CN106811330A - One kind laundry effervescent tablet and preparation method thereof - Google Patents
One kind laundry effervescent tablet and preparation method thereof Download PDFInfo
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- CN106811330A CN106811330A CN201611122432.5A CN201611122432A CN106811330A CN 106811330 A CN106811330 A CN 106811330A CN 201611122432 A CN201611122432 A CN 201611122432A CN 106811330 A CN106811330 A CN 106811330A
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- effervescent tablet
- compound
- laundry
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- 239000007938 effervescent tablet Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000003826 tablet Substances 0.000 claims abstract description 41
- 241000209094 Oryza Species 0.000 claims abstract description 32
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 32
- 235000009566 rice Nutrition 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 30
- 239000006188 syrup Substances 0.000 claims abstract description 30
- 235000020357 syrup Nutrition 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 24
- -1 softener Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000007884 disintegrant Substances 0.000 claims abstract description 12
- 239000003755 preservative agent Substances 0.000 claims abstract description 12
- 230000002335 preservative effect Effects 0.000 claims abstract description 12
- 239000003086 colorant Substances 0.000 claims abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 10
- 108091005804 Peptidases Proteins 0.000 claims abstract description 9
- 239000004365 Protease Substances 0.000 claims abstract description 9
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 9
- 239000011812 mixed powder Substances 0.000 claims abstract description 9
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- 239000011734 sodium Substances 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 229920002472 Starch Polymers 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000007932 molded tablet Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 102000002322 Egg Proteins Human genes 0.000 claims 1
- 108010000912 Egg Proteins Proteins 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 claims 1
- 108090000790 Enzymes Proteins 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000014103 egg white Nutrition 0.000 claims 1
- 210000000969 egg white Anatomy 0.000 claims 1
- 229930182470 glycoside Natural products 0.000 claims 1
- 150000002338 glycosides Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 7
- 239000012467 final product Substances 0.000 abstract 1
- 229930182478 glucoside Natural products 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 5
- LKZVJKCSPGCLCH-UHFFFAOYSA-N 4,5-dihydro-1h-imidazole;quinoline Chemical compound C1CN=CN1.N1=CC=CC2=CC=CC=C21 LKZVJKCSPGCLCH-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000227 bioadhesive Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
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Abstract
The invention provides one kind laundry effervescent tablet and preparation method thereof, the effervescent tablet includes following raw material：Nonionic surfactant, anion surfactant, softener, disintegrant, sticky rice syrup, protease, effervescent agent composition, essence particle, colorant particle and preservative.Its preparation method is first to mix colorant particle, essence particle, preservative, nonionic surfactant, anion surfactant and protease, crush, add the mixed-powder of softener and sticky rice syrup, it is subsequently adding disintegrant and effervescent agent composition, sticky rice syrup is added after stirring, compound is added into plastotype, it is last to be rolled with effervescent agent composition after tablet surface even application sticky rice syrup is molded, mixed, obtain final product.Laundry effervescent tablet of the invention not only has excellent hardness and friability, is easily dispersed after being dissolved in water, washing, submissive effect is significant.
Description
Technical field
The invention belongs to detergent body technical field, and in particular to one kind laundry effervescent tablet and preparation method thereof.
Background technology
Laundry sheet develops relatively rapidly as a kind of new detergent form in recent years, and the advantage that it possesses is very bright
It is aobvious, mainly it is following some：First, change washing powder, liquid detergent need metering use it is cumbersome.Two and traditional washing powder,
Detergent is compared, and laundry effervescent tablet contains more active ingredients, greatly reduces the use of inserts, auxiliary material, water etc., matches somebody with somebody
The effect that Fang Shixian economizes on resources.3rd, laundry effervescent tablet is with its small volume, and lightweight, packaging consumptive material is small, storage is convenient, no
Perishable the advantages of, canned flow relatively complicated to traditional liquid detergent, laundry sheet has more advantage in drop present aspect, green,
Environmentally friendly aspect also has prominent contribution.
Effervescent tablet is a kind of tablet containing gas-producing disintegrant.Gas-producing disintegrant is typically organic acid and sodium acid carbonate
The mixture of (sodium bicarbonate)；Effervescent tablet dries moisture-free in itself, and two in gas-producing disintegrant kind material is unionized can not to be sent out
Raw reaction；But after effervescent tablet is put into water, organic acid and sodium acid carbonate are ionized in the presence of water, and double decomposition occurs
Reaction, produces great amount of carbon dioxide, tablet disintegration and is melted rapidly, and the bubble of generation is disintegrated sometimes can also make tablet in water
Roll up and down, accelerate it to be disintegrated and melt.During the carbon dioxide produced during disintegration of tablet is partially dissolved in, laundry effervescent tablet
Advantage is, because a large amount of foams that disintegration is produced increased surfactant and treat the directly contact of laundering of textile fabrics, preferably
Play washing, submissive effect.
Used as a kind of tablet, it is related to some key propertys of tablet to laundry effervescent tablet, such as hardness, friability, resistance to
Tide.Must also possess the characteristic of detergent simultaneously, all high requirement in terms of dissolubility, detergency, environmental protection.
The content of the invention
The technical problem of solution：It is an object of the invention to provide one kind laundry effervescent tablet and preparation method thereof, using molten
The good solid-state softener of solution property, by coated with uniform fabric serous coat, is allowed to solidify, and improves tablet hardness, friability；Pass through
Inside tablet and the equally distributed effervescent agent composition in surface, short time decompose tablet is played, reach the submissive component of washing equal
Even scattered effect.
Technical scheme：One kind laundry effervescent tablet, by weight including following raw material：Nonionic surfactant
20.0-30.0 parts, anion surfactant 20.0-50.0 parts, softener 0.5-2.0 parts, disintegrant 6.0-10.0 parts, glutinous rice
1.0-4.0 parts of slurry, protease 0.1-1.0 parts, 2.0-6.0 parts of effervescent agent composition, 0.01-0.1 parts of essence particle, colouring agent
Particle 0.01-0.04 parts, preservative 0.01-0.03 parts.
Further, the nonionic surfactant is alcohol ether glucoside.
Further, the anion surfactant is methyl sodiosul foaliphatate, α-sodium olefin sulfonate or fatty alcohol
One or more in ether sodium sulfate.
Further, the softener is cold water film.
Further, the cold water film is that aliphatic acid, aliphatic polybasic acid alcoholic compound, fatty acid amide spread out weak cation
The mixture of one or more in compound or fatty acid imidazoline quinoline compound.
Further, the disintegrant is sodium carboxymethyl starch.
Further, the effervescent agent composition is the dry powder mixture of organic acid and sodium acid carbonate.
The preparation method of above-mentioned laundry effervescent tablet, comprises the following steps：
Step 1, by colorant particle, essence particle, preservative, nonionic surfactant, anion surfactant
With protease mixing, crushing, mixed-powder one is obtained；
Step 2, adds the sticky rice syrup of 1/2 weight portion after softener is crushed, mixing, drying obtain mixed-powder two；
Step 3, mixed-powder two is added in mixed-powder one, mixing, obtains compound one；
Step 4, during the effervescent agent composition of disintegrant and 3/4 weight portion added into compound one, stirring adds 1/4 weight
The sticky rice syrup of part is measured, mixing, stirring obtain compound two；
Step 5, plastotype in tablet mould is added to by compound two, obtains being molded tablet；
Step 6, shaping tablet is taken out, and the sticky rice syrup of the weight portion of even application 1/4 on surface adds 1/4 weight portion
Effervescent agent composition, fully rolls, mixes, and is finally screened, filtered, and obtains effervescent tablet finished product of doing washing, packaging.
Further, step 5 gained shaping tablet thickness >=5mm, kenel is oval, circle, square and other solid types
State.
Beneficial effect：
(1) by way of in softener Surface coating bioadhesive (sticky rice syrup), softener component is solved to tablet
The problem that hardness is deteriorated after shaping, friability is deteriorated；Because softener belongs to the small surfactant of surface tension, it is mainly made
Softening agent, the antistatic additive of fiber are used as, its physical property is to have slippery under solid state, so tablet is molded increasing
Difficulty.Due to sticky rice syrup modest viscosity, and good biocompatibility, after being coated on softener surface, enhance softener component with
The bond properties of other components, lifting tablet hardness, friability；
(2) reacted by inside tablet and the equally distributed effervescent agent composition in surface, meeting water, increase tablet with
The contact area of water, and it is exothermic reaction to react, and can further function as decompose tablet, plays short time decompose tablet, is reached
In evenly spreading to solution to washing, submissive component, washing, submissive effect are improved；
(3) disintegrant is evenly mixed in formula, under the synergy of effervescent agent, can constantly touches water, rapidly
Disintegrating tablet, accelerates surfactant diffusion, dissolution velocity；
(4) present invention uses sticky rice syrup as adhesive, film forming agent, is not only obviously improved tablet moisture resistivity, and raw material
Technique environmental protection, make consumer using, storage carry all obtain conveniently, safely；The sanitary sewage produced after washing, with water body
Good biocompatibility, adhesive, film forming agent than chemical composition are easy to degraded.
Specific embodiment
Invention is described in further detail below by specific embodiment.But it will be understood to those of skill in the art that under
Row embodiment is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.
Embodiment 1
(1) laundry effervescent tablet raw material components
20 parts of alcohol ether glucoside, 10 parts of methyl sodiosul foaliphatate, 5 parts of α-sodium olefin sulfonate, 10 parts of fatty alcohol-ether sodium sulfate,
0.3 part of aliphatic acid film, 0.2 part of fatty polyol film, 1.0 parts of sticky rice syrup, 6.0 parts of sodium carboxymethyl starch, proteinase-10 .2
Part, 2.0 parts of effervescent agent composition, 0.01 part of essence particle, 0.02 part of colorant particle, 0.01 part of preservative.
(2) preparation process
Step 1, by colorant particle, essence particle, preservative, alcohol ether glucoside, methyl sodiosul foaliphatate, α-alkenyl sulphur
Sour sodium, fatty alcohol-ether sodium sulfate, protease are added in cutter, high speed shear, crushing 30min, are well mixed, standby；
Step 2, aliphatic acid film, fatty polyol film is crushed, is stirred, and is slowly added to 0.5 part of sticky rice syrup, is stirred
30min, is well mixed, standby；
Step 3, the powder of step 2 gained is added in the mix powder of step 1, stirs 60min；
Step 4,1.5 parts of effervescent agent compositions, sodium carboxymethyl starches are added in the compound of step 3, stirring
30min, adds 0.25 part of sticky rice syrup, stirs 30min；
Step 5, plastotype in tablet mould is added to by the compound that step 4 is obtained；
Step 6, the tablet that will be molded takes out, and in 0.25 part of sticky rice syrup of tablet surface even application, adds 0.5 part of effervescent agent
Composition, fully rolls, mixes, and is finally screened, filtered, and obtains softening laundry effervescent tablet finished product, packs.
Embodiment 2
(1) laundry effervescent tablet raw material components
25 parts of alcohol ether glucoside, 15 parts of methyl sodiosul foaliphatate, 5 parts of α-sodium olefin sulfonate, 10 parts of fatty alcohol-ether sodium sulfate,
1.0 parts of fatty acid imidazoline quinoline film, 2.0 parts of sticky rice syrup, 8.0 parts of sodium carboxymethyl starch, proteinase-10 .5 parts, effervescent agent composition
4.0 parts, 0.04 part of essence particle, 0.03 part of colorant particle, 0.02 part of preservative.
(2) preparation process
Step 1, by colorant particle, essence particle, preservative, alcohol ether glucoside, methyl sodiosul foaliphatate, α-alkenyl sulphur
Sour sodium, fatty alcohol-ether sodium sulfate, protease are added in cutter, high speed shear, crushing 30min, are well mixed, standby；
Step 2, fatty acid imidazoline quinoline film is crushed, is stirred, and is slowly added to 1.0 parts of sticky rice syrups, stirs 30min, mixing
Uniformly, it is standby；
Step 3, the powder of step 2 gained is added in the mix powder of step 1, stirs 60min；
Step 4,3.0 parts of effervescent agent compositions, sodium carboxymethyl starches are added in the compound of step 3, stirring
30min, adds 0.5 part of sticky rice syrup, stirs 30min；
Step 5, plastotype in tablet mould is added to by the compound that step 4 is obtained；
Step 6, the tablet that will be molded takes out, and in 0.5 part of sticky rice syrup of tablet surface even application, adds 1.0 parts of effervescent agents
Composition powder, fully rolls, mixes, and is finally screened, filtered, and obtains softening laundry effervescent tablet finished product, packs.
Embodiment 3
(1) laundry effervescent tablet raw material components
30 parts of alcohol ether glucoside, 15 parts of methyl sodiosul foaliphatate, 5 parts of α-sodium olefin sulfonate, 25 parts of fatty alcohol-ether sodium sulfate,
Fatty acid amide spreads out 1.0 parts of weak cation compound, 1.0 parts of fatty acid imidazoline quinoline film, 4.0 parts of sticky rice syrup, CMS
10.0 parts of sodium, 1.0 parts of protease, 6.0 parts of effervescent agent composition, 0.08 part of essence particle, 0.04 part of colorant particle, preservative
0.03 part.
(2) preparation process
Step 1, by colorant particle, essence particle, preservative, alcohol ether glucoside, methyl sodiosul foaliphatate, α-alkenyl sulphur
Sour sodium, fatty alcohol-ether sodium sulfate, protease are added in cutter, high speed shear, crushing 30min, are well mixed, standby；
Step 2, fatty acid imidazoline quinoline film is crushed, is stirred, and is slowly added to 2.0 parts of sticky rice syrups, stirs 30min, mixing
Uniformly, it is standby；
Step 3, the powder of step 2 gained is added in the mix powder of step 1, stirs 60min；
Step 4,4.5 parts of effervescent agent compositions, sodium carboxymethyl starches are added in the compound of step 3, stirring
30min, adds 1.0 parts of sticky rice syrups, stirs 30min；
Step 5, plastotype in tablet mould is added to by the compound that step 4 is obtained；
Step 6, the tablet that will be molded takes out, and in 1.0 parts of sticky rice syrups of tablet surface even application, adds 1.5 parts of effervescent agents
Composition powder, fully rolls, mixes, and is finally screened, filtered, and obtains softening laundry effervescent tablet finished product, packs.
Reference examples 1
Reference examples 1 differ primarily in that step 2 is without sticky rice syrup, and other are constant with embodiment 2.
Reference examples 2
Reference examples 2 differ primarily in that the deal of softener is 4.0 parts, and other are constant with embodiment 2.
Reference examples 3
Reference examples 3 differ primarily in that with embodiment 2, cancellation step 6, other constant
Reference examples 4
Reference examples 4 differ primarily in that softener type selects liquid, semisolid softener, and other are equal with embodiment 2
It is constant.
Embodiment and reference examples gained laundry effervescent tablet are carried out into performance test, it is as a result as follows：
By embodiment 2, reference examples 1 understand that do not use sticky rice syrup, the solubility property of effervesce laundry sheet, hardness friability are equal
Poor, it is known that sticky rice syrup plays adhesive in invention, the effect of film forming agent plays a role to effervescent agent, tablet it is physical
Good action can be played；
By embodiment 2, reference examples 2 understand that addition is excessive, and softener addition is excessive, can influence product hardness, friability
Degree, preserves to product and transports unfavorable, influences product practicality；
From embodiment 2 and reference examples 3, the step (6) in the present invention has very big shadow to the dissolution velocity of effervescent tablet
Ring, essentially consist in tablet surface and there is effervescent agent chance water generation flood tide bubble, accelerate contact of the tablet with water, improve dissolving
Property；Other step 6 has castering action for the hardness of tablet, friability, and main sticky rice syrup is played as good film forming agent
Protect the effect of tablet；
From embodiment 2 and reference examples 4, effervescent tablet of the invention, its physical state is chip solid, by crushing
The powder for being formed afterwards, under the coating function of sticky rice syrup adhesive, solves it to tablet hardness, the harmful effect of friability,
If converted to the softener of liquid or semi-solid state, tablet hardness, friability are poor after its shaping.
Claims (9)
1. a kind of laundry effervescent tablet, it is characterised in that：Include following raw material by weight：Nonionic surfactant
20.0-30.0 parts, anion surfactant 20.0-50.0 parts, softener 0.5-2.0 parts, disintegrant 6.0-10.0 parts, glutinous rice
1.0-4.0 parts of slurry, protease 0.1-1.0 parts, 2.0-6.0 parts of effervescent agent composition, 0.01-0.1 parts of essence particle, colouring agent
Particle 0.01-0.04 parts, preservative 0.01-0.03 parts.
2. laundry effervescent tablet according to claim 1, it is characterised in that：The nonionic surfactant is alcohol ether sugar
Glycosides.
3. laundry effervescent tablet according to claim 1, it is characterised in that：The anion surfactant is aliphatic acid
One or more in methyl ester sulfonate, α-sodium olefin sulfonate or fatty alcohol-ether sodium sulfate.
4. laundry effervescent tablet according to claim 1, it is characterised in that：The softener is cold water film.
5. laundry effervescent tablet according to claim 4, it is characterised in that：The cold water film is aliphatic acid, aliphatic acid
One or more mixed that polyol compound, fatty acid amide spread out in weak cation compound or fatty acid imidazoline quinoline compound
Compound.
6. laundry effervescent tablet according to claim 1, it is characterised in that：The disintegrant is sodium carboxymethyl starch.
7. laundry effervescent tablet according to claim 1, it is characterised in that：The effervescent agent composition is organic acid and carbon
The dry powder mixture of sour hydrogen sodium.
8. described in claim 1 laundry effervescent tablet preparation method, it is characterised in that：Comprise the following steps：
Step 1, by colorant particle, essence particle, preservative, nonionic surfactant, anion surfactant and egg
White enzyme mixing, crushing, obtain mixed-powder one；
Step 2, adds the sticky rice syrup of 1/2 weight portion after softener is crushed, mixing, drying obtain mixed-powder two；
Step 3, mixed-powder two is added in mixed-powder one, mixing, obtains compound one；
Step 4, during the effervescent agent composition of disintegrant and 3/4 weight portion added into compound one, stirring adds 1/4 weight portion
Sticky rice syrup, mixing, stirring, obtain compound two；
Step 5, plastotype in tablet mould is added to by compound two, obtains being molded tablet；
Step 6, shaping tablet is taken out, and the sticky rice syrup of the weight portion of even application 1/4 on surface adds the effervesce of 1/4 weight portion
Agent composition, fully rolls, mixes, and is finally screened, filtered, and obtains effervescent tablet finished product of doing washing, packaging.
9. it is according to claim 8 laundry effervescent tablet preparation method, it is characterised in that：Step 5 gained shaping tablet
Thickness >=5mm, kenel is oval, circle, square and other solid type states.
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| CN111155314A (en) * | 2018-11-07 | 2020-05-15 | 广州优涤日化有限公司 | Granular fabric care agent and preparation method thereof |
| CN111234966A (en) * | 2020-02-18 | 2020-06-05 | 广州市爱家有方日用品有限公司 | Laundry effervescent tablet and preparation method thereof |
| WO2021259647A1 (en) * | 2020-06-23 | 2021-12-30 | Unilever Ip Holdings B.V. | Laundry composition |
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| CN106811330B (en) | 2019-07-09 |
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