CN1041118C - Scaling agent for water tank of automobile - Google Patents
Scaling agent for water tank of automobile Download PDFInfo
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- CN1041118C CN1041118C CN94118478A CN94118478A CN1041118C CN 1041118 C CN1041118 C CN 1041118C CN 94118478 A CN94118478 A CN 94118478A CN 94118478 A CN94118478 A CN 94118478A CN 1041118 C CN1041118 C CN 1041118C
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- Prior art keywords
- scale
- scale remover
- water
- inhibiter
- automobile
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Abstract
The present invention relates to a scale removing agent for water tanks of automobiles. The scale removing agent achieves the purpose of scale removal by dissolving water scale and rust scale in an acid medium under the precondition of effective protection for metal. The scale removing agent of the present invention can remove all the water scale in a water tank of an automobile and water side parts of an automobile engine in one time. Besides, the present invention has the advantages of simple operation, stable performance and no any damage to cleaned positions.
Description
The present invention relates to a kind of scaling agent for water tank of automobile that adopts chemical cleaning technique.
Each developed country begins one's study and develops scaling agent for water tank of automobile at middle nineteen seventies in the world, up to the present scale remover has all kinds on the world market, but these products and all kinds of automobiles that are not suitable within Chinese territory use, its reason at first is the tectonic structure difference of different areas, the world, the water quality situation can be not identical yet, therefore the accumulative composition of scale is also different in the radiator, so the prescription of scale remover can't be completely unified.Next is that the automobile popularity rate of developed country is higher in the world, factor is understood very much and the energy dissipation, damage, maintenance, the influence that cause are normally travelled etc. to the existence of incrustation scale in the radiator, for avoiding the final appearance of this class situation, car steering person's year regular scaling agent for water tank of automobile that adds every half a year to one, carry out the scale removal maintenance, the formulating of recipe of scale remover also is to generate total amount according to the incrustation scale during this to formulate.Automobile daily maintenance part in the automobile specification sheets of China's import all has this regulation.
China domestic market occurred three in recent years, four kind of scale remover, its prescription is formed and using dosage is foreign imitation product and through improveing basically, simultaneously external imported product also once occurred on market, but do not cause result of use poor owing to conforming to China's national situation, finally on market, make no public appearances.Cause this result's reason to be that also China's automobile assembles in a large number from bringing into use to the water side part incrustation scale of water tank, engine, cause the difficulty of travelling, even just consider to clean can't travel the time.And use this moment currently available products or external import scale remover on the market to have no effect, because this series products itself does not have the effectiveness of removing a large amount of incrustation scales.
In addition, the removing of incrustation scale in China's radiator, so far still prolong with the way of breaking the back mechanical removal and carry out, cause easily mechanical force to the damage of water tank, influence a series of problems such as can't remove in its normal work-ing life, descaling rate incrustation scale low, engine water side part.
The purpose of this invention is to provide a kind of whole incrustation scales that can reach disposable removing radiator and motor car engine water side part, simple to operate, stable performance does not damage any scaling agent for water tank of automobile that is cleaned the position.
Scaling agent for water tank of automobile of the present invention is under the prerequisite that metal is effectively protected, dissolving incrustation scale and rust deposite in acid medium.Scale remover of the present invention comprises inhibiter, for example the LW-5 wide spectrum cleans inhibiter (also sale of Shanghai Kai Najie chemical institute production, main component is thiocyanate-, thiocarbamide and hexamethylenetetramine) and hexamethylenetetramine, and acidic descaling agent, nitric acid for example, oxyacetic acid, thionamic acid and EDTA-Na
2, and an amount of water.
When scaling agent for water tank of automobile of the present invention was used for the scale removal of general-utility car water tank, the consumption of each component was respectively the inhibiter of 3.2%-3.8% (weight), the acidic descaling agent of 41.5%-54.8% (weight) and the surplus water that removes amount.When scaling agent for water tank of automobile of the present invention was used for the water box for car scale removal, the consumption of each component was respectively the inhibiter of 8.0%-8.7% (weight), the acidic descaling agent of 35%-37% (weight) and the water of residual content.The common in use thin up of above-mentioned medicament becomes 5%~10% the aqueous solution.
In order to improve the scale removal efficient and the descale effect of scale remover of the present invention, it also can contain a small amount of other additive, comprises the protective material to inhibiter, for example EDTA-Na
2Speed of response promotor, for example penetrating agent BX (Shanghai auxiliary agent head factory is made and sold, and main component is a sodium butylnaphthalenesulfonate) and dinonyl naphthalene sulfonate barium; Remove Hydrogenated Polyisobutene, for example Triton X-100 and Sodium dodecylbenzene sulfonate; Remove grease auxiliary agent, for example Repone K; And tin, zinc coating protective material, for example dicyclohexyl amine octanoate, dinonylnaphthalene sulfonic acid sodium and LW-5 wide spectrum clean inhibiter.
Scaling agent for water tank of automobile of the present invention overcomes thoroughly that dismounting, manpower are struck off, grow servicing time, easy damaged, must specialized factory's maintenance, problems such as expense height.Any officer is feeding operations voluntarily all, and, can in two hours, reach medicine to the effect that dirt removes, solved the problem that the automobile radiator descaling aspect accumulates all the year round.And there is not any detrimentally affect.
The incrustation scale, the rust deposite that not only are applied in radiator and engine water side are removed, simultaneously also can be applicable to by stainless steel, carbon steel, low alloy steel, copper and copper alloy the incrustation scale of any watering equipment that aluminium and aluminium alloy are formed, container, pipeline etc., the quick removing of rust deposite.
Below by embodiment the present invention is described in further detail, but scope of the present invention is not limited to these embodiment.Embodiment 1-6
The general-utility car preparation of scale remover: the consumption of used all ingredients is as shown in table 1.
Preparation method: with a certain amount of hexamethylenetetramine, penetrating agent BX (Shanghai auxiliary agent head factory is produced and sold), EDTA-Na
2, Repone K is dissolved in 40~50 ℃ of water of about 200ml, use again by table 1 remaining water dilution nitric acid, and thionamic acid is put into salpeter solution immediately dissolve, solution that obtains and LW-5 inhibiter (Shanghai Kai Najie chemical institute is produced and sold) mix, and promptly get general-utility car scale remover of the present invention.
The table 1 general-utility car composition of scale remover
Embodiment 7-12
Reagent name | Content % (weight) | |||||
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
LW-5 inhibiter | 2.2 | 2.2 | 2.3 | 2.4 | 2.5 | 2.6 |
Hexamethylenetetramine | 1.2 | 1.2 | 1.1 | 1.1 | 1.0 | 1.0 |
Nitric acid (47%) | 20.0 | 21.0 | 22.0 | 23.0 | 24.0 | 25.0 |
Oxyacetic acid | 15.8 | 15.0 | 14.0 | 12.0 | 11.0 | 10.0 |
Thionamic acid | 8.0 | 8.0 | 9.0 | 9.0 | 10.0 | 10.0 |
EDTA—Na 2 | 4.0 | 3.9 | 3.8 | 3.7 | 3.6 | 3.5 |
Penetrating agent BX | 1.2 | 1.3 | 1.3 | 1.4 | 1.4 | 1.5 |
Repone K | 2.5 | 2.6 | 2.7 | 2.8 | 2.9 | 3.0 |
Water | Surplus |
The car preparation of scale remover: the consumption of used all ingredients is as shown in table 2.
Preparation method: with a certain amount of dinonyl naphthalene sulfonate barium, dicyclohexyl amine octanoate, penetrating agent BX (Shanghai auxiliary agent head factory is produced and sold), Triton X-100, Sodium dodecylbenzene sulfonate, hexamethylenetetramine.EDTA-Na
2, LW-5 inhibiter (Shanghai Kai Najie chemical institute produce also sell) is dissolved in respectively in whole water of 55~60 ℃, places after 24 hours, again oxyacetic acid, thionamic acid are put into solution respectively and dissolve.Can obtain car scale remover of the present invention.
The table 2. car composition of scale remover
Embodiment 13~18
Reagent name | Content % (weight) | |||||
Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | |
The LW-5 inhibiter | 4.0 | 4.1 | 4.2 | 4.3 | 4.4 | 4.5 |
Hexamethylenetetramine | 4.2 | 4.2 | 4.1 | 4.1 | 4.0 | 4.0 |
Oxyacetic acid | 10.0 | 10.5 | 11.0 | 11.5 | 11.8 | 12.0 |
Thionamic acid | 35.0 | 33.0 | 31.0 | 29.0 | 27.0 | 25.0 |
EDTA—Na 2 | 1.5 | 1.5 | 1.5 | 1.6 | 1.6 | 1.6 |
Penetrating agent BX | 5.0 | 5.1 | 5.2 | 5.2 | 5.3 | 5.4 |
Dinonyl naphthalene sulfonate barium | 1.8 | 1.8 | 1.7 | 1.7 | 1.6 | 1.6 |
Triton X-100 | 5.0 | 5.2 | 5.4 | 5.6 | 5.8 | 6.0 |
Sodium dodecylbenzene sulfonate | 1.6 | 1.6 | 1.5 | 1.5 | 1.4 | 1.4 |
The dicyclohexyl amine octanoate | 2.8 | 2.9 | 3.0 | 3.0 | 3.1 | 3.2 |
Water | Surplus |
General-utility car with embodiment 1~6 preparation cleans the diesel oil goods vehicle respectively with scale remover, the case lid of at first fetching boiling water, and start up the car, add scale remover, stop to start about two minutes, place.The lower box part drainage switch of fetching boiling water after two hours is emitted raffinate, finishes after the water flushing.After scale remover was handled, water temperature and new car standard were equal in the vehicle traveling process.Through taking water tank and engine inspection apart, do not find any incrustation scale, the metallic surface that is cleaned does not have any variation.Embodiment 19~24
Car with embodiment 7~12 preparations cleans the luxurious benz car of import respectively with scale remover.Once being sent to Auto repair shop before the cleaning repairs, after radiator unloads in manufacturer, find in the radiating pipe and engine water side knot full water dirt, there is the heat-dissipating space about 40% to be stopped up approximately by incrustation scale, because structure and technical reason can't manually be removed, if renew water tank, spending greatlyyer, but also is the incrustation scale problem that can't solve the engine water side.After cleaning (treatment process is with embodiment 13~18) with scale remover with car of the present invention, after tested, recover the cooling system standard of new car fully, capable again overhaul, the existence of incrustation scale is not all found at visible position, is cleaned the part metals no any variation in surface.
Claims (6)
1. scale remover that is used for radiator is characterized in that it contains:
(1) be selected from the inhibiter that the LW-5 wide spectrum cleans inhibiter and hexamethylenetetramine, consumption is 3.2%-3.8% (weight) and 8.0%-8.7% (weight);
(2) be selected from nitric acid, oxyacetic acid, thionamic acid and EDTA-Na
2Acidic descaling agent, consumption is 41.5-54.8% (weight) and 35%-37% (weight);
(3) water of surplus.
2. scale remover as claimed in claim 1 is characterized in that it also contains the protective material EDTA-Na of inhibiter
2
3. scale remover as claimed in claim 1 is characterized in that it also contains the speed of response promotor that is selected from penetrating agent BX and dinonyl naphthalene sulfonate barium.
4. scale remover as claimed in claim 1 is characterized in that it also contains the Hydrogenated Polyisobutene that removes that is selected from Triton X-100 and Sodium dodecylbenzene sulfonate.
5. scale remover as claimed in claim 1 is characterized in that it also contains except that grease auxiliary agent Repone K.
6. scale remover as claimed in claim 1 is characterized in that it also contains to be selected from tin, the zinc coating protective material that dicyclohexyl amine octanoate, dinonylnaphthalene sulfonic acid sodium and LW-5 wide spectrum clean inhibiter.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN94118478A CN1041118C (en) | 1994-11-18 | 1994-11-18 | Scaling agent for water tank of automobile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN94118478A CN1041118C (en) | 1994-11-18 | 1994-11-18 | Scaling agent for water tank of automobile |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1123343A CN1123343A (en) | 1996-05-29 |
CN1041118C true CN1041118C (en) | 1998-12-09 |
Family
ID=5038861
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Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94118478A Expired - Fee Related CN1041118C (en) | 1994-11-18 | 1994-11-18 | Scaling agent for water tank of automobile |
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CN (1) | CN1041118C (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100348779C (en) * | 2004-09-17 | 2007-11-14 | 中国科学院海洋研究所 | Natural green acid washing slow corrosion agent and its use |
AU2007227380B2 (en) * | 2006-03-23 | 2011-02-24 | M-I Drilling Fluids U.K. Limited | A method for dissolving oilfield scale |
CN101906633B (en) * | 2010-08-18 | 2012-03-28 | 河南省科学院能源研究所有限公司 | Cleaning agent of automobile cooling system and preparation method thereof |
CN103484871B (en) * | 2013-09-26 | 2015-07-29 | 麦特汽车服务股份有限公司 | A kind of cooling system does not disintegrate clean-out system |
CN103740489A (en) * | 2014-02-12 | 2014-04-23 | 北京戴斯科技有限公司 | Pipeline cleaning agent |
CN105441961A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Metal cleaning agent |
CN105441962A (en) * | 2015-11-29 | 2016-03-30 | 洛阳绿仁环保设备有限公司 | Water-based metal cleaning agent |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1095694A (en) * | 1993-05-25 | 1994-11-30 | 王文举 | Automobile radiator descaling cleaning agent |
-
1994
- 1994-11-18 CN CN94118478A patent/CN1041118C/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1095694A (en) * | 1993-05-25 | 1994-11-30 | 王文举 | Automobile radiator descaling cleaning agent |
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CN1123343A (en) | 1996-05-29 |
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