan as thickening material, and use at least one in boric acid, metaboric acid, metaborate and borate as linking agent, and be that the thickening material of 0.4 part～8 parts, the linking agent of 0.06 part～2 parts, the active substance of 2 parts～30 parts and 60 parts～97.54 parts water are as component by operating weight umber, wherein, active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.Said components is under water effect, linking agent can form the network-like macromolecular compound gel with lock water effect, good filming and parcel ability with polygalactomannan, glucomannan generation crosslinked action, thereby wrap well active substance, make active substance in the situation that there is no external adding water, be difficult for dissociating out, and this network-like macromolecular compound can tightly be locked moisture, making it is no longer free water, the gel forming can not glue hand, therefore, above-mentioned cleaning agent can not stick to packing material or on hand.
Accompanying drawing explanation
Fig. 1 is preparation method's the schema of the cleaning agent of an embodiment;
Fig. 2 is preparation method's the schema of the cleaning agent of another embodiment.
Embodiment
Mainly in conjunction with the drawings and the specific embodiments cleaning agent and preparation method thereof is described in further detail below.
The cleaning agent of one embodiment, according to parts by weight, comprises following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water.
Wherein, thickening material is selected from least one in polygalactomannan and glucomannan.
Preferably, polygalactomannan is selected from least one in guar gum, Viscogum BE, fenugreek gum, sesbania gum, Chinese honey locust bean gum, thorn kidney bean glue and Cassia bean gum.
Preferably, glucomannan is konjak gum.
Wherein, linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate.
Preferably, metaborate is selected from least one in sodium metaborate and potassium metaborate; Borate is selected from least one in sodium tetraborate and potassium tetraborate.
More preferably, linking agent is sodium tetraborate.
Wherein, the activeconstituents that active substance is cleaning agent, is the effective constituent of clean and cleaning function.Wherein, active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.Due to hydrophile-lipophile balance value, be more than or equal to 12 tensio-active agent and there is higher wetting ability, soluble in water, and be transparent or translucent after water-soluble.
Preferably, active substance is selected from Emulphor FM (hydrophile-lipophile balance value is 12), cocoyl sodium isethionate (hydrophile-lipophile balance value is 14), C10 alkyl glycoside (hydrophile-lipophile balance value is 15), C12 alpha-olefin sodium sulfonate (hydrophile-lipophile balance value is 16), sodium oleate (hydrophile-lipophile balance value is 18), potassium oleate (hydrophile-lipophile balance value is 20), AMONYL 380LC (hydrophile-lipophile balance value is 22), cocoanut fatty acid diethanolamide (hydrophile-lipophile balance value is 25), N-hexadecyl-N-ethylmorpholine base sodium ethyl sulfate (hydrophile-lipophile balance value is 27), sodium lauryl sulphate (hydrophile-lipophile balance value is 40), at least one in ammonium lauryl sulfate (hydrophile-lipophile balance value is 40) and Dodecyl Polyoxyethylene Ether sodium sulfate (hydrophile-lipophile balance value is 41).These materials are all that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent, and these materials have higher wetting ability, soluble in water, and are transparent or translucent after water-soluble.
Preferred, active substance is that hydrophile-lipophile balance value is more than or equal to 16 tensio-active agent.The aqueous solution of the tensio-active agent of this hydrophile-lipophile balance value has higher transparency, and solution is difficult for layering and separates out, and water-soluble speed is fast, and processing is quick, and product is attractive in appearance.
Wherein, under the effect of water, above-mentioned linking agent can with above-mentioned polygalactomannan or glucomannan generation crosslinked action, ortho position cis hydroxyl groups on sugar ring is combined with boron and is formed network-like macromolecular compound gel, water molecules is combined in this network-like structure securely, thereby reach and effectively lock water effect, and this network-like macromolecular compound gel has good film-forming properties and parcel ability, to wrap active substance, make in the situation that there is no external adding water, active substance is difficult for dissociating out, and this network-like macromolecular compound gel has stretchiness, ductility, after breaking, self-adhesion is as a whole again, it can also be used as toy.
For example, polygalactomannan or glucomannan and boric acid generation crosslinked action, chemical equation is as follows:
In addition, this macromolecular compound has water-solubility function well, makes can dissolve fast or cracking after cleaning agent chance water, thereby active substance is discharged, to reach function clean and washing.
Tack-free and there is autohension just because of above-mentioned cleaning agent, if the cleaning agent taking out is too many, can also be by unnecessary partial replacement packing material, and the part of putting back to again can with packing material in cleaning agent be bonded into an integral body, thereby avoid waste.
Preferably, according to parts by weight, cleaning agent comprises following component: 77.6 parts～93.9 parts, 1 part～5 parts of thickening materials, 0.1 part～1.4 parts of linking agents, 5 parts～16 parts of active substances and water.The thickening material of this consumption, feel soft durometer is moderate, and sanitising agent is met water and is dissolved decomposition also than comparatively fast again.If thickening material very little, gel is partially rare, and hand is grabbed not firm.If thickening material is too many, gel is partially abundant, water-soluble partially slow, affects result of use.
Further, cleaning agent also comprises that parts by weight are the sequestrant of 0.02 part～0.5 part.
Preferably, sequestrant is disodium ethylene diamine tetraacetate or tetrasodium ethylenediamine tetraacetate.
Further, cleaning agent also comprises that parts by weight are the amendment of 0.05 part～3 parts.Adding amendment to make cleaning agent clean cleaning materials later can have submissiveer.
Amendment is preferably silicone oil, titanic acid ester or polyquaternium.Wherein, silicone oil is preferably polyether silicone oil (polyether-modified dimethyl siloxane); Titanic acid ester is preferably di-isopropyl titanic acid ester; Polyquaternium is preferably Dodecyl trimethyl ammonium chloride.
Further, cleaning agent also comprises that parts by weight are the wetting Agent for Printing Inks of 1 part～16 parts.Add wetting Agent for Printing Inks make cleaning agent can be more moisturizing for a long time.
Preferably, wetting Agent for Printing Inks is selected from least one in glycerol and ricinolic acid monooctyl ester.
Further, cleaning agent also comprises that weight percentage is the buffer reagent of 0.2 part～3 parts.Add buffer reagent, make the pH value stabilization of cleaning agent, potential of hydrogen fluctuation is little.
Preferably, buffer reagent is trolamine or SODIUM PHOSPHATE, MONOBASIC.
Be appreciated that amendment, wetting Agent for Printing Inks, sequestrant and buffer reagent also can omit.
Above-mentioned cleaning agent is by being used at least one in polygalactomannan and glucomannan as thickening material, and use at least one in boric acid, metaboric acid, metaborate and borate as linking agent, and be that the thickening material of 0.4 part～8 parts, the linking agent of 0.06 part～2 parts, the active substance of 2 parts～30 parts and 60 parts～97.54 parts water are as component by operating weight umber, wherein, active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.Under the effect of water, above-mentioned linking agent can form the network-like macromolecular compound gel with lock water effect, good filming and parcel ability with polygalactomannan, glucomannan generation crosslinked action, thereby wrap well active substance, make active substance in the situation that there is no external adding water, be difficult for dissociating out, because moisture is tightly locked in this network-like macromolecular compound gel, be no longer just free water, therefore, the gel of formation can not stick to packing material or on hand.
Wherein, above-mentioned cleaning agent can be used for cleaning clothes, hair, skin, tableware, vegetable and fruit etc.
As shown in Figure 1, a kind of preparation method of cleaning agent, is a kind of preparation method of above-mentioned cleaning agent, and this preparation method comprises the steps:
Step S110: take following component according to parts by weight: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water.
Wherein, thickening material is selected from least one in polygalactomannan and glucomannan.
Preferably, polygalactomannan is selected from least one in guar gum, Viscogum BE, fenugreek gum, sesbania gum, Chinese honey locust bean gum, thorn kidney bean glue and Cassia bean gum.
Preferably, glucomannan is konjak gum.
Wherein, linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate.
Preferably, metaborate is selected from least one in sodium metaborate and potassium metaborate; Borate is selected from least one in sodium tetraborate and potassium tetraborate.
Preferred, linking agent is sodium tetraborate.
Wherein, the activeconstituents that active substance is cleaning agent, is the effective constituent of clean and cleaning function.Wherein, active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.Due to hydrophile-lipophile balance value, be more than or equal to 12 tensio-active agent and there is higher wetting ability, soluble in water, and be transparent or translucent after water-soluble.
Preferably, active substance is selected from Emulphor FM (hydrophile-lipophile balance value is 12), cocoyl sodium isethionate (hydrophile-lipophile balance value is 14), C10 alkyl glycoside (hydrophile-lipophile balance value is 15), C12 alpha-olefin sodium sulfonate (hydrophile-lipophile balance value is 16), sodium oleate (hydrophile-lipophile balance value is 18), potassium oleate (hydrophile-lipophile balance value is 20), AMONYL 380LC (hydrophile-lipophile balance value is 22), cocoanut fatty acid diethanolamide (hydrophile-lipophile balance value is 25), N-hexadecyl-N-ethylmorpholine base sodium ethyl sulfate (hydrophile-lipophile balance value is 27), sodium lauryl sulphate (hydrophile-lipophile balance value is 40), at least one in ammonium lauryl sulfate (hydrophile-lipophile balance value is 40) and Dodecyl Polyoxyethylene Ether sodium sulfate (hydrophile-lipophile balance value is 41).These materials are all that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent, and these materials have higher wetting ability, soluble in water, and are transparent or translucent after water-soluble.
Preferred, active substance is that hydrophile-lipophile balance value is more than or equal to 16 tensio-active agent.The aqueous solution of the tensio-active agent of this hydrophile-lipophile balance value has higher transparency, and solution is difficult for layering and separates out, and water-soluble speed is fast, and processing is quick, and product is attractive in appearance.
Preferably, according to parts by weight, cleaning agent comprises following component: 77.6 parts～93.9 parts, 1 part～5 parts of thickening materials, 0.1 part～1.4 parts of linking agents, 5 parts～16 parts of active substances and water.The thickening material of this consumption, feel soft durometer is moderate, and sanitising agent is met water and is dissolved decomposition also than comparatively fast again.If thickening material very little, gel is partially rare, and hand is grabbed not firm.If thickening material is too many, gel is partially abundant, water-soluble partially slow, affects result of use.
Step S120: active substance, thickening material are mixed with water, and then add linking agent to be mixed to form gel.
Wherein, under the effect of water, above-mentioned linking agent can form network-like macromolecular compound gel with above-mentioned polygalactomannan or glucomannan generation crosslinked action, water molecules is combined in this network-like structure securely, thereby reach and effectively lock water effect, and this network-like macromolecular compound gel has good film-forming properties and parcel ability, to wrap active substance, make in the situation that there is no external adding water, active substance is difficult for dissociating out; And this network-like macromolecular compound gel has stretchiness, ductility, after breaking, self-adhesion is as a whole again, and it can also be used as toy.In addition, this macromolecular compound has water-solubility function well, makes can dissolve fast or cracking after cleaning agent chance water, thereby active substance is discharged, to reach function clean and washing.
Preferably, in step S110, also comprise that taking parts by weight is the amendment of 0.05 part～3 parts.Adding amendment to make cleaning agent clean cleaning materials later can have submissiveer.
Wherein, amendment is preferably silicone oil, titanic acid ester or polyquaternium.Wherein, silicone oil is preferably polyether silicone oil (polyether-modified dimethyl siloxane); Titanic acid ester is preferably di-isopropyl titanic acid ester; Polyquaternium is preferably Dodecyl trimethyl ammonium chloride.
Preferably, in step S110, also comprise that taking parts by weight is the sequestrant of 0.02 part～0.5 part.
Preferably, sequestrant is disodium ethylene diamine tetraacetate or tetrasodium ethylenediamine tetraacetate.
Preferably, in step S110, also comprise that taking parts by weight is the wetting Agent for Printing Inks of 1 part～16 parts.Add wetting Agent for Printing Inks make cleaning agent can be more moisturizing for a long time.Preferably, wetting Agent for Printing Inks is selected from least one in glycerol and ricinolic acid monooctyl ester.
Preferably, in step S110, also comprise that weight percentage is the buffer reagent of 0.2 part～3 parts.Add buffer reagent, make the pH value stabilization of cleaning agent, potential of hydrogen fluctuation is little.Preferably, buffer reagent is trolamine or SODIUM PHOSPHATE, MONOBASIC.
Now, step S120 is specially: active substance, thickening material, sequestrant, amendment, wetting Agent for Printing Inks and buffer reagent are mixed with water, and then add linking agent to be mixed to form gel.
The preparation method of above-mentioned cleaning agent is by active substance, thickening material are first mixed with water, and then adds linking agent to mix just can to prepare cleaning agent, operation very simply.
As shown in Figure 2, the preparation method of the cleaning agent of another embodiment, is the another kind of preparation method of above-mentioned cleaning agent, and the preparation method of this cleaning agent comprises the steps:
Step S210: take following component according to parts by weight: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water.
Wherein, thickening material is selected from least one in polygalactomannan and glucomannan.
Preferably, polygalactomannan is selected from least one in guar gum, Viscogum BE, fenugreek gum, sesbania gum, Chinese honey locust bean gum, thorn kidney bean glue and Cassia bean gum; Glucomannan is konjak gum.
Linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate.
Preferably, metaborate is selected from least one in sodium metaborate and potassium metaborate; Borate is selected from least one in sodium tetraborate and potassium tetraborate.
Preferred, linking agent is sodium tetraborate.
Wherein, the activeconstituents that active substance is cleaning agent, is the effective constituent of clean and cleaning function.Active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.Due to hydrophile-lipophile balance value, be more than or equal to 12 tensio-active agent and there is higher wetting ability, soluble in water, and be transparent or translucent after water-soluble.
Preferably, active substance is selected from Emulphor FM (hydrophile-lipophile balance value is 12), cocoyl sodium isethionate (hydrophile-lipophile balance value is 14), C10 alkyl glycoside (hydrophile-lipophile balance value is 15), C12 alpha-olefin sodium sulfonate (hydrophile-lipophile balance value is 16), sodium oleate (hydrophile-lipophile balance value is 18), potassium oleate (hydrophile-lipophile balance value is 20), AMONYL 380LC (hydrophile-lipophile balance value is 22), cocoanut fatty acid diethanolamide (hydrophile-lipophile balance value is 25), N-hexadecyl-N-ethylmorpholine base sodium ethyl sulfate (hydrophile-lipophile balance value is 27), sodium lauryl sulphate (hydrophile-lipophile balance value is 40), at least one in ammonium lauryl sulfate (hydrophile-lipophile balance value is 40) and Dodecyl Polyoxyethylene Ether sodium sulfate (hydrophile-lipophile balance value is 41).These materials are all that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent, and these materials have higher wetting ability, soluble in water, and are transparent or translucent after water-soluble.
Preferred, active substance is that hydrophile-lipophile balance value is more than or equal to 16 tensio-active agent.The aqueous solution of the tensio-active agent of this hydrophile-lipophile balance value has higher transparency, and solution is difficult for layering and separates out, and water-soluble speed is fast, and processing is quick, and product is attractive in appearance.
Preferably, according to parts by weight, cleaning agent comprises following component: 77.6 parts～93.9 parts, 1 part～5 parts of thickening materials, 0.1 part～1.4 parts of linking agents, 5 parts～16 parts of active substances and water.The thickening material of this consumption, feel soft durometer is moderate, and sanitising agent is met water and is dissolved decomposition also than comparatively fast again.If thickening material very little, gel is partially rare, and hand is grabbed not firm.If thickening material is too many, gel is partially abundant, water-soluble partially slow, affects result of use.
Step S220: thickening material is dissolved in the water, then adds linking agent to form gel, then gel is mixed with active substance.
Wherein, under the effect of water, above-mentioned linking agent and above-mentioned polygalactomannan or glucomannan generation crosslinked action form network-like macromolecular compound gel, water molecules is combined in this network-like structure securely, thereby reach and effectively lock water effect, and this network-like macromolecular compound gel has good film-forming properties and parcel ability, active substance is mixed to the macromolecular compound gel network-like with this to be mixed, to wrap active substance, make in the situation that there is no external adding water, active substance is difficult for dissociating out; And this network-like macromolecular compound gel has stretchiness, ductility, after breaking, self-adhesion is as a whole again, and it can also be used as toy.In addition, this macromolecular compound has water-solubility function well, makes can dissolve fast or cracking after cleaning agent chance water, thereby active substance is discharged, to reach function clean and washing.
Preferably, in step S210, also comprise that taking parts by weight is the amendment of 0.05 part～3 parts.Adding amendment to make cleaning agent clean cleaning materials later can have submissiveer.Amendment is preferably silicone oil, titanic acid ester or polyquaternium.Wherein, silicone oil is preferably polyether silicone oil (polyether-modified dimethyl siloxane); Titanic acid ester is preferably di-isopropyl titanic acid ester; Polyquaternium is preferably Dodecyl trimethyl ammonium chloride.
Preferably, in step S210, also comprise that taking parts by weight is the sequestrant of 0.02 part～0.5 part.
Preferably, sequestrant is disodium ethylene diamine tetraacetate or tetrasodium ethylenediamine tetraacetate.
Preferably, in step S210, also comprise that taking parts by weight is the wetting Agent for Printing Inks of 1 part～16 parts.Add wetting Agent for Printing Inks make cleaning agent can be more moisturizing for a long time.Preferably, wetting Agent for Printing Inks is selected from least one in glycerol and ricinolic acid monooctyl ester.
Preferably, in step S210, also comprise that weight percentage is the buffer reagent of 0.2 part～3 parts.Add buffer reagent, make the pH value stabilization of cleaning agent, potential of hydrogen fluctuation is little.Preferably, buffer reagent is trolamine or SODIUM PHOSPHATE, MONOBASIC.
Now, the step of step S220 is specially: thickening material, amendment, sequestrant, wetting Agent for Printing Inks and buffer reagent are dissolved in the water, then add linking agent to form gel, then gel is mixed with active substance.
The preparation method of above-mentioned cleaning agent is by being dissolved in the water thickening material, then adds after linking agent forms high-molecular gel, then gel is just mixed and can prepare cleaning agent with active substance, operate very simply.
It is below specific embodiment part, testing apparatus is twin-roll machine (specification: the roller by 2 304 stainless steels forms, 5 centimetres of the diameters of roller, long 30 centimetres, on roller, there are 2 twills that are 30 degree spirals interlaced, article one, twill distributes from left to right in the shape of a spiral, and another twill distributes from right to left in the shape of a spiral.1 millimeter of twill width, 1.5 millimeters of the twill degree of depth, the spacing of two rollers can regulate between 0～5 millimeter, and the rotating speed of roller can regulate between 10～120 revs/min.)：
Embodiment 1
The preparation process of the cleaning agent of the present embodiment is as follows:
(1) according to following parts by weight, take component:
(2) in dispersion machine, first sodium lauryl sulphate, Dodecyl trimethyl ammonium chloride, SODIUM PHOSPHATE, MONOBASIC, disodium ethylene diamine tetraacetate are added to the water, stir at normal temperatures, maintain the state of rapid stirring, slowly add sesbania gum, stir more than 2 minutes, allow sesbania gum be uniformly dispersed, then add glycerol, stir 1 minute, add sodium tetraborate, continue stirring and be cross-linked for 4 minutes, form uniform gel, obtain the cleaning agent of the present embodiment.
Cleaning agent that the present embodiment is obtained is used twin-roll machine to roll test under different roller rotating speeds and different roller spacing, and to test adhesion property and the water soluble characteristic of the cleaning agent that the present embodiment obtains, testing method is as follows:
Test 1: the adhesion property of the cleaning agent that test the present embodiment obtains under high speed thin space, specific as follows: the spacing of two rollers is adjusted to 1 millimeter, 120 revs/min of rotating speeds, take 100 grams of cleaning agents, pour in roller, and continuing again to put back in roller by the cleaning agent after roller, rotate and after kind, stop for 60 seconds, observe cleaning agent and whether stick on roller.
Test 2: the adhesion property of the cleaning agent that test the present embodiment obtains under the wide spacing of low speed, specific as follows: the spacing of two rollers is adjusted to 5 millimeters, 10 revs/min of rotating speeds, take 100 grams of cleaning agents, pour in roller, and continuing again to put back in roller by the cleaning agent after roller, rotate and after kind, stop for 60 seconds, observe cleaning agent and whether stick on roller.
Test 3: the adhesion property of the cleaning agent that test the present embodiment obtains under the wide spacing of high speed, specific as follows: the spacing of two rollers is adjusted to 5 millimeters, 120 revs/min of rotating speeds, take 100 grams of cleaning agents, pour in roller, and continuing again to put back in roller by the cleaning agent after roller, rotate and after kind, stop for 60 seconds, observe cleaning agent and whether stick on roller.
Test 4: the adhesion property of test under low speed thin space, specific as follows: the spacing of two rollers is adjusted to 1 millimeter, 10 revs/min of rotating speeds, take 100 grams of cleaning agents, pour in roller, and continuing again to put back in roller by the cleaning agent after roller, rotate and after kind, stop for 60 seconds, observe cleaning agent and whether stick on roller.
Test 5: test the present embodiment is in the water-soluble situation of middling speed thin space, specific as follows: the spacing of two rollers to be adjusted to 1 millimeter, 60 revs/min of rotating speeds.Take 50 grams of cleaning agents, add 50 grams of pure water, mix, after water mixes with cleaning agent, within 60 seconds, pour in the twin-roll machine of rotation, again the colloid mixture through twin-roll machine is poured in the twin-roll machine of rotation again, rotate and after kind, stop for 60 seconds, observe water and whether cleaning agent is molten is integrated, whether foam produces.
The test result of the cleaning agent of the present embodiment is as follows:
Test 1: roll banding not, noresidue in lines.
Test 2: roll banding not, noresidue in lines.
Test 3: roll banding not, noresidue in lines.
Test 4: roll banding not, noresidue in lines.
Test 5: cleaning agent and water-soluble being integrated, and become foams.
From testing 1, to test 4 result, show, the cleaning agent of the present embodiment can not stick on object completely, and the result of test 5 shows, the cleaning agent of the present embodiment has well water-soluble.
Embodiment 2
The preparation process of the cleaning agent of the present embodiment is as follows:
(1) according to following parts by weight, take component:
(2) in dispersion machine, ricinolic acid monooctyl ester, di-isopropyl titanic acid ester, tetrasodium ethylenediamine tetraacetate, trolamine are added to the water, stir after 2 minutes, while adding konjak gum to stir, after konjak gum all adds, continue to stir more than 3 minutes, make mixture thickened, then add boric acid, continue to stir more than 3 minutes, be cross-linked to form gel, then add C12 alpha-olefin sodium sulfonate, stirring and evenly mixing, obtains the cleaning agent of the present embodiment.
Adopt the Lung biopsy in embodiment 1 to test the cleaning agent of the present embodiment, the test result of cleaning agent that obtains the present embodiment is as follows:
Test 1: roll banding not, noresidue in lines.
Test 2: roll banding not, noresidue in lines.
Test 3: roll banding not, noresidue in lines.
Test 4: roll banding not, noresidue in lines.
Test 5: cleaning agent and water-soluble being integrated, and become foams.
From testing 1, to test 4 result, show, the cleaning agent of the present embodiment can not stick on object completely, and the result of test 5 shows, the cleaning agent of the present embodiment has well water-soluble.
Embodiment 3
According to following parts by weight, take component:
(2) in dispersion machine, first by sodium oleate, C10 alkyl glycoside, Dodecyl Polyoxyethylene Ether sodium sulfate, Emulphor FM, trolamine, di-isopropyl titanic acid ester and tetrasodium ethylenediamine tetraacetate are added to the water, stir at normal temperatures, maintain the state of rapid stirring, slowly add guar gum and Cassia bean gum, stir more than 2 minutes, allow guar gum and Cassia bean gum be uniformly dispersed, then add glycerol, stir 1 minute, add potassium tetraborate and metaboric acid, continue to stir and be cross-linked for 4 minutes, form uniform gel, obtain the cleaning agent of the present embodiment.
Adopt the Lung biopsy in embodiment 1 to test the cleaning agent of the present embodiment, the test result of cleaning agent that obtains the present embodiment is as follows:
Test 1: roll banding not, noresidue in lines.
Test 2: roll banding not, noresidue in lines.
Test 3: roll banding not, noresidue in lines.
Test 4: roll banding not, noresidue in lines.
Test 5: cleaning agent and water-soluble being integrated, and become foams.
From testing 1, to test 4 result, show, the cleaning agent of the present embodiment can not stick on object completely, and the result of test 5 shows, the cleaning agent of the present embodiment has well water-soluble.
Embodiment 4
The preparation process of the cleaning agent of the present embodiment is as follows:
(1) according to following parts by weight, take component:
(2) in dispersion machine, by disodium ethylene diamine tetraacetate, ricinolic acid monooctyl ester, polyether silicone oil, SODIUM PHOSPHATE, MONOBASIC is added to the water, stir after 2 minutes, add Viscogum BE on one side, fenugreek gum and konjak gum, stir on one side, Viscogum BE, after fenugreek gum and konjak gum all add, continue to stir more than 3 minutes, make mixture thickened, then add sodium metaborate, continue to stir more than 3 minutes, be cross-linked to form gel, then add N-hexadecyl-N-ethylmorpholine base sodium ethyl sulfate, AMONYL 380LC and potassium oleate, stirring and evenly mixing, obtain the cleaning agent of the present embodiment.
Adopt the Lung biopsy in embodiment 1 to test the cleaning agent of the present embodiment, the test result of cleaning agent that obtains the present embodiment is as follows:
Test 1: roll banding not, noresidue in lines.
Test 2: roll banding not, noresidue in lines.
Test 3: roll banding not, noresidue in lines.
Test 4: roll banding not, noresidue in lines.
Test 5: cleaning agent and water-soluble being integrated, and become foams.
From testing 1, to test 4 result, show, the cleaning agent of the present embodiment can not stick on object completely, and the result of test 5 shows, the cleaning agent of the present embodiment has well water-soluble.
Embodiment 5
The preparation process of the cleaning agent of the present embodiment is as follows:
(1) according to following parts by weight, take component:
(2) in dispersion machine, by tetrasodium ethylenediamine tetraacetate, Dodecyl trimethyl ammonium chloride, ricinolic acid monooctyl ester, Sodium phosphate dibasic, di-isopropyl titanic acid ester and glycerol are added to the water, stir after 2 minutes, add Chinese honey locust bean gum on one side, thorn kidney bean glue, guar gum and sesbania gum stir on one side, Chinese honey locust bean gum, thorn kidney bean glue, after guar gum and sesbania gum all add, continue to stir more than 3 minutes, make mixture thickened, then add sodium tetraborate, potassium metaborate and boric acid, continue to stir more than 3 minutes, be cross-linked to form gel, then add cocounut oil sodium isethionate, cocoanut fatty acid diethanolamide, ammonium lauryl sulfate, stirring and evenly mixing, obtain the cleaning agent of the present embodiment.
Adopt the Lung biopsy in embodiment 1 to test the cleaning agent of the present embodiment, the test result of cleaning agent that obtains the present embodiment is as follows:
Test 1: roll banding not, noresidue in lines.
Test 2: roll banding not, noresidue in lines.
Test 3: roll banding not, noresidue in lines.
Test 4: roll banding not, noresidue in lines.
Test 5: cleaning agent and water-soluble being integrated, and become foams.
From testing 1, to test 4 result, show, the cleaning agent of the present embodiment can not stick on object completely, and the result of test 5 shows, the cleaning agent of the present embodiment has well water-soluble.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. a cleaning agent, is characterized in that, according to parts by weight, comprises following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water; Wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent.
2. cleaning agent according to claim 1, is characterized in that, described polygalactomannan is selected from least one in guar gum, Viscogum BE, fenugreek gum, sesbania gum, Chinese honey locust bean gum, thorn kidney bean glue and Cassia bean gum; Described glucomannan is konjak gum.
3. cleaning agent according to claim 1, is characterized in that, described metaborate is selected from least one in sodium metaborate and potassium metaborate; Described borate is selected from least one in sodium tetraborate and potassium tetraborate.
4. cleaning agent according to claim 1, is characterized in that, described active substance is that hydrophile-lipophile balance value is more than or equal to 16 tensio-active agent.
5. cleaning agent according to claim 1, is characterized in that, also comprises that parts by weight are the sequestrant of 0.02 part～0.5 part.
6. cleaning agent according to claim 1, is characterized in that, also comprises that parts by weight are the amendment of 0.05 part～3 parts.
7. cleaning agent according to claim 1, is characterized in that, also comprises that parts by weight are the wetting Agent for Printing Inks of 1 part～16 parts.
8. cleaning agent according to claim 1, is characterized in that, also comprises that parts by weight are the buffer reagent of 0.2 part～3 parts.
9. a preparation method for cleaning agent, is characterized in that, comprises the steps:
According to parts by weight, take following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water, wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent; And
Described active substance, described thickening material are mixed with described water, and then add described linking agent to be mixed to form gel.
10. a preparation method for cleaning agent, is characterized in that, comprises the steps:
According to parts by weight, take following component: 60 parts～97.54 parts, 0.4 part～8 parts of thickening materials, 0.06 part～2 parts of linking agents, 2 parts～30 parts of active substances and water, wherein, described thickening material is selected from least one in polygalactomannan and glucomannan, described linking agent is selected from least one in boric acid, metaboric acid, metaborate and borate, and described active substance is that hydrophile-lipophile balance value is more than or equal to 12 tensio-active agent; And
Described thickening material is dissolved in described water, then adds described linking agent to form gel, more described gel is mixed with described active substance.
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Application publication date: 20140813 |