CN110408943A - The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning - Google Patents
The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning Download PDFInfo
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- CN110408943A CN110408943A CN201910615882.5A CN201910615882A CN110408943A CN 110408943 A CN110408943 A CN 110408943A CN 201910615882 A CN201910615882 A CN 201910615882A CN 110408943 A CN110408943 A CN 110408943A
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- agent
- cleaning
- cleaning solution
- hard surface
- water rinsing
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention provides a kind of cleaning solution excision agent and preparation method thereof of substitution water rinsing after hard surface cleaning, including following quality than component: alkane solvent, D100 hydrocarbon solvent, Span, polyoxyethylene polyoxypropylene is poly- to wait composition, it can need to remove surface such as LCD frame to various, wafer body, optical mirror slip, plated item, silicon wafer, the cleaning solution and moisture content of remained on surface or attachment after precision machinery processing cleaned dose of metal parts surface cleaning are effectively cut off, there is rust prevention during manufacture effect simultaneously, product is free of strong acid salt, manufacture craft is simple, it is at low cost, odorlessness, effect is good, effluent no pollution to the environment.
Description
Technical field:
The invention belongs to industrial cleaning agent fields in terms of fine chemistry industry, are related to a kind of for substituting the hard surface cleaning of water rinsing
Liquid substitutes the cleaning solution excision agent and its preparation side that water rinses after cutting off agent and preparation method more particularly to a kind of hard surface cleaning
Method.
Background technique:
There are many product category type of cleaning agent currently on the market, and the cleaning agent of daily life is even more innumerable, together
The cleaning agent that sample is applied to connection metal is also more, after the cleaning to hard surface such as metal surface greasy dirt, it is also necessary to cleaning
The remaining cleaning agent of metal surface afterwards is washed, and the mode for usually reusing water rinsing cleans removal to it again.
But metal surface metallic surface Yi Sheng again again when using water rinsed surfaces cleaning solution after waterborne cleaning agent clean the surface greasy dirt
Rust, oxidation, discoloration and the cleaning agent residual for still having part in metal surface simultaneously;Besides to precisions such as optics, LCD
Instrument cannot carry out cleaning agent being thoroughly rinsed clean etc. when being rinsed after cleaning using cleaning agent with water.
How to provide the cleaning solution of substitution water rinsing after a kind of especially metal cleaner cleaning of hard surface agent is cut off,
Surface such as LCD frame, wafer body, optical mirror slip, plated item, silicon wafer, precision machinery processing metal can be needed to remove to various
The cleaning solution and moisture content of remained on surface or attachment after cleaned dose of component surface cleaning are effectively cut off.And have
Good volatility, the rate of drying of workpiece, which is exceedingly fast, after cleaning solution excision to volatilize fastly than water, and can favorably reduce baking process
Time;It is produced to solve poaching wastewater processing and the cleaning solution excision agent of substitution water rinsing after the hard surface cleaning of emission problem
Product.
Summary of the invention:
The present invention provides a kind of cleaning solution excision agent and preparation method thereof of substitution water rinsing after hard surface cleaning, can be right
It is various to need to remove surface such as LCD frame, wafer body, optical mirror slip, plated item, silicon wafer, precision machinery processing zero, metal
The cleaning solution and moisture content of remained on surface or attachment after the cleaning of cleaned dose of part surface are effectively cut off, while having process
Between rust-proof effect, product be free of strong acid salt, manufacture craft is simple, and at low cost, odorlessness, effect is good, and effluent is to environment without dirt
Dye.
The cleaning solution that water rinsing is substituted after a kind of hard surface cleaning disclosed by the invention cuts off agent, including following mass ratio group
Point:
Alkane solvent 86-92%,
D100 hydrocarbon solvent 5-8%,
Span 0.6-1.5%,
Polyoxyethylene polyoxypropylene polyethers 0.3-0.7%,
Diethylene glycol monobutyl ether or polyalcohol or its compound 2-4%.
The cleaning solution that water rinsing is substituted after a kind of hard surface cleaning of the present invention cuts off agent, and it is molten to control the alkane
Agent is isoparaffin or normal alkane solvent, and the flash-point for controlling isoparaffin or normal alkane solvent is 50-70 degree.
It preferably, is the flash-point 90-110 degree for controlling the D100 hydrocarbon solvent.
Further, be the Span be sorbitan fatty acid ester.
Another object of the present invention substitutes the preparation that the cleaning solution that water rinses cuts off agent after realizing the hard surface cleaning
Method carries out as follows:
1), under normal temperature conditions, by Span or sorbitan fatty acid ester, polyoxyethylene polyoxypropylene
Polyethers sequentially adds in diethylene glycol monobutyl ether or polyalcohol or its compound, and stirring and dissolving is uniformly mixed liquor;
2), then D100 hydrocarbon solvent stirring and dissolving is added into the mixed liquor of 1) step, be eventually adding isoparaffin or
Normal alkane solvent, and constantly stirring and dissolving is uniform, filling is product.
The cleaning solution that water rinsing is substituted after hard surface cleaning of the present invention cuts off agent, substitutes after having filled up domestic hard surface cleaning
The cleaning solution of water rinsing cuts off agent blank, on the one hand solves steel, copper, aluminium and its alloy metalloid and cleans through waterborne cleaning agent
Easily get rusty, aoxidize when after surface and oil contaminant with water rinsed surfaces cleaning solution, changing colour and cleaning agent residual etc. technical problems, on the other hand
Also it is rinsed with water after solving the precision cleanings such as optics, LCD and clean cleaning technique problem cannot be thoroughly rinsed, through the present invention
Excision agent processing after the bright and clean seamless, immaculate of workpiece surface, the grey point that clean.Also specific advantage is as follows simultaneously:
First is that product of the present invention is suitable for the various occasions for needing to remove surface moisture and cleaning solution, such as LCD frame, crystalline substance
Remained on surface after first body, optical mirror slip, plated item, silicon wafer, precision machinery processing cleaned dose of metal parts surface cleaning
Or the cleaning solution and moisture content of attachment;
Second is that there is product excellent cleaning agent to replace performance, while also have excellent water substituting energy, and replace speed
Degree is fast, permeability is strong, and cleaning solution and moisture in minimum gap can also thoroughly be cut off;
Third is that product has good volatility, the rate of drying of workpiece is exceedingly fast (faster than water volatilization) after cleaning solution excision,
It is advantageous to reduce the baking process time;
Fourth is that due to the product be substitute water rinsing excision agent, cleaning process be not necessarily to use water, to solve rinsing
Wastewater treatment and emission problem;
Fifth is that product is environmentally friendly non-aqueous solvent type complexing agent, use process waste liquid amount is seldom generated, and the waste liquid of generation is only
For the cleaning agent composition that excision agent scales off, it only need to often add excision agent and be used to supplement the loss in use process.Together
When product of the invention be that odorlessness, flash-point are high, nonflammable, use is safe and nontoxic.
Stability: observation solution delamination after composition prepared by the present invention is placed 4-6 hour, stabilize to it is not stratified,
Not muddy, shakiness is set to layering or muddiness.
Product of the present invention is detected through Institute of Analysis, Jiangxi Province, and all technical reaches requirement, and every technology refers to
It marks as follows.
Table 1
Appearance | It is colourless to light yellow transparent liquid |
Boiling range (DEG C) | 160~210 |
Density (20 DEG C, g/cm3) | 0.72~0.78 |
Physical stability | It is precipitated without precipitating, without layering, nodeless mesh object |
Nonvolatile matter | Nothing |
Flash-point DEG C | ≥50 |
Poisonous and harmful inspection | Nothing |
Illustrate: 1, the corrosivity (40 DEG C ± 2 DEG C) of product of the present invention, 45 ﹟ steel discs, 0 grade of 4h,
0 grade of duralumin LY12,2h,
0 grade of brass H62,2h;
2, product of the present invention stability is good, and the holding time is long, and cleaning efficiency is high;
Product of the present invention reaches requirement through detecting indices.
Specific embodiment: below with reference to embodiment, the present invention is described in further detail.
Embodiment: as follows
Illustrate: diethylene glycol monobutyl ether or polyalcohol or its compound of the present invention can be diethylene glycol mono butyl
Ether or polyalcohol or polyalcohol and its compound diethylene glycol monobutyl ether and its compound or diethylene glycol list
Butyl ether and polyalcohol and its compound etc.;Above-mentioned each component of the invention is commercially available.
The various embodiments described above of the invention can be prepared by following methods: it carries out as follows:
1), under normal temperature conditions, by Span or sorbitan fatty acid ester, polyoxyethylene polyoxypropylene
Polyethers sequentially adds in diethylene glycol monobutyl ether or polyalcohol or its compound, and stirring and dissolving is uniformly mixed liquor;
2), then D100 hydrocarbon solvent stirring and dissolving is added into the mixed liquor of 1) step, be eventually adding isoparaffin or
Normal alkane solvent, and constantly stirring and dissolving is uniform, filling is product.
Technical characteristic in the present invention without description can realize that details are not described herein by or using the prior art.When
So, the above description is not a limitation of the present invention, and the present invention is also not limited to above embodiment, the common skill of this field
The variations, modifications, additions or substitutions that art personnel are made within the essential scope of the present invention also should belong to protection model of the invention
It encloses.
Claims (5)
1. the cleaning solution for substituting water rinsing after a kind of hard surface cleaning cuts off agent, including following quality is than component:
Alkane solvent 86-92 %,
D100 hydrocarbon solvent 5-8 %,
Span 0.6-1.5 %,
Polyoxyethylene polyoxypropylene polyethers 0.3-0.7 %,
Diethylene glycol monobutyl ether or polyalcohol or its compound 2-4 %.
2. the cleaning solution for substituting water rinsing after a kind of hard surface cleaning according to claim 1 cuts off agent, it is characterized in that control
Making the alkane solvent is isoparaffin or normal alkane solvent, and the flash-point for controlling isoparaffin or normal alkane solvent is 50-
70 degree.
3. the cleaning solution for substituting water rinsing after a kind of hard surface cleaning according to claim 1 cuts off agent, it is characterized in that control
Make the flash-point 90-110 degree of the D100 hydrocarbon solvent.
4. the cleaning solution for substituting water rinsing after a kind of hard surface cleaning according to claim 1 cuts off agent, it is characterized in that institute
Stating Span is sorbitan fatty acid ester.
5. the preparation method of the cleaning solution excision agent of water rinsing is substituted after a kind of hard surface cleaning as claimed in claim 1 or 2,
It is characterized in that carrying out as follows:
1), under normal temperature conditions, Span or sorbitan fatty acid ester, polyoxyethylene polyoxypropylene are gathered
Ether sequentially adds in diethylene glycol monobutyl ether or polyalcohol or its compound, and stirring and dissolving is uniformly mixed liquor;
2) D100 hydrocarbon solvent stirring and dissolving then, is added into the mixed liquor of 1) step, is eventually adding isoparaffin or positive structure
Alkane solvent, and constantly stirring and dissolving is uniform, filling is product.
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CN201910615882.5A CN110408943B (en) | 2019-07-09 | 2019-07-09 | Cleaning solution cutting agent for replacing water rinsing after hard surface cleaning and preparation method thereof |
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CN201910615882.5A CN110408943B (en) | 2019-07-09 | 2019-07-09 | Cleaning solution cutting agent for replacing water rinsing after hard surface cleaning and preparation method thereof |
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CN110408943A true CN110408943A (en) | 2019-11-05 |
CN110408943B CN110408943B (en) | 2021-07-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2119646A1 (en) * | 1991-09-24 | 1993-04-01 | Felipe A. Donate | Semi-aqueous cleaning process and solvent compositions |
CN102330106A (en) * | 2011-09-01 | 2012-01-25 | 华阳新兴科技(天津)集团有限公司 | Environment-friendly type cleaning water cutting agent and preparation method thereof as well as displacer for same |
CN102747380A (en) * | 2011-04-19 | 2012-10-24 | 上海九盛实业有限公司 | Environmentally-friendly cleaning agent and preparation method thereof |
CN107541741A (en) * | 2017-08-29 | 2018-01-05 | 天津普罗米新材料有限公司 | A kind of alkane cleaning agent for substituting washing |
CN108998296A (en) * | 2018-09-11 | 2018-12-14 | 深圳市港联化工有限公司 | A kind of high-flash agent for carbon hydrogen detergent and preparation method thereof that removal gap is dirty |
CN109504563A (en) * | 2018-12-31 | 2019-03-22 | 广东新球清洗科技股份有限公司 | Agent for carbon hydrogen detergent is used in cutting fluid removing |
-
2019
- 2019-07-09 CN CN201910615882.5A patent/CN110408943B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2119646A1 (en) * | 1991-09-24 | 1993-04-01 | Felipe A. Donate | Semi-aqueous cleaning process and solvent compositions |
CN102747380A (en) * | 2011-04-19 | 2012-10-24 | 上海九盛实业有限公司 | Environmentally-friendly cleaning agent and preparation method thereof |
CN102330106A (en) * | 2011-09-01 | 2012-01-25 | 华阳新兴科技(天津)集团有限公司 | Environment-friendly type cleaning water cutting agent and preparation method thereof as well as displacer for same |
CN107541741A (en) * | 2017-08-29 | 2018-01-05 | 天津普罗米新材料有限公司 | A kind of alkane cleaning agent for substituting washing |
CN108998296A (en) * | 2018-09-11 | 2018-12-14 | 深圳市港联化工有限公司 | A kind of high-flash agent for carbon hydrogen detergent and preparation method thereof that removal gap is dirty |
CN109504563A (en) * | 2018-12-31 | 2019-03-22 | 广东新球清洗科技股份有限公司 | Agent for carbon hydrogen detergent is used in cutting fluid removing |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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