CN105754741A - Dry cleaning agent for stubborn stains and preparation method of dry cleaning agent - Google Patents
Dry cleaning agent for stubborn stains and preparation method of dry cleaning agent Download PDFInfo
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- CN105754741A CN105754741A CN201610181497.0A CN201610181497A CN105754741A CN 105754741 A CN105754741 A CN 105754741A CN 201610181497 A CN201610181497 A CN 201610181497A CN 105754741 A CN105754741 A CN 105754741A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
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Abstract
The invention belongs to the technical field of daily chemical products and particularly relates to a dry cleaning agent for stubborn stains and a preparation method of the dry cleaning agent. The dry cleaning agent comprises the following raw materials: 70% AES, isomeric alcohol ethoxylates, a non-ionic polyether modified trisiloxane surfactant, 3-methoxy-3-methyl-1-butanol, a chelating agent, citric acid, a preservative, essence and deionized water. The dry cleaning agent is convenient and fast to use and environment-friendly, and has the advantages that the stain removal effect is good and no trace is left after the dry cleaning agent is used.
Description
Technical field
The invention belongs to cosmetics of everyday use technical field, more particularly it relates to stain dry cleaning agent and preparation thereof
Method.
Background technology
With the quickening pace of modern life, conveniently become city Man's Demands with life style efficiently, naturally, obstinate dirty
Stain dry cleaning agent has also become the first-selection that people live.Fabric is washed with Organic chemical solvents, goes oil removing by dry cleaning fabric exactly
The mode of washing of a kind of dry-in dry-out of dirt or spot, saves cleaning time and the energy.The main feature of dry-cleaning is avoided exactly
Fabric is damaged by washing, shrink-proof, indeformable, color and luster protectiveness is good, does not easily cause fabric fading, soft, it is simple to
Flatiron also can thoroughly clean the greasy dirt on fabric or spot.
The most widely used dry cleaning agent includes following four classes: petroleum solvent dry cleaning agent, tetrachloroethylene dry-cleaning agent, freon
Solvent dry cleaning agent and liquid carbon dioxide dry cleaning agent.Although the stain dry cleaning agent of prior art has stronger decontamination energy
Power, but it uses the hazardous solvent such as tetrachloro-ethylene, acetone, but serious environmental pollution and the harm to health can be caused.
For the defect overcoming prior art to exist, await exploitation a kind of more environmentally-friendly, dirt-removing power is strong, volatile and
The stain dry cleaning agent left no trace.
Summary of the invention
It is an object of the invention to overcome deficiency of the prior art, it is provided that stain dry cleaning agent and preparation method thereof.This
The stain dry cleaning agent of invention has convenient, fast and environmental protection, have clean effect good and with after the advantage that leaves no trace.
In order to realize foregoing invention purpose, this invention takes techniques below scheme:
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% sodium sulfate of polyethenoxy ether of fatty alcohol 12-30
Isomeric alcohol polyethenoxy ether 10-35
Nonionic polyether modification trisiloxane surfactant 30-45
MMB 5-10
Chelating agent 1-6
Citric acid 0.5-2
Preservative 0.5-1
Essence 0.1-0.8
Deionized water 40-55；
Wherein, described 70% sodium sulfate of polyethenoxy ether of fatty alcohol molecular formula is R (CH2CH2O)3OSO3Na, R are C12-C15；Institute
Stating isomeric alcohol polyethenoxy ether is to be carried out polymerisation by the isomery alcohol of C8-C12 and oxirane to prepare；Described nonionic gathers
Ether modification trisiloxane surfactant is by allyl alcohol polyoxy alkane hydroxy ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane
For raw material, prepared by solvent-free polymeric.
In one embodiment, described isomery alcohol is isomery alcohol or the isomery alcohol of C9 of C8.
In one embodiment, in described allyl alcohol polyoxy alkane hydroxy ether, containing 7-8 oxirane in polyether segment
Group.
In one embodiment, the average relative molecular mass of described allyl alcohol polyoxy alkane hydroxy ether is 350-400.
In one embodiment, the average relative molecular mass of described allyl alcohol polyoxy alkane hydroxy ether is 380.
In one embodiment, described chelating agent is sodium citrate, polyacrylate, ethylenediamine tetra-acetic acid, ethylenediamine
One in tetraacethyl sodium salt, ethylenediamine tetrapropionic acid, ethylenediamine tetrapropionic acid sodium salt, nitrilotriacetic acid or nitrilotriacetic acid sodium salt or
Multiple it is used in mixed way.
In one embodiment, described preservative is OIT.
Further object is that the method that stain dry cleaning agent is prepared in offer, comprise the following steps:
According to described weight portion meter, the 25-35% of deionized water total amount is poured in material still, is heated to 60-80 DEG C, then limit
Stirring limit is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, modified three silicon of nonionic polyether
Oxygen alkane surfactant, MMB, chelating agent, after stirring, add remaining deionized water, treat
After material all dissolves, cooling, add preservative, essence and stir, being 7.0-7.5 with lemon acid for adjusting pH value, mistake
Filter, to obtain final product.
In one embodiment, described cooling refers to be cooled to 25-40 DEG C.
In one embodiment, the described filtration mesh number used that filters is 100-200 mesh.
It is more readily understood the above-mentioned of the application and other features, aspect and advantage with reference to described further below.
Detailed description of the invention
Unless otherwise defined, all technology used herein and scientific terminology have skill common with art of the present invention
The identical implication that art personnel are generally understood that.When there is contradiction, it is as the criterion with the definition in this specification.
Term as used herein " by ... preparation " and " comprising " synonym.Term used herein " comprises ", " including ",
" have ", " containing " or its other deformation any, it is intended that cover the including of non-exclusionism.Such as, the combination of listed elements is comprised
Thing, step, method, goods or device are not necessarily solely those key elements, but can include other not expressly listed key element or
The key element that this kind of composition, step, method, goods or device are intrinsic.
Conjunction " Consists of " gets rid of any key element, step or component do not pointed out.If in claim, this
Phrase will make claim be closed so that it is does not comprise the material in addition to the material that those describe, but relative often
Except rule impurity.When being rather than immediately following during phrase " Consists of " occurs in the clause of claim main body after theme,
It is only limited to the key element described in this clause；Other key element is not excluded outside as overall described claim.
Equivalent, concentration or other value or parameter are excellent with scope, preferred scope or a series of upper limit preferred value and lower limit
During the Range Representation that choosing value limits, this is appreciated that and specifically discloses by any range limit or preferred value and any scope
All scopes that arbitrary pairing of lower limit or preferred value is formed, regardless of whether whether this scope separately discloses.Such as, when open
During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1-2 ", " 1-2 and 4-5 ",
" 1-3 and 5 " etc..When number range is described in this article, unless otherwise indicated, otherwise this scope be intended to include its end value and
All integers within the range and mark.
Additionally, indefinite article " a kind of " before key element of the present invention or component and " one " are to key element or the quantitative requirement of component
(i.e. occurrence number) unrestriction.Therefore " one " or " a kind of " should be read as including one or at least one, and odd number
The key element of form or component also include plural form, unless described quantity substantially refers to singulative.
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% sodium sulfate of polyethenoxy ether of fatty alcohol 12-30
Isomeric alcohol polyethenoxy ether 10-35
Nonionic polyether modification trisiloxane surfactant 30-45
MMB 5-10
Chelating agent 1-6
Citric acid 0.5-2
Preservative 0.5-1
Essence 0.1-0.8
Deionized water 40-55；
Wherein, described 70% sodium sulfate of polyethenoxy ether of fatty alcohol molecular formula is R (CH2CH2O)3OSO3Na, R are C12-C15；Institute
Stating isomeric alcohol polyethenoxy ether is to be carried out polymerisation by the isomery alcohol of C8-C12 and oxirane to prepare；Described nonionic gathers
Ether modification trisiloxane surfactant is by allyl alcohol polyoxy alkane hydroxy ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane
For raw material, prepared by solvent-free polymeric.
The molecular formula of term of the present invention " 70% sodium sulfate of polyethenoxy ether of fatty alcohol " is R (CH2CH2O)3OSO3Na, R
For C12-C15, mass concentration is 70%.Described 70% sodium sulfate of polyethenoxy ether of fatty alcohol is hard water resistance property preferable anion table
Face activating agent, has good dirt-removing power to solids foul, and excitant is less, and biological degradability is good.
Term of the present invention " isomeric alcohol polyethenoxy ether " is the nonionic generated by isomery alcohol and reacting ethylene oxide
Surfactant.The hydrophobic group of described isomeric alcohol polyethenoxy ether contains side chain, and compared with the alcohol ether of carbon chain lengths, and its solution
It is not easily formed micella, there is preferable wetability, water-soluble dispersiveness and stability of solution and preferable dirt-removing power, with other
Each anionoid, nonionic, cationic surfactant are compounding to be used, and has good cooperative effect.In one preferably
In embodiment, described isomery alcohol is isomery alcohol or the isomery alcohol of C9 of C8.
Term of the present invention " nonionic polyether modification trisiloxane surfactant " is by oxirane, allyl alcohol
Polyoxy alkane hydroxy ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane is raw material, by solvent-free polymeric, under nitrogen protection
It is prepared through Karstedt catalyzing addition reaction of silicon with hydrogen.Described nonionic polyether modification trisiloxane surfactant is permissible
The surface tension making water is down to about 25mN/m, and this is owing to the efficient surfactant of this collateralization enters after the aqueous solution,
Being arranged in " umbrella shape " structure distribution on interface with intensive methyl, beneficially complete wetting and sprawling, this is it is avoided that in dry-cleaning
Agent prescription system adds the ethers such as dipropylene come solubilized and improve surface spreading ability.Modified at nonionic polyether
In trisiloxane surfactant, the flexible frame that its Si-O-Si main chain simply depends on simply as a methyl, Si-O-
Si chain is flexible very well, promotes to define the close-packed arrays of methyl in air liquid interface, between the tightly packed and siloxanes of this methyl
Trisiloxane surfactant solution is made to have relatively low surface tension in relatively low adhesion.Therefore, described nonionic gathers
Ether modification trisiloxane surfactant relative to other modified siloxane surfactant have the strongest solubilising, sprawl,
Penetrating power.The preparation method of described nonionic polyether modification trisiloxane surfactant: with by the allyl alcohol of 10.5mol
The Karstedt catalyst of polyoxy alkane hydroxy ether and 0.02mol is equipped with the reaction there-necked flask of reflux condensing tube, stirrer
In, present 80 DEG C mix 30min with stirring under the protection of nitrogen, make activation of catalyst, be sufficiently formed alkene-metal complex,
Then, temperature being increased to 110 DEG C, start slowly to drip 1,1,1,3,5,5,5-heptamethyltrisiloxane 30min, question response is tied
After bundle, decompression removes unreacted 1,1,1,3,5,5,5-heptamethyltrisiloxane and other low-boiling-point substances, to obtain final product.
In one embodiment, in described allyl alcohol polyoxy alkane hydroxy ether, containing 7-8 oxirane in polyether segment
Group.
In one embodiment, the average relative molecular mass of described allyl alcohol polyoxy alkane hydroxy ether is 350-400.
In one embodiment, the average relative molecular mass of described allyl alcohol polyoxy alkane hydroxy ether is 380.
In one embodiment, described chelating agent is sodium citrate, polyacrylate, ethylenediamine tetra-acetic acid, ethylenediamine
One in tetraacethyl sodium salt, ethylenediamine tetrapropionic acid, ethylenediamine tetrapropionic acid sodium salt, nitrilotriacetic acid or nitrilotriacetic acid sodium salt or
Multiple it is used in mixed way.
In one embodiment, described preservative is OIT.The dry cleaning agent product of the present invention can suppress
Growth of microorganism, prevents corruption.
" essence " of the present invention be the industry frequently with essence.In formula, can freely select as required
Select corresponding essence.
Further object is that the method that stain dry cleaning agent is prepared in offer, comprise the following steps:
According to described weight portion meter, the 25-35% of deionized water total amount is poured in material still, is heated to 60-80 DEG C, then limit
Stirring limit is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, modified three silicon of nonionic polyether
Oxygen alkane surfactant, MMB, chelating agent, after stirring, add remaining deionized water, treat
After material all dissolves, cooling, add preservative, essence and stir, being 7.0-7.5 with citric acid regulation pH value, mistake
Filter, to obtain final product.
In one embodiment, described cooling refers to be cooled to 25-40 DEG C.
In one embodiment, the described filtration mesh number used that filters is 100-200 mesh.
Embodiment:
Embodiment 1, a kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% sodium sulfate of polyethenoxy ether of fatty alcohol 12-30
Isomeric alcohol polyethenoxy ether 10-35
Nonionic polyether modification trisiloxane surfactant 30-45
MMB 5-10
Chelating agent 1-6
Citric acid 0.5-2
Preservative 0.5-1
Essence 0.1-0.8
Deionized water 40-55；
Wherein, described 70% sodium sulfate of polyethenoxy ether of fatty alcohol molecular formula is R (CH2CH2O)3OSO3Na, R are C12-C15；Institute
Stating isomeric alcohol polyethenoxy ether is to be carried out polymerisation by the isomery alcohol of C8-C12 and oxirane to prepare；Described nonionic gathers
Ether modification trisiloxane surfactant is by allyl alcohol polyoxy alkane hydroxy ether and 1,1,1,3,5,5,5-heptamethyltrisiloxane
For raw material, prepared by solvent-free polymeric.
Embodiment 2, identical with embodiment 1, different places is, described isomery alcohol is the different of the isomery alcohol of C8 or C9
Structure alcohol.
Embodiment 3, identical with embodiment 1, different places is, in described allyl alcohol polyoxy alkane hydroxy ether, polyethers
Containing 7-8 ethylene oxide group in segment.
Embodiment 4, identical with embodiment 1, different places is, the average phase of described allyl alcohol polyoxy alkane hydroxy ether
It is 350-400 to molecular weight.
Embodiment 5, identical with embodiment 4, different places is, the average phase of described allyl alcohol polyoxy alkane hydroxy ether
It is 380 to molecular weight.
Embodiment 6, identical with embodiment 1, different places is, described chelating agent is sodium citrate, polyacrylic acid
Salt, ethylenediamine tetra-acetic acid, disodium edta, ethylenediamine tetrapropionic acid, ethylenediamine tetrapropionic acid sodium salt, nitrilotriacetic acid or nitrogen
One or more in the triacetic acid sodium salt of river are used in mixed way.
Embodiment 7, identical with embodiment 1, different places is, described preservative is OIT.
Embodiment 8, it is provided that the method preparing stain dry cleaning agent, comprises the following steps:
According to described weight portion meter, the 25-35% of deionized water total amount is poured in material still, is heated to 60-80 DEG C, then limit
Stirring limit is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, modified three silicon of nonionic polyether
Oxygen alkane surfactant, MMB, chelating agent, after stirring, add remaining deionized water, treat
After material all dissolves, cooling, add preservative, essence and stir, being 7.0-7.5 with lemon acid for adjusting pH value, mistake
Filter, to obtain final product.
Embodiment 9, identical with embodiment 8, different places is, described cooling refers to be cooled to 25-40 DEG C.
Embodiment 10, identical with embodiment 8, different places is, the described filtration mesh number used that filters is
100-200 mesh.
Below by embodiment, the present invention is specifically described.Be necessary it is pointed out here that, following example are served only for right
The present invention is described further, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field according to
Some nonessential improvement and adjustment that the content of foregoing invention is made, still fall within protection scope of the present invention.
It addition, illustrate without other, raw materials used is all commercially available.
Embodiment 1
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 30 parts, MMB 10 parts, sodium citrate 5 parts, OIT 1
Part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, after stirring, add remaining deionized water, treat material
After all dissolving, it is cooled to 35 DEG C, adds OIT, essence and stir, be 7.0 with lemon acid for adjusting pH value,
By the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 2
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 35 parts, MMB 10 parts, sodium citrate 5 parts, OIT 1
Part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, after stirring, add remaining deionized water, treat material
After all dissolving, it is cooled to 35 DEG C, adds OIT, essence and stir, be 7.0 with lemon acid for adjusting pH value,
By the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 3
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 38 parts, MMB 10 parts, sodium citrate 5 parts, OIT 1
Part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, after stirring, add remaining deionized water, treat material
After all dissolving, it is cooled to 35 DEG C, adds OIT, essence and stir, be 7.0 with lemon acid for adjusting pH value,
By the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 4
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 40 parts, MMB 10 parts, sodium citrate 5 parts, OIT 1
Part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, after stirring, add remaining deionized water, treat material
After all dissolving, it is cooled to 35 DEG C, adds OIT, essence and stir, be 7.0 with lemon acid for adjusting pH value,
By the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 5
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 45 parts, MMB 10 parts, sodium citrate 5 parts, OIT 1
Part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, after stirring, add remaining deionized water, treat material
After all dissolving, it is cooled to 35 DEG C, adds OIT, essence and stir, be 7.0 with lemon acid for adjusting pH value,
By the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 6
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 12 parts, the isomeric alcohol polyethenoxy ether 30 parts of C9, nonionic polyether change
Property trisiloxane surfactant 30 parts, MMB 10 parts, sodium citrate 3 parts, polyacrylate 3
Part, OIT 1 part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 7
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 25 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8, nonionic polyether change
Property trisiloxane surfactant 35 parts, MMB 10 parts, sodium citrate 3 parts, polyacrylate 3
Part, OIT 1 part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 8
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 25 parts, the isomeric alcohol polyethenoxy ether 30 parts of C9, nonionic polyether change
Property trisiloxane surfactant 35 parts, MMB 10 parts, sodium citrate 3 parts, polyacrylate 3
Part, OIT 1 part, 0.5 part of essence and deionized water 50 parts；
According to described weight portion meter, pour into the 30% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 9
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 30 parts, the isomeric alcohol polyethenoxy ether 35 parts of C9, nonionic polyether change
Property trisiloxane surfactant 40 parts, MMB 10 parts, sodium citrate 3 parts, polyacrylate 3
Part, OIT 1 part, 0.5 part of essence and deionized water 50 parts；
According to described weight portion meter, pour into the 30% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 10
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 30 parts, the isomeric alcohol polyethenoxy ether 35 parts of C8, nonionic polyether change
Property trisiloxane surfactant 42 parts, MMB 10 parts, sodium citrate 3 parts, polyacrylate 3
Part, OIT 1 part, 0.5 part of essence and deionized water 50 parts；
According to described weight portion meter, pour into the 30% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 200 mesh, to obtain final product.
Embodiment 11
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 30 parts, the isomeric alcohol polyethenoxy ether 35 parts of C8, nonionic polyether change
Property trisiloxane surfactant 45 parts, MMB 10 parts, sodium citrate 2 parts, polyacrylate 4
Part, OIT 1 part, 0.5 part of essence and deionized water 50 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 150 mesh, to obtain final product.
Embodiment 12
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 30 parts, the isomeric alcohol polyethenoxy ether 35 parts of C8, nonionic polyether change
Property trisiloxane surfactant 38 parts, MMB 10 parts, sodium citrate 2 parts, polyacrylate 4
Part, OIT 1 part, 0.5 part of essence and deionized water 55 parts；
According to described weight portion meter, pour into the 35% of deionized water total amount in material still, be heated to 75 DEG C, the most while stirring
It is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, nonionic polyether modification trisiloxanes table
Face activating agent, MMB, sodium citrate, polyacrylate, after stirring, add remaining go from
Sub-water, after material all dissolves, is cooled to 35 DEG C, adds OIT, essence and stir, regulating with citric acid
PH value is 7.0, by the filter screen filtration of 150 mesh, to obtain final product.
Comparative example 1
A kind of stain dry cleaning agent, described dry cleaning agent includes the component of following weight portion:
70% CH3(CH2)11(CH2CH2O)3OSO3Na 28 parts, the isomeric alcohol polyethenoxy ether 30 parts of C8,3-methoxyl group-3-first
Base-n-butyl alcohol 10 parts, sodium citrate 5 parts, OIT 1 part, 0.5 part of essence and deionized water 45 parts；
According to described weight portion meter, the 25-35% of deionized water total amount is poured in material still, be heated to 75 DEG C, then limit stirring
While be sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, MMB,
Chelating agent, after stirring, adds remaining deionized water, after material all dissolves, is cooled to 35 DEG C, adds isothiazole
Quinoline ketone, essence also stir, and are 7.0 with lemon acid for adjusting pH value, by the filter screen filtration of 200 mesh, to obtain final product.
Method of testing:
(1) shrink contrast test
Use the wool shrink sample cloth 300*300mm size dimension that GB MLBT4288-2008 requires as test sample cloth, soak
30min in the beaker fill solvent, described solvent is uninterruptedly to stir with glass bar, complete after dry at a temperature of 60 DEG C,
Measure deformation size.
(2) detergency test
Take cotton that GB MLBT4288-2008 requires as spot cloth substrate, coat soy sauce spot on its surface, treat that it is dried
After be used for testing, be cut into the spot cloth of 120*120mm size.
Make the keg of 2 liter capacity sizes, keg is fixed on the equipment that similar cylinder rotates, simulates drum wash side
Formula carries out detergency ability test, takes the soiled cotton of 1 piece of 120*120mm size, DC naphtha 1kg, and normal temperature washs, and wash time is
30min, after take out spot cloth, naturally dry, test spot cloth whiteness.
(3) anti-colour contamination test
Making the keg of 2 liter capacity sizes, be fixed on by keg on the equipment that similar cylinder rotates, simulation drum wash mode is entered
Row chromatic value is tested, and respectively takes the red byssus of 4 pieces of 120*120mm sizes, DC naphtha 1kg, and normal temperature washs, and wash time is
30min, after take out cotton, naturally dry.
Common silk cotton cloth and common white cotton read value before washing and, as standard value, after simulation dry cleaning processes terminates, read respectively
Take the chromatic value of red cloth and calico.Colour fixation washed by measurement after red cloth and do not wash the color distinction of red cloth, i.e. Δ E carrys out table
Showing, aberration is the biggest, illustrates that painting cloth fades the most serious, the fixation of dry cleaning agent and the weak effect of anti-colour contamination, the most then colour fixation.
Dye transfer inhibition effect is then the value of chromatism of calico after use is washed, and the lowest dyestuff showing to transfer on calico of Δ E value is the least, anti-
Dyestuff transfer effect is the most obvious.
On embodiment 1-12 and comparative example 1, commercially available prod (tetrachloro-ethylene) and water being carried out according to above-mentioned method of testing
The performance test stated.Test result is shown in Table 1.
The performance test results of table 1 stain dry cleaning agent
Aforesaid example is merely illustrative, for explaining some features of inventive feature.Appended claim is intended to
Require the widest scope that it is contemplated that, and embodiments as presented herein is only the group according to all possible embodiment
The explanation of the embodiment of the selection closed.Therefore, the purpose of applicant is that appended claim is not by the spy of the explanation present invention
The selectional restriction of the example levied.And the progress in science and technology will be formed due to language performance inaccurate reason and not by mesh
Possible equivalent or the son of front consideration are replaced, and these changes also should be interpreted in the conceived case by appended right
Require to cover.
Claims (10)
1. stain dry cleaning agent, it is characterised in that described dry cleaning agent includes the component of following weight portion:
70% sodium sulfate of polyethenoxy ether of fatty alcohol 12-30
Isomeric alcohol polyethenoxy ether 10-35
Nonionic polyether modification trisiloxane surfactant 30-45
MMB 5-10
Chelating agent 1-6
Citric acid 0.5-2
Preservative 0.5-1
Essence 0.1-0.8
Deionized water 40-55；
Wherein, described 70% sodium sulfate of polyethenoxy ether of fatty alcohol molecular formula is R (CH2CH2O)3OSO3Na, R are C12-C15；Described
Isomeric alcohol polyethenoxy ether is to be carried out polymerisation by the isomery alcohol of C8-C12 and oxirane to prepare；Described nonionic polyether
Modified trisiloxane surfactant is that 1,1,3,5,5,5-heptamethyltrisiloxane is by allyl alcohol polyoxy alkane hydroxy ether and 1
Raw material, is prepared by solvent-free polymeric.
Stain dry cleaning agent the most according to claim 1, it is characterised in that described isomery alcohol is isomery alcohol or the C9 of C8
Isomery alcohol.
Stain dry cleaning agent the most according to claim 1, it is characterised in that in described allyl alcohol polyoxy alkane hydroxy ether,
Containing 7-8 ethylene oxide group in polyether segment.
Stain dry cleaning agent the most according to claim 1, it is characterised in that putting down of described allyl alcohol polyoxy alkane hydroxy ether
All relative molecular weights are 350-400.
Stain dry cleaning agent the most according to claim 4, it is characterised in that putting down of described allyl alcohol polyoxy alkane hydroxy ether
All relative molecular weights are 380.
Stain dry cleaning agent the most according to claim 1, it is characterised in that described chelating agent be sodium citrate, poly-third
Olefin(e) acid salt, ethylenediamine tetra-acetic acid, disodium edta, ethylenediamine tetrapropionic acid, ethylenediamine tetrapropionic acid sodium salt, nitrilotriacetic acid
Or one or more in nitrilotriacetic acid sodium salt are used in mixed way.
Stain dry cleaning agent the most according to claim 1, it is characterised in that described preservative is OIT.
8. the method preparing stain dry cleaning agent as claimed in claim 1, it is characterised in that comprise the following steps:
According to described weight portion meter, the 25-35% of deionized water total amount is poured in material still, is heated to 60-80 DEG C, then limit
Stirring limit is sequentially added into 70% sodium sulfate of polyethenoxy ether of fatty alcohol, isomeric alcohol polyethenoxy ether, modified three silicon of nonionic polyether
Oxygen alkane surfactant, MMB, chelating agent, after stirring, add remaining deionized water, treat
After material all dissolves, cooling, add preservative, essence and stir, being 7.0-7.5 with lemon acid for adjusting pH value, mistake
Filter, to obtain final product.
The preparation method of stain dry cleaning agent the most according to claim 8, it is characterised in that described cooling refers to be cooled to
25-40℃。
The preparation method of stain dry cleaning agent the most according to claim 9, it is characterised in that the mistake that described filtration uses
The mesh number of filter screen is 100-200 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610181497.0A CN105754741A (en) | 2016-03-28 | 2016-03-28 | Dry cleaning agent for stubborn stains and preparation method of dry cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610181497.0A CN105754741A (en) | 2016-03-28 | 2016-03-28 | Dry cleaning agent for stubborn stains and preparation method of dry cleaning agent |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679772A (en) * | 2019-02-19 | 2019-04-26 | 上海皇宇科技发展有限公司 | A kind of silk dry cleaning agent |
| CN109705989A (en) * | 2019-02-22 | 2019-05-03 | 上海皇宇科技发展有限公司 | A kind of fabrics dry cleaning agent |
| JP2019081865A (en) * | 2017-10-31 | 2019-05-30 | ライオン株式会社 | Liquid detergent composition |
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| CN101514311A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Dry cleaning agent for clothes and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101514311A (en) * | 2008-12-31 | 2009-08-26 | 北京绿伞化学股份有限公司 | Dry cleaning agent for clothes and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019081865A (en) * | 2017-10-31 | 2019-05-30 | ライオン株式会社 | Liquid detergent composition |
| JP7063576B2 (en) | 2017-10-31 | 2022-05-09 | ライオン株式会社 | Liquid detergent composition for textile products |
| CN109679772A (en) * | 2019-02-19 | 2019-04-26 | 上海皇宇科技发展有限公司 | A kind of silk dry cleaning agent |
| CN109705989A (en) * | 2019-02-22 | 2019-05-03 | 上海皇宇科技发展有限公司 | A kind of fabrics dry cleaning agent |
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Application publication date: 20160713 |