CN108842156A - A kind of stainless steel steel wire special plant cleaning agent - Google Patents

A kind of stainless steel steel wire special plant cleaning agent Download PDF

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Publication number
CN108842156A
CN108842156A CN201810549698.0A CN201810549698A CN108842156A CN 108842156 A CN108842156 A CN 108842156A CN 201810549698 A CN201810549698 A CN 201810549698A CN 108842156 A CN108842156 A CN 108842156A
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CN
China
Prior art keywords
parts
stainless steel
cleaning agent
steel wire
modified clay
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CN201810549698.0A
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Chinese (zh)
Inventor
时金明
崔斌
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SUZHOU DOUBLE GOLD INDUSTRY Co Ltd
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SUZHOU DOUBLE GOLD INDUSTRY Co Ltd
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Priority to CN201810549698.0A priority Critical patent/CN108842156A/en
Publication of CN108842156A publication Critical patent/CN108842156A/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of stainless steel steel wire special plant cleaning agents, including following component according to parts by weight:1-8 parts of organic silicon defoamer, 15-28 parts of methyl benzoate, 20-28 parts of starch, 18-25 parts of citric acid, 25-38 parts of peach leaf extract, 20-28 parts of Pu'er tea, 5-8 parts of sodium pyrophosphate, 12-25 parts of nano-sized carbon, 5-12 parts of sodium metasilicate, 18-27 parts of polyethylene glycol, modified clay 1-8 parts, 1-3 parts of Marsellies Soap, 45-58 parts of water, 0.4-0.8 parts of bacillus subtilis, 0.5-0.8 parts of Bacillus acidi lactici, 5-16 parts of ethylene glycol, 1-5 parts of cellulose acetate;PH is 7-8;The modified clay is formed by nanometer aluminium powder, chitosan and graphene mixture.The ability of cleaning greasy dirt of cleaning agent of the invention is strong, safe, non-corrosive, cleaning effect is good, has good bactericidal effect, easy cleaning is clean, and not damaged to stainless steel steel wire surface.

Description

A kind of stainless steel steel wire special plant cleaning agent
Technical field
The invention belongs to lathe cleaning applications, and in particular to a kind of stainless steel steel wire special plant cleaning agent.
Background technique
Currently, scientific technological advance is rapid, processing efficiency and machining accuracy are continuously improved, and stainless steel wire material is popularized Using if maintenance is not good at having will be greatly reduced the service life of stainless steel steel wire;But it is not easy when cleaning because diameter is meticulous Cleaning, and machine oil is difficult to clear up, and is easy to leave mark on steel wire.
There are three ways to tradition degreases:1) solvent oil removal process:Using cool wash and vapour degreasing, for cleaning Organic solvent has petroleum series solvent, fluorination series solvent and fluorine carbon series solvent three categories, its advantage is that it is high-efficient to degrease, disadvantage It is that organic solvent generally all has the shortcomings that flash-point is low, toxicity is big, inflammable, pollution is strong, the antiseptic property after cleaning is poor.2) Highly basic oil removal process:Using immersion and jet cleaning, its advantage is that price is low, raw material is easy to get, but alkaline matter corrosivity is stronger, and And only just there is preferable oil removing ability under higher alkaline condition.3) surfactant oil removing:According to surfactant Then wetting, infiltration, the effect emulsified make dirt fall off by greasy dirt emulsion dispersion at tiny particle by mechanism, reach Oil removing purpose.
Application number 201510214910.1, entitled a kind of efficient lathe detergent, by the original of following parts by weight Material is made:FMEE4.5-7.3 parts of fatty acid methyl ester b-oxide, 3.2-4.8 parts of sodium pyrophosphate, 5-7 parts of sodium bicarbonate, organosilicon 5-8 parts of defoaming agent, 6-7 parts of ethylene glycol butyraldehyde, 4-6 parts of petroleum alkylaryl sulfonates, 1.7-2.4 parts of n-octylpyrrolidone, 2.5-3.5 parts of Oxyfluorfen, 1.6-3.7 parts of pH adjusting agent, 1.2-3.4 parts of potassium tripolyphosphate, 12-24 parts of salicylate, 1-4 parts of titanium dioxide, 6-11 parts of inorganic agent, 6-12 parts of methyl benzoate, 4-9 parts of tartaric acid, 4-11 parts of butyl glycol ether.Although The cleaning agent cleaning effect is good, but difficult flushing, and the shipwreck processing of flushing easily causes environmental pollution.
Summary of the invention
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of stainless steel steel wire special plant cleaning agent, The cleaning agent cleaning capacity is strong, is easy to rinse, and the cost of sewage disposal after flushing is low, is not easy to impact environment.
To solve prior art problem, the technical scheme adopted by the invention is as follows:
A kind of stainless steel steel wire special plant cleaning agent, including following component according to parts by weight:Organic silicon defoamer 1-8 parts, 15-28 parts of methyl benzoate, 20-28 parts of starch, 18-25 parts of citric acid, 25-38 parts of peach leaf extract, Pu'er tea mention Take 20-28 parts of object, 5-8 parts of sodium pyrophosphate, 12-25 parts of nano-sized carbon, 5-12 parts of sodium metasilicate, 18-27 parts of polyethylene glycol, modified clay 1-8 parts, 1-3 parts of Marsellies Soap, 45-58 parts of water, 0.4-0.8 parts of bacillus subtilis, 0.5-0.8 parts of Bacillus acidi lactici, ethylene glycol 5- 16 parts, 1-5 parts of cellulose acetate;PH is 7-8;The modified clay is formed by nanometer aluminium powder, chitosan and graphene mixture.
It is a kind of stainless steel steel wire special plant cleaning agent, including following component according to parts by weight as improved: 5 parts of organic silicon defoamer, 20 parts of methyl benzoate, 25 parts of starch, 22 parts of citric acid, 35 parts of peach leaf extract, Pu'er tea extract 25 parts of object, 6 parts of sodium pyrophosphate, 20 parts of nano-sized carbon, 10 parts of sodium metasilicate, 25 parts of polyethylene glycol, modified 6 parts of clay, 2 parts of Marsellies Soap, 50 parts of water, 0.5 part of bacillus subtilis, 0.6 part of Bacillus acidi lactici, 12 parts of ethylene glycol, 3 parts of cellulose acetate.
It is that the organic silicon defoamer is sodium metasilicate as improved.
It is that the molar ratio of nanometer aluminium powder, chitosan and graphene is 45-58 in the modified clay as improved:1: 2-8。
It is that the preparation method of the modified clay is as improved, after (1) dissolves nanometer aluminium powder, chitosan is added, After magnetic agitation, mixture A is obtained;(2) graphene is added in mixture A, after stirring, spray drying obtains modified clay.
It is that the specific surface area of the nano-sized carbon is 150-180m as improved2/g。
Beneficial effect:
Compared with prior art, cleaning agent of the invention materials are derived from plant, and the ability of cleaning greasy dirt of gained cleaning agent is strong, pacifies Entirely, non-corrosive, cleaning effect is good, has good bactericidal effect, and water consumption is few, and easy cleaning is clean, and to stainless steel steel The surface of silk is not damaged.
Specific embodiment
The present invention is further described in detail below by specific embodiment.
The dosage of each component is parts by weight in following embodiment.
Embodiment 1
A kind of stainless steel steel wire special plant cleaning agent, including following component according to parts by weight:1 part of sodium metasilicate, benzene 15 parts of methyl formate, 20 parts of starch, 18 parts of citric acid, 25 parts of peach leaf extract, 20 parts of Pu'er tea, 5 parts of sodium pyrophosphate, Specific surface area is 150m212 parts of/g nano-sized carbon, 5 parts of sodium metasilicate, 18 parts of polyethylene glycol, modified 1 part of clay, 1 part of Marsellies Soap, water 45 Part, 0.4 part of bacillus subtilis, 0.5 part of Bacillus acidi lactici, 5 parts of ethylene glycol, 1 part of cellulose acetate;PH is 7;The modified clay It is formed by nanometer aluminium powder, chitosan and graphene mixture, and molar ratio is 45:1:2.
Wherein, the preparation method of the modified clay is that after (1) dissolves nanometer aluminium powder, chitosan, magnetic agitation is added Afterwards, mixture A is obtained;(2) graphene is added in mixture A, after stirring, spray drying obtains modified clay.
The preparation method of the peach leaf extract is, after peach leaf is cleaned up, is cut into 2 square centimeters of small pieces, is added 2 times of deionized water of leaf weight, boiling at 30-45 DEG C after filtering, again plus water boiling filtering, repeat 1-3 time, merging Filtrate is to get peach leaf extract.
The preparation method of the Pu'er tea is, after discarded Pu'er tea is cleaned up, puts into ball mill and grinds It is broken, extraction 1-4 times is added, combined extract is to get Pu'er tea.
Preparation method:It is same as the prior art.
Embodiment 2
A kind of stainless steel steel wire special plant cleaning agent, including following component according to parts by weight:5 parts of sodium metasilicate, benzene 20 parts of methyl formate, 25 parts of starch, 22 parts of citric acid, 35 parts of peach leaf extract, 25 parts of Pu'er tea, 6 parts of sodium pyrophosphate, Specific surface area is 170m220 parts of/g nano-sized carbon, 10 parts of sodium metasilicate, 25 parts of polyethylene glycol, modified 6 parts of clay, 2 parts of Marsellies Soap, water 50 parts, 0.5 part of bacillus subtilis, 0.6 part of Bacillus acidi lactici, 12 parts of ethylene glycol, 3 parts of cellulose acetate, pH 7;The modification Clay is formed by nanometer aluminium powder, chitosan and graphene mixture, and molar ratio is 48:1:6.
Wherein, the preparation method of the modified clay is that after (1) dissolves nanometer aluminium powder, chitosan, magnetic agitation is added Afterwards, mixture A is obtained;(2) graphene is added in mixture A, after stirring, spray drying obtains modified clay.
The preparation method of the peach leaf extract is, after peach leaf is cleaned up, is cut into 2 square centimeters of small pieces, is added 2 times of deionized water of leaf weight, boiling at 30-45 DEG C after filtering, again plus water boiling filtering, repeat 1-3 time, merging Filtrate is to get peach leaf extract.
The preparation method of the Pu'er tea is, after discarded Pu'er tea is cleaned up, puts into ball mill and grinds It is broken, extraction 1-4 times is added, combined extract is to get Pu'er tea.
Preparation method:It is same as the prior art.
Embodiment 3
A kind of stainless steel steel wire special plant cleaning agent, including following component according to parts by weight:1-8 parts of sodium metasilicate, 15-28 parts of methyl benzoate, 20-28 parts of starch, 18-25 parts of citric acid, 25-38 parts of peach leaf extract, Pu'er tea 20- 28 parts, 5-8 parts of sodium pyrophosphate, specific surface area 180m212-25 parts of/g nano-sized carbon, 5-12 parts of sodium metasilicate, polyethylene glycol 18-27 Part, modified clay 1-8 parts, 1-3 parts of Marsellies Soap, 45-58 parts of water, 0.4-0.8 parts of bacillus subtilis, Bacillus acidi lactici 0.5-0.8 Part, 5-16 parts of ethylene glycol, 1-5 parts of cellulose acetate;PH is 7-8;The modified clay is by nanometer aluminium powder, chitosan and graphene Mixture forms, molar ratio 58:1:8.
Wherein, the preparation method of the modified clay is that after (1) dissolves nanometer aluminium powder, chitosan, magnetic agitation is added Afterwards, mixture A is obtained;(2) graphene is added in mixture A, after stirring, spray drying obtains modified clay.
The preparation method of the peach leaf extract is, after peach leaf is cleaned up, is cut into 2 square centimeters of small pieces, is added 2 times of deionized water of leaf weight, boiling at 30-45 DEG C after filtering, again plus water boiling filtering, repeat 1-3 time, merging Filtrate is to get peach leaf extract.
The preparation method of the Pu'er tea is, after discarded Pu'er tea is cleaned up, puts into ball mill and grinds It is broken, extraction 1-4 times is added, combined extract is to get Pu'er tea.
Preparation method:It is same as the prior art.
Comparative example 1
In addition to replacing modified clay with nanometer aluminium powder, remaining is the same as embodiment 2.
Performance test
According to the characteristics of industrial aqueous cleaning agent to embodiment preparation cleaning agent carry out washing oil rate, corrosivity, permeability, Emulsibility and stability analysis, test method is such as:
It is impregnated with detergent solution and puts the washcoated metal testing plate for having machinery oil, washing oil rate is calculated by the greasy dirt amount washed away.It will It provides ready stainless steel test piece, after even test piece is placed in 40 ± 2 DEG C of baking ovens dry 30min, moves into cooling in drier After weigh, i.e. m0, accurate that the test piece after weighing is immersed 30s in machinery oil, then will coat the test piece of greasy dirt to ± 0.2mg Hung on test piece frame with S-hook, at room temperature it is quiet put 30min after, the greasy dirt on bottom edge is wiped in taking-up with filter paper, weigh quality, That is m1;In then pendulum oil, 400ml detergent solution temperature is poured into 500ml beaker and is maintained at 60 DEG C, is impregnated in cleaning agent 3min, pendulum washes 3min immediately, and pendulum washes 30s in 60 DEG C, 400ml distilled water, and test piece is put into 2h in 40 ± 2 DEG C of thermostatic drying chambers It is cooling, weighing, i.e. m2
1. washing oil rate
X=(m1-m2)/(m1-m0) × 100%
2. company standard QB/T2117-95 is shown in the test of corrosivity, rust-preventing characteristic
3. testing permeance property according to GB11983-2008 canvas sedimentation.
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1
Washing oil rate (%) 98.5 99.4 94.5 85.1
Etching extent/g 0.0014 0.00012 0.0025 0.0045
Time of penetration/s 15 18 14 10
It can be seen from the results above that cleaning agent of the present invention goes oil cut rate high, it is small to lathe etching extent and easy to clean.Than Compared with
Embodiment 2, comparative example 1 are it is found that detergent effectively improves the cleaning force of detergent.Cleaning agent water of the present invention Amount is few, the similarly suitable cleaning treatment applied to machinery field lathe.
In addition, the present invention is not limited to the above embodiments, as long as can take various in without departing from the scope of the present invention Mode implements the present invention.

Claims (6)

1. a kind of stainless steel steel wire special plant cleaning agent, which is characterized in that including following component according to parts by weight:It is organic 1-8 parts of silicon defoaming agent, 15-28 parts of methyl benzoate, 20-28 parts of starch, 18-25 parts of citric acid, 25-38 parts of peach leaf extract, 20-28 parts of Pu'er tea, 5-8 parts of sodium pyrophosphate, 12-25 parts of nano-sized carbon, 5-12 parts of sodium metasilicate, 18-27 parts of polyethylene glycol, Modified clay 1-8 parts, 1-3 parts of Marsellies Soap, 45-58 parts of water, 0.4-0.8 parts of bacillus subtilis, 0.5-0.8 parts of Bacillus acidi lactici, 5-16 parts of ethylene glycol, 1-5 parts of cellulose acetate;PH is 7-8;The modified clay is mixed by nanometer aluminium powder, chitosan and graphene Object is closed to form.
2. a kind of stainless steel steel wire special plant cleaning agent according to claim 1, which is characterized in that including below by weight Measure the component of number meter:5 parts of organic silicon defoamer, 20 parts of methyl benzoate, 25 parts of starch, 22 parts of citric acid, peach leaf extract 35 parts, 25 parts of Pu'er tea, 6 parts of sodium pyrophosphate, 20 parts of nano-sized carbon, 10 parts of sodium metasilicate, 25 parts of polyethylene glycol, modified clay 6 parts, 2 parts of Marsellies Soap, 50 parts of water, 0.5 part of bacillus subtilis, 0.6 part of Bacillus acidi lactici, 12 parts of ethylene glycol, cellulose acetate 3 Part.
3. a kind of stainless steel steel wire special plant cleaning agent according to claim 1, which is characterized in that the organosilicon disappears Infusion is sodium metasilicate.
4. a kind of stainless steel steel wire special plant cleaning agent according to claim 1, which is characterized in that the modified clay The molar ratio of middle nanometer aluminium powder, chitosan and graphene is 45-58:1:2-8.
5. a kind of stainless steel steel wire special plant cleaning agent according to claim 1, which is characterized in that the modified clay Preparation method be,(1)After nanometer aluminium powder is dissolved, chitosan is added, after magnetic agitation, obtains mixture A;(2)By graphene It is added in mixture A, after stirring, spray drying obtains modified clay.
6. a kind of stainless steel steel wire special plant cleaning agent according to claim 1, which is characterized in that the nano-sized carbon Specific surface area is 150-180m2/g。
CN201810549698.0A 2018-05-31 2018-05-31 A kind of stainless steel steel wire special plant cleaning agent Pending CN108842156A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349941A (en) * 2020-03-16 2020-06-30 北京京蝠环保科技有限公司 Natural plant hub cleaning agent
CN114000155A (en) * 2021-09-26 2022-02-01 西北大学 Universal aluminum and aluminum alloy environment-friendly dedusting agent

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105970232A (en) * 2016-05-26 2016-09-28 何瑞云 Environment-friendly degreasing agent
CN107841750A (en) * 2017-11-07 2018-03-27 常州禾吉纺织品有限公司 A kind of anti-rust metal detergent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105970232A (en) * 2016-05-26 2016-09-28 何瑞云 Environment-friendly degreasing agent
CN107841750A (en) * 2017-11-07 2018-03-27 常州禾吉纺织品有限公司 A kind of anti-rust metal detergent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111349941A (en) * 2020-03-16 2020-06-30 北京京蝠环保科技有限公司 Natural plant hub cleaning agent
CN114000155A (en) * 2021-09-26 2022-02-01 西北大学 Universal aluminum and aluminum alloy environment-friendly dedusting agent
CN114000155B (en) * 2021-09-26 2023-09-12 西北大学 General aluminum and alloy environment-friendly ash remover thereof

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Application publication date: 20181120

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