CN109055024A - A kind of multi-functional cleaning solution - Google Patents

A kind of multi-functional cleaning solution Download PDF

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Publication number
CN109055024A
CN109055024A CN201810968512.5A CN201810968512A CN109055024A CN 109055024 A CN109055024 A CN 109055024A CN 201810968512 A CN201810968512 A CN 201810968512A CN 109055024 A CN109055024 A CN 109055024A
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CN
China
Prior art keywords
cleaning solution
sodium
alcohol
raw
fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810968512.5A
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Chinese (zh)
Inventor
丁爱平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anqing One Zhi Mei Chemical Industry Co Ltd
Original Assignee
Anqing One Zhi Mei Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anqing One Zhi Mei Chemical Industry Co Ltd filed Critical Anqing One Zhi Mei Chemical Industry Co Ltd
Priority to CN201810968512.5A priority Critical patent/CN109055024A/en
Publication of CN109055024A publication Critical patent/CN109055024A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008Polymeric surface-active agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds

Abstract

The present invention provides a kind of multi-functional cleaning solution, it is prepared by the raw material of following weight percent: sodium citrate 8%-15%, sodium sulfate of polyethenoxy ether of fatty alcohol 7%-12%, citric acid 6%-11%, benzotriazole 0.05%-0.15%, ethyl alcohol 15%-30%, sodium alcohol ether carboxylate 3%-8%, alpha-sulfo-fatty acid formicester sodium salt 0.5%-1.5%, oleic acid triisopropanolamine rouge 0.1%-0.5%, triethanolamine 10%-20%, surplus are deionized water, wherein the sum of each raw material weight percentage is 100%;Multi-functional cleaning solution of the invention does not corrode, odorlessness, it is nontoxic, stability is high, and applicability is wide, is applied not only to the cleaning of textile product and plastic products, it may also be used for the surface blot for stainless steel, stainless iron, aluminium, copper material, kirsite and precision equipment cleans, and decontamination cleaning ability is strong, it is not damaged to cleaning substance.

Description

A kind of multi-functional cleaning solution
Technical field
The present invention relates to a kind of cleaning solution technical field, specially a kind of multi-functional cleaning solution.
Background technique
Currently, the cleaning solution occurred in the market mostly uses greatly organic solvent washing liquid and acid-alkali washing liquid.Organic solvent is used Measure big, at high cost, and most organic solvent is volatile, easy firing and there are certain toxicity, it be easy to cause secondary pollution, and by In the reasons such as the selection of surfactant and formulation composition be unreasonable, the cleaning effect of heavy oil stain is not very ideal, usually It is difficult to achieve the effect that clean.And acid-alkali washing fluidity can be relatively single, smaller scope of application, and it is high to be badly in need of a kind of stability And the cleaning solution that applicability is wide.
Summary of the invention
The purpose of the present invention is to provide a kind of cleaning solutions, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme: a kind of multi-functional cleaning solution, by following parts by weight Raw material is prepared:
A kind of multi-functional cleaning solution, it is characterised in that: be prepared by the raw material of following weight percent:
Sodium citrate 8%-15%
Sodium sulfate of polyethenoxy ether of fatty alcohol 7%-12%
Citric acid 6%-11%
Benzotriazole 0.05%-0.15%
Ethyl alcohol 15%-30%
Sodium alcohol ether carboxylate 3%-8%
Alpha-sulfo-fatty acid formicester sodium salt 0.5%-1.5%
Oleic acid triisopropanolamine rouge 0.1%-0.5%
Triethanolamine 10%-20%
Surplus is deionized water, wherein the sum of each raw material weight percentage is 100%.
Preferably, a kind of multi-functional cleaning solution, is prepared by the raw material of following weight percent:
Sodium citrate 10%-13%
Sodium sulfate of polyethenoxy ether of fatty alcohol 8%-10%
Citric acid 7%-9%
Benzotriazole 0.08%-0.1%
Ethyl alcohol 20%-25%
Sodium alcohol ether carboxylate 5%-7%
Alpha-sulfo-fatty acid formicester sodium salt 0.8%-1.1%
Oleic acid triisopropanolamine rouge 0.2%-0.3%
Triethanolamine 13%-17%
Surplus is deionized water, wherein the sum of each raw material weight percentage is 100%.
Above-mentioned cleaning solution further comprises preparation method, specifically:
(1) raw material is weighed by above-mentioned weight percent, first deionized water is added in blender, then successively added into blender Enter sodium citrate, sodium sulfate of polyethenoxy ether of fatty alcohol, citric acid, citric acid, triethanolamine and sodium alcohol ether carboxylate, when being added Stirring, until stirring evenly, mixing speed 50-70r/min, mixing time 30-40min, whipping temp is 60-80 DEG C;
(2) alpha-sulfo-fatty acid formicester sodium salt, oleic acid triisopropanolamine rouge and second are sequentially added in mixed liquor in step (1) Alcohol is stirred while adding to uniform, mixing time 20-30min, and whipping temp is 30-40 DEG C, stand 1h up to the present invention at Product cleaning solution.
Sodium sulfate of polyethenoxy ether of fatty alcohol is soluble easily in water in the present invention, have excellent decontamination, emulsification, foam performance and Hard water resistance performance, mild washing property will not damage skin;Benzotriazole, mainly as water treatment agent, metal antirusting agent And corrosion inhibiter;Sodium alcohol ether carboxylate, a kind of anionic surfactant have good soil release performance, wetability, emulsibility, dispersion Property and dispersion of calcium soap;Alpha-sulfo-fatty acid formicester sodium salt, a kind of surfactant, resistance to hard water is strong, also has good Hydrolytic stability, strong dirt-removing power and foaming characteristic are strong;Oleic acid triisopropanolamine rouge, a kind of cationic surface active agent have Stronger emulsifying capacity and clean ability;Sodium citrate, the present invention in thickener, be adjusted cleaning solution concentration;Citric acid, PH value is adjusted in a kind of PH regulator;Ethyl alcohol, the present invention in organic additive;Triethanolamine can improve oily dirt, meanwhile, By improving detergency ability, and triethanolamine has its fabulous compatibility, the highly effective chelating agent as each heavy metal species.
Compared with prior art, the beneficial effects of the present invention are:
(1) do not corrode, odorlessness is nontoxic, and stability is high;
(2) applicability is wide, is applied not only to the cleaning of textile product and plastic products, it may also be used for is used for stainless steel, stainless iron, aluminium The surface blot cleaning of material, copper material, kirsite and precision equipment, and decontamination cleaning ability is strong, it is not damaged to cleaning substance.
Specific embodiment
Technical scheme of the present invention will be further described combined with specific embodiments below, but the present invention is not limited to this A little embodiments.
Embodiment 1 weighs each raw material by corresponding 1 data of embodiment of table 1;
(1) raw material is weighed by above-mentioned weight percent, first deionized water is added in blender, then successively added into blender Enter sodium citrate, sodium sulfate of polyethenoxy ether of fatty alcohol, citric acid, citric acid, triethanolamine and sodium alcohol ether carboxylate, when being added Stirring, until stirring evenly, mixing speed 60r/min, mixing time 30min, whipping temp is 70 DEG C;
(2) alpha-sulfo-fatty acid formicester sodium salt, oleic acid triisopropanolamine rouge and second are sequentially added in mixed liquor in step (1) Alcohol is stirred while adding to uniform, mixing time 25min, and whipping temp is 30 DEG C, stands 1h up to embodiment 1.
Embodiment 2 weighs each raw material by corresponding 2 data of embodiment of table 1;
The preparation method is the same as that of Example 1.
Embodiment 3 weighs each raw material by corresponding 3 data of embodiment of table 1;
The preparation method is the same as that of Example 1.
Embodiment 4 weighs each raw material by corresponding 4 data of embodiment of table 1;
(1) raw material is weighed by above-mentioned weight percent, first deionized water is added in blender, then successively added into blender Enter sodium citrate, sodium sulfate of polyethenoxy ether of fatty alcohol, citric acid, citric acid, triethanolamine and sodium alcohol ether carboxylate, when being added Stirring, until stirring evenly, mixing speed 70r/min, mixing time 40min, whipping temp is 60 DEG C;
(2) alpha-sulfo-fatty acid formicester sodium salt, oleic acid triisopropanolamine rouge and second are sequentially added in mixed liquor in step (1) Alcohol is stirred while adding to uniform, mixing time 30min, and whipping temp is 30 DEG C, stands 1h up to embodiment 4.
Embodiment 5 weighs each raw material by corresponding 5 data of embodiment of table 1;
Preparation method is the same as embodiment 4.
Embodiment 6 weighs each raw material by corresponding 6 data of embodiment of table 1;
Preparation method is the same as embodiment 4.
Table one: each Example formulations list position: L
It is used to cleaning solution prepared by embodiment 1-6 to test its performance, as described in table one.It wherein cleans rust staining performance test: adopting It is dipped into ferrous solution after 5 hours and is taken out with six groups of identical copper sheets, after dry, cleaned with cleaning solution, test cleaning rust staining performance.
Cleaning solution decontaminates performance test: being dipped into butter after half an hour and is taken out using the identical clothing of six groups of specifications, done It after dry, is cleaned with cleaning solution, test cleaning oil mark performance.
Corrosive nature test: clothing and iron plate have corrosion-free in observation the various embodiments described above.
Table two: each embodiment performance test
Multi-functional cleaning solution prepared by embodiment 1-6, which is respectively put into different materials, to be cleaned, and is observed its cleaning effect and is obtained table Three.
Table three: the application of each embodiment on a different material
By table one and table two it is found that the beneficial effects of the present invention are:
(1) do not corrode, odorlessness is nontoxic, and stability is high;
(2) applicability is wide, is applied not only to the cleaning of textile product and plastic products, it may also be used for is used for stainless steel, stainless iron, aluminium The surface blot cleaning of material, copper material, kirsite and precision equipment, and decontamination cleaning ability is strong, it is not damaged to cleaning substance.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of multi-functional cleaning solution, it is characterised in that: be prepared by the raw material of following weight percent:
Sodium citrate 8%-15%
Sodium sulfate of polyethenoxy ether of fatty alcohol 7%-12%
Citric acid 6%-11%
Benzotriazole 0.05%-0.15%
Ethyl alcohol 15%-30%
Sodium alcohol ether carboxylate 3%-8%
Alpha-sulfo-fatty acid formicester sodium salt 0.5%-1.5%
Oleic acid triisopropanolamine rouge 0.1%-0.5%
Triethanolamine 10%-20%
Surplus is deionized water, wherein the sum of each raw material weight percentage is 100%.
2. a kind of multi-functional cleaning solution according to claim 1, it is characterised in that: by the raw material system of following weight percent It is standby to form:
Sodium citrate 10%-13%
Sodium sulfate of polyethenoxy ether of fatty alcohol 8%-10%
Citric acid 7%-9%
Benzotriazole 0.08%-0.1%
Ethyl alcohol 20%-25%
Sodium alcohol ether carboxylate 5%-7%
Alpha-sulfo-fatty acid formicester sodium salt 0.8%-1.1%
Oleic acid triisopropanolamine rouge 0.2%-0.3%
Triethanolamine 13%-17%
Surplus is deionized water, wherein the sum of each raw material weight percentage is 100%.
3. any multi-functional cleaning solution according to claim 1 to 2, it is characterised in that: the cleaning solution further includes its system Preparation Method, comprising the following steps:
(1) raw material is weighed by above-mentioned weight percent, first deionized water is added in blender, then successively added into blender Enter sodium citrate, sodium sulfate of polyethenoxy ether of fatty alcohol, citric acid, citric acid, triethanolamine and sodium alcohol ether carboxylate, when being added Stirring, until stirring evenly;
(2) alpha-sulfo-fatty acid formicester sodium salt, oleic acid triisopropanolamine rouge and second are sequentially added in mixed liquor in step (1) Alcohol stirs while adding to uniform, cleaning solution is got product after standing.
4. a kind of cleaning solution according to claim 3, it is characterised in that: mixing speed is 50-70r/ in the step (1) Min, mixing time 30-40min, whipping temp are 60-80 DEG C.
5. a kind of cleaning solution according to claim 3, it is characterised in that: mixing time is 20- in the step (2) 30min, whipping temp are 30-40 DEG C.
CN201810968512.5A 2018-08-23 2018-08-23 A kind of multi-functional cleaning solution Pending CN109055024A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810968512.5A CN109055024A (en) 2018-08-23 2018-08-23 A kind of multi-functional cleaning solution

Publications (1)

Publication Number Publication Date
CN109055024A true CN109055024A (en) 2018-12-21

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111304015A (en) * 2020-03-04 2020-06-19 广州衣鸣日化科技有限公司 Antibacterial high-concentration laundry detergent and preparation method thereof
CN111945215A (en) * 2020-07-24 2020-11-17 深圳市裕展精密科技有限公司 Deplating solution and deplating method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618398A (en) * 2012-02-15 2012-08-01 中国日用化学工业研究院 Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent
CN106479723A (en) * 2016-09-22 2017-03-08 长兴净安环保科技有限公司 Net Multifunctional detergent of a kind of effect entirely and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102618398A (en) * 2012-02-15 2012-08-01 中国日用化学工业研究院 Concentrated fabric liquid detergent containing fatty acid methyl ester sulfonate and preparation method of concentrated fabric liquid detergent
CN106479723A (en) * 2016-09-22 2017-03-08 长兴净安环保科技有限公司 Net Multifunctional detergent of a kind of effect entirely and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111304015A (en) * 2020-03-04 2020-06-19 广州衣鸣日化科技有限公司 Antibacterial high-concentration laundry detergent and preparation method thereof
CN111945215A (en) * 2020-07-24 2020-11-17 深圳市裕展精密科技有限公司 Deplating solution and deplating method

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Application publication date: 20181221

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