CN109735860A - Metal product multiple groups part agent for carbon hydrogen detergent and preparation method thereof and application method - Google Patents
Metal product multiple groups part agent for carbon hydrogen detergent and preparation method thereof and application method Download PDFInfo
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Abstract
The present invention provides a kind of metal product multiple groups part agent for carbon hydrogen detergent and preparation method thereof and application methods, metal product multiple groups part agent for carbon hydrogen detergent includes component A agent for carbon hydrogen detergent and B component agent for carbon hydrogen detergent, component A agent for carbon hydrogen detergent is water-in-oil emulsion agent for carbon hydrogen detergent, and preparing raw material includes following component by weight percentage: the first hydrocarbon: 50~70%；First cosurfactant: 20~49.8%；Emulsifier: 0.1~10%；Water: 0.1~5%, B component agent for carbon hydrogen detergent is anhydrous type agent for carbon hydrogen detergent, and preparing raw material includes following component by weight percentage: the second hydrocarbon: 50~70%；Second cosurfactant: 30~50%.The carbon distribution, metal fines of component A agent for carbon hydrogen detergent (water-in-oil emulsion agent for carbon hydrogen detergent) main wash surface of metal product, the oil of B component agent for carbon hydrogen detergent (anhydrous type agent for carbon hydrogen detergent) main wash surface of metal product, thus the surface clean of metal product can be made to obtain by the combination of the two more thorough, surface cleanliness is higher.
Description
Technical field
The present invention relates to a kind of cleaning agent more particularly to a kind of metal product multiple groups part agent for carbon hydrogen detergent, and its preparation side
Method and application method.
Background technique
As the improvement of people's living standards, processing of the people for some precision instruments, precision equipment, electronic product etc.
It is required that also higher and higher, in order to meet appearance or some functional requirements, the surface for the substrate for needing to process presents higher
Surface tension, smoothness, glossiness etc..Such as, the metal-back of some batteries or mobile phone metal-back, require the table of metal base
Face is presented preferable surface tension, smoothness, glossiness, and metal-back all can be in the process such as cutting, plated film, stretching
Metal surface generates metal fines, carbon distribution and oil etc..
Metal product itself is easily corroded according to acid solution cleaning, according to aqueous cleaning agent, aqueous cleaning agent is mainly borrowed
Help a variety of surfactants that inorganic builders is added to compound in water, although its cleaning effect is obvious, aqueous cleaning agent makes
It is easily contaminated with the solvent (water) of the serious discharge for being bound to cause waste water, while aqueous cleaning agent, and influence it makes repeatedly
With, thus do not meet the development trend for the energy-saving and emission-reduction advocated at present；The second is oil base cleaning agent, usually agent for carbon hydrogen detergent,
It is generally obtained by mixing by hydrocarbon, alcohol compound, ester type compound and ether compound, this kind of cleaning agent can be preferable
Oil removing is still not obvious the cleaning effect of metal fines and carbon distribution.
Therefore it provides can not only realize high-efficiency washing surface of metal product but also the demand for development of energy-saving and emission-reduction, environmental protection can be met
Metal product cleaning agent, be the difficult point and hot spot of current cleaning agent industry research.
Summary of the invention
The present invention is intended to provide a kind of metal product multiple groups part agent for carbon hydrogen detergent and preparation method thereof and application method, metal
Product multiple groups part agent for carbon hydrogen detergent may be implemented what the conventional agent for carbon hydrogen detergent such as carbon distribution in metal product, metal fines can not clean
Effective cleaning of particulate matter, or even oil also have preferable cleaning ability, and the surface of metal product after over cleaning is clean
It spends higher.
To achieve the above object, first aspect present invention provides a kind of metal product multiple groups part agent for carbon hydrogen detergent, including A
Component agent for carbon hydrogen detergent and B component agent for carbon hydrogen detergent,
Wherein, component A agent for carbon hydrogen detergent is water-in-oil emulsion agent for carbon hydrogen detergent, and preparing raw material includes with weight percent
The following component of meter:
First hydrocarbon: 50~70%；
First cosurfactant: 20~49.8%；
Emulsifier: 0.1~10%；
Water: 0.1~5%,
B component agent for carbon hydrogen detergent is anhydrous type agent for carbon hydrogen detergent, and preparing raw material includes by weight percentage such as the following group
Part:
Second hydrocarbon: 50~70%；
Second cosurfactant: 30~50%.
Metal product multiple groups part agent for carbon hydrogen detergent of the invention includes that (water-in-oil emulsion is hydrocarbon for component A agent for carbon hydrogen detergent
Cleaning agent) and B component agent for carbon hydrogen detergent (anhydrous type agent for carbon hydrogen detergent), it selects two kinds of different component cleaning agents to carry out collaboration and matches
It closes, carbon distribution, the metal fines of water-in-oil emulsion agent for carbon hydrogen detergent main wash surface of metal product, anhydrous type agent for carbon hydrogen detergent
The oil of main wash surface of metal product, thus by both combination that the surface clean of metal product can be made to obtain is more thorough,
Surface of metal product cleanliness after over cleaning is higher.In component A agent for carbon hydrogen detergent in the first hydrocarbon of oiliness and
0.1~10% emulsifier and 0.1~5% water are added in first cosurfactant, water dispersion can be made in the first hydrocarbonization
It closes in object and the first cosurfactant and forms stable water-in-oil emulsion, so that component A agent for carbon hydrogen detergent possesses often
Advise the unexistent dispersibility of agent for carbon hydrogen detergent, wellability, cleaning force, thus the gold that conventional agent for carbon hydrogen detergent can not be cleaned
The particulate matters such as carbon distribution, metal fines clean up in metal products.
Further, the first hydrocarbon can be 50%, 55%, 60%, 65%, 70% in component A agent for carbon hydrogen detergent,
First cosurfactant can be 20%, 25%, 30%, 35%, 40%, 45%, 49.8%, emulsifier can for 0.1%,
0.5%, 1.0%, 3.0%, 5.0%, 7.5%, 10%, water can be deionized water or distilled water, content can for 0.1%,
0.5%, 1.0%, 1.5%, 2.5%, 4.0%, 5.0%.In B component agent for carbon hydrogen detergent the second hydrocarbon can for 50%,
55%, 60%, 65%, 70%, the second cosurfactant can be 30%, 35%, 40%, 45%, 50%.
Further, the hydrocarbon is positive structure or isoparaffin of the boiling range at 140~220 DEG C, hydrocarbon using this
The flash-point of metal base paraffin removal Halogen agent for carbon hydrogen detergent can be improved in compound, can reduce security risk, and boiling range is relatively narrow, distillation
Recovering effect is good, and recoverable rate is high.Further, the first hydrocarbon and the second hydrocarbon each are selected from just
One of nonane, isomery nonane, n-decane, isomery decane, positive carbon hendecane and isomery hendecane are a variety of, i.e., first is hydrocarbon
Compound and the second hydrocarbon can be that same substance also can be different.
Further, the first cosurfactant and the second cosurfactant each are selected from alcohol ethers compound and carboxylic acid
One or both of ester.Further, alcohol ethers compound is selected from propandiol butyl ether (PNB), dipropylene
(DPNB), dipropylene glycol methyl ether (DPM), Propylene glycol n-propyl ether (PnP), dipropylene glycol n-propyl ether (DPNP) and 3- methoxyl group -3-
One of methyl-1-butanol (MMB) is a variety of.Carboxylate is selected from ethylene diacetate (EGDA), dimethyl succinate
(DBE), one of dimethyl glutarate (DMG) and dimethyl adipate (DMA) or a variety of.Propylene glycol ether compound (third
Glycol butyl ether, dipropylene, dipropylene glycol methyl ether, Propylene glycol n-propyl ether, dipropylene glycol n-propyl ether) it can be solubilized most of molten
Agent, and can fabulous dissolution and coupling oil, a variety of propylene glycol compounds share can make it is more preferable with hydrocarbon cosolvency,
And it is also stronger to the dissolution and coupling capacity of oil.Possess hydroxyl and first in the molecule of 3-Methoxy-3-methyl-1-butanol simultaneously
Oxygroup makes it form very strong hydrogen bond with intermolecular in the molecule, thus not only soluble in water but also be dissolved in oil, while 3- methoxy
The flash-point of base -3- methyl-1-butanol is high, safety with higher, thus it is a kind of high security, high performance cleaning group
Part.Alcohol ethers compound and carboxylate and emulsifier are there are stronger hydrogen bond action and intermolecular force, thus alcohol ethers
Booster action can be played by closing object and carboxylate, and the pasty mass for constituting water and emulsifier is dispersed in the first hydrocarbon
In the system of the first cosurfactant composition, to form stable water-in-oil emulsion.First cosurfactant and
Second cosurfactant can be that same substance also can be different.
Further, emulsifier is nonionic surface active agent, or, nonionic surface active agent and anionic surface
The mixture of activating agent.Nonionic surface active agent is selected from Span-80 (sorbitan fatty ester), (mountain Span-60
Pears alcohol acid anhydride monostearate), Tween-80 (sorbitan monooleate polyoxyethylene ether), Tween-60 (polyoxyethylene lose
Water sorb alcohol ether stearate), AEO-3 (fatty alcohol polyoxyethylene ether), AEO-7 (fatty alcohol polyoxyethylene ether), MOA-3P (rouge
Fat alcohol ether phosphate) and one of MOA-9P (fatty alcohol ether phosphate) or a variety of, anionic surfactant MOA-3PK
(fatty alcohol ether phosphate kalium salt).Selection nonionic surface active agent can make the first hydrocarbon and first help surface-active
The oleaginous system of agent composition becomes stable water-in-oil emulsion, and the MOA-3PK anionic surfactant being additionally added can make
Emulsifying capacity is stronger.
The second aspect of the present invention provides a kind of preparation method of metal product multiple groups part agent for carbon hydrogen detergent, component A carbon
Hydrogen cleaning agent is by being first mixed into paste for emulsifier and water, then is dispersed with the first cosurfactant, is added the
It can be obtained after the mixing of one hydrocarbon；B component agent for carbon hydrogen detergent is to mix the second hydrocarbon and the second cosurfactant
Conjunction can obtain.
In the preparation method of metal product multiple groups part agent for carbon hydrogen detergent of the invention, component A agent for carbon hydrogen detergent, which passes through, first will
Emulsifier is uniformly mixed with water and stirs into paste, since the emulsification of emulsification easily forms Water-In-Oil structure, therefore passes through stirring
Uniformly；First cosurfactant of subsequent addition and emulsifier there are stronger hydrogen bond action and intermolecular force,
Booster action can be played, the pasty mass for constituting water and emulsifier is dispersed in the first cosurfactant；Dispersion with
Adding suitable first hydrocarbon thereto again afterwards can be obtained water-in-oil emulsion, the component A prepared by the method
Hydrocarbon cleaning agent emulsion is more stable, and transparent clarification shape.The second cosurfactant in B component agent for carbon hydrogen detergent, point
There is hydrogen bond action and stronger intermolecular force between son and molecule, and the second cosurfactant and the second hydrocarbonization
There is stronger intermolecular forces between conjunction object, therefore the two can mix well and form stable colourless transparent liquid.
The third aspect of the present invention provides a kind of application method of metal product multiple groups part agent for carbon hydrogen detergent, by made of metal
Product pass through pre-processing after, using vacuum ultrasonic successively carry out using B component agent for carbon hydrogen detergent slightly wash, component A it is hydrocarbon
The rinsing of the fine purifiation, B component agent for carbon hydrogen detergent of cleaning agent.
Further, it is cleaned using the vacuum ultrasonic of multiple-grooved, 3~4min of every slot scavenging period, cleaning temperature 50
~55 DEG C, the frequency of ultrasonic wave is 40KHz, is slightly washed using B component agent for carbon hydrogen detergent to metal product in leading portion slot, intermediate
Fine purifiation is carried out to metal product using component A agent for carbon hydrogen detergent in slot, utilizes B component agent for carbon hydrogen detergent to made of metal in back segment slot
Product are rinsed.The pre-processing of metal product is that metal product is carried out 2~3min, 400~600r/min in centrifuge
Drying deoiling treatment.
In the preparation method of metal product multiple groups part agent for carbon hydrogen detergent of the invention, the thick of B component agent for carbon hydrogen detergent is utilized
The thicker oil of metal product outermost can be removed by washing, and recycle the fine purifiation of component A agent for carbon hydrogen detergent that can remove metal product
Carbon distribution, the metal fines on surface, finally in conjunction with B component agent for carbon hydrogen detergent rinsing can remove front slightly wash in fine purifiation in metal
The residue of product surface.
Specific embodiment
Below by specific embodiment to further illustrate the technical scheme of the present invention, involved in the embodiment of the present invention
Raw material can be obtained by commercially available.It is write a Chinese character in simplified form for the convenience of description, part material involved in the embodiment of the present invention uses.
Embodiment 1
A kind of metal product multiple groups part agent for carbon hydrogen detergent, including component A agent for carbon hydrogen detergent and B component agent for carbon hydrogen detergent,
Wherein, component A agent for carbon hydrogen detergent is water-in-oil emulsion agent for carbon hydrogen detergent, and preparing raw material includes with weight percent
The following component of meter:
N -nonane: 60%；
PNB:30%；
Span-80:8%；
Deionized water: 2%,
B component agent for carbon hydrogen detergent is anhydrous type agent for carbon hydrogen detergent, and preparing raw material includes by weight percentage such as the following group
Part:
N -nonane: 60%；
PNB:20%；
MMB:20%,
The preparation of component A agent for carbon hydrogen detergent:
The deionized water of the Span-80 of formula ratio and formula ratio are first mixed into paste, add formula ratio PNB into
Row dispersion, the n -nonane that formula ratio is added after dispersion are uniformly mixed.
The preparation of B component agent for carbon hydrogen detergent:
By the first cosurfactant (PNB and MMB) of the second hydrocarbon (n -nonane) of formula ratio and formula ratio
Being uniformly mixed can obtain.
Comparative example 1
A kind of metal product agent for carbon hydrogen detergent, preparing raw material includes following component by weight percentage:
N -nonane: 60%；
PNB:30%；
Span-80:8%；
Deionized water: 2%.
The deionized water of the Span-80 of formula ratio and formula ratio are first mixed into paste, add formula ratio PNB into
Row dispersion, the n -nonane that formula ratio is added after dispersion are uniformly mixed.
Comparative example 2
A kind of metal product agent for carbon hydrogen detergent, preparing raw material includes following component by weight percentage:
N -nonane: 60%；
PNB:20%；
MMB:20%,
By the first cosurfactant (PNB and MMB) of the second hydrocarbon (n -nonane) of formula ratio and formula ratio
Being uniformly mixed can obtain.
The each component of metal product multiple groups part agent for carbon hydrogen detergent of embodiment 2~9 is as shown in table 1, preparation method and reality
It is identical to apply example 1.
By metal product multiple groups part agent for carbon hydrogen detergent of Examples 1 to 9 and the metal product hydrocarbon cleaning of comparative example 1~2
Agent carries out physical property detection, and the results are shown in Table 2, wherein appearance passes through visual observation；KB value, which refers to, to be marked at 25 DEG C from 120g
The ml number of diluent required for kaurigum is precipitated in quasi- kaurigum- butanol solution, KB value is higher to show that dissolubility is better；Benzene
Measured by the aniline point analyzer that " GB/T 262-1988 oil product aniline point measuring method " is formulated according to amine point, and aniline
Point is higher to illustrate that dissolubility is poorer, and on the contrary then dissolubility is better.Using " GB/T 16497-2007 surfactant water in oil emulsion
The measurement of liquid storage-stable " regulation will be in metal product multiple groups part agent for carbon hydrogen detergent of Examples 1 to 9 and comparative example 1~2
Component A agent for carbon hydrogen detergent carries out stability of emulsion detection, wherein I type is stability lotion, II is unstability lotion, and III is to face
Boundary's stability lotion.
The each component of 1 Examples 1 to 9 of table
As shown in Table 2, in metal product multiple groups part agent for carbon hydrogen detergent of the invention, component A agent for carbon hydrogen detergent is transparent clear
Clear water-in-oil emulsion, and lotion is the stability lotion of I type, all has lower aniline value and higher KB value, explanation
The dissolubility of lotion is preferable, has stronger cleaning ability, while being used in mixed way using first cosurfactant of multiple groups part
When, aniline value is lower, and KB value is higher, and dissolubility is more preferably.The aniline value of B component agent for carbon hydrogen detergent is than component A hydrocarbon cleaning
Agent it is lower, KB value is higher, to oil cleaning ability it is stronger.
The physical property testing result of 2 Examples 1 to 9 of table and comparative example 1~2
Metal product multiple groups part agent for carbon hydrogen detergent of Examples 1 to 9 is respectively washed same battery-shell surface, cleaning machine
For 6 slot vacuum ultrasonic cleaning machines；Cleaning workpiece is metal battery shell；Material is aluminium；Preceding working procedure is to stretch；Cleaning object is
Carbon distribution, metal fines and drawing oil on metal battery shell.
Cleaning process are as follows: metal battery shell is first carried out to 2~3min in centrifuge, the drying of 400~600r/min is de-
Oil processing, it is specific to handle the time as 3min, revolving speed 500r/min.In leading portion slot (1 slot) using B component agent for carbon hydrogen detergent into
Row is slightly washed, and fine purifiation is carried out using component A agent for carbon hydrogen detergent in medial launder (2 slots and 3 slots), then in back segment slot (4~6 slot)
It is middle to be rinsed with B component agent for carbon hydrogen detergent.The scavenging period 3min of every slot, cleaning temperature in 6 slot vacuum ultrasonic cleaning machines
50 DEG C, the frequency of ultrasonic wave is 40KHz.
The metal product agent for carbon hydrogen detergent of comparative example 1~2 is respectively washed same battery-shell surface, cleaning machine is similarly
6 slot vacuum ultrasonic cleaning machines；Cleaning workpiece is metal battery shell；Material is aluminium；Preceding working procedure is to stretch；Cleaning object is gold
Belong to carbon distribution, metal fines and the drawing oil on battery case.
Cleaning process are as follows: metal battery shell is first carried out to 2~3min in centrifuge, the drying of 400~600r/min is de-
Oil processing, it is specific to handle the time as 3min, revolving speed 500r/min.Slot 1~6 all uses same metal product hydrocarbon cleaning
Agent is rinsed.The scavenging period 3min of every slot in 6 slot vacuum ultrasonic cleaning machines, 50 DEG C of cleaning temperature, the frequency of ultrasonic wave
For 40KHz.
It will be tested after the metal battery shell drying of Examples 1 to 9 and the cleaning of comparative example 1~2 using 38# dynes of pen,
The very average distribution of the setting-out on the surface of the metal battery shell of Examples 1 to 9 cleaning treatment, does not play any pearl point, does not shrink, say
The surface tension of bright metal battery shell is preferable, and cleanliness is high；The picture on the surface of the metal battery shell of 1~2 cleaning treatment of comparative example
The contraction of line slowly, illustrate surface tension be slightly less than dyne pen on labelled in index, cleanliness be not so good as Examples 1 to 9.This
It include that (water-in-oil emulsion is hydrocarbon for component A agent for carbon hydrogen detergent mainly due to metal product multiple groups part agent for carbon hydrogen detergent of the invention
Cleaning agent) and B component agent for carbon hydrogen detergent (anhydrous type agent for carbon hydrogen detergent), water-in-oil emulsion agent for carbon hydrogen detergent main wash metal
Carbon distribution, the metal fines of product surface, the oil of anhydrous type agent for carbon hydrogen detergent main wash surface of metal product, thus pass through two
It is more thorough that the combination of person can be such that the surface clean of metal product obtains, and the surface of metal product cleanliness after over cleaning is higher.And
Comparative example 1 and comparative example 2 are individual water-in-oil emulsion agent for carbon hydrogen detergent or anhydrous type agent for carbon hydrogen detergent, or are only capable of locating
The carbon distribution and metal fines of surface of metal product are managed, or only handles the oil of surface of metal product, thus is unable to get surface
The high metal product of cleanliness.
It should be pointed out that embodiments above is only illustrative of the invention and is not intended to limit the scope of the invention, readding
After having read the present invention, those skilled in the art each fall within right appended by the present invention to the modification of various equivalent forms of the invention
It is required that the range limited.
Claims (10)
1. a kind of metal product multiple groups part agent for carbon hydrogen detergent, which is characterized in that hydrocarbon including component A agent for carbon hydrogen detergent and B component
Cleaning agent,
The component A agent for carbon hydrogen detergent is water-in-oil emulsion agent for carbon hydrogen detergent, and preparing raw material includes by weight percentage
Following component:
First hydrocarbon: 50~70%；
First cosurfactant: 20~49.8%；
Emulsifier: 0.1~10%；
Water: 0.1~5%,
The B component agent for carbon hydrogen detergent is anhydrous type agent for carbon hydrogen detergent, and preparing raw material includes by weight percentage such as the following group
Part:
Second hydrocarbon: 50~70%；
Second cosurfactant: 30~50%.
2. metal product multiple groups part agent for carbon hydrogen detergent according to claim 1, which is characterized in that first nytron
Object and second hydrocarbon are all positive structure or isoparaffin of the boiling range at 140~220 DEG C.
3. metal product multiple groups part agent for carbon hydrogen detergent according to claim 2, which is characterized in that first nytron
Object and second hydrocarbon each are selected from n -nonane, isomery nonane, n-decane, isomery decane, positive carbon hendecane and different
One of structure hendecane is a variety of.
4. metal product multiple groups part agent for carbon hydrogen detergent according to claim 1, which is characterized in that described first helps surface living
Property agent and second cosurfactant each are selected from one or both of alcohol ethers compound and carboxylate.
5. metal product multiple groups part agent for carbon hydrogen detergent according to claim 4, which is characterized in that the alcohol ethers compound
Selected from propandiol butyl ether, dipropylene, dipropylene glycol methyl ether, Propylene glycol n-propyl ether, dipropylene glycol n-propyl ether and 3- methoxy
One of base -3- methyl-1-butanol is a variety of.
6. metal product multiple groups part agent for carbon hydrogen detergent according to claim 4, which is characterized in that the carboxylate is selected from second
One of glycol diacetate, dimethyl succinate, dimethyl glutarate and dimethyl adipate are a variety of.
7. metal product multiple groups part agent for carbon hydrogen detergent according to claim 1, which is characterized in that the emulsifier be it is non-from
Subtype surfactant, or, the mixture of nonionic surface active agent and anionic surfactant.
8. metal product multiple groups part agent for carbon hydrogen detergent according to claim 7, which is characterized in that the non-ionic surface
Activating agent in Span-80, Span-60, Tween-80, Tween-60, AEO-3, AEO-7, MOA-3P and MOA-9P one
Kind is a variety of, and the anionic surfactant is MOA-3PK.
9. the preparation method of any metal product multiple groups part agent for carbon hydrogen detergent, feature exist according to claim 1~8
In, the component A agent for carbon hydrogen detergent by the way that the emulsifier and the water are first mixed into paste, then helped with described first
Surfactant is dispersed, and can be obtained after the first hydrocarbon mixing is added；The B component agent for carbon hydrogen detergent is by institute
Stating the second hydrocarbon and second cosurfactant mixing can obtain.
10. the application method of any metal product multiple groups part agent for carbon hydrogen detergent, feature exist according to claim 1~8
In by metal product by successively being carried out using vacuum ultrasonic using the thick of B component agent for carbon hydrogen detergent after pre-processing
It washes, the rinsing of the fine purifiation of component A agent for carbon hydrogen detergent, B component agent for carbon hydrogen detergent.
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| CN110318063A (en) * | 2019-07-26 | 2019-10-11 | 东莞市麦克莱恩新材料有限公司 | A kind of agent for carbon hydrogen detergent and preparation method thereof enhancing surface tension |
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| CN111154556A (en) * | 2019-12-31 | 2020-05-15 | 广东新球清洗科技股份有限公司 | Hydrocarbon cleaning agent for efficiently cleaning particles and use method thereof |
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| CN113528248A (en) * | 2021-07-27 | 2021-10-22 | 诺而曼环保科技（江苏）有限公司 | Hydrocarbon cleaning agent for semiconductor and preparation method |
| CN113583761A (en) * | 2021-08-11 | 2021-11-02 | 诺而曼环保科技（江苏）有限公司 | High-protection corrosion-resistant hydrocarbon cleaning agent for semiconductor cleaning and preparation method thereof |
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| CN110318063A (en) * | 2019-07-26 | 2019-10-11 | 东莞市麦克莱恩新材料有限公司 | A kind of agent for carbon hydrogen detergent and preparation method thereof enhancing surface tension |
| CN111155135A (en) * | 2019-12-31 | 2020-05-15 | 广东新球清洗科技股份有限公司 | Semi-water-based cleaning agent for cleaning stretching black marks and application method thereof |
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| CN111155135B (en) * | 2019-12-31 | 2022-05-17 | 广东新球清洗科技股份有限公司 | Semi-water-based cleaning agent for cleaning stretching black marks and application method thereof |
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Application publication date: 20190510 |