CN109694785A - A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof - Google Patents
A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof Download PDFInfo
- Publication number
- CN109694785A CN109694785A CN201710989132.5A CN201710989132A CN109694785A CN 109694785 A CN109694785 A CN 109694785A CN 201710989132 A CN201710989132 A CN 201710989132A CN 109694785 A CN109694785 A CN 109694785A
- Authority
- CN
- China
- Prior art keywords
- carbon hydrogen
- agent
- highly effective
- hydrogen detergent
- type ring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/241—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3209—Amines or imines with one to four nitrogen atoms; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5027—Hydrocarbons
Abstract
The present invention relates to cleaning agent technical field, in particular to a kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof.Its constituent includes: n-tetradecane 40% -50% according to mass percent；Hexadecane 30% -40%；N-pentadecane 9% -29%；Dioctylamine 0.4% -0.8%；RP333H hard film rust preventives 0.2% -0.6%.A kind of highly effective antirust type ring of the invention protects agent for carbon hydrogen detergent and preparation method thereof, rustless property is increased under the premise of guaranteeing the performance of original agent for carbon hydrogen detergent, the working efficiency of production enterprise can be greatly improved, cleaning and antirust are solved the problems, such as simultaneously with a kind of product, solve the problems, such as that different processes must use different products.
Description
Technical field
The present invention relates to cleaning agent technical field, in particular to a kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and its preparation
Method.
Background technique
With the fast development of machinery manufacturing industry, national and some feature of environmental protection department is higher and higher to the attention of environmental protection,
All trades and professions propose more environmental requirements to cleaning industry, are one for cleaning industry and cleaning manufacturing enterprise
Huge challenge, especially machinery manufacturing industry, at present major part machinery manufacturing industry all use the hydrocarbon environment-friendly cleaning agent of solvent type into
No matter row cleaning operation operation has great advantage because solvent type agent for carbon hydrogen detergent is compared with traditional aqueous cleaning agent
It is the processing of subsequent sewage also to be had great advantages simultaneously, after cleaning to environment or all unusual safety of the person
Waste liquid is easy to handle, but popularizing with agent for carbon hydrogen detergent, and major part agent for carbon hydrogen detergent only has cleaning action, product at present
Can be single, unlike traditional aqueous cleaning agent is provided simultaneously with cleaning and rustless property.
Although different processes can satisfy the use demand in client using different products, from production efficiency and
It is said on production cost, there are the following problems:
1, production efficiency is low, and different processes must select different products, and cleaning and antirust process require manual operation,
Waste a large amount of human cost.
2, management is inconvenient, and the management of two or more product needs to consume more manpowers, if management is not
It is mixed when will lead to product.
Though 3, agent for carbon hydrogen detergent Environmental Safety at present, most of product contains nitrite etc. and has antirust agent in the market
Malicious harmful components.
4, in antirust oils product use process there are inflammable and explosive characteristic, the problems such as there are security risks.
5, antirust oils product is easy to happen safety accident during storage because flash-point is lower.
By analysis, the reason of generating the above problem must be selected between different processes different because product category is more
The levels of audit quality of product, antirust process product is uneven, poisonous and harmful, inflammable and explosive.
Summary of the invention
In order to solve problems in the prior art, the present invention provides a kind of highly effective antirust type rings to protect agent for carbon hydrogen detergent and its system
Preparation Method increases rustless property under the premise of guaranteeing the performance of original agent for carbon hydrogen detergent, can greatly improve production
The working efficiency of type enterprise solves the problems, such as cleaning and antirust with a kind of product simultaneously, and solving different processes must be using difference
Product problem.
The technical solution adopted in the present invention is as follows:
A kind of highly effective antirust type ring guarantor agent for carbon hydrogen detergent, constituent include: according to mass percent
N-tetradecane 40% -50%；
Hexadecane 30% -40%；
N-pentadecane 9% -29%；
Dioctylamine 0.4% -0.8%；
RP333H hard film rust preventives 0.2% -0.6%.
A kind of highly effective antirust type ring protects the preparation method of agent for carbon hydrogen detergent, comprising the following steps:
A, solvent reaction kettle is opened under room temperature, and starts the stirring of reaction kettle uniform speed slow preheating 5-10 minutes；
B, it is matched by constituent as claimed in any one of claims 1-3 by n-tetradecane, positive 16 under room temperature
Carbon alkane and n-pentadecane are sequentially placed into solvent reaction kettle, and are started reaction kettle uniform speed slow and stirred 20-30 minutes, stirring
Reaction kettle cover must be covered in the process keeps closed；
C, dioctylamine and RP333H dura mater antirust is added by constituent as claimed in any one of claims 1-3 proportion
Agent is heated in solvent reaction kettle, but temperature must not be higher than 60 degrees Celsius, be further continued for stirring 30-50 minute up to
Solvent clear homogeneous；
D, it takes a small amount of cleaning agent to be placed on highlight with beaker or plastic measuring glass to be observed, solution presents yellowish
When color is transparent.
N-tetradecane, hexadecane and n-pentadecane must distill acquisition repeatedly, and boiling range is in following range:
200-300 DEG C of n-tetradecane；
200-300 DEG C of hexadecane；
200-300 DEG C of n-pentadecane.
Technical solution provided by the invention has the benefit that
By the hydrocarbon environment-friendly cleaning agent of rust-proof type prepared by this method according to Chinese Government and Montreal foundation
" Chinese cleaning industry ODS integrally eliminates plan " signed, China will gradually limit and final thoroughly superseded ODS (destroys ozone
Substance) cleaning agent.The environmental protection in many areas and labour protection department also issue laws and regulations, be forbidden to use methylene chloride,
The poisonous and hazardous halogenated hydrocarbons cleaning agent such as trichloro ethylene.
It is involved in the present invention to agent for carbon hydrogen detergent have the advantage that
1, solvent can volatilize, completely without any residual；
2, ozone substance, harmless to humans is destroyed without ODS；For environmentally friendly solvent, not containing benezene, without halogenated hydrocarbon, be free of
ODS substance.
3, there is extremely strong clean ability, all kinds of dirts such as greasy dirt, moisture, dust can be thoroughly removed；
4, flash-point is more than 93 DEG C, belongs to not dangerous chemicals；It is to substitute the freon very harmful to environment and people, halogenated
The optimal selection of hydrocarbon product.
Since boiling point is above 200 DEG C, the volatilization loss in storage and transportation and use process is minimum.
Since flash-point is more than 93 DEG C, safety is good, can be with applied at elevated temperature, and speed clean in this way is fast, high-efficient.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, make below in conjunction with specific embodiment into one
Step ground detailed description.
Embodiment one
A kind of highly effective antirust type ring guarantor agent for carbon hydrogen detergent, the solvent boiling range of selected each component, content of impurities
And weight proportion is respectively as follows:
Embodiment two
A kind of highly effective antirust type ring guarantor agent for carbon hydrogen detergent, the solvent boiling range of selected each component, content of impurities
And weight proportion is respectively as follows:
Embodiment three
A kind of highly effective antirust type ring protects the preparation method of agent for carbon hydrogen detergent, and step is:
(1) raw material needed for must be executed in strict accordance with standard, and the repeated multiple times distillation of palpus obtains, and required purity requirement is higher,
It must entrust large enterprise (petroleum etc. in such as), spare after the purchasing of raw materials, the existing buying of now production；
(2) solvent special reactor is opened under room temperature, and starts the stirring of reaction kettle uniform speed slow preheating 5-10 minutes；
(3) under room temperature according to the ratio by n-tetradecane, hexadecane and n-pentadecane according to a certain percentage successively
It is put into solvent special reactor, and start reaction kettle uniform speed slow stirring 20-30 minutes (reaction kettle cover must be covered and keep close
It closes)；
(4) dioctylamine and RP333H are added according to the ratio in solvent special reactor, and heats, but temperature must not
Higher than 60 degree, stirring is further continued for 30-50 minutes until solvent clear homogeneous；
(5) it takes a small amount of cleaning agent to be placed on highlight with beaker or plastic measuring glass to be observed, solution presents light
When yellow transparent.
The quality standard of product is as follows:
Appearance: colourless to light yellow transparent liquid
Smell: minor solvent taste
Flash-point (silent), DEG C: >=100
Ozone destruction coefficient: 0.00
Acute oral toxicity (LD50mg/Kg): > 15000
Explosion limit: 0.6-8.0vol%
Hazardous chemical grade: belong to not dangerous chemicals
The mechanism of action of this cleaning agent:
It is to utilize to mix to form environment-friendly type agent for carbon hydrogen detergent with positive carbon alkane first, there is quick capillary humidification
To reducing surface tension, wetting and infiltration dissolution greasy dirt rapidly play efficient cleaning performance, at the same by dioctylamine and
The antirust coat of RP333H composition is adsorbed on workpiece surface, and solvent composition quickly volatilizees, and antirust coat plays the rustless property of overlength.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (5)
1. a kind of highly effective antirust type ring protects agent for carbon hydrogen detergent, constituent includes: according to mass percent
N-tetradecane 40% -50%；
Hexadecane 30% -40%；
N-pentadecane 9% -29%；
Dioctylamine 0.4% -0.8%；
RP333H hard film rust preventives 0.2% -0.6%.
2. a kind of highly effective antirust type ring according to claim 1 protects agent for carbon hydrogen detergent, which is characterized in that the constituent
Include: according to mass percent
N-tetradecane 45%；
Hexadecane 35%；
N-pentadecane 19%；
Dioctylamine 0.4%；
RP333H hard film rust preventives 0.6%.
3. a kind of highly effective antirust type ring according to claim 1 protects agent for carbon hydrogen detergent, which is characterized in that the constituent
Include: according to mass percent
N-tetradecane 50%；
Hexadecane 40%；
N-pentadecane 9%；
Dioctylamine 0.5%；
RP333H hard film rust preventives 0.5%.
4. the preparation method that a kind of highly effective antirust type ring protects agent for carbon hydrogen detergent, comprising the following steps:
A, solvent reaction kettle is opened under room temperature, and starts the stirring of reaction kettle uniform speed slow preheating 5-10 minutes；
B, it is matched by constituent as claimed in any one of claims 1-3 by n-tetradecane, hexadecane under room temperature
And n-pentadecane is sequentially placed into solvent reaction kettle, and is started reaction kettle uniform speed slow and stirred 20-30 minutes, whipping process
In must cover reaction kettle cover keep it is closed；
C, by constituent as claimed in any one of claims 1-3 proportion be added dioctylamine and RP333H hard film rust preventives in
In solvent reaction kettle, and heat, but temperature must not be higher than 60 degrees Celsius, be further continued for stirring 30-50 minutes until solvent
Clear homogeneous；
D, it takes a small amount of cleaning agent to be placed on highlight with beaker or plastic measuring glass to be observed, solution presents faint yellow
When bright.
5. the preparation method that a kind of highly effective antirust type ring according to claim 4 protects agent for carbon hydrogen detergent, which is characterized in that institute
N-tetradecane, hexadecane and the n-pentadecane stated must distill acquisition repeatedly, and boiling range is in following range:
200-300 DEG C of n-tetradecane；
200-300 DEG C of hexadecane；
200-300 DEG C of n-pentadecane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710989132.5A CN109694785A (en) | 2017-10-22 | 2017-10-22 | A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710989132.5A CN109694785A (en) | 2017-10-22 | 2017-10-22 | A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109694785A true CN109694785A (en) | 2019-04-30 |
Family
ID=66226575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710989132.5A Pending CN109694785A (en) | 2017-10-22 | 2017-10-22 | A kind of highly effective antirust type ring protects agent for carbon hydrogen detergent and preparation method thereof |
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| Country | Link |
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| CN (1) | CN109694785A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110306197A (en) * | 2019-07-26 | 2019-10-08 | 东莞市麦克莱恩新材料有限公司 | A kind of rust-proof type agent for carbon hydrogen detergent and preparation method thereof |
| CN112760663A (en) * | 2021-01-22 | 2021-05-07 | 宁波莱昂德尔化工科技有限公司 | Special hydrocarbon cleaning agent with strong cleaning power for environment-friendly heat exchanger parts |
| CN113583761A (en) * | 2021-08-11 | 2021-11-02 | 诺而曼环保科技（江苏）有限公司 | High-protection corrosion-resistant hydrocarbon cleaning agent for semiconductor cleaning and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0925497A (en) * | 1995-07-11 | 1997-01-28 | Nitto Chem Ind Co Ltd | Detergent for wax and water-soluble processing solution |
| JP4069466B2 (en) * | 2002-02-04 | 2008-04-02 | 小林製薬株式会社 | Yani dirt cleaning composition |
| CN101591590A (en) * | 2008-05-28 | 2009-12-02 | 天津市华阳新兴科技有限公司 | A kind of environmental protection and safety type hydrocarbon cleaning agent |
| CN105297058A (en) * | 2015-11-09 | 2016-02-03 | 广东新球清洗科技股份有限公司 | Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application |
| KR101653336B1 (en) * | 2013-05-28 | 2016-09-01 | 제일모직주식회사 | Rinse solution for polyhydrosiloxazane thin film and method of patterning polyhydrosiloxazane thin film using the same |
-
2017
- 2017-10-22 CN CN201710989132.5A patent/CN109694785A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0925497A (en) * | 1995-07-11 | 1997-01-28 | Nitto Chem Ind Co Ltd | Detergent for wax and water-soluble processing solution |
| JP4069466B2 (en) * | 2002-02-04 | 2008-04-02 | 小林製薬株式会社 | Yani dirt cleaning composition |
| CN101591590A (en) * | 2008-05-28 | 2009-12-02 | 天津市华阳新兴科技有限公司 | A kind of environmental protection and safety type hydrocarbon cleaning agent |
| KR101653336B1 (en) * | 2013-05-28 | 2016-09-01 | 제일모직주식회사 | Rinse solution for polyhydrosiloxazane thin film and method of patterning polyhydrosiloxazane thin film using the same |
| CN105297058A (en) * | 2015-11-09 | 2016-02-03 | 广东新球清洗科技股份有限公司 | Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110306197A (en) * | 2019-07-26 | 2019-10-08 | 东莞市麦克莱恩新材料有限公司 | A kind of rust-proof type agent for carbon hydrogen detergent and preparation method thereof |
| CN112760663A (en) * | 2021-01-22 | 2021-05-07 | 宁波莱昂德尔化工科技有限公司 | Special hydrocarbon cleaning agent with strong cleaning power for environment-friendly heat exchanger parts |
| CN113583761A (en) * | 2021-08-11 | 2021-11-02 | 诺而曼环保科技（江苏）有限公司 | High-protection corrosion-resistant hydrocarbon cleaning agent for semiconductor cleaning and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190430 |
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| RJ01 | Rejection of invention patent application after publication |