GB1603047A - Cleaners containing d-limonene - Google Patents

Cleaners containing d-limonene Download PDF

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Publication number
GB1603047A
GB1603047A GB1725078A GB1725078A GB1603047A GB 1603047 A GB1603047 A GB 1603047A GB 1725078 A GB1725078 A GB 1725078A GB 1725078 A GB1725078 A GB 1725078A GB 1603047 A GB1603047 A GB 1603047A
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Prior art keywords
limonene
parts
cleaner
surfactant
water
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Expired
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GB1725078A
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DOTOLO V
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DOTOLO V
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Publication of GB1603047A publication Critical patent/GB1603047A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0031—Carpet, upholstery, fur or leather cleansers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

(54) CLEANERS CONTAINING D-LIMONENE (71) I, VINCENT DOTOLO, a citizen of the United States of America, 1989 Bellair Road, Clearwater, Florida 33516, United States of America, do hereby declare the invention, for which I pray that a patent may be granted to me, and the method by which it is to be performed, to be particularly described in and by the following statement: BACKGROUND OF THE INVENTION This invention relates to cleaning compositions containing D-limonene which are useful as cleaners for hands, carpets, glass and other hard surfaces, office equipment, etc.
D-limonene is a water white to slightly yellow mono-cyclic terpene usually obtained as a by-product from the manufacture of citrus molasses. It is obtained by steam distillation of citrus peels and pulp resulting from the production of citrus juices and is referred to a stripper oil, which contains about 94-98% of the D-limonene.
BRIEF DESCRIPTION OF THE INVENTION It is an object of this invention to provide cleaning compositions comprising D-limonene.
It is another object of this invention to provide a hand cleaning composition comprising D-limonene in the gel or liquid state.
It is a further object of this invention to provide a cleaning composition comprising D-limonene as a concentrate to be diluted with water in use.
An additional object of this invention is to provide a cleaning composition containing D-limonene which is suitable for use on glass and hard surfaces.
Another object of this invention is to provide a cleaning composition containing D-limonene suitable for use as on office equipment.
Still a further object of this invention is to provide a cleaning composition containing D-limonene and an abrasive suitable for use as an oven cleaner or metal cleaner.
DETAILED DESCRIPTION OF THE INVENTION The invention is particularly concerned with the provision of a wide variety of cleaning compositions, generally all purpose, containing as their principal ingredient D-Limonene in an amount not less than 10% by volume. Depending upon the type of cleaning action desired from the cleaning compositions, the D-limonene is used as a cleaning solvent along with surfactants, emulsifiers, other solvents, abrasives and water.
Any suitable surface-active agents, i.e. emulsifiers and surfactants, can be used in the cleamng compositions which serve to emulsify with the D-limonene. A surfactant particularly suitable is octylphenyl polyethoxy ethanol, which surfactant is commercially available from the Rohm and Haas Company under the tradename, "TRITON X-100".
This surfactant is stated to contain 10 moles of ethylene oxide per molecule and to have a viscosity of 250 centipoises at 77 F. (Brookfield) and a specific gravity of about 1.065 at 77 F. A suitable emulsifier which can be used is commercially available from the Stepan Company under the trade name of "emulsifier WHC" and is a mixture comprising 20-40% mixed soap, 10-20% polyhydric alcohol, and 5-15% mixed fatty acids. Another suitable surfactant which can be used herein are surfactants commercially available from the GAF Corporation under the tradename of IGEPAL CO-630 which is a nonylphenoxypoly (ethyleneoxy)ethanol with 65% ethylene oxide and a molar ratio of 9 (i.e. the number of moles of ethylene oxide per mole of nonylphenol.
Although the above specific surfactants and emulsifiers have been set forth, it is understood that any suitable surfactant or emulsifier can be used, can be of the non-ionic, anionic, cationic or amphoteric type, and of natural or synthetic origin, with the only requirement being that fit is liquid as used herein and serves to emulsify with the D-limonene and any other components of the composition which require to be emulsified.
Another component suitable for use with the cleaning compositions, when used as cleaners for glass, hard surfaces, and office equipment, are water, miscible solvents along with the D-limonene. A suitable solvent which can be used is sold by the Du Pont Company under the trademark "FREON" TE solvent which is an azeotrope of ethyl alcohol in a saturated fluorocarbon solvent. Another suitable solvent is a chlorinated type solvent e.g.
1,1,1-trichloroethylene. Still other solvents can be used with the only requirement being that it be liquid, and that it be compatible with the other ingredients of the cleaning compositions.
An additional component of the cleaning compositions when used as e.g. oven or metal cleaners, is an abrasive. Suitable abrasives are diatomaceous earth, pumic. Other various well-known abrasives can also be used depending on the particular metal surface to be cleaned.
The various components of the cleaning compositions are to be used in various proportions depending on the use to be made of the specific cleaning composition. When used as a gel hand cleaner or lotion, the composition comprises 10-50% D-limonene, 3-18% surfactant or emulsifier and the remainder water by volume, preferably 35-37.5%, D-limonene, 13.5-15.5% surfactant or emulsifer, and the remainder water. When used as a carpet cleaner concentrate, the composition comprises about 50% D-limonene, 4-11% surfactant, preferably 8%, and the remainder water. When used as a glass or hard surface cleaner including a solvent, the composition comprises 10-50% D-limonene, 1-15% surfactant, 1-40% solvent and the remainder water by volume, preferably 42-45% D-limonene, 1-3% solvent, 3-11% surfactant and the remainder water.When used as an office equipment cleaner, the composition comprises 85-98% D-limonene and 2-15% solvent by volume. When used as an oven or metal cleaner including an abrasive, the composition comprises the hand cleaner of 10-50% D-limonene, 3-18% surfactant, and the remainder water. Generally, about 100 parts of the hand cleaner to 2-40 parts of abrasive, by volume is suitable, preferably 6-30 parts of the abrasive to about 100 parts of the hand cleaner.
The composition may be prepared in any suitable manner. Specifically, for the gel type hand cleaner, the composition is prepared by mixing and blending the D-limonene with water, and the subsequent addition of the surfactant with additional mixing until a gel is formed. When preparing the hand lotion, or carpet cleaner, the same procedure is followed but no gel is formed because the amount of surfactant added is insufficient to form a gel. In the preparation of the composition as a hard surface cleaner where an additional solvent is added, the same procedure is followed and the solvent is added after the mixing and blending of the components. Where an abrasive is included in the composition to be used as an oven or metal cleaner, the abrasive is added to the D-limonene and water prior to the addition of the surfactant.
The following Examples are set forth to further illustrate the present invention but are not intended to be limiting in any sense. The proportions of components are set forth in volume percentages.
EXAMPLE 1 - HAND CLEANER GEL Emulsifier WIIC 15% (Stepan Chemical Co.
Northfield, Illinois) D-limonene 35% Water remainder EXAMPLE 2 - HAND CLEANER GEL Emulsifier DOW 555 (Dow Chemical Co.) 14% D-limonene 36% Water remainder EXAMPLE 3 - HAND CLEANER GEL Emulsifier Triton X-100 15% (Ashland Chemical Co., Columbus Ohio) D-Limonene 37.5% Water remainder.
When using the gel cleaners of the above Examples to clean dirty hands, hard to remove hand soilers are easily removed, leave the hands soft, and leave a plesant citrus scent. The gel does not normally need water for removal from the hands, an can be wiped off with a towel.
EXAMPLE 4 -- HAND LOTION CLEANER Emulsifier WHC (Stepan Chemical Co.) 13% D-limonene 35% Water remainder EXAMPLE 5 - HAND LOTION CLEANER Emulsifier DOW 555 (Dow Chem. Co.) 10% D-limonene 36% Water remainder EXAMPLE 6 - HAND LOTION CLEANER Emulsifier TRITON X-100 11% D-limonene 35% Water remainder The hand lotion cleaner is a milder cleaner for the hands than the gel cleaner and can be used with or without water for rinsing.
EXAMPLE 7 -- CARPET CLEANER CONCENTRATE Emulsifier WHC 8% D-limonene 50% Water 42% EXAMPLE 8 -- CARPET CLEANER CONCENTRATE Emulsifier DOW 555 8% D-limonene 50% Water 42% EXAMPLE 9 -- CARPET CLEANER CONCENTRATE Emulsifier TRITON X-100 8% D-limonene 50% Water remainder EXAMPLE 9A - CARPET CLEANER CONCENTRATE Stepan WHC 6% Igepal CO-630 2% D-limonene 50% Water remainder EXAMPLE 9B -- CARPET CLEANER CONCENTRATE TRITON X-100 5% Igepal CO-630 3% D-limonene 50% Water remainder EXAMPLE 9C - CARPET CLEANER CONCENTRATE Stepan WHC 3% Igepal CO-630 5% D-limonene 50% Water remainder.
The concentrate is diluted by adding 1 part thereof to 25-50 parts of water, depending upon the cleaning equipment used. The concentrate itself is a good spot remover in carpets. The concentrate is also a good upholstery cleaner.
EXAMPLE 10 -- GLASS AND HARD SURFACE CLEANER Emulsifier WHC 6% FREON TE (Du Pont Chemicals) 2% D-limonene 43% Water remainder EXAMPLE 11 - GLASS AND HARD SURFACE CLEANER Emulsifier DOW 555 5% FREON TE 2% D-limonene 43% Water remainder EXAMPLE 12 - GLASS AND HARD SURFACE CLEANER Emulsifier TRITON X-100 4% FREON TE 3% D-limonene 44% Water remainder EXAMPLE 13 - GLASS AND HARD SURFACE CLEANER Emulsifier Igepol CO-630 5% TRITON X-100 2% FREON TE 2% D-limonene 43% Water remainder EXAMPLE 14 - GLASS AND HARD SURFACE CLEANER Trichlorethylene 4% Emulsifier IgeDol CO-630 5% TRITON X-100 2% D-limonene 43% Water remainder 2-6 parts concentrate per 100 parts of water makes an effective glass cleaner and 2-25 parts per 100 parts of water makes a good hard surface cleaner (tile, formica, porcelain, etc.).
EXAMPLE 15 - OFFICE EQUIPMENT CLEANER Solvent FREON TE 2% D-limonene 98% EXAMPLE 16 - OFFICE EQUIPMENT CLEANER Chlorinated solvent (Trichlorethylene) 3% D-limonene 97% EXAMPLE 17 -- OFFICE EQUIPMENT CLEANER Chlorinated solvent 1, 1, 1, 1% (Trichlorethylene - DOW Chemicals) D-limonene 99% EXAMPLE 18 - OFFICE EQUIPMENT CLEANER FREON TE 15% D-limonene 85% The above office equipment cleaner leaves a film residue which protects and lubricates the surface. The use of less D-limonene and more of the solvent, results in less film being left.
The greater the amount of D-limonene and less of solvent, the greater the amount of film left. The film acts as lubricant on the surface. The solvent can be increased from 3% to 25% to provide less lubricating film residue in office equipment cleaners.
The following Examples set forth the use of the cleaning compositions of the invention as oven and metal cleaners containing abrasives. The basic composition is the above set forth gel and lotion hand cleaners with the addition of an abrasive. Generally, 3-40 parts of abrasive is added to 100 parts of the basic hand cleaner composition by volume.In the following Examples the following basic composition is used: EXAMPLE 19 - (BASIC COMPOSITION) Emulsifier WlIC 15% D-limonene 35% Water remainder EXAMPLE 20 -- OVEN CLEANER 100 parts - Example 19 25 parts - diatomaceous earth EXAMPLE 21 - SILVER METAL CLEANER 100 parts - Example 19 3 parts - diatomaceous earth EXAMPLE 22 - BRASS METAL CLEANER 100 parts - Example 19 30 parts - diatomaceous earth EXAMPLE 23 - ALUMINUM METAL CLEANER 100 parts - Example 19 20 parts - diatomaceous earth EXAMPLE 24 -- STAINLESS STEEL CLEANER 100 parts - Example 19 15 parts - diamaceous earth The following Examples set forth hand cleaners which can be cleaned off after use by merely rinsing with water.The basic gel or lotion hand cleaners discussed above combine two surfactants. Generally the composition containing two surfactants comprises 10-50% D-limonene, 3-18% of the mixed surfactants and the remainder water. The mixed surfactants can comprise as one surfactant 1-5% Igepal CO-630 and as a second surfactant 2-13% of either Emulsifier WlIC or TRITON X-100. This type of composition can be made into a gel or lotion, and also as a carpet cleaner and as a cleaner containing an abrasive EXAMPLE 25 D-limonene 35% 2% Igepal CO-630 10% Emulsifier WHC 15% Water remainder EXAMPLE 26 D-limonene 36% 3% Igepal 13% 7% TR1TON X-100 13% Water remainder.
The above cleaning compositions containing D-limonene are bio-degradable, nonpollutant, and non-irritating to the skin. When used as a carpet cleaner it is bactericidal and fungicidal but not harmful to persons handling the composition.
The D-limonene used in the compositions herein should preferably contain a suitable commercially available stabiliser to retain its original state and prevent it from becoming rancid.
WHAT I CLAIM IS: 1. A cleaning composition comprising 10-50% D-limonene, 3-18% surfactant and the remainder water, by volume.
2. The cleaning composition of claim 1, wherein said D-limonene comprises 35-37.5%, and said surfactant comprises 13.5-15.5%.
3. The cleaning composition of claim 1, wherein said surfactant comprises a mixture of two surface active agents.
4. A cleaner concentrate comprising 50% D-limonene, 4-11% surfactant and the remainder water, by volume.
5. The cleaner concentrate of claim 4, wherein said surfactant comprises about 8%.
6. A cleaning composition comprising 10-50% D-limonene, 1-15% surfactant, 1-40% solvent and the remainder water, by volume.
7. The cleaning composition of claim 6, wherein said D-limonene comprises 42-45%, said solvent comprises 1-3%, and said surfactant comprises 3-11%.
8. A cleaning composition comprising 85-98% D-limonene and 2-15% solvent, by volume.
9. A cleaning composition comprising: A. 10-50% D-limonene, 3-18% surfactant, and the remainder water, by volume, and B. an abrasive, wherein said abrasive is present in a volume amount of 2-40 parts per 100 parts of A.
10. The cleaning composition of claim 9, wherein said abrasive comprises 6-30 parts per 100 parts of A.
11. A cleaning composition substantially as herein described with reference to the Examples.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (11)

  1. **WARNING** start of CLMS field may overlap end of DESC **.
    EXAMPLE 21 - SILVER METAL CLEANER 100 parts - Example 19
    3 parts - diatomaceous earth EXAMPLE 22 - BRASS METAL CLEANER 100 parts - Example 19
    30 parts - diatomaceous earth EXAMPLE 23 - ALUMINUM METAL CLEANER 100 parts - Example 19
    20 parts - diatomaceous earth EXAMPLE 24 -- STAINLESS STEEL CLEANER 100 parts - Example 19
    15 parts - diamaceous earth The following Examples set forth hand cleaners which can be cleaned off after use by merely rinsing with water. The basic gel or lotion hand cleaners discussed above combine two surfactants. Generally the composition containing two surfactants comprises 10-50% D-limonene, 3-18% of the mixed surfactants and the remainder water.The mixed surfactants can comprise as one surfactant 1-5% Igepal CO-630 and as a second surfactant 2-13% of either Emulsifier WlIC or TRITON X-100. This type of composition can be made into a gel or lotion, and also as a carpet cleaner and as a cleaner containing an abrasive EXAMPLE 25 D-limonene 35% 2% Igepal CO-630 10% Emulsifier WHC 15% Water remainder EXAMPLE 26 D-limonene 36% 3% Igepal 13% 7% TR1TON X-100 13% Water remainder.
    The above cleaning compositions containing D-limonene are bio-degradable, nonpollutant, and non-irritating to the skin. When used as a carpet cleaner it is bactericidal and fungicidal but not harmful to persons handling the composition.
    The D-limonene used in the compositions herein should preferably contain a suitable commercially available stabiliser to retain its original state and prevent it from becoming rancid.
    WHAT I CLAIM IS: 1. A cleaning composition comprising 10-50% D-limonene, 3-18% surfactant and the remainder water, by volume.
  2. 2. The cleaning composition of claim 1, wherein said D-limonene comprises 35-37.5%, and said surfactant comprises 13.5-15.5%.
  3. 3. The cleaning composition of claim 1, wherein said surfactant comprises a mixture of two surface active agents.
  4. 4. A cleaner concentrate comprising 50% D-limonene, 4-11% surfactant and the remainder water, by volume.
  5. 5. The cleaner concentrate of claim 4, wherein said surfactant comprises about 8%.
  6. 6. A cleaning composition comprising 10-50% D-limonene, 1-15% surfactant, 1-40% solvent and the remainder water, by volume.
  7. 7. The cleaning composition of claim 6, wherein said D-limonene comprises 42-45%, said solvent comprises 1-3%, and said surfactant comprises 3-11%.
  8. 8. A cleaning composition comprising 85-98% D-limonene and 2-15% solvent, by volume.
  9. 9. A cleaning composition comprising: A. 10-50% D-limonene, 3-18% surfactant, and the remainder water, by volume, and B. an abrasive, wherein said abrasive is present in a volume amount of 2-40 parts per 100 parts of A.
  10. 10. The cleaning composition of claim 9, wherein said abrasive comprises 6-30 parts per 100 parts of A.
  11. 11. A cleaning composition substantially as herein described with reference to the Examples.
GB1725078A 1977-07-05 1978-05-02 Cleaners containing d-limonene Expired GB1603047A (en)

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Cited By (45)

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Publication number Priority date Publication date Assignee Title
EP0080749A1 (en) * 1981-11-12 1983-06-08 THE PROCTER & GAMBLE COMPANY Liquid detergent compositions
US4414128A (en) 1981-06-08 1983-11-08 The Procter & Gamble Company Liquid detergent compositions
EP0106266A2 (en) * 1980-05-27 1984-04-25 The Procter & Gamble Company Terpene-solvent mixture useful for making liquid detergent compositions
DE3316988A1 (en) * 1983-05-10 1984-11-15 Jürgen 6926 Kirchardt Rohrmoser MEANS FOR CLEANING MACHINES AND DEVICES AND PARTS THEREOF
US4533487A (en) * 1983-08-15 1985-08-06 Pitre-Jones Process for producing blended d-Limonene and uses of the blended product
EP0157975A2 (en) * 1984-03-12 1985-10-16 Varn Products Company, Inc. Method for removing printing ink from printing press component parts and cleaning compositions therefor
US4561991A (en) * 1984-08-06 1985-12-31 The Procter & Gamble Company Fabric cleaning compositions for clay-based stains
EP0174711A1 (en) * 1984-08-28 1986-03-19 Varn Products Company, Inc. Biodegradable emulsion for removing printing ink from printing press component parts
US4620937A (en) * 1985-02-11 1986-11-04 Joseph Dellutri All purpose cleaner containing D-Limonene
WO1990015858A1 (en) * 1989-06-16 1990-12-27 Golden Technologies Company, Inc. Non-caustic oven cleaner, method for making and method of use
US5075026A (en) * 1986-05-21 1991-12-24 Colgate-Palmolive Company Microemulsion all purpose liquid cleaning composition
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WO2014096926A1 (en) 2012-12-21 2014-06-26 Floral Packaging Ip Holdings, Llc Method and system for removing ink from films
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JPS62165199A (en) * 1986-01-17 1987-07-21 東京電力株式会社 Radioactivity decontaminating agent
ES2146254T3 (en) * 1993-03-30 2000-08-01 Minnesota Mining & Mfg MULTI-SURFACE CLEANING COMPOSITIONS AND METHOD OF USE.
BR9405912A (en) * 1993-03-30 1996-01-30 Minnesota Mining & Mfg Composition suitable for extracting coatings from a surface
CA2157672C (en) * 1993-03-30 2005-07-26 Augustine Liu Cleaning compositions and methods of use
BR9508318A (en) * 1994-07-21 1997-12-23 Minnesota Mining & Mfg Concentrated impator composition
US5922665A (en) * 1997-05-28 1999-07-13 Minnesota Mining And Manufacturing Company Aqueous cleaning composition including a nonionic surfactant and a very slightly water-soluble organic solvent suitable for hydrophobic soil removal
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Cited By (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0106266A2 (en) * 1980-05-27 1984-04-25 The Procter & Gamble Company Terpene-solvent mixture useful for making liquid detergent compositions
EP0106266A3 (en) * 1980-05-27 1984-07-25 The Procter & Gamble Company Terpene-solvent mixture useful for making liquid detergent compositions
US4414128A (en) 1981-06-08 1983-11-08 The Procter & Gamble Company Liquid detergent compositions
EP0080749A1 (en) * 1981-11-12 1983-06-08 THE PROCTER & GAMBLE COMPANY Liquid detergent compositions
DE3316988A1 (en) * 1983-05-10 1984-11-15 Jürgen 6926 Kirchardt Rohrmoser MEANS FOR CLEANING MACHINES AND DEVICES AND PARTS THEREOF
US4533487A (en) * 1983-08-15 1985-08-06 Pitre-Jones Process for producing blended d-Limonene and uses of the blended product
EP0157975A2 (en) * 1984-03-12 1985-10-16 Varn Products Company, Inc. Method for removing printing ink from printing press component parts and cleaning compositions therefor
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