CN105297058A - Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application - Google Patents
Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application Download PDFInfo
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- CN105297058A CN105297058A CN201510762827.0A CN201510762827A CN105297058A CN 105297058 A CN105297058 A CN 105297058A CN 201510762827 A CN201510762827 A CN 201510762827A CN 105297058 A CN105297058 A CN 105297058A
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Abstract
The invention belongs to the technical field of industrial cleaning and particularly relates to an environment-friendly easily-rinsed easily-cleaned water draining agent and a preparation method thereof and application. The environment-friendly easily-rinsed easily-cleaned water draining agent comprises, by weight percentage, 89-99% of solvent, 0.05-1% of active matter, 1-10% of cosolvent and 0.5-5% of demulsifier. The preparation method comprises the step of sequentially adding each component into the solvent to be dissolved. The environment-friendly easily-rinsed easily-cleaned water draining agent has high water draining capability and can thoroughly remove water drops carried by parts in a last cleaning process, the water drops which fall off are deposited at the bottom of a rinse tank and drained from the bottom of the rinse tank in a mode of pollution discharge; moreover, the service life is long, and an active agent remaining on the surface of a workpiece after water draining can be cleaned easily.
Description
Technical field
The invention belongs to industry cleaning link technical field, be specifically related to a kind of environment protection type easy rinsing cleaning and cut aqua and its preparation method and application.
Background technology
China is a manufacturing powerhouse, and industrial production is in occupation of dominant position in national economy, and industry cleaning link is an indispensable link in the industrial production.Making a start of Chinese industrial cleaning industry, originates from phase early 1980s.In recent years, along with the progressively expansion of Chinese industrial production system, domestic industry cleaning industry is rapidly developed, and progressively ripe various industrialization cleaning techniques are used widely, environmental-protecting chemical cleaning technique upgrading paces are also progressively accelerated, and state of the art have also been obtained and increases substantially.
In industry cleaning link, matting is the way utilizing pharmaceutical chemicals or other removal of solvents body surface dirt, in industrial production, the cleaning of component will be removed and is adsorbed in body surface, accumulated inside, because Industrial products are at the various pollutents produced, use and be subject in storage process.The precision prescribed of traditional industry cleaning link is not high, to water mark and surface a small amount of dirt cleaning neither be very thorough.Along with the raising of production technology level, the performance requriements of Industrial products is also improved gradually, also more and more higher to the requirement of product reliability.Especially at high-accuracy industrial circle, improve constantly the requirement of the precision of product, product, constantly to high-performance, high reliability, high integration and microminiaturized future development, makes the susceptibility of product to pollutent increase.
But when using agent for carbon hydrogen detergent cleaning workpiece, workpiece surface, as remained water mark, does not reach the requirement of high cleanliness when follow-up cleaning.Therefore, most insider thoroughly will remove water mark as emphasis, but also bring negative impact thus, and residual being difficult to that namely high-performance cuts water actives cleans up.
Summary of the invention
In order to solve the problem, the object of the present invention is to provide a kind of environment protection type easy rinsing to clean and cutting aqua composition.This cuts aqua composition while thoroughly deviating from the workpiece surface globule, and the promoting agent caused by it remaining at workpiece surface, easier can clean removing in follow-up matting.
Two of object of the present invention there is provided the preparation method that aqua composition is cut in described environment protection type easy rinsing cleaning.
Three of object of the present invention there is provided the application that aqua composition is cut in described environment protection type easy rinsing cleaning.The present invention is achieved through the following technical solutions:
Aqua composition is cut in the easy rinsing cleaning of a kind of environmental protection, described composition comprises the following material that weight percent calculates: actives 0.05% ~ 0.5% (is preferably 0.10% ~ 0.25%, more excellent is 0.125% ~ 0.15%), solubility promoter: 0.4% ~ 7% (be preferably 3% ~ 7%, be more preferably 4.5% ~ 5.5%), emulsion splitter: 0.1% ~ 5% (be preferably 1.0% ~ 5%, more excellent is 2.5% ~ 3%) and hydrocarbon solvent: 89% ~ 99%.
Preferably, described active substance is octadecyl trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, one or more mixtures in the two octadecyl ammonium of dodecyl benzyl dimethyl ammonium chloride, chlorodimethyl.
Preferably, described solubility promoter is alcohol ether; One or more mixtures further in preferred ethylene glycol iso-octyl ether, ethylene glycol tertbutyl ether, ethylene glycol monobutyl ether.
Preferably, described emulsion splitter is primary alconol; One further in preferred nonylcarbinol, 2-propyl enanthol, n-Octanol, 2-ethyl octanol or its several mixture.
Preferably, described hydrocarbon solvent is one in n-decane, the positive structure of carbon 11 or isoparaffin or its several mixture.
Prepare the method that aqua composition is cut in the easy rinsing cleaning of described environmental protection, preparation process is as follows:
(1), in a kettle. add cosolvent solution, in reactor, add promoting agent more afterwards, keep temperature to be 70 ~ 90 DEG C, keep constant temperature 3 ~ 5min, stir into homogeneous transparent liquid.
(2), in reactor add hydrocarbon solvent and emulsion splitter successively, be mixed and made into the easy rinsing cleaning of described environmental protection and cut aqua composition.
The application method of aqua composition is cut in the easy rinsing cleaning of described environmental protection, after workpiece with greasy dirt is first used clear water rinsing, put into described cleaning in the easy rinsing of environmental protection again and cut aqua composition, static 1 ~ 2min, slowly shake 2 ~ 3 times up and down, more static 1 ~ 2min, the water beading on workpiece falls, then mention again, be disposed by surface without the globule remain workpiece be transported to next procedure.After workpiece with greasy dirt is first used clear water rinsing, put into cleaning in the easy rinsing of environmental protection described in claim 1-8 any one again and cut aqua composition, static 1 ~ 2min, then ultrasonic vibration 1 ~ 2min, and 1min is left standstill at temperature 30 ~ 40 DEG C, water beading on workpiece falls, more then mentions, be disposed by surface without the globule remain workpiece be transported to next procedure.
The present invention, by the extremely strong adsorptive power of promoting agent in metallic surface, under the synergy of solubility promoter ether and emulsifying agent alcohol, squeezes the water of metallic surface and falls in solvent, and the globule is by rapid stripping metal surface.Emulsion splitter can make profit sharp separation, and water can tumble rapidly bottom solvent in a solvent, reaches the object of dehydration, and the promoting agent film of absorption in metallic surface has certain antirust ability, can make workpiece non-corrosive in cleaning process.
Tool of the present invention has the following advantages:
(1), environment protection type easy rinsing cleaning of the present invention is cut aqua mixture and is cut water mechanism and the simple science of scavenging mechanism, to cut in aqua the objectionable impurities such as halohydrocarbon, aromatic hydrocarbon not to human body and bad environmental, use safety and environmental protection, and the resistance to corrosion of workpiece can be improved.
(2), environment protection type easy rinsing of the present invention cleaning is cut each component in aqua mixture and can effectively be worked in coordination with together, the water being adsorbed on workpiece surface is made to be pearl landing, the greasy dirt of workpiece surface can rapidly dissolve in be cut in aqua, and workpiece surface light is as new.
(3), environment protection type easy rinsing cleaning of the present invention cuts aqua except having stronger cleansing power, more can slough rapidly and up hill and dale the water remaining in workpiece surface in front road matting, the water deviate from can fast deposition in the bottom of cutting aqua, can be discharged from the bottom of rinse bath by the mode of blowdown, more than 3 months work-ing life of prolongation clean-out system.
(4), environment protection type easy rinsing of the present invention cleaning cuts aqua and not only has stronger clean ability and cut outlet capacity, and be highly susceptible to rinsing with the workpiece originally cutting water cleaned, and that can remove workpiece surface very simply cuts aqua.
(5), that aqua production process is cut in environment protection type easy rinsing of the present invention cleaning is simple, and raw materials used acquisition is easy, and source is comparatively extensive, easy to operate and safe, is very suitable for scale operation, and originally cuts aqua and use also very simple.
In a word, the present invention, on the basis ensureing good cleaning performance, provides a kind of rinsing cleaning of being easy to for regular industrial parts, precision and high-accuracy industrial part, and fast, safe and environmental protection thoroughly cuts aqua.Originally cut aqua and can take off workpiece surface residual moisture in 2 ~ 3min, cutting aqua can rinsed clean easily, but also makes workpiece have certain anti-corrosion capability.
concrete embodiment
Below in conjunction with embodiment, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Embodiment 1
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: pure carbon ten 950g, ethylene glycol iso-octyl ether 40g, octadecyldimethyl ammonium chloride 5g and n-Octanol 5g.
Preparation process is as follows:
(1) cosolvent solution of promoting agent, is prepared: add ethylene glycol iso-octyl ether (solubility promoter) 44g solution in a kettle., octadecyldimethyl ammonium chloride (active substance) 5g is added again afterwards in reactor, temperature is kept to be 80 DEG C, keep constant temperature 3 ~ 5min, stirring into homogeneous transparent liquid, is the cosolvent solution of promoting agent.
(2) to adding carbon ten solvent (hydrocarbon solvent) 950g and n-Octanol (emulsion splitter) 5g in a kettle., making easy rinsing cleaning and cutting aqua composition.
Embodiment 2
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: pure carbon ten 970g, ethylene glycol tertbutyl ether 26g, octadecyldimethyl ammonium chloride 3g and 2-propyl enanthol 1g.
Its preparation method and step are with example 1.
Embodiment 3
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: pure carbon ten 990g, ethylene glycol tertbutyl ether 4.5g, octadecyldimethyl ammonium chloride 5g and 2-propyl enanthol 0.5g.
Its preparation method and step are with example 1.
Embodiment 4
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: normal paraffin 890g, the ethylene glycol monobutyl ether 50g of carbon 11, palmityl trimethyl ammonium chloride 57.5g and 2-ethyl octanol 2.5g.
Its preparation method and step are with example 1.
Embodiment 5
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: isoparaffin 800g, the ethylene glycol iso-octyl ether 20g of n-decane 100g, carbon 11, ethylene glycol monobutyl ether 50g, octadecyl trimethyl ammonium chloride 2g, palmityl trimethyl ammonium chloride 2g, Dodecyl trimethyl ammonium chloride 4g, the two octadecyl ammonium 20g of chlorodimethyl, nonylcarbinol, 2-propyl enanthol 1g, n-Octanol 1g.
Its preparation method and step are with example 1.
Embodiment 6
Aqua composition is cut in easy rinsing cleaning, and its composition and weight (for 1000g) are: the normal paraffin 330g of pure carbon ten 500g, n-decane 100g, carbon 11, ethylene glycol iso-octyl ether 30g, stearyl dimethyl benzyl ammonium chloride 38.5g and n-Octanol 1.5g.
Its preparation method and step are with example 1.
Application example 1
The metal productss such as stainless steel, steel alloy, titanium alloy are after drawing process, surface is containing drawing oil, after using clean-out system cleaning, then after using tap water 3 times, easy rinsing cleaning workpiece being placed on embodiment 1 is cut in aqua composition, static 1min, slowly shake 2 ~ 3 times up and down, more static 1min, the water beading on workpiece falls, then mention, workpiece enters lower road program (workpiece surface remains without the globule) again.
Application example 2
The machine oil of the main equipment such as lathe, punch press in operation, stretching wet goods are heated evaporation, equipment surface can be attached to after cooling and form greasy dirt, through spray and scouring, then use tap water rinse, pure water rinsing, finally put into the static 1 ~ 2min of product of embodiment 1, then ultrasonic vibration 1 ~ 2min, and 1min is left standstill at temperature 30 ~ 40 DEG C, the water beading on workpiece falls, then mention again, be disposed by surface without the globule remain workpiece be transported to next procedure.
Conclusion: rapidly, noresidue, workpiece surface is sparkling clean in dehydration.
Outward appearance: colourless transparent liquid
Density: 0.65 ~ 0.87 (g/cm
3)
Suggestion working concentration: stoste
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the feature described in the claims in the present invention and principle change or modify, and all should be included within the claims in the present invention scope.
Claims (10)
1. an aqua composition is cut in the easy rinsing cleaning of environmental protection, it is characterized in that: described composition comprises the following material that weight percent calculates:
2. cut aqua composition according to the easy rinsing cleaning of the said environmental protection of claim 1 or 2, it is characterized in that: described active substance is octadecyl trimethyl ammonium chloride, palmityl trimethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, one or more mixtures in the two octadecyl ammonium of dodecyl benzyl dimethyl ammonium chloride, chlorodimethyl.
3. cut aqua composition according to the easy rinsing cleaning of the said environmental protection of claim 1 or 2, it is characterized in that: described solubility promoter is alcohol ether.
4. cut aqua composition according to the easy rinsing cleaning of the said environmental protection of claim 3, it is characterized in that: described solubility promoter is one or more mixtures in ethylene glycol iso-octyl ether, ethylene glycol tertbutyl ether, ethylene glycol monobutyl ether.
5. cut aqua composition according to the easy rinsing cleaning of the said environmental protection of claim 1, it is characterized in that: described emulsion splitter is primary alconol.
6. cut aqua composition according to the said environmental protection of claim 5 easy rinsing cleaning, it is characterized in that: described emulsion splitter is one in nonylcarbinol, 2-propyl enanthol, n-Octanol, 2-ethyl octanol or its several mixture.
7. cut aqua composition according to the said environmental protection of claim 1 easy rinsing cleaning, it is characterized in that: described hydrocarbon solvent is one in n-decane, the positive structure of carbon 11 or isoparaffin or its several mixture.
8. prepare the method that aqua composition is cut in the easy rinsing cleaning of environmental protection described in any one in claim 1-7, it is characterized in that: preparation process is as follows,
(1), in a kettle. add cosolvent solution, in reactor A, add promoting agent more afterwards, keep temperature to be 70 ~ 90 DEG C, keep constant temperature 3 ~ 5min, stir into homogeneous transparent liquid;
(2), in reactor add hydrocarbon solvent and emulsion splitter successively, be mixed and made into the easy rinsing cleaning of described environmental protection and cut aqua composition.
9. in claim 1-8, the application method of aqua composition is cut in the easy rinsing cleaning of environmental protection described in any one, it is characterized in that: after the workpiece with greasy dirt is first used clear water rinsing, put into cleaning in the easy rinsing of environmental protection described in claim 1-8 any one again and cut aqua composition, static 1 ~ 2min, slowly shake 2 ~ 3 times up and down, more static 1 ~ 2min, the water beading on workpiece falls, then mention again, be disposed by surface without the globule remain workpiece be transported to next procedure.
10. in claim 1-8, the application method of aqua composition is cut in the easy rinsing cleaning of environmental protection described in any one, it is characterized in that: after the workpiece with greasy dirt is first used clear water rinsing, put into cleaning in the easy rinsing of environmental protection described in claim 1-8 any one again and cut aqua composition, static 1 ~ 2min, then ultrasonic vibration 1 ~ 2min, and 1min is left standstill at temperature 30 ~ 40 DEG C, water beading on workpiece falls, then mention again, be disposed by surface without the globule remain workpiece be transported to next procedure.
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Cited By (6)
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| CN108531314A (en) * | 2018-04-20 | 2018-09-14 | 广东红日星实业有限公司 | Aqua and preparation method thereof is cut in environmental protection |
| CN108949383A (en) * | 2017-05-17 | 2018-12-07 | 东曹株式会社 | Cleansing composition and the cleaning method for using it |
| CN109694785A (en) * | 2017-10-22 | 2019-04-30 | 麦达可尔(烟台)科技有限公司 | A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof |
| CN110055140A (en) * | 2019-05-28 | 2019-07-26 | 马鞍山华之杰金属表面处理剂有限公司 | It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof |
| CN114134548A (en) * | 2021-12-07 | 2022-03-04 | 安美科技股份有限公司 | Hydrocarbon water cutting agent and preparation process thereof |
| CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108949383A (en) * | 2017-05-17 | 2018-12-07 | 东曹株式会社 | Cleansing composition and the cleaning method for using it |
| CN108949383B (en) * | 2017-05-17 | 2021-05-25 | 东曹株式会社 | Cleaning agent composition and cleaning method using same |
| CN109694785A (en) * | 2017-10-22 | 2019-04-30 | 麦达可尔(烟台)科技有限公司 | A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof |
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| CN114134548A (en) * | 2021-12-07 | 2022-03-04 | 安美科技股份有限公司 | Hydrocarbon water cutting agent and preparation process thereof |
| CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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Application publication date: 20160203 |