CN109153942A - Pretreatment compositions for textile stains - Google Patents
Pretreatment compositions for textile stains Download PDFInfo
- Publication number
- CN109153942A CN109153942A CN201780030264.3A CN201780030264A CN109153942A CN 109153942 A CN109153942 A CN 109153942A CN 201780030264 A CN201780030264 A CN 201780030264A CN 109153942 A CN109153942 A CN 109153942A
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- Prior art keywords
- composition
- acid
- water
- surfactant
- electrolyte
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- 239000000203 mixture Substances 0.000 title claims abstract description 132
- 239000004753 textile Substances 0.000 title claims description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 55
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- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 125000000129 anionic group Chemical group 0.000 claims abstract description 9
- 235000005985 organic acids Nutrition 0.000 claims abstract description 7
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000003599 detergent Substances 0.000 claims description 20
- -1 carboxyl Glycine betaine Chemical compound 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000007844 bleaching agent Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 11
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- LRBQNJMCXXYXIU-QWKBTXIPSA-N gallotannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@H]2[C@@H]([C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-QWKBTXIPSA-N 0.000 claims description 2
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- 125000000217 alkyl group Chemical group 0.000 description 13
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- 125000004432 carbon atom Chemical group C* 0.000 description 7
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical class [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of pH be 1 to 4 aqueous greasiness removal composition, it includes: the total surfactant content of (i) 2 to 10 weight % is made of three kinds of different types of surfactants；(ii) one or more organic acids are enough to make the pH of the composition in the range；The electrolyte of (iii) 0.5 to 15 weight %, wherein first kind surfactant is anionic, and the second class is non-ionic, and third class is amphoteric ion type.
Description
Technical field
Method the present invention relates to fabric pretreating compositions and for discharging some stains.This pretreatment combination size
Object is for just the serious of processing fabric to be stained or dyestain region before being washed with laundry detergent composition.Pretreatment compositions
Application facilitate the release and/or removal of spot.Region is easy to happen seriously is stained or dyestain by sebum comprising collar,
Cuff and shirt edge, are easy to happen and seriously stain.Some other includes industrial garments, dunnage, sheet and furniture.
Background technique
Laundry pretreatment compositions or prewashing greasiness removal composition have used for many years.Some newer products can be used
The form of family close friend obtains, such as pen and spot corrector (spot corrector).Other forms include liquid, spraying, gel,
Cleaning piece and foam.Consumer needs that composition is applied in spot before with laundry detergent composition laundering of textile fabrics.
These products generally comprise one or more organic solvents and one or more surfactants, optionally contain other addition
Agent.Usual surfactant is non-ionic, and organic solvent is one of many solvents known in the art.
Some spots can also be washed away using clear water easily.Some other can be washed away with detergent composition.
Machine oil, mechanical grease and other hydrophobicity oil-dirts are more obstinate, especially on cotton, polyester and polyester cotton.Cause
This, consumer removes spot usually using laundry pretreatment compositions as much as possible.
A variety of greasiness removal compositions are known.It is some effective to specific spot or a kind of spot.
2015/0315518 A1 of US (John Walls etc.) discloses alkali grain fabric cleaning composition, containing non-
Ionic surfactant, anionic surfactant and both sexes (amphoteric ion) surfactant and EDTA.Composition contains
There is exhibiting high surface activating agent.
US5948745A (Colgate Palmolive, 1990) discloses the detergent group that can be used within the scope of wide pH
Close object.Composition contains the mixture of the surfactant comprising anionic, amphoteric and nonionic surface active agent, with
And watersoluble organic polymer, such as polyethylene glycol.Enhancing by polymer cleaning.PH is 5 to 7.
2012/0270764 A1 of US (Stepan Co) is disclosed (to live on anionic surface containing sulphur methyl succinic hydrochlorate
Property agent), as the CAPB of glycine betaine and the aqueous acidic cleaning compositions of nonionic surface active agent.Composition to oiliness and
Greasy soils are effective.Composition contains exhibiting high surface activating agent.
6482786 B1 of US (P&G) discloses the alkaline fabric treatment composition based on bleaching agent, contains more than one
Surfactant.
WO2013092184 A1 (Unilever), which is disclosed, makes to stain the method that fabric is more easily cleaned.Keep fabric closeer
Water, to enhance the ability that they discharge oil-dirt.Fabric treatment composition includes metal salt, such as aluminium polychloride, carboxylic
Acid polymer, organic acid and polysaccharide.
GB338121 (Marquardt and Walter, 1930) is disclosed for cleaning the two-step method for staining fabric, wherein the
One component has saponifiable fatty acid, such as oleic acid, palmitinic acid or stearic acid, and the second component has basic soap agent,
Such as sodium carbonate, sodium bicarbonate or sodium hydroxide.
US20040058838 A1 (Unilever) discloses shear thinning gel detergent compositions.Composition contains spy
Quantitative unneutralized fatty acid depends on total surfactant content.The product provides pretreatment in the form of single product
With the main double dominant for washing detergency.WO10023043 A1 (Unilever) discloses laundry pretreatment compositions, has extremely
The fusing point of few 55 weight % is greater than 20 DEG C of fatty acid, polyol binder, water and surfactant.
WO2011/163457 A1 (P&G) discloses laundry detergent composition, with about 8 pH.
EP2767582 A1 (P&G) discloses the detergent composition without water-insoluble aliphatic ester.
WO2015/135866 A1 (Henkel) discloses detergent and pretreated group without water-insoluble aliphatic ester
Close object.
US4457857 A (Sepulveda Ralph R, 1984) discloses greasiness removal composition, contain with it is non-from
The Arrcostab of 25 to 100 weight % of subtype surfactant mixing.
EP0256354 A1 (Henkel, 1988) discloses laundry pretreatment compositions, contains solvent and 10 to 90 weights
Measure the aliphatic ester of %.Composition is free of organic acid.
Summary of the invention
According in a first aspect, disclose the aqueous greasiness removal composition that a kind of pH is 1 to 4, it includes:
(i) total surfactant content of 2 to 10 weight % is made of three kinds of different types of surfactants；
(ii) one or more organic acids are enough to make the pH of the composition in the range；With
(iii) electrolyte of 0.5 to 15 weight %,
Wherein first kind surfactant is anionic, and the second class is ethoxylated alcohol nonionic, and third class
It is amphoteric ion type.
According to second aspect, a kind of packaging product is disclosed comprising the product comprising the composition optionally includes
For distributing the device of the composition.
According to the third aspect, purposes of the composition of first aspect as textile stains remover is disclosed.
According to fourth aspect, a kind of method for mitigating textile stains is disclosed comprising make at least dyestain of the fabric
The first step that is contacted with the composition of 0.2 to 5ml first aspect of part, followed by making the fabric and alkaline detergent group
Close the second step of object contact.
It will be explained in detail the present invention.
Specific embodiment
Compared with oil, hydrophilic fibre such as cotton has bigger affinity to water.In laundry processes, water is from fabric
Oily dirt is shifted on surface, leads to dirt " rolling "；Then dirt can easily be removed by mechanism.Polyester fiber,
Those of such as be made of the copolymer of ethylene glycol and terephthalic acid (TPA), do not have this selective affinity to water, but is thin
Aqueous.It has been observed that common laundry does not satisfactorily remove oily dirt from this fabric, because existing between the two strong
Affinity.
The present invention provides a kind of laundry pretreatment compositions, and spot can be made loose, to make it in washing process
In be easier remove.
Composition according to the present invention is aqueous.It is that composition includes a large amount of water in other words.Preferred composition has
The water of 60 weight % to 95 weight %.More preferably water of the composition with 70 to 95 weight %.The water company of being formed in the composition
Continuous water phase, and it provides the medium for being easy to be applied on spot fabric.
Composition according to the present invention
pH
The pH of composition according to the present invention is in the range of 1 to 4.In other words, composition is acid.We are
It is highly effective to mechanical grease to observe that the composition in the scope of the invention is especially.Therefore, unlike existing with higher pH
At least some of technical combinations object, pH plays an important role.
In order to provide acidity, composition according to the present invention includes one or more organic acids, is enough to make pH described
In range.Skilled addressee will appreciate that or the amounts of one or more acid necessary to reaching desired pH can be calculated.
It is preferred that the pKa of one or more organic acids is 1 to 5 at 20 DEG C.Term pKa is introduced as the acidity for indicating weak acid
Index, wherein pKa is defined as pKa=-log10Ka, wherein Ka is acidity constant.For example, the pKa of acetic acid is 0.0000158
(=10-4.8), but pKa is 4.8, is simpler expression.PKa value is smaller, and acid is stronger.
It is preferred that organic acid is oxalic acid, tannic acid, lactic acid, citric acid, glycolic, maleic acid, tartaric acid, malic acid, acetic acid
Or at least one of ethanedioic acid.
It is expected that when, by the way that the salt of acid, such as sodium citrate, and corresponding acid is added, pH can be slightly increased.Therefore,
For example, when being desired to have the composition of pH about 3.5, then this composition preferably group containing citric acid and sodium citrate
It closes.Other suitable combinations include lactic acid and sodium lactate, acetic acid and sodium acetate.PH can be by reducing acid content and adding simultaneously
Or increase corresponding salt content to increase.In this case, salt such as sodium citrate also functions as electrolyte, is highly basic and weak
The salt of acid.Therefore, in such composition, other salt are optional as the use of " electrolyte ".
The pKa value of above-mentioned most of organic acids can be found in organic or physicochemical standard textbook.For example, oneself
The pKa of diacid is 4.43, and the pKa of malic acid is that the 3.40 and pKa of citric acid is 3.08.When acid has more than one carboxyl
When, the negative logarithm of the first acidity constant, such as oxalic acid are referred to referring to for pKa.In such a situation it is preferred to which pKa value is at least
One at 20 DEG C 1 to 5 in the range of.
Total surfactant content
The total surfactant content of composition according to the present invention is 2 to 10 weight %.This means that given combination object
Present in all surface activating agent summation.Composition tool is necessary there are three types of different types of surfactant, amount
Add up to 2-10 weight %.
First kind surfactant is anionic, and the second class is ethoxylated alcohol nonionic, and third class is two
Property ionic.It is preferred that the amphoteric ion or at least one of anionic surfactant account for the 10 of total surfactant content
To 30 parts by weight.
Surfactant is necessary cleaning action.They are also because they are in the emulsified oiliness/rouge of wash conditions
Fat dirt and be necessary.
Surfactant can be selected from " Surface Active Agents ", volume 1, Schwartz&Perry,
Interscience 1949；Roll up 2, Schwartz, Perry&Berch, Interscience 1958；Manufacturing
The current version of " McCutcheon's Emulsifiers and Detergents " published by Confectioners Company
This, or " Tenside-Taschenbuch ", H.Stache, second edition, Carl Hauser Verlag, surface described in 1981
Activating agent.
First kind surfactant is anionic.Suitable anionic surfactant is that have containing about 8 to about 22
The organic sulfate of the alkyl of a carbon atom and the water-soluble alkali metal salts of sulfonate, term alkyl are used for including higher acyl
Moieties.The example of suitable synthetic anion surface active agent is sodium alkyl sulfate and alkylsurfuric acid potassium, especially by
Make such as more advanced C as made from butter or cocounut oil6-18Alcohol sulphation and those of obtain, alkyl C8-20Benzene sulfonic acid sodium salt and potassium, it is special
It is not linear secondary alkyl C10To C15Benzene sulfonic acid sodium salt；And alkyl glycerol ether sodium sulfate, especially derived from butter or cocounut oil compared with
Those of higher alcohol and synthol derived from petroleum ether；Sulfonated ester and alhpa olefin sulfonate.Other preferred anionic tables
Face activating agent is C12To C18Ethoxylated alkyl sulfates.Surfactant such as alkyl polyglycoside and alkyl list can also be used
Glucosides.Preferred anionic type surfactant is non-soap surfactants.Term non-soap surfactants is those skilled in the art
Known to member, and generally speaking it, for distinguishing the surfactant based on soap and being not based on those of soap, is fatty acid
Salt.
Particularly preferred anionic surfactant is alkoxy sulfate surfactant.The surfactant can have
There are the normal chain or branched alkyl of the rudimentary ethyoxyl containing two or three carbon atoms.The general formula of this surfactant is RO
(C2H4O)xSO3 -M+, wherein R is the saturated or unsaturated alkyl chain with 10 to 22 carbon atoms, and M is to make compound water
The cation of dissolubility, especially alkali metal, ammonium replace ammonium cation, and x average out to 1 to 15.Preferably, R is that have 12
To the alkyl chain of 16 carbon atoms, M is sodium, and x average out to 1 to 3, more preferable x are 1.Particularly preferred ethoxylation anion
Type surfactant is laurel ether sodium sulfate (SLES).It is the sodium salt of laurel ether sulfonic acid, wherein mainly C12Laurel alkyl quilt
Ethoxylation, every mole has average 1 to 7 moles of ethylene oxide.
Second class surfactant is ethoxylated alcohol nonionic surfactant.The spy of nonionic surface active agent
Sign is the presence of hydrophobic grouping and organic hydrophilic group, and passes through organic aliphatic series or alkyl aromatic hydrophobic compound and epoxy
It is prepared by the condensation of ethane (being in nature hydrophily).
In general, nonionic surface active agent is poly-alkoxylation lipophile, wherein desired hydrophil lipophil balance
It (HLB) is obtained and hydrophilic alkoxy is added to lipophilic portion.Preferred class nonionic surface active agent is
Ethoxylized fatty alcohol, wherein alkanol has 9 to 20 carbon atoms, and its alkylene oxide (with 2 or 3 carbon atoms) rubs
Your number is 5 to 20.In these materials, it is preferable to use wherein alkanol be 9 to 11 or 12 to 15 carbon atoms fatty alcohol and
Every mole contains those of 5 to 8 or 5 to 9 alkoxies.Alcohol further preferably based on alkane is (such as from Huntsman
Or the nonionic surface active agent of Sassol).
The example of these compounds is that wherein alkanol has 10 to 15 carbon atoms and every mole contains about 5 to 12 rings
Those of oxidative ethane group, such as NeodolTMFamily.These are the mixing of the higher aliphatic of average about 12 to 15 carbon atoms
The condensation product of object and about 9 moles of ethylene oxide.Higher alcohol is primary alkanol.
Another subclass of alkoxy-based surface-active agent contains accurate alkyl chain length rather than alkoxylated surfactants
The alkyl chain of agent is distributed.In general, these are the alcoxylates of close limit.These example includes NeodolTM- 1 serial surface
Activating agent.
Other useful nonionic surface active agent are from BASF with trade mark PlurafacTMSale.PlurafacTMIt is high
The reaction product of the mixture of grade straight chain alcohol and ethylene oxide and propylene oxide, the mixing containing ethylene oxide and propylene oxide
Chain, and with hydroxy-end capped.Example includes the C being condensed with 6 moles of ethylene oxide and 3 mol propylenoxies13-15Fatty alcohol rubs with 7
The C of your propylene oxide and the condensation of 4 moles of ethylene oxide13-15Fatty alcohol is condensed with 5 mol propylenoxies and 10 moles of ethylene oxide
C13-15Fatty alcohol or any of above mixture.
Another group of nonionic surface active agent can be used as DobanolTMIt is commercially available, it is that there is every mole of fatty alcohol average 7
The ethoxylation C of moles of ethylene oxide12-15Fatty alcohol.
Third class surfactant types are both sexes or amphoteric ionic surfactant.Particularly preferably glycine betaine,
Especially sulfobetaines and carboxybetaine (carbobetaine).
Preferred alkyl betaine has formula CH3(CH2)6CH2N+(CH3)2CH2COO-.Other alkyl betaine includes
(dodecyl dimethyl ammonium) acetate (also referred to as lauryl betaine, (dodecyldimethylamine base ammonium) acetate (also referred to as meat
Myristyl glycine betaine), (coco dimethyl ammonium) acetate and (oleyl dimethyl ammonium) acetate (also referred to as oil-based betaine).
The example of alkyl betaine is EmpigenTMBB surfactant, available from Sigma Aldrich.Preferred amide
Base glycine betaine is C6-18Alkyl amidoalkyl betaines；Such as (cocoamidopropyl dimethyl ammonium) acetate (also referred to as coconut palm
Oleamide propyl betaine or CAPB).The example of sulfuric acid glycine betaine (sulphatobetaine) is 3- (dodecyl dimethyl
Ammonium) -1- propane sulfate；With 2- (coco dimethyl ammonium) -1- ethanesulfonate.The example of sulfobetaines is 3- (dodecane
Base dimethyl ammonium) -2- hydroxyl -1- propane sulfonate；3- (dodecyldimethylamine base ammonium) -1- propane sulfonate；3-(C12-C14Alkane
Base amido propyl dimethyl ammonium) -2- hydroxyl -1- propane sulfonate；With 3- (coco dimethyl ammonium) -1- propane sulfonate.
Another group of amphoteric ionic surfactant is amine oxide amphoteric ionic surfactant.Example includes but unlimited
In cocoamidopropyl dimethyl amine oxide and alkene dimethyl amine.
In particularly preferred composition, anionic surfactant is alkoxy sulfate, described non-ionic
Surfactant is ethoxylized fatty alcohol, and the amphoteric ionic surfactant is carboxybetaine or sulfobetaines
Alkali.
Electrolyte
Composition according to the present invention includes the electrolyte of 0.5 to 15 weight %.More preferable composition includes 0.5 to 10 weight
Measure the electrolyte of %.It include the electrolyte of 0.5 to 5 weight % even more preferably from composition.Preferred electrolyte is the salt of bronsted lowry acids and bases bronsted lowry,
At least one of be strong.Preferably, electrolyte is the salt of alkali or alkaline earth metal.Suitable example includes sodium chloride, carbon
Sour sodium, potassium chloride and potassium nitrate.Other suitable electrolyte include salt sour present in composition.Suitable example includes cream
Sour sodium and sodium citrate.Observe that the increase of electrolyte content leads to more greasiness removals, however, this technical effect is super
Claimed range and at least sodium chloride is gradually reduced out, is particularly preferred electrolyte, effect is in 10 weight %
Salt under gradually decrease.In other words, further increasing does not enhance greasiness removal.
Bleaching agent
The addition of bleaching agent especially oxidative bleaches is beneficial.It is therefore preferable that composition packet according to the present invention
Containing bleaching agent, especially oxidative bleaches, more particularly per-compound, especially hydrogen peroxide.The addition of bleaching agent is led
More spots are caused to discharge, especially grease soils, tea stain and fruit stain.It is therefore preferable that composition according to the present invention includes 0.5
To 8 weight %, the bleaching agent of more preferable 1 to 6 weight %.
WhenMeasured at 25 DEG C on viscosimeter DV II, the viscosity of preferred composition 1cP extremely
In the range of 2000cP.The distribution of this advantageously combined object of viscosity especially it is expected composition sprayed on dyestain cloth
In the case where.
Composition of the invention promotes optionally including other compositions, such as flavouring agent, preservative and colorant, foam
Agent, preservative (such as fungicide), pH buffer, polyelectrolyte and antioxidant.
Pack product
According to second aspect, a kind of packaging product is disclosed comprising the product of the composition comprising first aspect, optionally
Ground includes the device for distributing composition.
Packaging can be the form of any packaging known in the art.Non-limiting example include bottle, pipe, carton,
Box or other containers.Preferred articles of manufacture has distribution mechanism, makes it easy to distribution content, i.e. composition.It is particularly preferred
Be wherein composition pass through include spot pen as e-Pointer any of greasiness removal or blob modification means, device
Tool or the packaging of given hand-held article filling or distribution.Or composition can be in the form of the cleaning piece/sheet material for being impregnated with composition
It provides.In addition, composition can be provided in the form of greasiness removal spot applicator, there is handle and sponge at one end
Or spongy product.The sponge impregnating has composition.Product is also possible to roll daubing type applicator or pipe, spraying, aerosol or pump
The distributor of operation.Product can also have scouring component, and with brush, bristle, cluster, protrusion, fritter, relief or its is any
Combination, further to help the application of composition.
Purposes
According to the third aspect, purposes of the composition of first aspect as textile stains remover is disclosed.It is preferred that combining
Object is used for anti-stain, is at least one of following: mechanical grease stain, tea stain, fruit stain.Further preferably spot is present in cotton, gathers
On ester or polyester cotton fabric.Therefore, composition mitigates at least one of mechanical grease stain, tea stain or fruit stain.
Method
According to fourth aspect, a kind of method for mitigating textile stains is disclosed comprising make at least dyestain of the fabric
The first step that is contacted with the composition of 0.2 to 5ml first aspect of part, followed by making the fabric and alkaline detergent group
Close the second step of object contact.
Method preferably includes water washing process.Dyestain fabric is immersed in composition according to the present invention, alternatively, can be with
Composition is applied to dyestain fabric in the form of pure or is diluted.Alternatively or additionally, pre-treatment step may include by
Matrix is immersed in the step being added in the aqueous solution for the treatment of compositions.
Second step is that " master " washes, and can be manually or in washing machine.Any suitable detergent can be used in second step
Composition.Preferably, which includes one or more surfactants and/or other function ingredient.
Preferably, method of the invention needs to be less than 90 minute duration, and even more preferably less than 60 minutes and most preferably
Less than 30 minutes.In pretreatment embodiment, pre-treatment step is preferably needed less than 5 minutes and more preferably less than 2 minutes.
Preferably pretreatment compositions are environment activities.Therefore, therefore the temperature of the washing lotion step of water washing process exists
It excludes to be always less than 40 DEG C, preferably smaller than 30 DEG C during dry washing, more preferably less than 25 DEG C, more preferably less than or equal to 22
DEG C, even more preferably from 15 DEG C or smaller.
Laundry detergent composition any one of can take various forms: example includes powder, particle, item, gel
And liquid.Preferably composition is liquid form.Preferably they are that master washes product.It can be using for the main laundry group washed
The form for closing object, can be dilutable or not dilutable.Laundry composition can be such as isotropic liquid or table
Face active agent structures liquid.Particularly preferred form includes providing composition, detergent/softening agent production of " softening in washing "
Product.Preferably, detergent composition has 6 to 11.5 pH, more preferable pH 6.5 to 9.5, most preferably pH 7 to 9, such as pH
7.5 to 8.5.
Detergent composition can have down to moderate bulk density.It that case, it can be starched by spray-drying
Material, and optionally afterwards feed (dry-mixed) other ingredient and prepare.The route that can be used for powder manufacture includes spray drying, roller
Dry, fluidized bed drying and knifing drying device, such as scraped film evaporator.
Alternatively, main cleaning composition is concentration or intimate powder.This powder can be prepared by mixing or being granulated, example
Such as, using high-speed mixer/granulator or other non-tower process.
Preferably alkaline detergent composition is used in the form of water lotion, and it includes the alkalinity that 0.3 to 10g/ rises
Detergent composition.Furthermore it is preferred that allowing at least five minutes time differences between the first and second steps.
The pH difference of further preferably aqueous greasiness removal composition and washing lotion is at least four unit, and condition is further
The pH of the ground washing lotion is at least 8.
Fabric
Fabric (referred to herein as clothes/textile/cloth/clothes) can be any fabric, such as cotton (braiding,
Knitting and coarse drill), polyester (braiding, knitting and microfibre), nylon, silk, (polyester/cotton is mixed for polyester cotton
Spin), Elastic Polyester Fibers, cotton elastomer, viscose rayon yarn, acrylic fiber or wool.Composition according to the present invention and
Method is more particularly suited for particularly suitable for hydrophilic fabric in cotton or polyester cotton.It is therefore preferable that hydrophilic fabric is cotton or polyester
Cotton.Alternatively, it is suitable for polyester.
Other manageable fabrics include other synthesis and natural fabric.Imagination this method can be used for handling washes in family
The clothes and other clothes and clothing of typical wash load are formed in clothing.Accessible household material include but is not limited to bedcover,
Blanket, carpet, curtain and dunnage.
Spot
Spot can be any oil-dirt or sebum spot.Preferably, oiliness is substantially contained in the dyestain part of fabric
Or sebum spot.They are mainly solid in nature, and such spot usually in its conventional use process with fabric
Contact.Non-limiting example includes mechanical grease, tomato oil spot, curry in oil spot, dirty machine oil and the derivative spot of sebum.Or
Person, spot are tea stain or fruit stain.
Following specific embodiments further illustrate the present invention, however, the present invention is not limited thereto.It is mentioned that term be to wash
Known to the technical staff of clothing detergent applications.
Embodiment
Some important parameter/variables related with embodiment are summarised in table 1.
Table 1
Decontamination index (SRI)
SRI is the measurement that the spot on how many fabric is removed during washing process.The intensity of any spot can be with
By difference of the reflectometry between spot and clean cloth, the Δ Ε of every kind of spot is provided*.It is defined as Δ Ε*,
It calculates are as follows:
L*、a*And b*It is the 1976 (L of CIE measured using standard reflection meter*、a*、b*) color space coordinate.ΔΕ*It can
To be measured before and after washing spot, to provide AE* bw(before washing) and AE* aw(after washing).
Then SRI is defined as SRI=100- Δ Ε* After washing。
SRI means completely removing for spot for 100.
Completely (or original) fabric is not washed " absolute standard ".For each experiment, it refers to dirty with application
The identical piece of fabric of the fabric of stain.Therefore, it is in L*a*b*Point in color space remains unchanged.
Prepare a series of compositions.Some within the scope of the present invention, and some do not exist then.Each composition is carried out aforementioned
It tests (SRI).The concrete condition and observation result of each composition are summarised in table 2,3,4 and 5.
Embodiment 1: influence of the surfactant to greasiness removal
Table 2
It is in table 2 statistics indicate that, composition 4 according to the present invention provide by corresponding SRI value support maximum spot goes
It removes, is highest in table.Every other composition is all in addition to the present invention.
The data are also supported as pH and salt content also within the scope of the invention, between the surfactant of three types
Synergistic effect opinion.
Embodiment 2: influence of the salt to greasiness removal
Table 3
It is in table 3 statistics indicate that the increase of salt content has direct and apparent influence to greasiness removal.However, effect is in salt
The upper limit of content is gradually reduced, and the salt content is sodium chloride in the case.Embodiment 6 is except the scope of the present invention；Institute
There are other all within.
The influence of embodiment 4:pH
Table 4
Embodiment 11,12 and 13 is except the scope of the present invention.The pH of composition 10 is 3.5, and the pH of composition 11 is
4.8.But their performance does not have difference.The increase of pH reduces performance (composition 12 and 13).Therefore, according to the present invention
The pH of composition be limited to 1 to 4.
Embodiment 5: the influence of bleaching agent
Table 5
Composition 14 represents the preferred form of composition according to the present invention.Data in the table show bleaching agent (oxygen
Change property bleaching agent) effect.Composition containing bleaching agent is better than the correspondent composition without bleaching agent.Should statistics indicate that, such as
The pH of fruit composition is kept constant, and the composition containing bleaching agent removes more spots than the composition without bleaching agent.Group
Close both objects 14 and 15 within the scope of the invention, but composition 14 is better than 15.
The data also support as pH and salt content also within the scope of the invention that the surfactant of three types mixes
Close the opinion of the synergistic effect between object and bleaching agent.
Claims (15)
1. the aqueous greasiness removal composition that a kind of pH is 1 to 4, it includes:
(i) total surfactant content of 2 to 10 weight % is made of three kinds of different types of surfactants；
(ii) one or more organic acids are enough to make the pH of the composition in the range；With
(iii) electrolyte of 0.5 to 15 weight %,
Wherein first kind surfactant is anionic, and the second class is ethoxylated alcohol nonionic, and third class is two
Property ionic.
2. water-based composition as described in claim 1, wherein in the amphoteric ion or anionic surfactant extremely
A kind of few 10 to 30 parts by weight for accounting for the total surfactant content.
3. water-based composition as claimed in claim 1 or 2, wherein the anionic surfactant is alkoxylate sulfuric acid
Salt, the nonionic surface active agent is ethoxylized fatty alcohol, and the amphoteric ionic surfactant is carboxyl
Glycine betaine or sulfobetaines.
4. the water-based composition as described in any one of preceding claims 1 to 3, wherein the composition includes 0.5 to 10 weight
Measure the electrolyte of %.
5. water-based composition as claimed in claim 4, wherein the composition includes the electrolyte of 0.5 to 5 weight %.
6. the water-based composition as described in any one of preceding claims 1 to 5, wherein the composition also includes bleaching agent.
7. water-based composition as claimed in claim 6, wherein the bleaching agent is oxidative bleaches.
8. the water-based composition as described in any one of preceding claims 1 to 7, wherein one or more organic acids
PKa is 1 to 5 at 20 DEG C.
9. water-based composition as claimed in claim 8, wherein the organic acid is oxalic acid, tannic acid, lactic acid, citric acid, second
At least one of alkyd, maleic acid, tartaric acid, malic acid, acetic acid or ethanedioic acid.
10. water-based composition as claimed in any one of claims 1-9 wherein, wherein the electrolyte is the salt of bronsted lowry acids and bases bronsted lowry, wherein
At least one is strong.
11. water-based composition as claimed in claim 10, wherein the electrolyte includes alkali or alkaline earth metal.
12. a kind of packaging product comprising the product comprising the composition further includes the dress for distributing the composition
It sets.
13. purposes of the composition as described in claim 1 as textile stains remover.
14. purposes as claimed in claim 13, wherein the composition mitigates at least one in mechanical grease stain, tea stain or fruit stain
Kind.
15. a kind of method for mitigating textile stains comprising make at least dyestain part of the fabric with 0.2 to 5ml such as power
Benefit require 1 described in composition contact first step, followed by make that the fabric contacts with alkaline detergent composition the
Two steps.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16169763 | 2016-05-16 | ||
| EP16169763.6 | 2016-05-16 | ||
| PCT/EP2017/059485 WO2017198419A1 (en) | 2016-05-16 | 2017-04-21 | Pre-treatment composition for fabric stains |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109153942A true CN109153942A (en) | 2019-01-04 |
Family
ID=55969062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780030264.3A Pending CN109153942A (en) | 2016-05-16 | 2017-04-21 | Pretreatment compositions for textile stains |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP3458565A1 (en) |
| CN (1) | CN109153942A (en) |
| BR (1) | BR112018073596A2 (en) |
| WO (1) | WO2017198419A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113186041A (en) * | 2021-05-21 | 2021-07-30 | 大连欧派科技有限公司 | Clothes decontamination wet tissue and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210171880A1 (en) * | 2017-12-12 | 2021-06-10 | Conopco, Inc., D/B/A Unilever | Foamable cleaning composition |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP3458565A1 (en) | 2019-03-27 |
| WO2017198419A1 (en) | 2017-11-23 |
| BR112018073596A2 (en) | 2019-02-26 |
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