CN105524743A - Industrial crude oil pipeline cleaning agent - Google Patents

Industrial crude oil pipeline cleaning agent Download PDF

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Publication number
CN105524743A
CN105524743A CN201510946199.1A CN201510946199A CN105524743A CN 105524743 A CN105524743 A CN 105524743A CN 201510946199 A CN201510946199 A CN 201510946199A CN 105524743 A CN105524743 A CN 105524743A
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CN
China
Prior art keywords
parts
crude oil
agent
oil pipeline
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510946199.1A
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Chinese (zh)
Inventor
刘进军
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Wuxi Jijin Environmental Protection Technology Co Ltd
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Wuxi Jijin Environmental Protection Technology Co Ltd
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Filing date
Publication date
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Priority to CN201510946199.1A priority Critical patent/CN105524743A/en
Publication of CN105524743A publication Critical patent/CN105524743A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0084Antioxidants; Free-radical scavengers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products

Abstract

The invention discloses an industrial crude oil pipeline cleaning agent composed of the following components in parts by weight: 5-8 parts of an active silicon micro powder, 2-6 parts of anhydrous sodium sulfite, 4-8 parts of sodium citrate, 2-5 parts of sodium dodecyl sulfate, 1-3 parts of potassium hydrogen tartrate, 12-22 parts of methylal, 5-10 parts of ethanol, 3-9 parts of p-hydroxybenzoic acid, 3-5 parts of an antioxidant, 4-9 parts of a surface active agent, 3-7 parts of an anti-rust agent and 50-60 parts of deionized water. The crude oil pipeline cleaning agent has the advantages of strong industrial crude oil removing ability, no toxicity, good cleaning effect, safety and environmental protection, has rust prevention effect on a crude oil pipeline, and prolongs the service life of equipment.

Description

A kind of industrial crude oil pipeline sanitising agent
Technical field
The present invention relates to a kind of industrial crude oil pipeline sanitising agent, belong to sanitising agent technical field.
Background technology
In petroleum recovery operations, usually can run into a lot of petroleum pipe line by crude oil greasy dirt, if cleaning is not thorough, can results in blockage to petroleum pipe line, even corrode, not only have impact on the result of use of equipment, also reduce the work-ing life of pipeline simultaneously.And China to the construction scale of crude oil pipeline also at expanding day, the cleaning problems of crude oil pipeline is problem very important in carried of crude oil process always.
Domestic clean main some strongly-acids of use to crude oil pipeline or alkaline chemical cleaner at present, such sanitising agent not only cleaning effect is not good, also can cause secondary pollution to environment, and to crude oil pipeline, there is larger corrodibility, decrease the work-ing life of pipeline; In addition, such sanitising agent its cleaning effect extreme difference at a lower temperature.
Summary of the invention
The defect that the present invention seeks to exist for prior art provides a kind of industrial crude oil pipeline sanitising agent.
The present invention for achieving the above object, adopt following technical scheme: a kind of industrial crude oil pipeline sanitising agent, is made up of the component of following weight part: active micro silicon powder 5-8 part, sodium sulphite anhydrous 99.3 2-6 part, Trisodium Citrate 4-8 part, sodium lauryl sulphate 2-5 part, tartarus 1-3 part, methylal 12-22 part, ethanol 5-10 part, P-hydroxybenzoic acid 3-9 part, oxidation inhibitor 3-5 part, tensio-active agent 4-9 part, rust-preventive agent 3-7 part and deionized water 50-60 part.
Further, be made up of the component of following weight part: active micro silicon powder 5 parts, sodium sulphite anhydrous 99.3 2 parts, Trisodium Citrate 4 parts, sodium lauryl sulphate 2 parts, tartarus 1 part, methylal 12 parts, ethanol 5 parts, P-hydroxybenzoic acid 3 parts, 3 parts, oxidation inhibitor, 4 parts, tensio-active agent, rust-preventive agent 3 parts and deionized water 50 parts.
Further, be made up of the component of following weight part: active micro silicon powder 7 parts, sodium sulphite anhydrous 99.3 4 parts, Trisodium Citrate 6 parts, sodium lauryl sulphate 4 parts, tartarus 2 parts, methylal 18 parts, ethanol 8 parts, P-hydroxybenzoic acid 6 parts, 4 parts, oxidation inhibitor, 7 parts, tensio-active agent, rust-preventive agent 5 parts and deionized water 56 parts.
Further, be made up of the component of following weight part: active micro silicon powder 8 parts, sodium sulphite anhydrous 99.3 6 parts, Trisodium Citrate 8 parts, sodium lauryl sulphate 5 parts, tartarus 3 parts, methylal 22 parts, ethanol 10 parts, P-hydroxybenzoic acid 9 parts, 5 parts, oxidation inhibitor, 9 parts, tensio-active agent, rust-preventive agent 7 parts and deionized water 60 parts.
Further, described tensio-active agent is the mixture of any four kinds in TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y-35.
Further, described rust-preventive agent by soda ash, tertiary sodium phosphate, Sodium Propionate, tripoly phosphate sodium STPP and distilled water according to 1: 1: 2: 2: 20 ratio mix.
Beneficial effect of the present invention: crude oil pipeline sanitising agent of the present invention go that industrial crude oil ability is strong, nontoxic, cleaning effect is good, safety and environmental protection, and to crude oil pipeline, there is rust cleaning protective effect, the work-ing life of extension device.
Embodiment
The present invention relates to a kind of industrial crude oil pipeline sanitising agent, be made up of the component of following weight part: active micro silicon powder 5-8 part, sodium sulphite anhydrous 99.3 2-6 part, Trisodium Citrate 4-8 part, sodium lauryl sulphate 2-5 part, tartarus 1-3 part, methylal 12-22 part, ethanol 5-10 part, P-hydroxybenzoic acid 3-9 part, oxidation inhibitor 3-5 part, tensio-active agent 4-9 part, rust-preventive agent 3-7 part and deionized water 50-60 part.
Wherein, described tensio-active agent is the mixture of any four kinds in TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y-35.Wherein, described rust-preventive agent by soda ash, tertiary sodium phosphate, Sodium Propionate, tripoly phosphate sodium STPP and distilled water according to 1: 1: 2: 2: 20 ratio mix.
Embodiment 1:
The preparation method of above-mentioned crude oil pipeline sanitising agent, according to weight parts, comprises the steps:
1) deionized water of 50 parts, is got, put in reactor, then the active micro silicon powder of 5 parts, the sodium sulphite anhydrous 99.3 of 2 parts and the Trisodium Citrate of 4 parts is got, and be poured into successively in reactor and carry out mix and blend, stirring velocity is 50 revs/min, whipping temp is 23 degree, and churning time is 12 minutes, obtains mixed liquor A;
2), in reactor, slowly add the sodium lauryl sulphate of 2 parts and the tartarus of 1 part, and carry out mix and blend, stirring velocity is 40 revs/min, and whipping temp is 15 degree, and churning time is 10 minutes, obtains mixed liquid B;
3), in mixed liquid B, add the oxidation inhibitor of the methylal of 12 parts, the ethanol of 5 parts, the P-hydroxybenzoic acid of 3 parts and 3 parts, and carry out mix and blend, stirring velocity is 45 revs/min, and whipping temp is 26 degree, and churning time is 5 minutes, obtains mixed solution C;
4), the tensio-active agent of 4 parts and the rust-preventive agent of 3 parts is added in the most backward mixed solution C, and carry out mix and blend, stirring velocity is 60 revs/min, whipping temp is 55 degree, churning time is 20 minutes, then normal temperature leaves standstill 2 hours, and regulates PH to 6.5, finally obtained duct cleaning agent of the present invention.
During use, be encased in pressure sprayer by above-mentioned obtained sanitising agent, then carry out sprinkling by sprinker to crude oil pipeline and rinse, oily waste degradation rate reaches more than 90%.
Embodiment 2:
The preparation method of above-mentioned crude oil pipeline sanitising agent, according to weight parts, comprises the steps:
Active micro silicon powder 7 parts, sodium sulphite anhydrous 99.3 4 parts, Trisodium Citrate 6 parts, sodium lauryl sulphate 4 parts, tartarus 2 parts, methylal 18 parts, ethanol 8 parts, P-hydroxybenzoic acid 6 parts, 4 parts, oxidation inhibitor, 7 parts, tensio-active agent, rust-preventive agent 5 parts and deionized water 56 parts
1) deionized water of 56 parts, is got, put in reactor, then the active micro silicon powder of 7 parts, the sodium sulphite anhydrous 99.3 of 4 parts and the Trisodium Citrate of 6 parts is got, and be poured into successively in reactor and carry out mix and blend, stirring velocity is 55 revs/min, whipping temp is 28 degree, and churning time is 16 minutes, obtains mixed liquor A;
2), in reactor, slowly add the sodium lauryl sulphate of 4 parts and the tartarus of 2 parts, and carry out mix and blend, stirring velocity is 50 revs/min, and whipping temp is 18 degree, and churning time is 13 minutes, obtains mixed liquid B;
3), in mixed liquid B, add the oxidation inhibitor of the methylal of 18 parts, the ethanol of 8 parts, the P-hydroxybenzoic acid of 6 parts and 4 parts, and carry out mix and blend, stirring velocity is 52 revs/min, and whipping temp is 29 degree, and churning time is 9 minutes, obtains mixed solution C;
4), the tensio-active agent of 7 parts and the rust-preventive agent of 5 parts is added in the most backward mixed solution C, and carry out mix and blend, stirring velocity is 65 revs/min, whipping temp is 59 degree, churning time is 25 minutes, then normal temperature leaves standstill 2.5 hours, and regulates PH to 7, finally obtained duct cleaning agent of the present invention.
During use, be encased in pressure sprayer by above-mentioned obtained sanitising agent, then carry out sprinkling by sprinker to crude oil pipeline and rinse, oily waste degradation rate reaches more than 95%.
Embodiment 3:
The preparation method of above-mentioned crude oil pipeline sanitising agent, according to weight parts, comprises the steps:
1) deionized water of 60 parts, is got, put in reactor, then the active micro silicon powder of 8 parts, the sodium sulphite anhydrous 99.3 of 6 parts and the Trisodium Citrate of 8 parts is got, and be poured into successively in reactor and carry out mix and blend, stirring velocity is 58 revs/min, whipping temp is 33 degree, and churning time is 18 minutes, obtains mixed liquor A;
2), in reactor, slowly add the sodium lauryl sulphate of 5 parts and the tartarus of 3 parts, and carry out mix and blend, stirring velocity is 60 revs/min, and whipping temp is 20 degree, and churning time is 15 minutes, obtains mixed liquid B;
3) in mixed liquid B, add the oxidation inhibitor of the methylal of 22 parts, the ethanol of 10 parts, the P-hydroxybenzoic acid of 9 parts and 5 parts, and carry out mix and blend, stirring velocity is 60 revs/min, and whipping temp is 32 degree, churning time is 12 minutes, obtains mixed solution C;
4), the tensio-active agent of 9 parts and the rust-preventive agent of 7 parts is added in the most backward mixed solution C, and carry out mix and blend, stirring velocity is 70 revs/min, whipping temp is 65 degree, churning time is 30 minutes, then normal temperature leaves standstill 3 hours, and regulates PH to 7.5, finally obtained duct cleaning agent of the present invention.
During use, be encased in pressure sprayer by above-mentioned obtained sanitising agent, then carry out sprinkling by sprinker to crude oil pipeline and rinse, oily waste degradation rate reaches more than 99.5%.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (6)

1. an industrial crude oil pipeline sanitising agent, it is characterized in that, be made up of the component of following weight part: active micro silicon powder 5-8 part, sodium sulphite anhydrous 99.3 2-6 part, Trisodium Citrate 4-8 part, sodium lauryl sulphate 2-5 part, tartarus 1-3 part, methylal 12-22 part, ethanol 5-10 part, P-hydroxybenzoic acid 3-9 part, oxidation inhibitor 3-5 part, tensio-active agent 4-9 part, rust-preventive agent 3-7 part and deionized water 50-60 part.
2. a kind of industrial crude oil pipeline sanitising agent as claimed in claim 1, it is characterized in that, be made up of the component of following weight part: active micro silicon powder 5 parts, sodium sulphite anhydrous 99.3 2 parts, Trisodium Citrate 4 parts, sodium lauryl sulphate 2 parts, tartarus 1 part, methylal 12 parts, ethanol 5 parts, P-hydroxybenzoic acid 3 parts, 3 parts, oxidation inhibitor, 4 parts, tensio-active agent, rust-preventive agent 3 parts and deionized water 50 parts.
3. a kind of industrial crude oil pipeline sanitising agent as claimed in claim 1, it is characterized in that, be made up of the component of following weight part: active micro silicon powder 7 parts, sodium sulphite anhydrous 99.3 4 parts, Trisodium Citrate 6 parts, sodium lauryl sulphate 4 parts, tartarus 2 parts, methylal 18 parts, ethanol 8 parts, P-hydroxybenzoic acid 6 parts, 4 parts, oxidation inhibitor, 7 parts, tensio-active agent, rust-preventive agent 5 parts and deionized water 56 parts.
4. a kind of industrial crude oil pipeline sanitising agent as claimed in claim 1, it is characterized in that, be made up of the component of following weight part: active micro silicon powder 8 parts, sodium sulphite anhydrous 99.3 6 parts, Trisodium Citrate 8 parts, sodium lauryl sulphate 5 parts, tartarus 3 parts, methylal 22 parts, ethanol 10 parts, P-hydroxybenzoic acid 9 parts, 5 parts, oxidation inhibitor, 9 parts, tensio-active agent, rust-preventive agent 7 parts and deionized water 60 parts.
5. a kind of industrial crude oil pipeline sanitising agent as claimed in claim 1, is characterized in that, described tensio-active agent is the mixture of any four kinds in TX-10, FMES, LAS, AEO-9, TX-10, OP-10, QYL-83C and Y-35.
6. a kind of industrial crude oil pipeline sanitising agent as claimed in claim 1, is characterized in that, described rust-preventive agent by soda ash, tertiary sodium phosphate, Sodium Propionate, tripoly phosphate sodium STPP and distilled water according to 1: 1: 2: 2: 20 ratio mix.
CN201510946199.1A 2015-12-16 2015-12-16 Industrial crude oil pipeline cleaning agent Pending CN105524743A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106350267A (en) * 2016-08-18 2017-01-25 胡向荣 Outdoor equipment detergent
CN107446718A (en) * 2017-07-25 2017-12-08 安徽胜利精密制造科技有限公司 Micro mist cleaning fluid is remained after a kind of notebook computer casing moulding blasting treatment
CN108034948A (en) * 2017-11-29 2018-05-15 浙江郑氏刀剑有限公司 A kind of double-edged sword environmentally-frieantirust antirust agent
CN111154557A (en) * 2020-01-14 2020-05-15 深圳市燃气集团股份有限公司 Pipeline valve detergent, preparation method and decontamination method

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106350267A (en) * 2016-08-18 2017-01-25 胡向荣 Outdoor equipment detergent
CN107446718A (en) * 2017-07-25 2017-12-08 安徽胜利精密制造科技有限公司 Micro mist cleaning fluid is remained after a kind of notebook computer casing moulding blasting treatment
CN108034948A (en) * 2017-11-29 2018-05-15 浙江郑氏刀剑有限公司 A kind of double-edged sword environmentally-frieantirust antirust agent
CN111154557A (en) * 2020-01-14 2020-05-15 深圳市燃气集团股份有限公司 Pipeline valve detergent, preparation method and decontamination method

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