CN109504563A - Agent for carbon hydrogen detergent is used in cutting fluid removing - Google Patents
Agent for carbon hydrogen detergent is used in cutting fluid removing Download PDFInfo
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- CN109504563A CN109504563A CN201811654898.9A CN201811654898A CN109504563A CN 109504563 A CN109504563 A CN 109504563A CN 201811654898 A CN201811654898 A CN 201811654898A CN 109504563 A CN109504563 A CN 109504563A
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- cutting fluid
- ether
- compound
- carbon hydrogen
- hydrocarbon
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/241—Hydrocarbons linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/24—Hydrocarbons
- C11D7/242—Hydrocarbons branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention provides a kind of cutting fluid removing agent for carbon hydrogen detergent, including following component by weight percentage: hydrocarbon 50~70%；Alcohol ethers compound 10~25%；Ester ether compound 10~20%；Ethyl lactate 1~10%.Hydrocarbon, alcohol ethers compound, ester ether compound combine the base oil and oiliness function additive that can remove in cutting fluid；Alcohol ethers compound and ester ether compound can dissolve each other and can increase solubility of the ethyl lactate in hydrocarbon；The carbochain of ethyl lactate is shorter and has the extremely strong hydroxyl of hydrophily and ester group, can wetted workpieces surface well cutting fluid, there is extremely strong solvability to the water-soluble stains in cutting fluid, meanwhile the molecule overall structure of ethyl lactate is smaller, and has hydroxyl in the chiral carbon of small molecule, thus there is good permeability, it can penetrate into cutting fluid and disperse cutting fluid, under the collective effect of ethyl lactate and other solvents, cutting fluid can be made to elute from workpiece surface.
Description
Technical field
The present invention relates to a kind of cleaning agents more particularly to a kind of removing of cutting fluid to use agent for carbon hydrogen detergent.
Background technique
Cutting fluid (cutting fluid, coolant) is a kind of in metal cutting, mill process, for cooling down
With lubrication cutter and workpiece industrial type fluid, have good cooling performance, greasy property, rustless property, anti-corrosion function,
Easily dilutable feature.The defect for overcoming easy smelly, the winter difficult dilution of traditional tradition soap base emulsion summer, rust-proof effect difference, to lathe
Paint also has no adverse effects, and suitable for the cutting and mill processing of ferrous metal, belongs to current most leading abrasive product.Cutting fluid is every
Index is superior to saponified oil, it has the characteristics that good lubrication, antirust, and have it is nontoxic, tasteless, to human body without invading
Erosion, to equipment burn into does not pollute environment the features such as.
Cutting fluid is generally by base oil and a variety of super strong functional auxiliary agents (such as antirust agent, the agent of non-ferrous metal corrosion and passivation, defoaming
Agent etc.) it all can be on workpiece usually after carrying out cutting fluid processing to workpiece through water-soluble metalworking liquid made of science compounding
Remain some water-soluble metalworking liquids.The workpiece after processing through cutting fluid is first being cut water solubility with high pressure water cleaning at present
Water-solubility function auxiliary agent in liquid is removed, and is reused and is cut remaining high pressure water on aqua removing workpiece, is finally cleaned using oil base
The base oil and oiliness function additive in water-soluble metalworking liquid are removed in agent.The cleaning of high pressure water is bound to cause the serious row of waste water
It puts, thus does not meet the development trend for the energy-saving and emission-reduction advocated at present, and the removing of cutting fluid relates to more process, no
Conducive to the raising of processing efficiency, while the removing of a variety of oiliness components also proposed the exploitation of oil base cleaning agent in cutting fluid
Higher requirement.
Therefore it provides not only can effectively be removed to cutting fluid, but can meet energy-saving and emission-reduction, environmental protection demand for development it is clear
Lotion is the difficult point and hot spot of current cutting fluid removing agent for carbon hydrogen detergent research.
Summary of the invention
It is the present invention is intended to provide a kind of cutting fluid, which is removed, uses agent for carbon hydrogen detergent, i.e., a kind of to remove the clear of cutting fluid on workpiece
Lotion can effectively remove oil component and water-soluble components in cutting fluid, and can save in traditional cutting fluid removing
High pressure water cleaning process, thus meet the demand for development of energy-saving and emission-reduction.
To achieve the above object, the present invention provides a kind of cutting fluid removing agent for carbon hydrogen detergent, including with weight percent
The following component of number meter:
Hydrocarbon 50~70%；
Alcohol ethers compound 10~25%；
Ester ether compound 10~20%；
Ethyl lactate 1~10%.
Wherein, alcohol ethers compound refers in molecule the not only compound containing hydroxyl but also containing ether, ester ether compound
Refer in molecule the not only compound containing ester group but also containing ether.
Further, cutting fluid, which is removed, uses agent for carbon hydrogen detergent, including following component by weight percentage:
Hydrocarbon 55~65%；
Alcohol ethers compound 12~20%；
Ester ether compound 12~16%；
Ethyl lactate 1~6%.
Further, hydrocarbon concretely 50%, 55%, 60%, 65%, 70%；Alcohol ethers compound is specific
It can be 10%, 13%, 15%, 18%, 20%, 25%；Ester ether compound concretely 10%, 13%, 15%, 18%,
20%；Ethyl lactate concretely 1%, 3%, 5%, 8%, 10%.
Further, the hydrocarbon is positive structure or isoparaffin of the boiling range at 140~220 DEG C, hydrocarbon using this
The flash-point of cutting fluid removing agent for carbon hydrogen detergent can be improved in compound, can reduce security risk, and boiling range is relatively narrow, is distilled to recover
Effect is good, and recoverable rate is high.Further, the hydrocarbon is selected from n -nonane, isomery nonane, n-decane, different
One of structure decane, positive structure hendecane and isomery hendecane are a variety of.
Further, the alcohol ethers compound is selected from propylene glycol ether compound and 3-Methoxy-3-methyl-1-butanol
One or both of.Propylene glycol ether compound can the most of solvents of solubilising, and dissolution and coupling oil that can be fabulous, more into
One step, the propylene glycol ether compound is selected from propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene glycol fourth
One of ether, tripropylene glycol methyl ether, tripropylene glycol butyl ether, Propylene glycol n-propyl ether and dipropylene glycol n-propyl ether are a variety of, a variety of
Propylene glycol share can make it is more preferable with the cosolvency of other components, and to oil dissolution and coupling capacity it is also stronger.3- methoxy
Possess hydroxyl and methoxyl group simultaneously in the molecule of base -3- methyl-1-butanol, it is made to form very strong hydrogen with intermolecular in the molecule
Key, thus it is not only soluble in water but also be dissolved in oil, it is meant that, not only can dissolve the oil component in cutting fluid, but also can dissolve therein
Water-soluble components, while the flash-point of 3-Methoxy-3-methyl-1-butanol is high, safety with higher, thus it is a kind of high
Safety, high performance cleaning agent component.
Further, the ester ether compound is selected from 3- methoxyl group -3- methylene diacetate butyl ester, propylene glycol monomethyl ether acetic acid
Ester, butyl glycol ether acetic acid esters and ethyl cellosolve acetate, diethylene glycol ether acetic acid esters, butyl acetic acid esters,
One of two propyl alcohol methyl ether acetates and propylene glycol monomethyl ether acetate are a variety of.
Cutting fluid of the invention is removed with the hydrocarbon in agent for carbon hydrogen detergent, alcohol ethers compound, ester ethers chemical combination
Object combination can remove base oil and oiliness function additive in cutting fluid；Alcohol ethers compound and ester ether compound can dissolve each other and
The two dissolubility is fabulous, it is possible to increase solubility of the ethyl lactate in hydrocarbon；The carbochain of ethyl lactate is shorter and has
The extremely strong hydroxyl of hydrophily and ester group, polarity is larger, can wetted workpieces surface well cutting fluid, to water-soluble in cutting fluid
Property dirt have extremely strong solvability, meanwhile, the molecule overall structure of ethyl lactate is smaller, and has in the chiral carbon of small molecule
There is hydroxyl, thus there is good permeability, can penetrate into cutting fluid and disperse cutting fluid, thus in ethyl lactate
Under the collective effect of other solvents (hydrocarbon, alcohol ethers compound, ester ether compound), cutting fluid can be made from workpiece
Surface elutes, and take away part other graininess it is dirty, reinforce the cleanliness of workpiece surface.Using cutting of the invention
Liquid removing can remove oil component and aqueous component in cutting fluid with agent for carbon hydrogen detergent simultaneously, thus can save traditional cutting fluid
High pressure water cleaning process in removing, thus meet the demand for development of energy-saving and emission-reduction.
Specific embodiment
Below by specific embodiment to further illustrate the technical scheme of the present invention, involved in the embodiment of the present invention
Raw material can be obtained by commercially available.
It is write a Chinese character in simplified form for the convenience of description, part material involved in the embodiment of the present invention uses, e.g., 3- methoxyl group -3-
Methyl-1-butanol (MMB), propandiol butyl ether (PNB), dipropylene glycol methyl ether (DPM), 3- methoxyl group -3- methylene diacetate butyl ester
(MMBA), propylene glycol methyl ether acetate (PMA).
Embodiment 1
A kind of cutting fluid removing agent for carbon hydrogen detergent, including following component by weight percentage:
Hydrocarbon 60%；
Alcohol ethers compound 20%；
Ester ether compound 15%；
Ethyl lactate 5%,
Wherein, hydrocarbon is n-decane, and alcohol ethers compound DPM, ester ether compound is PMA.
Above-mentioned each component be sufficiently mixed up to cutting fluid removing agent for carbon hydrogen detergent.
Comparative example 1
A kind of cutting fluid removing agent for carbon hydrogen detergent, including following component by weight percentage:
Hydrocarbon 65%；
Alcohol ethers compound 20%；
Ester ether compound 15%,
Wherein, hydrocarbon is n-decane, and alcohol ethers compound DPM, ester ether compound is PMA.
Above-mentioned each component be sufficiently mixed up to cutting fluid removing agent for carbon hydrogen detergent.
Comparative example 2
A kind of cutting fluid removing agent for carbon hydrogen detergent, including following component by weight percentage:
Hydrocarbon 70%；
Alcohol ethers compound 25%；
Ethyl lactate 5%,
Wherein, hydrocarbon is n-decane, alcohol ethers compound DPM.
Above-mentioned each component be sufficiently mixed up to cutting fluid removing agent for carbon hydrogen detergent.
Comparative example 3
A kind of cutting fluid removing agent for carbon hydrogen detergent, including following component by weight percentage:
Hydrocarbon 65%；
Ester ether compound 25%；
Ethyl lactate 10%,
Wherein, hydrocarbon is n-decane, and ester ether compound is PMA.
Above-mentioned each component be sufficiently mixed up to cutting fluid removing agent for carbon hydrogen detergent.
The each component of embodiment 2~13 is as shown in table 1, and preparation method is same as Example 1, all by filling each component
Divide and mixes up to cutting fluid removing agent for carbon hydrogen detergent.
The each component of 1 embodiment 1~13 of table
Embodiment 1~13 and comparative example 1~3 are subjected to physical property detection, the results are shown in Table 2, wherein appearance passes through view
Feel observation；Smell is incuded by the sense of taste, characterizes its irritating degree；KB value refers at 25 DEG C from 120g standard
The ml number of diluent required for kaurigum is precipitated in kaurigum- butanol solution, KB value is higher to show that dissolubility is better；Aniline
Measured by the aniline point analyzer that " GB/T 262-1988 oil product aniline point measuring method " is formulated according to point, and aniline point
Higher to illustrate that dissolubility is poorer, on the contrary then dissolubility is better.
The physical property testing result of table 2 embodiment 1~11 and comparative example 1~3
| Embodiment | Appearance | Smell | Aniline point/DEG C | KB value |
| Embodiment 1 | Colourless liquid | It is atomic | 45 | 47 |
| Embodiment 2 | Colourless liquid | It is atomic | 44 | 50 |
| Embodiment 3 | Colourless liquid | It is atomic | 44 | 51 |
| Embodiment 4 | Colourless liquid | It is atomic | 46 | 48 |
| Embodiment 5 | Colourless liquid | It is atomic | 46 | 47 |
| Embodiment 6 | Colourless liquid | It is atomic | 44 | 50 |
| Embodiment 7 | Colourless liquid | It is atomic | 44 | 51 |
| Embodiment 8 | Colourless liquid | It is atomic | 45.5 | 49 |
| Embodiment 9 | Colourless liquid | It is atomic | 42 | 54 |
| Embodiment 10 | Colourless liquid | It is atomic | 41 | 54 |
| Embodiment 11 | Colourless liquid | It is atomic | 43 | 52 |
| Comparative example 1 | Colourless liquid | It is atomic | 49 | 43 |
| Comparative example 2 | Colourless liquid | It is atomic | 46.5 | 46 |
| Comparative example 3 | Colourless liquid | It is atomic | 47 | 45 |
| Professional standard | Colourless liquid | Slightly | - | ≥27 |
According to the physical property testing result of the embodiment 1~11 of table 2 and comparative example 1~3 it is found that cutting fluid of the invention is removed
It is colourless liquid with agent for carbon hydrogen detergent and is atomic smell, meets wanting for the cutting fluid removing agent for carbon hydrogen detergent of current industry
It asks, and aniline point is lower than standard value and each comparative example, KB value is higher than standard value and each comparative example, that is, it is meant that the present invention
Cutting fluid remove with the cleaning effect of agent for carbon hydrogen detergent more preferably.
The aniline point of embodiment 1~11 is lower than comparative example 1~3, and KB value is higher than comparative example 1~3, mainly due to of the invention
Hydrocarbon, alcohol ethers compound, ester ether compound and ethyl lactate are used in cleaning agent, by between each component
Coordinated effect can make the solvability enhancing of cleaning agent obtained.
By comparing embodiment 1 and embodiment 9~11 it is found that being shared using propylene glycol ethers component, multiple groups part alcohol ether
When class compound shares and multiple groups part ester ether compound shares, solubility property is more preferably.
The cutting fluid removing of embodiment 1~11 and comparative example 1~3 is respectively washed with agent for carbon hydrogen detergent same type of
Metal works, cleaning machine are vacuum ultrasonic cleaning machine, and cleaning workpiece is metal knife, and preceding working procedure is cutting fluid cooling and profit
Sliding processing.Metal knife is placed in the cutting fluid removing agent for carbon hydrogen detergent for filling embodiment 1~11 and comparative example 1~3 respectively
Container in, time of ultrasonic cleaning is 25min, 40 ± 2 DEG C of the temperature of ultrasonic cleaning.
It will be tested after the metal knife drying of embodiment 1~11 and the cleaning of comparative example 1~3 using 38# dynes of pen, it is real
The very average distribution of the setting-out on the surface of the metal knife of 1~11 cleaning treatment of example is applied, any pearl point is not played, does not shrink, explanation
The surface tension of metal knife is preferable, and cleanliness is high；The setting-out on the surface of the metal knife of 1~3 cleaning treatment of comparative example is slowly
Contraction, illustrate surface tension be slightly less than dyne pen on labelled in index, cleanliness be not so good as embodiment 1~11.This is main
Due to, ethyl lactate is lacked in comparative example 1, ester ether compound is lacked in comparative example 2, comparative example 3 lacks alcohol ethers compound,
And cutting fluid removing of the invention uses hydrocarbon, alcohol ethers compound, ester ether compound and cream with agent for carbon hydrogen detergent
Acetoacetic ester compounding, wherein hydrocarbon, alcohol ethers compound, ester ether compound combination can remove the basis in cutting fluid
Oil and oiliness function additive；Alcohol ethers compound and ester ether compound can dissolve each other and the two dissolubility is fabulous, it is possible to increase lactic acid second
Solubility of the ester in hydrocarbon；The carbochain of ethyl lactate is shorter and has the extremely strong hydroxyl of hydrophily and ester group, polarity
It is larger, can wetted workpieces surface well cutting fluid, there is extremely strong solvability to the water-soluble stains in cutting fluid, together
When, the molecule overall structure of ethyl lactate is smaller, and has hydroxyl in the chiral carbon of small molecule, thus has good infiltration
Property, it can penetrate into cutting fluid and disperse cutting fluid, thus in ethyl lactate and other solvent (hydrocarbons, alcohol
Ether compound, ester ether compound) collective effect under, cutting fluid can be made to elute from workpiece surface, and take away part
Other graininess are dirty, reinforce the cleanliness of workpiece surface.
It should be pointed out that embodiments above is only illustrative of the invention and is not intended to limit the scope of the invention, readding
After having read the present invention, those skilled in the art each fall within right appended by the present invention to the modification of various equivalent forms of the invention
It is required that the range limited.
Claims (7)
1. a kind of cutting fluid, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that including following component by weight percentage:
Hydrocarbon 50~70%；
Alcohol ethers compound 10~25%；
Ester ether compound 10~20%；
Ethyl lactate 1~10%.
2. cutting fluid according to claim 1, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that including by weight percentage
Following component:
Hydrocarbon 55~65%；
Alcohol ethers compound 12~20%；
Ester ether compound 12~16%；
Ethyl lactate 1~6%.
3. cutting fluid according to claim 1, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that the hydrocarbon is boiling
Positive structure or isoparaffin of the journey at 140~220 DEG C.
4. cutting fluid according to claim 3, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that the hydrocarbon is selected from
One of n -nonane, isomery nonane, n-decane, isomery decane, positive structure hendecane and isomery hendecane are a variety of.
5. cutting fluid according to claim 1, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that the alcohol ethers compound choosing
From one or both of propylene glycol ether compound and 3-Methoxy-3-methyl-1-butanol.
6. cutting fluid according to claim 4, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that the propylene glycol ethers chemical combination
Object is selected from propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, dipropylene, tripropylene glycol methyl ether, tripropylene glycol fourth
One of ether, Propylene glycol n-propyl ether and dipropylene glycol n-propyl ether are a variety of.
7. cutting fluid according to claim 1, which is removed, uses agent for carbon hydrogen detergent, which is characterized in that the ester ether compound choosing
From 3- methoxyl group -3- methylene diacetate butyl ester, propylene glycol methyl ether acetate, butyl glycol ether acetic acid esters, ethyl cellosolve acetate,
In diethylene glycol ether acetic acid esters, butyl acetic acid esters, two propyl alcohol methyl ether acetates and propylene glycol monomethyl ether acetate
It is one or more.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201811654898.9A CN109504563B (en) | 2018-12-31 | 2018-12-31 | Hydrocarbon cleaning agent for removing cutting fluid |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811654898.9A CN109504563B (en) | 2018-12-31 | 2018-12-31 | Hydrocarbon cleaning agent for removing cutting fluid |
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| CN109504563A true CN109504563A (en) | 2019-03-22 |
| CN109504563B CN109504563B (en) | 2021-09-07 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110408943A (en) * | 2019-07-09 | 2019-11-05 | 江西瑞思博新材料有限公司 | The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning |
| CN110591840A (en) * | 2019-09-26 | 2019-12-20 | 麦达可尔(湖北)工业有限公司 | Solvent type cleaning agent |
| CN111154556A (en) * | 2019-12-31 | 2020-05-15 | 广东新球清洗科技股份有限公司 | Hydrocarbon cleaning agent for efficiently cleaning particles and use method thereof |
| CN111518638A (en) * | 2020-05-25 | 2020-08-11 | 乔卫峰 | Dry cleaning solvent and preparation process thereof |
| CN113667991A (en) * | 2021-08-04 | 2021-11-19 | 诺而曼环保科技（江苏）有限公司 | New energy aluminum battery shell oil and ash removing hydrocarbon cleaning agent and preparation method thereof |
| CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408943A (en) * | 2019-07-09 | 2019-11-05 | 江西瑞思博新材料有限公司 | The cleaning solution excision agent and preparation method thereof of water rinsing is substituted after hard surface cleaning |
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| CN110591840A (en) * | 2019-09-26 | 2019-12-20 | 麦达可尔(湖北)工业有限公司 | Solvent type cleaning agent |
| CN111154556A (en) * | 2019-12-31 | 2020-05-15 | 广东新球清洗科技股份有限公司 | Hydrocarbon cleaning agent for efficiently cleaning particles and use method thereof |
| CN111518638A (en) * | 2020-05-25 | 2020-08-11 | 乔卫峰 | Dry cleaning solvent and preparation process thereof |
| CN113667991A (en) * | 2021-08-04 | 2021-11-19 | 诺而曼环保科技（江苏）有限公司 | New energy aluminum battery shell oil and ash removing hydrocarbon cleaning agent and preparation method thereof |
| CN114277382A (en) * | 2021-12-29 | 2022-04-05 | 泰伦特生物工程股份有限公司 | Water-cutting cleaning agent replacing rinsing and drying process and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN109504563B (en) | 2021-09-07 |
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