CN105132199A - Surfactant composition for buildings, petroleum, cosmetics, textile and daily products - Google Patents
Surfactant composition for buildings, petroleum, cosmetics, textile and daily products Download PDFInfo
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- CN105132199A CN105132199A CN201510442544.8A CN201510442544A CN105132199A CN 105132199 A CN105132199 A CN 105132199A CN 201510442544 A CN201510442544 A CN 201510442544A CN 105132199 A CN105132199 A CN 105132199A
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Abstract
The invention relates to a surfactant composition for buildings, petroleum, cosmetics, textile and daily products, which comprises following raw materials, by weight, 2-6% of coconut diethanolamide, 3-5% of sodium lauryl polyoxy ethylene ether sulfate, 3-5% of nonyl phenol polyoxy ethylene ether, 0.5-1% of a dispersing agent, 3-6% of polyol, 0.5-2% of potassium pyrophosphate, 0.5-2% of sodium silicate, 0.1-0.5% of sodium polyacrylate and 0.1-0.5% of sodium carboxymethylcellulose. The surfactant composition includes various surfactants which are cooperated with each other, so that the surfactant composition can be used for cleaning various stains, has a good cleaning effect and a strong cleaning capability, is free of environment pollution and is safe and reliable to use.
Description
Technical field
The present invention relates to a kind of surfactant composition, in particular to one be used for building, oil, makeup,
Weaving and daily surfactant composition.
Background technology
In building coating, tensio-active agent mainly plays wetting, emulsification, dispersion, stable and anti-static electrification.As being used as the anion active agent such as methylene-bis bitter edible plant sodium sulfonate, polyacrylate of dispersion agent, the interfacial tension in emulsifying system can be reduced, stop flocculation, smash micelle, improve the opacifying power of coating, mobility and levelling property, reduce the grow diming phenomenon of coating and the sedimentation phenomenon etc. of pigment simultaneously.
The application of anion surfactant in makeup is got over extensive, and its Main Function makes emulsifying agent, solubilizing agent, wetting agent and active principle synergistic agent.It is security in its pharmacology and toxicology that anion surfactant obtains in this field with the most important consideration of widespread use.
Petroleum industry is also widely using tensio-active agent.According to estimates, the anion surfactant for oil-field development accounts for 17% of industrial consumption.In drilling well, prepare drilling fluid with anion surfactant, can moistening, cooling drilling tool.
In textile and dyeing industry, many operations all need to use a large amount of tensio-active agents.Such as, the abstergent anion surfactant of a large amount of tools can be used in pretreatment process, chemosmotic anion surfactant can be used in dyeing with Final finishing process.In addition, some functional products are as levelling agent, laking agent etc., and certain structures is also anionic type.
Clean-out system specificity on sale is at present stronger, for the real needs in daily life, often needs to prepare multiple clean-out system, as collar cleaner, washing composition etc.Mostly be metallic surface, comparatively outstanding to the cleanup action of paint, iron rust etc. in existing multifuctional cleaning agent, be applied to the spot removed in daily life, if effectively remove protein stain simultaneously, the multifuctional cleaning agent of the spots such as starch spot, carbon black spot, greasy dirt, sebum spot is comparatively rare.Also there are some multifuctional cleaning agents to be reach the effect of cleaning multiple spot, containing a large amount of organic solvents, are unfavorable for HUMAN HEALTH, great pollution is caused to environment.
Summary of the invention
The invention provides for building, oil, makeup, weaving and daily surfactant composition, can be used for cleaning protein stain, starch spot, carbon black spot, greasy dirt stain and sebum spot, can be used for cleaning fabric, floor, ceramic tile, bathtub and various home articles surface, cleaning performance is good, soil removability is strong, free from environmental pollution, safe and reliable.
Concrete, the present invention relates to and can be used for building, oil, makeup, weaving and daily surfactant composition, it is characterized in that, comprise tensio-active agent, dispersion agent, polyvalent alcohol, sequestrant, potassium pyrophosphate, potassium silicate, sodium sulfate, sodium polyacrylate, Xylo-Mucine.
In the embodiment that the present invention one is concrete, described can be used for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2-6%, alkylpolyoxyethylene sodium sulfate 3-5%, polyoxyethylene nonylphenol ether 3-5%, dispersion agent 0.5-1%, polyvalent alcohol 3-6%, sequestrant
0.5-1%, potassium pyrophosphate 0.5-2%, water glass 0.5-2%, sodium sulfate 0.5-2%, sodium polyacrylate 0.1-0.5%, Xylo-Mucine 0.1-0.5%.
Preferably, in the present invention, the molecular weight of sodium polyacrylate is between 1000-3000 (weight-average molecular weight is also matter average molecular weight).
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily
Surfactant composition, wherein polyvalent alcohol is glycerine or ethylene glycol.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily
Surfactant composition, wherein dispersion agent is Macrogol 200.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily
Surfactant composition, wherein sequestrant is EDTA.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily
Surfactant composition, also containing essence, pigment.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2-6%, alkylpolyoxyethylene sodium sulfate 3-5%, polyoxyethylene nonylphenol ether 3-5%, Macrogol 2000 .5-1%, glycerine 3-6%, EDTA
0.5-1%, potassium pyrophosphate 0.5-2%, water glass 0.5-2%, sodium sulfate 0.5-2%, sodium polyacrylate 0.1-0.5%, Xylo-Mucine 0.1-0.5%, surplus is deionized water.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 3%, polyoxyethylene nonylphenol ether 3%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5% is burnt
Potassiumphosphate 0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 6%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 5%, Macrogol 200 1%, glycerine 6%, EDTA1%, tetra-sodium
Potassium 2%, water glass 2%, sodium sulfate 2%, sodium polyacrylate 0.3%, Xylo-Mucine 0.5%, surplus is deionized water.
In the embodiment that the present invention one is concrete, described for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 3%, Macrogol 200 1%, glycerine 3%, EDTA1%, tetra-sodium
Potassium 0.5%, water glass 2%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.3%, surplus is deionized water.
Of the present inventionly can be used for building, oil, makeup, weaving and daily surfactant composition, conventionally can prepare, such as, comprise the steps:
(1) lauric acid amide of ethanol is taken by weight percentage, alkylpolyoxyethylene sodium sulfate, polyoxyethylene nonylphenol ether, polyoxyethylene glycol, glycerine, EDTA, potassium pyrophosphate, water glass, sodium sulfate, sodium polyacrylate, Xylo-Mucine, deionized water;
(2) get appropriate amount of deionized water, add in reaction vessel, open and stir, be warming up to 45-50 DEG C, add lauric acid amide of ethanol successively, alkylpolyoxyethylene sodium sulfate, polyoxyethylene nonylphenol ether, polyoxyethylene glycol, glycerine, EDTA, potassium pyrophosphate, water glass, sodium sulfate, sodium polyacrylate, Xylo-Mucine, is stirred to and dissolves completely;
(3) add essence, pigment, add deionized water to 100%.
Surfactant composition of the present invention has suitability widely, can be used for cleaning protein stain, starch spot, carbon black spot, greasy dirt stain and sebum spot, can be used for cleaning fabric, floor, ceramic tile, bathtub and various home articles, industrial machine surface, cleaning performance is good, and soil removability is strong, free from environmental pollution, safe and reliable, manufacture simple.
Embodiment
Embodiment 1:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 3%, polyoxyethylene nonylphenol ether 3%,
Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Embodiment 2:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 6%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 5%,
Macrogol 200 1%, glycerine 6%, EDTA1%, potassium pyrophosphate 2%, water glass 2%, sodium sulfate 2%, sodium polyacrylate 0.3%, Xylo-Mucine 0.5%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Embodiment 3:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 3%
Macrogol 200 1%, glycerine 3%, EDTA1%, potassium pyrophosphate 0.5%, water glass 2%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.3%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Embodiment 4:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 3%, alkylpolyoxyethylene sodium sulfate 4%, polyoxyethylene nonylphenol ether 4%, Macrogol 2000 .8%, glycerine 4%, EDTA0.8%, potassium pyrophosphate 1%, water glass 1%, sodium sulfate 1%, sodium polyacrylate 0.3%, Xylo-Mucine 0.3%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Embodiment 5:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 4%, alkylpolyoxyethylene sodium sulfate 3.5%, polyoxyethylene nonylphenol ether 4.5%, Macrogol 2000 .6%, glycerine 5%, EDTA0.9%, potassium pyrophosphate 1.5%, water glass 1.5%, sodium sulfate 1.5%, essence 0.02%, pigment 0.02%, sodium polyacrylate 0.3%, Xylo-Mucine 0.3%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Reference examples 1:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: alkylpolyoxyethylene sodium sulfate 4%, polyoxyethylene nonylphenol ether 4%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Reference examples 2:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 4%, polyoxyethylene nonylphenol ether 4%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Reference examples 3:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 4%, alkylpolyoxyethylene sodium sulfate 4%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Reference examples 4:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 3%, polyoxyethylene nonylphenol ether 3%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, water glass 0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Reference examples 5:
For building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 3%, polyoxyethylene nonylphenol ether 3%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water; The weight-average molecular weight of sodium polyacrylate is between 1000-3000.
Embodiment 6: surfactant composition measure of merit
The washing effect of the surfactant composition prepared in above-described embodiment 1-5 and reference examples 1-5 is tested based on GB GBT13174-2008.Using B value (whiteness maintenance ratio) as the evaluation index of washing effect.Test sample comprises JB-01 (carbon black greasy dirt cloth), JB-02 (albumen soiled cotton), JB-03 (sebum soiled cotton) and JB-05 (starch based soiled cotton).
Wash conditions: surfactant composition concentration 0.2%, wash temperature 30 DEG C, washing time 20min, water hardness 250mg/kg.Test result is in table 1.
Can be drawn by the test result in table 1, each component in tensio-active agent of the present invention is worked in coordination with mutually, surfactant composition of the present invention is made to have good cleaning performance to various spot, especially lauric acid amide of ethanol, alkylpolyoxyethylene sodium sulfate, polyoxyethylene nonylphenol ether, potassium pyrophosphate, sodium sulfate are indispensable components, and omit any one component in reference examples 1-5 cleaning performance all can be made significantly to decline.
The measure of merit result of table 1 surfactant composition of the present invention
Claims (10)
1., for building, oil, makeup, weaving and daily surfactant composition, it is characterized in that, comprise tensio-active agent, dispersion agent, polyvalent alcohol, sequestrant, potassium pyrophosphate, potassium silicate, sodium sulfate, sodium polyacrylate, Xylo-Mucine.
2. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2-6%, alkylpolyoxyethylene sodium sulfate 3-5%, polyoxyethylene nonylphenol ether 3-5%, dispersion agent 0.5-1%, polyvalent alcohol 3-6%, sequestrant 0.5-1%, potassium pyrophosphate 0.5-2%
Water glass 0.5-2%, sodium sulfate 0.5-2%, sodium polyacrylate 0.1-0.5%, Xylo-Mucine 0.1-0.5%.
3. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition,
Wherein polyvalent alcohol is glycerine or ethylene glycol.
4. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition,
Wherein dispersion agent is Macrogol 200.
5. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition,
Wherein sequestrant is EDTA.
6. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition,
Also containing essence, pigment.
7. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2-6%, alkylpolyoxyethylene sodium sulfate 3-5%, polyoxyethylene nonylphenol ether 3-5%, Macrogol 2000 .5-1%, glycerine 3-6%, EDTA0.5-1%, potassium pyrophosphate 0.5-2%
Water glass 0.5-2%, sodium sulfate 0.5-2%, sodium polyacrylate 0.1-0.5%, Xylo-Mucine 0.1-0.5%, surplus is deionized water.
8. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 3%, polyoxyethylene nonylphenol ether 3%, Macrogol 2000 .5%, glycerine 3%, EDTA0.5%, potassium pyrophosphate 0.5%, water glass
0.5%, sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.1%, surplus is deionized water.
9. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 6%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 5%, Macrogol 200 1%, glycerine 6%, EDTA1%, potassium pyrophosphate 2%, water glass 2%, sulphur
Acid sodium 2%, sodium polyacrylate 0.3%, Xylo-Mucine 0.5%, surplus is deionized water.
10. according to claim 1 for building, oil, makeup, weaving and daily surfactant composition, comprise the raw material of following weight percent: lauric acid amide of ethanol 2%, alkylpolyoxyethylene sodium sulfate 5%, polyoxyethylene nonylphenol ether 3%, Macrogol 200 1%, glycerine 3%, EDTA1%, potassium pyrophosphate 0.5%, water glass 2%
Sodium sulfate 0.5%, sodium polyacrylate 0.3%, Xylo-Mucine 0.3%, surplus is deionized water.
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| CN111356440A (en) * | 2017-11-30 | 2020-06-30 | 狮王株式会社 | Oral biofilm formation inhibitor and oral composition |
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Application publication date: 20151209 |