CN102041195A - Multifunctional environmental-friendly recyclable hydrocarbon detergent - Google Patents

Multifunctional environmental-friendly recyclable hydrocarbon detergent Download PDF

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Publication number
CN102041195A
CN102041195A CN 201010604116 CN201010604116A CN102041195A CN 102041195 A CN102041195 A CN 102041195A CN 201010604116 CN201010604116 CN 201010604116 CN 201010604116 A CN201010604116 A CN 201010604116A CN 102041195 A CN102041195 A CN 102041195A
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China
Prior art keywords
detergent
parts
hydrocarbon
protection
hydrocarbon detergent
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Pending
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CN 201010604116
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Chinese (zh)
Inventor
何国锐
魏妃
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DONGGUAN CITY ZHIGAO CHEMICAL MATERIALS Co Ltd
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DONGGUAN CITY ZHIGAO CHEMICAL MATERIALS Co Ltd
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Priority to CN 201010604116 priority Critical patent/CN102041195A/en
Publication of CN102041195A publication Critical patent/CN102041195A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a detergent, in particular to a multifunctional environmentally friendly recyclable hydrocarbon detergent used in a novel vacuum recycling hydrocarbon cleaning machine. The detergent comprises the following components in parts by weight: 50-60 parts of C11H24, 30-40 parts of C12H26 and 5-10 parts of alcohol ether compound or C5-C7 isomeric alcohol. The hydrocarbon detergent has the advantages that residual greasy dirt, moisture, fingerprint, metal dust and other dirts on hardware and plastic parts can be rapidly and effectively cleaned, residues of solder paste, soldering flux and the like also can be cleaned, volatilization speed is moderate, no residue is produced, and the detergent can be recycled in an appropriate pressure relief device, has longer service life and economy compared with a hydrocarbon detergent used in the current market, is not toxic or harmful to human body and is a non-ODS (ozone-depleting substance) product, thus the hydrocarbon detergent is the optimal substitute of the traditional Freon, halohydrocarbon solvent and common hydrocarbon detergent.

Description

The recyclable hydrocarbon detergent of a kind of multi-functional environment-protection
Technical field:
The present invention relates to a kind of detergent, refer in particular to the recyclable hydrocarbon detergent of a kind of multi-functional environment-protection that in the hydrocarbon cleaning machine of novel evacuated recovery, uses.
Background technology:
Conventional solvent type detergent is at present the most widely used to be common hydrocarbon detergent and halohydrocarbon detergent, the halohydrocarbon detergent has methylene dichloride, trichloromethane (chloroform), trichloroethane, trieline, zellon, tetracol phenixin, Freon 113 (F-113) etc., to possess cleansing power strong because of it, nonflammable, fast drying, advantages such as retortable recovery, but also can be in use to the people, be cleaned thing and environment and bring many danger: 1, toxicity problem: above-mentioned solvent all has very big toxicity except that Freon 113 (F-113) and trichloroethane, can pass through skin, breathe contact or eat by mistake and cause liver, kidney, septicemia, the lighter's dizziness, vomiting, weight person can cause shock even dead; And some solvents also can the great phosgene of toxigenicity under solar radiation, and carcinogenesis is arranged.2, etching problem: contain the chlorine atom in most of halohydrocarbon detergent, can decompose generation hydrochloric acid under certain condition, equipment and metal works are produced corrosion; And most of chlorinated hydrocarbon solvent can make plastic, rubber dissolving, swelling, distortion or embrittlement, and its clean range is restricted.3, vaporization losses problem: all belong to volatile liquid, boiling point low (generally at 40-80 degree centigrade) has 40% clean-out system to lose because of evaporation in transportation, storage and use approximately.4, environmental pollution problem: chlorinated hydrocarbon solvent all can not natural degradation, and there is more serious pollution the discharging back to air, water body and soil.5, the problem that damages the ozone layer: the volatilization gas of Freon 113 (F-113), trichloroethane, tetracol phenixin is trapped in the atmosphere, rise with air-flow, decomposed by uviolizing at stratosphere and produce the chlorine atom, the chlorine atom is as a kind of catalyzer, initiation that can be permanent damages the reaction of ozonosphere, the effect of ozonosphere shielding of ultraviolet is reduced, tellurian humans and animals, plant are brought harm.Therefore, most of industry has limited the use of this types of solvents, price is also progressively high in recent years, has lost their superiority at cleaning industry already.
And common hydrocarbon detergent only has solvency power preferably at oily dirt, and is relatively poor for water-based soils, fingerprint cleaning power; Secondly common hydrocarbon detergent adopts generally that boiling point is lower, evaporation rate is hydrocarbon faster, and volatilization is fast, and flash-point is low, and volatilization loss is very big, and safety performance is also lower; Once more, common hydrocarbon because refining degree restriction, purity is low, gold-plating journey broad, carbon number distribution is extensive, structural instability, after distillation was reclaimed, not only the rate of recovery was low, and clearing power significantly descends, and almost lost to reclaim and used meaning, thereby can't satisfy the demand in market.
Summary of the invention:
Technical problem to be solved by this invention just is to overcome above-mentioned existing deficiency, provides a kind of multi-functional environment-protection recyclable hydrocarbon detergent.
For solving the problems of the technologies described above, the technical solution used in the present invention is: the recyclable hydrocarbon detergent of this multi-functional environment-protection constitutes raw material and weight proportion is:
C 11H 2450-60 part;
C 12H 2630-40 part;
Alcohol ether compound or C 5-C 7Isomery alcohol 5-10 part.
In the technique scheme, the recyclable hydrocarbon detergent of described multi-functional environment-protection constitutes raw material and weight proportion is:
C 11H 2450 parts;
C 12H 2640 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
Or in the technique scheme, the recyclable hydrocarbon detergent of described multi-functional environment-protection constitutes raw material and weight proportion is:
C 11H 2455 parts;
C 12H 2635 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
Or in the technique scheme, the recyclable hydrocarbon detergent of described multi-functional environment-protection constitutes raw material and weight proportion is:
C 11H 2460 parts;
C 12H 2630 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
In the technique scheme, described C 11H 24Be the saturation isomerism undecane.
In the technique scheme, described C 12H 26Be saturated side chain dodecane.
In the technique scheme, described pure ether compound or C 5-C 7The boiling point of isomery alcohol is at 160-190 ℃, and is water oil two solvophilics.
The invention has the advantages that:
1, toxicity is low, and per os toxicity is nontoxic substantially, non-depletion of the ozone layer material, and the incineration of liquor product only is carbonic acid gas and water simultaneously, basic toxicological harmless has overcome the shortcoming of halohydrocarbon detergent in environment.
2, Polyoxyethylene Lauryl Ether not only has extremely strong solvency power to oily dirt, and unique prescription makes it for wetting ability dirt, metal break flour etc. equal clearing power be arranged also.
3, boiling point height, volatilization loss is few; Higher flash-point is also arranged, and safety performance is better.
4, refining degree height, Stability Analysis of Structures, boiling spread is narrow, is specially adapted to vacuum and reclaims cleaning equipment, and the rate of recovery can reach more than 80%.
5, consistency is good, be different from the destruction of halogenated hydrocarbon solvent to plastic rubber material, the recyclable hydrocarbon detergent of multi-functional environment-protection does not only have corrosive nature to metallic substance, for most of plastic cement, rubber mass good consistency is arranged also, can not produce dissolving, corrosive nature.
6, it is dirty effectively to clean on five metals and the plastic parts remaining greasy dirt, moisture, fingerprint, metal break flour etc. fast, resistatess such as tin cream also capable of washing, soldering flux, evaporation rate is moderate, noresidue, and can recycling use in suitable pressure regulating equipment, compared to the hydrocarbon detergent that uses on the market at present by longer work-ing life and economy, and the present invention is the best substitute of traditional freonll-11, halogenated hydrocarbon solvent and common hydrocarbon detergent to human body toxicological harmless, non-ODS product.
Embodiment:
The present invention is further described below in conjunction with specific embodiment:
Embodiment one
Present embodiment one concrete raw material and weight are:
50 kilograms of saturation isomerism undecanes;
40 kilograms of saturated side chain dodecanes;
10 kilograms of alcohol ether compounds.
Wherein, the boiling point of above-mentioned pure ether compound is at 175-190 ℃, and is water oil two solvophilics.
Adopt the present invention of above-mentioned raw materials and weight, it is as clear as crystal liquid, and is tasteless, and density is 0.73, and flash-point is 55, and the KB value is 31, and surface tension is 23.It is mainly used in removes all kinds of treated oils, the lines of the hand that adhere on the accurate five metals component, and the tin cream of electronic component remnants, soldering flux etc.Be applicable to various cleaning and drying devices, vacuum decompression degassing ultrasonic cleaning apparatus especially, rate of recovery height.
Embodiment two
Present embodiment two concrete raw materials and weight are:
55 kilograms of saturation isomerism undecanes;
35 kilograms of saturated side chain dodecanes;
C 5-C 710 kilograms of isomery alcohol.
Wherein, above-mentioned C 5-C 7The boiling point of isomery alcohol is at 170-185 ℃, and is water oil two solvophilics.
Adopt the present invention of above-mentioned raw materials and weight, it is as clear as crystal liquid, and is tasteless, and density is 0.73, and flash-point is 53, and the KB value is 30, and surface tension is 22.It is mainly used in the workpiece of blind hole, slit and Xiao Bao, can effectively remove remaining greasy dirt fast, especially at the aqueous machining fluid that adopts in the course of processing good effect be arranged also.Be applicable to various cleaning and drying devices, vacuum decompression degassing ultrasonic cleaning apparatus especially, rate of recovery height.
Embodiment three
Present embodiment three concrete raw materials and weight are:
60 kilograms of saturation isomerism undecanes;
30 kilograms of saturated side chain dodecanes;
5 kilograms of alcohol ether compounds;
C 5-C 75 kilograms of isomery alcohol.
Wherein, above-mentioned pure ether compound, C 5-C 7The boiling point of isomery alcohol is at 170-190 ℃, and is water oil two solvophilics.
Adopt the present invention of above-mentioned raw materials and weight, it is as clear as crystal liquid, and is tasteless, and density is 0.74, and flash-point is 56, and the KB value is 32, and surface tension is 24.It is mainly used in and cleans the treated oil that adheres on photovoltaic stamping parts, micro motor, the metallic sintered products, dust, water stain etc.; Applicable to various cleaning and drying devices, vacuum decompression degassing ultrasonic cleaning apparatus especially, rate of recovery height.
Certainly, the above only is several example of the present invention, be not to limit the scope of the present invention, all equivalences of doing according to the described structure of the present patent application claim, feature and principle change or modify, and all should be included in the present patent application claim.

Claims (7)

1. recyclable hydrocarbon detergent of multi-functional environment-protection, it is characterized in that: the formation raw material and the weight proportion of the recyclable hydrocarbon detergent of this multi-functional environment-protection are:
C 11H 2450-60 part;
C 12H 2630-40 part;
Alcohol ether compound or C 5-C 7Isomery alcohol 5-10 part.
2. the recyclable hydrocarbon detergent of a kind of multi-functional environment-protection according to claim 1 is characterized in that: the formation raw material and the weight proportion of the recyclable hydrocarbon detergent of described multi-functional environment-protection are:
C 11H 2450 parts;
C 12H 2640 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
3. the recyclable hydrocarbon detergent of a kind of multi-functional environment-protection according to claim 1 is characterized in that: the formation raw material and the weight proportion of the recyclable hydrocarbon detergent of described multi-functional environment-protection are:
C 11H 2455 parts;
C 12H 2635 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
4. the recyclable hydrocarbon detergent of a kind of multi-functional environment-protection according to claim 1 is characterized in that: the formation raw material and the weight proportion of the recyclable hydrocarbon detergent of described multi-functional environment-protection are:
C 11H 2460 parts;
C 12H 2630 parts;
Alcohol ether compound or C 5-C 710 parts of isomery alcohol.
5. according to any recyclable hydrocarbon detergent of described a kind of multi-functional environment-protection of claim 1-4, it is characterized in that: described C 11H 24Be the saturation isomerism undecane.
6. according to any recyclable hydrocarbon detergent of described a kind of multi-functional environment-protection of claim 1-4, it is characterized in that: described C 12H 26Be saturated side chain dodecane.
7. according to any recyclable hydrocarbon detergent of described a kind of multi-functional environment-protection of claim 1-4, it is characterized in that: described pure ether compound or C 5-C 7The boiling point of isomery alcohol is at 160-190 ℃, and is water oil two solvophilics.
CN 201010604116 2010-12-24 2010-12-24 Multifunctional environmental-friendly recyclable hydrocarbon detergent Pending CN102041195A (en)

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Application Number Priority Date Filing Date Title
CN 201010604116 CN102041195A (en) 2010-12-24 2010-12-24 Multifunctional environmental-friendly recyclable hydrocarbon detergent

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502478A (en) * 2017-09-21 2017-12-22 东莞智高化学科技有限公司 A kind of hydrocarbon remover of printed circuit board (PCB) and preparation method thereof
CN109294748A (en) * 2018-08-03 2019-02-01 天津普罗米新材料有限公司 It is a kind of for cleaning the agent for carbon hydrogen detergent of microparticle
CN109504563A (en) * 2018-12-31 2019-03-22 广东新球清洗科技股份有限公司 Agent for carbon hydrogen detergent is used in cutting fluid removing
CN111334381A (en) * 2018-12-19 2020-06-26 深圳市天正隆科技有限公司 Wind driven generator cleaning agent and use method thereof
CN113528248A (en) * 2021-07-27 2021-10-22 诺而曼环保科技(江苏)有限公司 Hydrocarbon cleaning agent for semiconductor and preparation method
CN113652312A (en) * 2021-08-27 2021-11-16 常州智高化学科技有限公司 Efficient hydrocarbon detergent for metal parts

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Publication number Priority date Publication date Assignee Title
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CN1990843A (en) * 2005-12-29 2007-07-04 比亚迪股份有限公司 Liquid crystal cleaning agent composition and preparing method thereof
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN101748003A (en) * 2009-12-23 2010-06-23 深圳市唯特偶化工开发实业有限公司 Halogen free environment-friendly cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1135394A (en) * 1995-02-17 1996-11-13 松下电器产业株式会社 Method for cleaning part
CN1990843A (en) * 2005-12-29 2007-07-04 比亚迪股份有限公司 Liquid crystal cleaning agent composition and preparing method thereof
CN101591590A (en) * 2008-05-28 2009-12-02 天津市华阳新兴科技有限公司 A kind of environmental protection and safety type hydrocarbon cleaning agent
CN101748003A (en) * 2009-12-23 2010-06-23 深圳市唯特偶化工开发实业有限公司 Halogen free environment-friendly cleaning agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502478A (en) * 2017-09-21 2017-12-22 东莞智高化学科技有限公司 A kind of hydrocarbon remover of printed circuit board (PCB) and preparation method thereof
CN109294748A (en) * 2018-08-03 2019-02-01 天津普罗米新材料有限公司 It is a kind of for cleaning the agent for carbon hydrogen detergent of microparticle
CN111334381A (en) * 2018-12-19 2020-06-26 深圳市天正隆科技有限公司 Wind driven generator cleaning agent and use method thereof
CN109504563A (en) * 2018-12-31 2019-03-22 广东新球清洗科技股份有限公司 Agent for carbon hydrogen detergent is used in cutting fluid removing
CN113528248A (en) * 2021-07-27 2021-10-22 诺而曼环保科技(江苏)有限公司 Hydrocarbon cleaning agent for semiconductor and preparation method
CN113652312A (en) * 2021-08-27 2021-11-16 常州智高化学科技有限公司 Efficient hydrocarbon detergent for metal parts

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Application publication date: 20110504