CN102330106A - Environment-friendly type cleaning water cutting agent and preparation method thereof as well as displacer for same - Google Patents

Environment-friendly type cleaning water cutting agent and preparation method thereof as well as displacer for same Download PDF

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Publication number
CN102330106A
CN102330106A CN201110256383A CN201110256383A CN102330106A CN 102330106 A CN102330106 A CN 102330106A CN 201110256383 A CN201110256383 A CN 201110256383A CN 201110256383 A CN201110256383 A CN 201110256383A CN 102330106 A CN102330106 A CN 102330106A
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environment
displacer
friendly type
aqua
cut
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CN201110256383A
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CN102330106B (en
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朱国梅
王旭明
黄勤国
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Huayang Xinxing Science And Technology (tianjin) Group Co Ltd
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Huayang Xinxing Science And Technology (tianjin) Group Co Ltd
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Abstract

The invention relates to an environment-friendly type cleaning water cutting agent and a preparation method thereof as well as a displacer for the same. The environment-friendly type cleaning water cutting agent comprises the following components calculated according to weight percentage: 95-98 percent of solvent and 2-5 percent of displacer, wherein the displacer comprises the following components calculated according to weight percentage: 1-5 percent of alcohols solvents, 20-30 percent of filming amine, 30-40 percent of organic carboxylic acid, 0.3-0.8 percent of emulsion splitter and hydrocarbon solvent of which the amount is supplemented to 100 percent. The preparation method is realized by sequentially mixing various components. The environment-friendly type cleaning water cutting agent disclosed by the invention has strong cleaning function; more importantly, the environment-friendly type cleaning water cutting agent can be used for quickly removing water brought by a previous work procedure for cleaning parts; and the removed water is deposited at the bottom of a cleaning agent and is drained through the bottom of a rinse tank by using a pollution discharge mode, thus the service life of the cleaning agent is prolonged by over 3 months.

Description

A kind of environment-friendly type is cleaned and is cut aqua and preparation method thereof and used displacer
Technical field
The invention belongs to the matting field, especially a kind of environment-friendly type is cleaned and is cut aqua and preparation method thereof and used displacer.
Background technology
The cleaning of metallic element is exactly to wash all contaminations that Industrial products receive in production, use and storage process off.The accuracy requirement that traditional machine parts cleans is not high, has water mark or a spot of pollution insensitive yet.Along with the development and the continuous progress in science and technology of producing, also increasingly high with requirement to performance of products, safety is also more and more tighter.Relatively working accuracy, the size control to part also improving constantly; The particularly appearance of high-tech product such as precision optical machinery and electronics, microelectronics; Product is constantly developed to high-performance, high reliability, high integration and microminiaturized direction, make product very responsive pollutent.Clean-out system is residual to influence outward appearance with the water mark and conventional clean often has; Therefore an urgent demand must have high cleanliness to guarantee; Promptly require cleanliness factor to reach the level of micron, submicron, molecular level; Product after requiring to clean can not have the residual of clean-out system, water mark, and the workpiece after the washing can't get rusty.
Summary of the invention
The objective of the invention is to overcome the weak point of prior art; Provide a kind of quick, safely a kind of completely environment-friendly type to clean and cut aqua and preparation method thereof and used displacer; Use this environment-friendly type to clean to cut workpiece after aqua cleans to take off residual moisture in 2-3min; Solvent volatilizees naturally, and workpiece surface also has certain rust-preventing characteristic.
The objective of the invention is to realize through following technical scheme:
A kind of environment-friendly type is cleaned and is cut the used displacer of aqua, and it constitutes component and weight percent is:
And said alcoholic solvent comprises one of 3-methyl-3 methoxyl group-1 butanols, positive ten alcohol, enanthol or the mixture that both are above.
And said filming amine comprises that amino dodecane, coco amine, cetylamine, 2-methylbutylamine, Di-Octyl amine also are N, one of N-two (methylheptyl) amine or the mixture that both are above.
And said organic carboxyl acid comprises one of ten carbonic acid, sad, lauric acid or mixtures that both are above.
And said emulsion splitter comprises the polyether glycol class, the mixture of one of reactant of alkylphenol block polyether or polyoxyethylene polyoxypropylene block polyether and fatty amidogen ether or two reactants.
And, positive structure or the isoparaffin of the boiling range of said hydrocarbon solvent between 140-190 ℃.
And said hydrocarbon solvent comprises one of positive structure and isoparaffin or both above mixtures of positive structure and isoparaffin, the carbon 11 of positive structure and isoparaffin, the carbon nine of carbon ten.
A kind of environment-friendly type is cleaned and is cut aqua, and it constitutes component and weight percent is: contain the 2-5% displacer, add the 95-98% solvent again.
And said solvent comprises one of 3-methyl-3 methoxyl group-1 butanols, positive ten alcohol, enanthol or the mixture that both are above.
A kind of environment-friendly type is cleaned the preparation method who cuts aqua, and the step of preparation is following:
(1) preparation displacer: hydrocarbon solvent is added among the reaction kettle A, add filming amine, alcoholic solvent more respectively, under agitation add organic carboxyl acid, keep 40-50 ℃ of temperature of reaction, react and add emulsion splitter after 1-3 hour, the transparent liquid that stirs is displacer;
(2) in reaction kettle B, add solvent, add displacer again and stir, process the environment-friendly type cleaning and cut aqua.
Advantage of the present invention and beneficial effect are:
1, environment-friendly type of the present invention is cleaned the simple science of the mechanism of action of cutting aqua, does not contain deleterious hydrochloric ether of human and environment and aromatic hydrocarbons, and is safe in utilization to the people, to not corrosion of workpiece.
2, this environment-friendly type is cleaned and to be cut aqua and contain filming amine; Filming amine can be adsorbed on workpiece surface uniformly, makes that the component after the dehydration have certain antirust ability, the high baking operation of its alternative power consumption; Antirust operation together can be reduced, the cost of machining manufacturing enterprise can be reduced.
3, this environment-friendly type is cleaned and to be cut the synergy of each component in the aqua and make water on the workpiece be pearl to tumble that greasy dirt dissolves rapidly, workpiece surface light as new.
4, the present invention is except having strong clean ability; The more important thing is it can remove rapidly preceding road clean the component operation with moisture; The deposit of moisture of taking off is in the bottom of clean-out system; Mode through blowdown is got rid of from the bottom of rinse bath, and reach more than 3 months the work-ing life that prolongs clean-out system.
5, the preparation method who the present invention relates to is simple, and raw materials used wide material sources obtain easily, are highly suitable for large-scale industrial production, and operational safety is easy to use.
Embodiment
Below in conjunction with embodiment, the present invention is further specified, following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
The raw material of the embodiment of the invention is marketable material.
Embodiment 1:
The used displacer of aqua is cut in a kind of cleaning, and its composition and weight are following:
Figure BDA0000088328310000021
This emulsion splitter is a polyether glycol.
Emulsion splitter is the big ltd in blue star east, Shandong for commercially available prod manufacturing enterprise, model EP553
A kind of environment-friendly type is cleaned and is cut aqua, and its composition and weight are following: (is example with the 1000g product):
Pure carbon ten content 99.5% proportioning 960g
Displacer 40g
The step that a kind of environment-friendly type is cleaned the preparation method who cuts aqua is following:
(1) preparation of displacer: the 13g hydrocarbon solvent is added among the reaction kettle A, add ten pure 0.8g and coco amine 10g and stir, under agitation slowly add sad 16g, kept 40 ℃-50 ℃ of temperature 2 hours, adding emulsion splitter 0.2g stirs and is displacer.
(2) environment-friendly type is cleaned the preparation of cutting aqua: in reaction kettle B, add pure carbon ten solvent 960g respectively, add displacer 40g again and be these article.
Embodiment 2:
The used displacer of aqua is cut in a kind of cleaning, and its composition and weight are following:
Displacer is formed
Figure BDA0000088328310000031
A kind of environment-friendly type is cleaned and is cut aqua, and its composition and weight are following: (is example with the 1000g product):
The isoparaffin of carbon ten: content 99.5% proportioning 950g
Displacer: proportioning 50g.
The step of its preparation method is same as embodiment 1.
The mechanism of action of the present invention:
Form a kind of new surfactant through the reaction of filming amine and organic carboxyl acid, it is extremely strong with the adsorptive power of metallic surface, under the synergy of alcohol, ether material, falls in the solvent the water of metallic surface is crowded, and the globule is peeled off rapidly.Emulsion splitter makes the profit sharp separation, and water tumbles the solution bottom rapidly in solvent, reaches the purpose of dehydration, and the film of the absorption on the metallic surface has certain antirust ability, keeps workpiece at the short period of time non-corrosive.
This environment-friendly type is cleaned and is cut aqua application example 1:
Contain punching oil after the phone housing punching press; Wash right 2 times with tap water again after using the aqueous cleaning agent oil removing, put the workpiece side of whole basket in the environment-friendly type cleaning of instance 1 and cut static 1min in the aqua, shake up and down 2 times; Static again 1min, the water beading on the workpiece falls.Workpiece gets into road packaging process down.
This environment-friendly type is cleaned and is cut aqua application example 2:
Steel test specimen after cutting; After spray and ultrasonic cleaning, remove cutting fluid and the greasy dirt on the test specimen, put static 1min in the product of embodiment 1, ultrasonic vibration 2min with the rear of tap water rinsing, pure water rinsing again; Temperature: 40-50 ℃; Leave standstill 1min, mention and leave standstill 1-3min again, be transported to down operation.
Conclusion: dehydration is rapid, and workpiece is sparkling clean, and anhydrous mark is residual.
This environment-friendly type is cleaned and is cut the aqua quality standard:
Outward appearance: colourless transparent liquid
Density: 0.73-0.75 (g/100ml)
Working concentration: stoste
Rust-preventing characteristic (35 ℃, RH90%, Z30 cast iron) is not less than 24 hours.

Claims (10)

1. an environment-friendly type is cleaned and cut the used displacer of aqua, it is characterized in that: it constitutes component and weight percent is:
2. environment-friendly type according to claim 1 is cleaned and cut the used displacer of aqua, it is characterized in that: said alcoholic solvent comprises one of 3-methyl-3 methoxyl group-1 butanols, positive ten alcohol, enanthol or the mixture that both are above.
3. environment-friendly type according to claim 1 is cleaned and is cut the used displacer of aqua; It is characterized in that: said filming amine comprises that amino dodecane, coco amine, cetylamine, 2-methylbutylamine, Di-Octyl amine also are N, one of N-two (methylheptyl) amine or the mixture that both are above.
4. environment-friendly type according to claim 1 is cleaned and cut the used displacer of aqua, it is characterized in that: said organic carboxyl acid comprises one of ten carbonic acid, sad, lauric acid or both above mixtures.
5. environment-friendly type according to claim 1 is cleaned and is cut the used displacer of aqua, and it is characterized in that: said emulsion splitter comprises the mixture of one of reactant of alkylphenol block polyether or polyoxyethylene polyoxypropylene block polyether and Fatty Alcohol(C12-C14 and C12-C18) or two reactants.
6. environment-friendly type according to claim 1 is cleaned and is cut the used displacer of aqua, it is characterized in that: positive structure or the isoparaffin of the boiling range of said hydrocarbon solvent between 140-190 ℃.
7. environment-friendly type according to claim 6 is cleaned and cut the used displacer of aqua, it is characterized in that: said hydrocarbon solvent comprises one of positive structure and isoparaffin or mixtures more than both of positive structure and isoparaffin, the carbon 11 of positive structure and isoparaffin, the carbon nine of carbon ten.
8. aqua is cut in an environment-friendly type cleaning that comprises the said displacer of claim 1, and it is characterized in that: it constitutes component and weight percent is: contain the 2-5% displacer, add the 95-98% solvent again.
9. environment-friendly type according to claim 8 is cleaned and cut aqua, it is characterized in that: said solvent comprises one of 3-methyl-3 methoxyl group-1 butanols, positive ten alcohol, enanthol or the mixture that both are above.
10. an environment-friendly type as claimed in claim 8 is cleaned the preparation method who cuts aqua, and it is characterized in that: the step of preparation is following:
(1) preparation displacer: hydrocarbon solvent is added among the reaction kettle A, add filming amine, alcoholic solvent more respectively, under agitation add organic carboxyl acid, keep 40-50 ℃ of temperature of reaction, react and add emulsion splitter after 1-3 hour, the transparent liquid that stirs is displacer;
(2) in reaction kettle B, add solvent, add displacer again and stir, process the environment-friendly type cleaning and cut aqua.
CN 201110256383 2011-09-01 2011-09-01 Environment-friendly type cleaning water cutting agent and preparation method thereof as well as displacer for same Expired - Fee Related CN102330106B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105008589A (en) * 2013-03-01 2015-10-28 通用电气公司 Compositions and methods for inhibiting corrosion in gas turbine air compressors
CN105297058A (en) * 2015-11-09 2016-02-03 广东新球清洗科技股份有限公司 Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application
CN106367220A (en) * 2016-08-24 2017-02-01 诺而曼环保科技(江苏)有限公司 Water replacement additive used in hydrocarbon cleaning agent, and preparation and use methods of same
CN108531314A (en) * 2018-04-20 2018-09-14 广东红日星实业有限公司 Aqua and preparation method thereof is cut in environmental protection
CN108658381A (en) * 2018-05-31 2018-10-16 西安石油大学 A kind of waste acidifying liquid in oil field processing method
CN110055140A (en) * 2019-05-28 2019-07-26 马鞍山华之杰金属表面处理剂有限公司 It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof
CN110408943A (en) * 2019-07-09 2019-11-05 江西瑞思博新材料有限公司 The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning
CN112010773A (en) * 2020-08-18 2020-12-01 深圳市辛骏翔科技有限公司 Dehydrating agent and preparation method thereof, and hydrocarbon water cutting agent and preparation method thereof
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

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CN1171131A (en) * 1994-12-22 1998-01-21 亨凯尔公司 Cleaning and conditioning method for formed metal surfaces
US6280527B1 (en) * 1998-06-12 2001-08-28 International Business Machines Corporation Aqueous quaternary ammonium hydroxide as a screening mask cleaner
CN1856566A (en) * 2003-11-11 2006-11-01 日华化学株式会社 Antirust oil water separation type detergent composition and method of cleaning
CN102312247A (en) * 2011-04-26 2012-01-11 东莞市安美润滑科技有限公司 General aqueous cleaning solution for non-ferrous metals

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CN1171131A (en) * 1994-12-22 1998-01-21 亨凯尔公司 Cleaning and conditioning method for formed metal surfaces
US6280527B1 (en) * 1998-06-12 2001-08-28 International Business Machines Corporation Aqueous quaternary ammonium hydroxide as a screening mask cleaner
CN1856566A (en) * 2003-11-11 2006-11-01 日华化学株式会社 Antirust oil water separation type detergent composition and method of cleaning
CN102312247A (en) * 2011-04-26 2012-01-11 东莞市安美润滑科技有限公司 General aqueous cleaning solution for non-ferrous metals

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105008589A (en) * 2013-03-01 2015-10-28 通用电气公司 Compositions and methods for inhibiting corrosion in gas turbine air compressors
US9758877B2 (en) 2013-03-01 2017-09-12 General Electric Company Compositions and methods for inhibiting corrosion in gas turbine air compressors
CN105008589B (en) * 2013-03-01 2017-09-22 通用电气公司 Composition and method for suppressing the corrosion in gas turbine air compressor
CN105297058A (en) * 2015-11-09 2016-02-03 广东新球清洗科技股份有限公司 Environment-friendly easily-rinsed easily-cleaned water draining agent and preparation method thereof and application
CN106367220A (en) * 2016-08-24 2017-02-01 诺而曼环保科技(江苏)有限公司 Water replacement additive used in hydrocarbon cleaning agent, and preparation and use methods of same
CN108531314A (en) * 2018-04-20 2018-09-14 广东红日星实业有限公司 Aqua and preparation method thereof is cut in environmental protection
CN108658381A (en) * 2018-05-31 2018-10-16 西安石油大学 A kind of waste acidifying liquid in oil field processing method
CN110055140A (en) * 2019-05-28 2019-07-26 马鞍山华之杰金属表面处理剂有限公司 It is a kind of to replace aqueous cleaning multiple-effect agent for carbon hydrogen detergent and preparation method thereof
CN110408943A (en) * 2019-07-09 2019-11-05 江西瑞思博新材料有限公司 The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning
CN110408943B (en) * 2019-07-09 2021-07-23 江西瑞思博新材料有限公司 Cleaning solution cutting agent for replacing water rinsing after hard surface cleaning and preparation method thereof
CN112010773A (en) * 2020-08-18 2020-12-01 深圳市辛骏翔科技有限公司 Dehydrating agent and preparation method thereof, and hydrocarbon water cutting agent and preparation method thereof
CN114277382A (en) * 2021-12-29 2022-04-05 泰伦特生物工程股份有限公司 Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof

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