CN113652312A - Efficient hydrocarbon detergent for metal parts - Google Patents
Efficient hydrocarbon detergent for metal parts Download PDFInfo
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- CN113652312A CN113652312A CN202110998426.0A CN202110998426A CN113652312A CN 113652312 A CN113652312 A CN 113652312A CN 202110998426 A CN202110998426 A CN 202110998426A CN 113652312 A CN113652312 A CN 113652312A
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- Prior art keywords
- mixture
- stirring
- stirring time
- metal parts
- reaction kettle
- Prior art date
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- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 32
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 32
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 32
- 239000003599 detergent Substances 0.000 title claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 22
- 239000002184 metal Substances 0.000 title claims abstract description 22
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 52
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims abstract description 28
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims abstract description 27
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 26
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000003755 preservative agent Substances 0.000 claims abstract description 21
- 230000002335 preservative effect Effects 0.000 claims abstract description 21
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 18
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 17
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005642 Oleic acid Substances 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 17
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229960001484 edetic acid Drugs 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 13
- 229960002969 oleic acid Drugs 0.000 claims abstract description 9
- 235000013162 Cocos nucifera Nutrition 0.000 claims abstract description 8
- 244000060011 Cocos nucifera Species 0.000 claims abstract description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 8
- 150000001408 amides Chemical class 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 104
- 239000000203 mixture Substances 0.000 claims description 85
- 238000006243 chemical reaction Methods 0.000 claims description 41
- -1 polyoxyethylene Polymers 0.000 claims description 20
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 12
- 229940043237 diethanolamine Drugs 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 239000012188 paraffin wax Substances 0.000 claims description 5
- 239000010702 perfluoropolyether Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920002530 polyetherether ketone Polymers 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 229920000223 polyglycerol Polymers 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 abstract description 23
- 230000000694 effects Effects 0.000 abstract description 10
- 229940098424 potassium pyrophosphate Drugs 0.000 abstract description 4
- 229940001593 sodium carbonate Drugs 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000021315 omega 9 monounsaturated fatty acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1226—Phosphorus containing
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1233—Carbonates, e.g. calcite or dolomite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/182—Hydrocarbons branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3749—Polyolefins; Halogenated polyolefins; Natural or synthetic rubber; Polyarylolefins or halogenated polyarylolefins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Abstract
The invention discloses a high-efficiency hydrocarbon cleaning agent for metal parts, which relates to the technical field of hydrocarbon cleaning agents and adopts the technical scheme that: the compound feed comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 60-80 g of water, 12-14 g of saturated branched dodecane, 8-10 g of absolute ethanol, 13-15 g of isoparaffin, 15-17 g of normal alkane, 13-15 g of cycloparaffin and 8-12 g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 8-12 g of coconut diethanol amide, 10-12 g of oleic acid, 6-8 g of ethylene diamine tetraacetic acid, 16-20 g of sodium xylene sulfonate, 16-18 g of potassium pyrophosphate, 8-12 g of sodium carbonate, 12-16 g of nonionic surfactant, 2-4 g of thickening agent, 20-22 g of preservative and 22-24 g of heat-resistant agent, and the efficient hydrocarbon detergent for metal parts has the beneficial effects that: the coconut diethanol amide, oleic acid, ethylene diamine tetraacetic acid, sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate have the function of improving the washing effect.
Description
Technical Field
The invention relates to the technical field of hydrocarbon cleaning agents, and particularly relates to a high-efficiency hydrocarbon cleaning agent for metal parts.
Background
The distillate solvent obtained by distilling crude oil is called petroleum, petroleum hydrocarbon, industrial gasoline and the like, the definition of which is not clear up to now, the hydrocarbon is just a compound consisting of two elements as the name suggests, the lamp oil obtained by simply distilling crude oil is directly used as a cleaning agent in the past, and the hydrocarbon cleaning agent is gradually not used due to the odor, the ignition property and the drying property, has good environmental protection property and cleaning capability, and gradually becomes one of important industrial cleaning agents.
The prior art has the following defects: most of the existing hydrocarbon cleaning agents have poor cleaning effect and short preservation time, so that the cost input is increased.
Therefore, it is necessary to develop an efficient hydrocarbon cleaning agent for metal parts.
Disclosure of Invention
Therefore, the invention provides an efficient hydrocarbon cleaning agent for metal parts, which is prepared by selecting water, saturated branched dodecane, absolute ethyl alcohol, isoparaffin, normal alkane, cycloparaffin and aromatic hydrocarbon as raw materials, selecting cocoyl diethanol amine, oleic acid, ethylene diamine tetraacetic acid, sodium xylene sulfonate, potassium pyrophosphate, sodium carbonate, a nonionic surfactant, a thickening agent, a preservative and a heat-resistant agent as auxiliary materials and then proportioning according to a certain proportion, so that the problems of poor cleaning effect and short storage time of most of the existing hydrocarbon cleaning agents are solved.
In order to achieve the above purpose, the invention provides the following technical scheme: the efficient hydrocarbon cleaning agent for the metal parts comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 60-80 g of water, 12-14 g of saturated branched dodecane, 8-10 g of absolute ethanol, 13-15 g of isoparaffin, 15-17 g of normal alkane, 13-15 g of cycloparaffin and 8-12 g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 8-12 g of coconut diethanol amide, 10-12 g of oleic acid, 6-8 g of ethylene diamine tetraacetic acid, 16-20 g of sodium xylene sulfonate, 16-18 g of potassium pyrophosphate, 8-12 g of sodium carbonate, 12-16 g of nonionic surfactant, 2-4 g of thickening agent, 20-22 g of preservative and 22-24 g of heat-resistant agent.
Preferably, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil, fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Preferably, the thickening agent is one or a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.
Preferably, the preservative is one or a mixture of more of aqueous epoxy resin, high alumina cement and glass flake.
Preferably, the heat-resistant agent is one or a mixture of more of perfluoropolyether, polyether ether ketone, organosilicon and polyethylene.
Preferably, the preparation method comprises the following specific steps:
s1, adding water, saturated branched dodecane and absolute ethyl alcohol into a reaction kettle, and stirring to obtain a mixture A;
s2, placing the mixture A, isoparaffin, normal paraffin, cycloparaffin and aromatic hydrocarbon into a reaction kettle to be stirred, thereby obtaining a mixture B;
s3, placing cocoyl diethanol amine, oleic acid and ethylene diamine tetraacetic acid into a reaction kettle for stirring, and then placing sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate into the reaction kettle for stirring to obtain a mixture C;
s4, putting the mixture B, the mixture C and the nonionic surfactant into a reaction kettle, and stirring to obtain a mixture D;
s5, putting the mixture D and the preservative into a reaction kettle, and stirring to obtain a mixture E;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;
s7, the mixture F and the thickener are put into a reaction kettle and stirred to obtain a detergent.
Preferably, in the step S1, the stirring time and temperature are 420-520 ℃, and the stirring time is 45-55 min;
in the step S2, the stirring time and temperature are 440-480 ℃, and the stirring time is 45-55 min.
Preferably, in the step S3, the stirring temperature of sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is not added is 540-580 ℃, the stirring time is 60-66 min, the stirring temperature of sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is 550-560 ℃, and the stirring time is 70-80 min.
Preferably, in the step S4, the stirring time and temperature are 420-440 ℃, and the stirring time is 55-60 min;
in the step S5, the stirring time and temperature are 440-460 ℃, and the stirring time is 56-62 min.
Preferably, in the step S6, the stirring time and temperature are 520-540 ℃, and the stirring time is 70-80 min;
in the step S7, the stirring time and temperature are 400-420 ℃, and the stirring time is 45-50 min.
The invention has the beneficial effects that:
1. the coconut diethanol amide, oleic acid, ethylene diamine tetraacetic acid, sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate have the function of improving the washing effect;
2. the coconut diethanol amide also has the function of improving rust prevention;
3. the preservative can improve the corrosion resistance of the cleaning agent;
4. the heat resistance of the cleaning agent is improved through the heat-resistant agent;
5. the preservative and the heat-resistant agent can prolong the storage time of the cleaning agent, thereby reducing the cost.
Detailed Description
The following description of the preferred embodiments of the present invention is provided for the purpose of illustration and description, and is in no way intended to limit the invention.
Example 1:
the invention provides a high-efficiency hydrocarbon cleaning agent for metal parts, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 60g of water, 12g of saturated branched dodecane, 8g of absolute ethanol, 13g of isoparaffin, 15g of normal alkane, 13g of cycloparaffin and 8g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 8g of cocoyl diethanolamine, 10g of oleic acid, 6g of ethylenediamine tetraacetic acid, 16g of sodium xylene sulfonate, 16g of potassium pyrophosphate, 8g of sodium carbonate, 12g of nonionic surfactant, 2g of thickener, 20g of preservative and 22g of heat-resistant agent;
furthermore, the cocoanut diethanol amine is amber viscous liquid, is soluble in water, has strong foamability, penetrability, detergency, antirust capacity, good dispersibility and the like, and is prepared by the reaction of coconut oleic acid and diethanol amine;
oleic acid is a monounsaturated Omega-9 fatty acid, exists in animals and plants, and is hydrogenated and added to obtain stearic acid, so that the stearic acid has good decontamination capability;
ethylenediaminetetraacetic acid is an organic compound that can be used in detergents;
sodium xylene sulfonate is white crystalline powder, have similar petroleum smell, flammable, it is apt to be damped, can be through xylene sulfonation back and neutralize and prepare with liquid caustic soda, use as solubilizer in the detergent, also used as the component of the dry cleaning agent, fungicide, metal processing cleaner, etc., sodium xylene sulfonate is used in the liquid detergent, can be used as coupling agent, hydrotrope, homogenizing agent, dispersing agent, and make cloud point, viscosity drop;
potassium pyrophosphate is an inorganic substance, and is industrially used for surface treatment, high-grade detergents, paint coatings, detergents, dispersants, buffers and the like;
sodium carbonate is an inorganic compound, has certain corrosivity, and can be used for cleaning agents and detergents;
the preservative has the effect of improving the corrosion prevention effect of the hydrocarbon cleaning agent;
the heat-resistant agent has the effect of improving the heat resistance of the hydrocarbon detergent.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil, fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickening agent is one or a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.
Further, the preservative is one or a mixture of more of aqueous epoxy resin, high-alumina cement and glass flake.
Further, the heat-resistant agent is one or a mixture of more of perfluoropolyether, polyether ether ketone, organosilicon and polyethylene.
Further, the preparation method comprises the following specific steps:
s1, adding water, saturated branched dodecane and absolute ethyl alcohol into a reaction kettle, and stirring to obtain a mixture A, wherein the stirring time is 420 ℃ and 45 min;
s2, placing the mixture A, isoparaffin, normal paraffin, cycloparaffin and aromatic hydrocarbon into a reaction kettle to be stirred, thereby obtaining a mixture B, wherein the stirring time is 440 ℃, and the stirring time is 45 min;
s3, placing cocoyl diethanolamine, oleic acid and ethylene diamine tetraacetic acid into a reaction kettle for stirring, placing sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate into the reaction kettle for stirring after stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is 540 ℃, the stirring time is 60min, the stirring temperature of the mixture C after the sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate are placed is 550 ℃, and the stirring time is 70 min;
s4, placing the mixture B, the mixture C and the nonionic surfactant into a reaction kettle, and stirring to obtain a mixture D, wherein the stirring time is 420 ℃ and 55 min;
s5, placing the mixture D and the preservative into a reaction kettle to be stirred, so as to obtain a mixture E, wherein the stirring time is 440 ℃, and the stirring time is 56 min;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 520 ℃, and the stirring time is 70 min;
and S7, putting the mixture F and the thickening agent into a reaction kettle, and stirring to obtain the detergent, wherein the stirring time is 400 ℃ and 45 min.
Example 2:
the invention provides a high-efficiency hydrocarbon cleaning agent for metal parts, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 70g of water, 13g of saturated branched dodecane, 9g of absolute ethanol, 14g of isoparaffin, 16g of normal alkane, 14g of cycloparaffin and 10g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 10g of cocoyl diethanolamine, 11g of oleic acid, 7g of ethylenediamine tetraacetic acid, 18g of sodium xylene sulfonate, 17g of potassium pyrophosphate, 10g of sodium carbonate, 14g of nonionic surfactant, 3g of thickener, 21g of preservative and 23g of heat-resistant agent.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil, fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickening agent is one or a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.
Further, the preservative is one or a mixture of more of aqueous epoxy resin, high-alumina cement and glass flake.
Further, the heat-resistant agent is one or a mixture of more of perfluoropolyether, polyether ether ketone, organosilicon and polyethylene.
Further, the preparation method comprises the following specific steps:
s1, adding water, saturated branched dodecane and absolute ethyl alcohol into a reaction kettle, and stirring to obtain a mixture A, wherein the stirring time is 470 ℃ and 50 min;
s2, placing the mixture A, isoparaffin, normal paraffin, cycloparaffin and aromatic hydrocarbon into a reaction kettle to be stirred, thereby obtaining a mixture B, wherein the stirring time is 460 ℃, and the stirring time is 50 min;
s3, placing cocoyl diethanol amine, oleic acid and ethylene diamine tetraacetic acid into a reaction kettle for stirring, placing sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate into the reaction kettle for stirring after stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without the sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is 560 ℃, the stirring time is 63min, the stirring temperature of the mixture C after the sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate are placed is 555 ℃, and the stirring time is 75 min;
s4, putting the mixture B, the mixture C and the nonionic surfactant into a reaction kettle, and stirring to obtain a mixture D, wherein the stirring time is 430 ℃ and 57.5 min;
s5, placing the mixture D and the preservative into a reaction kettle to be stirred, so as to obtain a mixture E, wherein the stirring time is 450 ℃, and the stirring time is 59 min;
s6, placing the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 530 ℃ and 75 min;
and S7, putting the mixture F and the thickening agent into a reaction kettle, and stirring to obtain the detergent, wherein the stirring time is 410 ℃ and 47.5 min.
Example 3:
the invention provides a high-efficiency hydrocarbon cleaning agent for metal parts, which comprises raw materials and auxiliary materials, wherein the raw materials (by weight) comprise: 80g of water, 14g of saturated branched dodecane, 10g of absolute ethanol, 15g of isoparaffin, 17g of normal alkane, 15g of cycloparaffin and 12g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 12g of cocoyl diethanolamine, 12g of oleic acid, 8g of ethylenediamine tetraacetic acid, 20g of sodium xylene sulfonate, 18g of potassium pyrophosphate, 12g of sodium carbonate, 16g of nonionic surfactant, 4g of thickener, 22g of preservative and 24g of heat-resistant agent.
Further, the nonionic surfactant is one or a mixture of more of polyoxyethylene castor oil, fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
Further, the thickening agent is one or a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.
Further, the preservative is one or a mixture of more of aqueous epoxy resin, high-alumina cement and glass flake.
Further, the heat-resistant agent is one or a mixture of more of perfluoropolyether, polyether ether ketone, organosilicon and polyethylene.
Further, the preparation method comprises the following specific steps:
s1, adding water, saturated branched dodecane and absolute ethyl alcohol into a reaction kettle, and stirring to obtain a mixture A, wherein the stirring time is 520 ℃ and 55 min;
s2, placing the mixture A, isoparaffin, normal paraffin, cycloparaffin and aromatic hydrocarbon into a reaction kettle to be stirred, thereby obtaining a mixture B, wherein the stirring time is 480 ℃ and the stirring time is 55 min;
s3, placing cocoyl diethanolamine, oleic acid and ethylene diamine tetraacetic acid into a reaction kettle for stirring, placing sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate into the reaction kettle for stirring after stirring to obtain a mixture C, wherein the stirring temperature of the mixture C without sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is 580 ℃, the stirring time is 66min, the stirring temperature of the mixture C after the sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate are placed is 560 ℃, and the stirring time is 80 min;
s4, placing the mixture B, the mixture C and the nonionic surfactant into a reaction kettle, and stirring to obtain a mixture D, wherein the stirring time is 440 ℃, and the stirring time is 60 min;
s5, placing the mixture D and the preservative into a reaction kettle to be stirred, so as to obtain a mixture E, wherein the stirring time is 460 ℃, and the stirring time is 62 min;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F, wherein the stirring time is 540 ℃, and the stirring time is 80 min;
and S7, putting the mixture F and the thickening agent into a reaction kettle, and stirring to obtain the detergent, wherein the stirring time is 420 ℃ and 50 min.
The hydrocarbon detergents prepared in examples 1-3 above were compared to obtain the following data:
as can be seen from the above table, the hydrocarbon cleaning agent prepared in examples 1 to 3 has better performance in terms of cleaning effect, corrosion resistance, heat resistance and storage time, but the hydrocarbon cleaning agent has different effects in terms of cleaning effect, corrosion resistance, heat resistance and storage time due to different proportions of water, saturated branched dodecane, absolute ethanol, isoparaffin, normal alkane, cycloalkane, aromatic hydrocarbon, cocoyl diethanolamine, oleic acid, ethylenediaminetetraacetic acid, sodium xylenesulfonate, potassium pyrophosphate, sodium carbonate, nonionic surfactant, thickener, preservative and heat resistance.
The above description is only a preferred embodiment of the present invention, and any person skilled in the art may modify the present invention or modify it into an equivalent technical solution by using the technical solution described above. Therefore, any simple modifications or equivalent substitutions made in accordance with the technical solution of the present invention are within the scope of the claims of the present invention.
Claims (10)
1. The high-efficiency hydrocarbon detergent for the metal parts comprises raw materials and auxiliary materials, and is characterized in that: the raw materials (by weight) comprise: 60-80 g of water, 12-14 g of saturated branched dodecane, 8-10 g of absolute ethanol, 13-15 g of isoparaffin, 15-17 g of normal alkane, 13-15 g of cycloparaffin and 8-12 g of aromatic hydrocarbon, wherein the auxiliary materials (by weight) comprise: 8-12 g of coconut diethanol amide, 10-12 g of oleic acid, 6-8 g of ethylene diamine tetraacetic acid, 16-20 g of sodium xylene sulfonate, 16-18 g of potassium pyrophosphate, 8-12 g of sodium carbonate, 12-16 g of nonionic surfactant, 2-4 g of thickening agent, 20-22 g of preservative and 22-24 g of heat-resistant agent.
2. The efficient hydrocarbon detergent for metal parts as claimed in claim 1, wherein: the nonionic surfactant is one or more of polyoxyethylene castor oil, fatty alcohol polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester and polyglycerol fatty acid ester.
3. The efficient hydrocarbon detergent for metal parts as claimed in claim 1, wherein: the thickening agent is one or a mixture of polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.
4. The efficient hydrocarbon detergent for metal parts as claimed in claim 1, wherein: the preservative is one or a mixture of more of waterborne epoxy resin, high-alumina cement and glass flakes.
5. The efficient hydrocarbon detergent for metal parts as claimed in claim 1, wherein: the heat-resistant agent is one or a mixture of more of perfluoropolyether, polyether ether ketone, organic silicon and polyethylene.
6. The efficient hydrocarbon detergent for metal parts as claimed in claim 1, wherein: the preparation method comprises the following specific steps:
s1, adding water, saturated branched dodecane and absolute ethyl alcohol into a reaction kettle, and stirring to obtain a mixture A;
s2, placing the mixture A, isoparaffin, normal paraffin, cycloparaffin and aromatic hydrocarbon into a reaction kettle to be stirred, thereby obtaining a mixture B;
s3, placing cocoyl diethanol amine, oleic acid and ethylene diamine tetraacetic acid into a reaction kettle for stirring, and then placing sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate into the reaction kettle for stirring to obtain a mixture C;
s4, putting the mixture B, the mixture C and the nonionic surfactant into a reaction kettle, and stirring to obtain a mixture D;
s5, putting the mixture D and the preservative into a reaction kettle, and stirring to obtain a mixture E;
s6, putting the mixture E and the heat-resistant agent into a reaction kettle, and stirring to obtain a mixture F;
s7, the mixture F and the thickener are put into a reaction kettle and stirred to obtain a detergent.
7. The efficient hydrocarbon detergent for metal parts as claimed in claim 6, wherein: in the step S1, the stirring time and temperature is 420-520 ℃, and the stirring time is 45-55 min;
in the step S2, the stirring time and temperature are 440-480 ℃, and the stirring time is 45-55 min.
8. The efficient hydrocarbon detergent for metal parts as claimed in claim 6, wherein: in the step S3, the stirring temperature of sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is not added is 540-580 ℃, the stirring time is 60-66 min, the stirring temperature of sodium xylene sulfonate, potassium pyrophosphate and sodium carbonate is 550-560 ℃, and the stirring time is 70-80 min.
9. The efficient hydrocarbon detergent for metal parts as claimed in claim 6, wherein: in the step S4, the stirring time and temperature is 420-440 ℃, and the stirring time is 55-60 min;
in the step S5, the stirring time and temperature are 440-460 ℃, and the stirring time is 56-62 min.
10. The efficient hydrocarbon detergent for metal parts as claimed in claim 6, wherein: in the step S6, the stirring time and temperature is 520-540 ℃, and the stirring time is 70-80 min;
in the step S7, the stirring time and temperature are 400-420 ℃, and the stirring time is 45-50 min.
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CN102041195A (en) * | 2010-12-24 | 2011-05-04 | 东莞市智高化学原料有限公司 | Multifunctional environmental-friendly recyclable hydrocarbon detergent |
CN106635542A (en) * | 2015-10-30 | 2017-05-10 | 江阴市五洋化工有限公司 | A novel hydrocarbon cleaning agent |
CN109762679A (en) * | 2019-03-07 | 2019-05-17 | 中山市浩科化工科技有限公司 | A kind of high-purity agent for carbon hydrogen detergent of environment-friendly type and preparation method thereof |
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CN102041195A (en) * | 2010-12-24 | 2011-05-04 | 东莞市智高化学原料有限公司 | Multifunctional environmental-friendly recyclable hydrocarbon detergent |
CN106635542A (en) * | 2015-10-30 | 2017-05-10 | 江阴市五洋化工有限公司 | A novel hydrocarbon cleaning agent |
CN109762679A (en) * | 2019-03-07 | 2019-05-17 | 中山市浩科化工科技有限公司 | A kind of high-purity agent for carbon hydrogen detergent of environment-friendly type and preparation method thereof |
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