CN103242974A - Fruit, vegetable and tableware detergent with good rheological property - Google Patents
Fruit, vegetable and tableware detergent with good rheological property Download PDFInfo
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Abstract
The invention discloses a fruit, vegetable and tableware detergent with a good rheological property. The detergent comprises the following raw material components in percentage by weight: 0.01-5.0% of a fluidity modifier, 5.0-40.0% of an anionic surfactant, 0.5-15.0% of a nonionic surfactant, 1.0-8.0% of an amphoteric surfactant, 0.1-8.0% of a viscosity modifier, 0.01-0.2% of an antiseptic agent, 0.01-0.5% of a chelating agent, 0.01-10% of other components, and the balance of deionized water. The invention relates to the detergent with viscosity characteristics, and the fluidity modifier is added into the detergent, so that the rheological property is improved, and the needs of consumers can be well satisfied.
Description
Technical field
The present invention relates to civilian sanitising agent technical field, specifically, the present invention relates to the good fruits and vegetables dish washing detergent of a kind of rheological.
Background technology
Liquid detergent at high temperature sense organ is rarer, and the liquid detergent rheological is poor under the low temperature, is difficult to topple over, and uses to the human consumer and brings very big inconvenience.Bibliographical information is arranged, concerning the liquid detergent system, in the certain temperature range, can adopt The Arrhenius Equation to investigate the situation that the washing composition viscosity with temperature changes, and coming the susceptibility of appraisement system viscosity temperature with the size of activation energy, the viscosity degree of washing composition is main relevant with the raw material of system to the susceptibility of temperature.
Be used for regulating susceptibility influence little (Chen Zhifeng, Jin Yan, the viscosity temperature Study of Sensitivity of liquid washing agent, daily chemical industry, 2001, (3): 9-10) of the small amounts of inorganic salt pair washing composition viscosity temperature of viscosity in the system.The described susceptibility of system viscosity to temperature of having studied of this document does not provide concrete terms of settlement.
Other has bibliographical information, by in liquid detergent, adding a spot of high molecular polymer fast clean plain 68, can change the viscosity characteristics of liquid detergent, the peak viscosity of liquid detergent is adjusted to middle warm area, and the viscosity when having improved the high-temperature zone, the viscosity stability of liquid detergent is improved relatively, relatively stable (Duan Yuchen, Study on stability of viscosity of dishwashing detergent, the application chemical industry of product viscosity in cold zone and high-temperature zone scope have been guaranteed, 2005, (5): 321-323).Fast clean plain 68 is vinylformic acid viscosity modifiers of a kind of modification, can freeze under cold condition, and itself is dissolving difficulty directly, must slowly add water after stirring fast clean plain 68 and other surfactant compounds, adds buck again and neutralizes.
All there is the defective in the use in above-mentioned all compositions that is used for regulating washing composition viscosity.Thereby how seeking a kind of effective viscosity modifier is the technical barrier that one of ordinary skill in the art are badly in need of solving.
Summary of the invention
The object of the present invention is to provide that a kind of rheological is good, the fruits and vegetables dish washing detergent of excellent combination property.
The object of the invention to solve the technical problems realizes by the following technical solutions.According to the good fruits and vegetables dish washing detergent of a kind of rheological that the present invention proposes, it contains each feed composition of following weight percent: fluidity regulator 0.01-5.0%; Anion surfactant 5.0~40.0%; Nonionogenic tenside 0.5~15.0%; Amphoterics 1.0~8.0%; Viscosity modifier 0.1~8.0%; Sanitas 0.01~0.2%; Sequestrant 0.01~0.5%; Other component 0.01~10%; The deionized water surplus.
Fruits and vegetables dish washing detergent of the present invention, described anion surfactant are at least a or two above mixtures in polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether carboxylic acid sodium, alkyl sodium sulfonate, the α-sodium olefin sulfonate.
Fruits and vegetables dish washing detergent of the present invention, described nonionogenic tenside are at least a or two above mixtures in fatty alcohol-polyoxyethylene ether-9, fatty alcohol-polyoxyethylene ether-7, polyoxyethylene glycol, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, the amine oxide.
Fruits and vegetables dish washing detergent of the present invention, described amphoterics are any one or two kinds of above mixtures in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, the trimethyl-glycine.
Fruits and vegetables dish washing detergent of the present invention, described viscosity modifier are at least a or two above mixtures in sodium-chlor, sodium sulfate, ethanol, propylene glycol, the cumene sodium sulfonate.
Fruits and vegetables dish washing detergent of the present invention, described sanitas are at least a in Sodium Benzoate, isothiazolinone, nipagin esters, the potassium sorbate.
Fruits and vegetables dish washing detergent of the present invention, described sequestrant are at least a in EDTA-2Na, EDTA-4Na, the citric acid.
Fruits and vegetables dish washing detergent of the present invention, described fluidity regulator are at least a or two above mixtures in PPG-20 methyl glucose ether, PPG-10 methyl glucose ether, glycerine, the sodium xylene sulfonate.
Fruits and vegetables dish washing detergent of the present invention, described other components are acid-base modifier, pigment, photostabilizer, antioxidant, essence, and these components are the universaling component of washing composition, and kind is not done specific restriction.
By technique scheme, the present invention has following advantage and beneficial effect:
1, the washing composition that contains fluidity regulator has good high low-temperature fluidity, make product when low temperature, can not become the jelly shape, can topple over very easily, and when high temperature, also can suitably keep certain viscosity, make product sensory unlikely rare excessively, make the human consumer use convenient to product.
2, fluidity regulator of the present invention all is the low readily biodegradable that stimulates, and the product gentleness is not hindered hand, and the form of fluidity regulator is liquid or solid, and state is more stable, can be well and tensio-active agent dissolve each other, need not pre-treatment, be convenient to industrial production.
3, the present invention has decontamination, and anti-hard water is wetting, emulsification, effect such as solubilising disperses, and bubbles, and is anticorrosion.
Embodiment
Know-why of the present invention is: the PPG-20 methyl glucose ether of employing, PPG-10 methyl glucose ether, one or more mixtures in glycerine and the sodium xylene sulfonate is as fluidity regulator, and can be applied to industrial production very easily.Has the source natural health, advantages such as readily biodegradable.
The present invention is described in further detail below in conjunction with embodiment, but embodiments of the present invention are not limited thereto.Below by concrete preferred embodiment more detailed description washing composition of the present invention.
Embodiment 1
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, polyoxyethylenated alcohol sodium sulfate, alkylamide propyl-betaine, alkyl glycoside, PPG-20 methyl glucose ether (the contrast sample need not add).Before adding, guarantee the dissolving fully of last raw material.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.
Washing composition to embodiment 1 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 1.
The performance measurement of the washing composition of table 1 embodiment 1 and contrast sample 1
As can be seen from Table 1, embodiment 1 has good detersive power and low-temperature stability, and the pH value is near human body skin.Embodiment 1 has added PPG-20 methyl glucose ether, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add, and detersive power also promotes a little.Therefore, the adding of PPG-20 methyl glucose ether has well improved the high low temperature rheological behaviour of embodiment 1.
Embodiment 2
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, polyoxyethylenated alcohol sodium sulfate, alkylamide propyl ammonium oxide, alkyl glycoside, PPG-20 methyl glucose ether (the contrast sample need not add), PPG-10 methyl glucose ether (the contrast sample need not add).Before adding, guarantee the dissolving fully of last raw material.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.
Washing composition to embodiment 2 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 2.
The performance measurement of the washing composition of table 2 embodiment 2 and contrast sample 2
As can be seen from Table 2, embodiment 2 has good detersive power and low-temperature stability, and the pH value is near human body skin.Embodiment 2 has added the mixture of PPG-20 methyl glucose ether and PPG-10 methyl glucose ether, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add, and detersive power also promotes a little.Therefore, PPG-20 methyl glucose ether, the adding of PPG-10 methyl glucose ether has well improved the high low temperature rheological behaviour of embodiment 2.
Embodiment 3
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, lauryl Sodium L-alaninate, alkylamide propyl ammonium oxide, PPG-10 methyl glucose ether (the contrast sample need not add), sodium xylene sulfonate (the contrast sample need not add).Guarantee the dissolving fully of last raw material before adding.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.
Washing composition to embodiment 3 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 3.
The performance measurement of the washing composition of table 3 embodiment 3 and contrast sample 3
As can be seen from Table 3, embodiment 3 has good detersive power and low-temperature stability, and the pH value is near human body skin.Embodiment 3 has added PPG-10 methyl glucose ether and sodium xylene sulfonate, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add, and detersive power also promotes a little.Therefore, the adding of PPG-10 methyl glucose ether and sodium xylene sulfonate has well improved the high low temperature rheological behaviour of embodiment 3.
Embodiment 4
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, lauryl L-Ala diethanolamine salt, α-sodium olefin sulfonate, fatty acid methyl ester ethoxylate, PPG-20 methyl glucose ether (the contrast sample need not add), sodium xylene sulfonate (the contrast sample need not add).Guarantee the dissolving fully of last raw material before adding.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.
Washing composition to embodiment 4 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 4.
The performance measurement of the washing composition of table 4 embodiment 4 and contrast sample 4
Embodiment 4 has good detersive power and low-temperature stability as can be seen from Table 4, and the pH value is near human body skin.Embodiment 4 has added PPG-20 methyl glucose ether and sodium xylene sulfonate, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add.Therefore, the adding of PPG-20 methyl glucose ether and sodium xylene sulfonate has well improved the high low temperature rheological behaviour of embodiment 4.
Embodiment 5
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, polyoxyethylenated alcohol sodium sulfate, alkylamide propyl ammonium oxide, α-sodium olefin sulfonate, lauryl Sodium L-alaninate, sodium xylene sulfonate (the contrast sample need not add).Before adding, guarantee the dissolving fully of last raw material.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.
Washing composition to embodiment 5 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 5.
The performance measurement of the washing composition of table 5 embodiment 5 and contrast sample 5
Embodiment 5 has good detersive power and low-temperature stability as can be seen from Table 5, and the pH value is near human body skin.Embodiment 5 has added sodium xylene sulfonate, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add.Therefore, the adding of sodium xylene sulfonate has well improved the high low temperature rheological behaviour of embodiment 5.
Embodiment 6
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add Sodium dodecylbenzene sulfonate successively, the fatty alcohol-polyoxyethylene ether carboxylic acid sodium, alkylamide propyl-betaine, alkyl glycoside, sodium xylene sulfonate (the contrast sample need not add), PPG-20 methyl glucose ether (the contrast sample need not add), PPG-10 methyl glucose ether (the contrast sample need not add).Guarantee the dissolving fully of last raw material before adding.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.Washing composition to embodiment 6 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 6.
The performance measurement of the washing composition of table 6 embodiment 6 and contrast sample 6
Embodiment 6 has good detersive power and low-temperature stability as can be seen from Table 6, and the pH value is near human body skin.Embodiment 6 has added sodium xylene sulfonate, PPG-10 methyl glucose ether, and PPG-20 methyl glucose ether, the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add.Therefore, sodium xylene sulfonate, PPG-10 methyl glucose ether, the adding of PPG-20 methyl glucose ether has well improved the high low temperature rheological behaviour of embodiment 6.
Embodiment 7
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add polyoxyethylenated alcohol sodium sulfate successively, fatty alcohol-polyoxyethylene ether-9, lauryl Sodium L-alaninate, α-sodium olefin sulfonate, glycerine (the contrast sample need not add), PPG-20 methyl glucose ether (the contrast sample need not add), PPG-10 methyl glucose ether (the contrast sample need not add).Guarantee the dissolving fully of last raw material before adding.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.Washing composition to embodiment 7 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 7.
The performance measurement of the washing composition of table 7 embodiment 7 and contrast sample 7
Embodiment 7 has good detersive power and low-temperature stability as can be seen from Table 7, and the pH value is near human body skin.Embodiment 7 has added glycerine, PPG-10 methyl glucose ether, and PPG-20 methyl glucose ether, the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add.Therefore, glycerine, PPG-10 methyl glucose ether, the adding of PPG-20 methyl glucose ether has well improved the high low temperature rheological behaviour of embodiment 7.
Embodiment 8
The preparation method of present embodiment is as follows:
1. add the deionized water that measures, add sequestrant, stir until dissolving fully.
2. add polyoxyethylenated alcohol sodium sulfate successively, Sodium dodecylbenzene sulfonate, alkyl glycoside, alkylamide propyl-betaine, glycerine (the contrast sample need not add).Guarantee the dissolving fully of last raw material before adding.
3. add sanitas, viscosity modifier, continue to be stirred to material and dissolve fully, evenly.Washing composition to embodiment 8 carries out temperature-viscosimetric analysis, and detersive power is measured, and stability is measured, the pH pH-value determination pH, and test result sees Table 8.
The performance measurement of the washing composition of table 8 embodiment 8 and contrast sample 8
Embodiment 8 has good detersive power and low-temperature stability as can be seen from Table 8, and the pH value is near human body skin.Embodiment 8 has added glycerine, and the susceptibility of viscosity temperature has obviously reduced many than the contrast sample that does not add.Therefore, the adding of glycerine has well improved the high low temperature rheological behaviour of embodiment 8.
The above, it only is preferred embodiment of the present invention, be not that the present invention is done any pro forma restriction, so every technical solution of the present invention content that do not break away from,, all still belong in the scope of technical solution of the present invention any simple modification, equivalent variations and modification that above embodiment does according to technical spirit of the present invention.
Claims (9)
1. fruits and vegetables dish washing detergent that rheological is good, it is characterized in that: it contains each feed composition of following weight percent:
Fluidity regulator 0.01-5.0%;
Anion surfactant 5.0~40.0%;
Nonionogenic tenside 0.5~15.0%;
Amphoterics 1.0~8.0%;
Viscosity modifier 0.1~8.0%;
Sanitas 0.01~0.2%;
Sequestrant 0.01~0.5%;
Other component 0.01~10%;
The deionized water surplus.
2. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described anion surfactant is at least a or two above mixtures in polyoxyethylenated alcohol sodium sulfate, fatty alcohol-polyoxyethylene ether carboxylic acid sodium, alkyl sodium sulfonate, the α-sodium olefin sulfonate.
3. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described nonionogenic tenside is at least a or two above mixtures in fatty alcohol-polyoxyethylene ether-9, fatty alcohol-polyoxyethylene ether-7, polyoxyethylene glycol, alkyl-glucoside, monoolein, sucrose ester, fatty acid methyl ester ethoxylate, polyglycerol fatty acid ester, the amine oxide.
4. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described amphoterics is any one or two kinds of above mixtures in lauryl L-Ala diethanolamine salt, lauryl Sodium L-alaninate, the trimethyl-glycine.
5. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described viscosity modifier is at least a or two above mixtures in sodium-chlor, sodium sulfate, ethanol, propylene glycol, the cumene sodium sulfonate.
6. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described sanitas is at least a in Sodium Benzoate, isothiazolinone, nipagin esters, the potassium sorbate.
7. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described sequestrant is at least a in EDTA-2Na, EDTA-4Na, the citric acid.
8. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good is characterized in that: described fluidity regulator is at least a or two above mixtures in PPG-20 methyl glucose ether, PPG-10 methyl glucose ether, glycerine, the sodium xylene sulfonate.
9. the fruits and vegetables dish washing detergent that rheological according to claim 1 is good, it is characterized in that: described other components are acid-base modifier, pigment, photostabilizer, antioxidant, essence, these components are the universaling component of washing composition, and kind is not done specific restriction.
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