CN103468427A - Viscosity stabilizer and mild detergent containing viscosity stabilizer - Google Patents
Viscosity stabilizer and mild detergent containing viscosity stabilizer Download PDFInfo
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Abstract
The invention provides a viscosity stabilizer and an application thereof in preparation of a detergent. The viscosity stabilizer comprises a component (a) and a component (b), wherein the component (a) is selected from at least one of carboxymethyl cellulose, hydroxyethyl cellulose or xanthan gum; the component (b) is selected from at least one of sodium citrate, potassium citrate, sodium chloride or sodium sulfate. The invention further provides a mild detergent with stable viscosity. The mild detergent comprises the following components in parts by weight based on the total weight of the mild detergent: 0.1% to 0.3% of the viscosity stabilizer, 28% to 32% of alpha-olefine sulfonate, 8% to 12% of alkyl glycoside, 3% to 7% of cocamidopropylamine oxide, 0.25% to 0.35% of citric acid, 0.03% to 0.5% of ethylene diamine tetraacetic acid disodium salt, 0.02% to 0.5% of a preservative, 0.01% to 0.5% of essence and the balance of water, wherein the viscosity stabilizer provided by the invention is adopted; the weight ratio of the component (a) to the component (b) in the viscosity stabilizer is (6:4)-(10:1).
Description
Technical field
The application relates to a kind of viscosity stabilizer and the application in the preparation of liquid detergent thereof.
And the application also relates to gentle liquid detergent of a kind of stable viscosity that contains described viscosity stabilizer and preparation method thereof.
Background technology
Viscosity is one of them parameter of liquid rheological property.Internal friction resistance during liquid-flow claims viscosity, and it represents the drag size that fluid is mobile.And viscosity number is larger, liquid is more difficult to flow.
Viscosity is also that tableware and fruits and vegetables clean one of important quality index with liquid detergent.Though viscosity and tableware and fruits and vegetables clean quality with liquid detergent without absolute relation, a good product, the exterior quality that must have.If the viscosity of every batch of product of listing is not quite similar, can make the human consumer produce the illusion that quality differs; And if viscosity is too low, can make the human consumer produce the bad or jerry sensation of quality.Viscosity also can be used as a standard weighing the quality product quality sometimes, and the index that can indirectly control other by the mensuration of viscosity is as mobility etc.
Common situation is now, and in the winter time, many dish washing detergents on the market are because viscosity is too high, and the user will wait the long period when pouring; And liquid is when there is not much left in bottle, crossing slow and most bottles due to liquid-flow is tall and thin types, and liquid does not have enough time to flow to bottom, the phenomenon that has just occurred because center of gravity is too high to fall bottle.And, under summer high temperature environment, because washing composition viscosity is too low, can pour out manyly because of out of control again, cause waste.The variation of this temperature in winter and summer can make tableware and fruits and vegetables clean, with the viscosity of liquid detergent, large variation occurs, cause tableware and fruits and vegetables clean too thick with liquid detergent winter, summer is too rare, had a strong impact on tableware and fruits and vegetables and cleaned the quality of using liquid detergent.
Main component in existing dish washing detergent is linear alkylbenzene sulphonic acid and polyoxyethylenated alcohol sodium sulfate mostly simultaneously, and its pungency is larger, and degreasing power is stronger, and Long Term Contact can make skin become coarse.
Therefore, develop a kind of stable viscosity and gentle liquid detergent is very important.
Summary of the invention
The application's a purpose is to provide a kind of viscosity stabilizer.
Particularly, the application provides a kind of viscosity stabilizer, and described viscosity stabilizer comprises at least one and the component (b) that component (a) is selected from carboxymethyl cellulose, Natvosol or xanthan gum and is selected from least one in Trisodium Citrate, Tripotassium Citrate, sodium-chlor or sodium sulfate.
In some embodiments, described component (a) can be xanthan gum.
In some embodiments, described component (b) can be Trisodium Citrate or sodium-chlor.
In this application, person of skill in the art will appreciate that each in aforementioned " carboxymethyl cellulose, Natvosol, xanthan gum, Trisodium Citrate, Tripotassium Citrate, sodium-chlor or sodium sulfate " can be preferably food grade.
In some embodiments, the weight ratio of described component (a) and described component (b) is 6:4～10:1.
On the other hand, the application's another purpose is to provide the application of above-mentioned viscosity stabilizer in preparing liquid detergent, described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1, and the weight fraction of the gross weight of described viscosity stabilizer based on described liquid detergent is 0.1～0.3%.
In aspect other, the application's another purpose is to provide a kind of gentle liquid detergent of stable viscosity.
Particularly, the application provides a kind of gentle liquid detergent of stable viscosity, the following component of the meter of percentage ratio by weight that described liquid detergent comprises the gross weight based on described liquid detergent:
Wherein, described viscosity stabilizer is aforementioned viscosity stabilizer, and the described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1.
In some embodiments, the weight percentage of the gross weight of described viscosity stabilizer based on described liquid detergent can be 0.2%.
In some embodiments, the weight percentage of the gross weight of described α olefin sulfonate based on described liquid detergent can be 30%; Preferably, described α olefin sulfonate can contain the alkyl chain of C16～18.
In some embodiments, the weight percentage of the gross weight of described alkyl glycoside based on described liquid detergent can be 10%; Preferably, the alkyl chain that described alkyl glycoside contains C8～10.
In some embodiments, the weight percentage of the gross weight of described cocamidopropyl propyl amide amine oxide based on described liquid detergent can be 5%.
The following component of the meter of percentage ratio by weight that in some embodiments, described liquid detergent comprises the gross weight based on described liquid detergent:
Wherein, described viscosity stabilizer is aforementioned viscosity stabilizer, and the described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1.
In this application, described " α olefin sulfonate ", " alkyl glycoside ", " cocamidopropyl propyl amide amine oxide " are products known in the art and that can be commercially available, such as " α olefin sulfonate " can be the C14-16 be available commercially at present, alkyl glycoside can be the product of the models such as 0810,0814,1214,0816,1216,1618 that are available commercially at present, the CAO-30 that the cocamidopropyl propyl amide amine oxide can be available commercially at present etc., these products are directly used after buying.It will be understood by those of skill in the art that, product mentioned above is much to sell with the form of solution, such as α olefin sulfonate can be the product of the solution form of the α olefin sulfonate that contains weight percentage 35%, alkyl glycoside can be the product of the solution form of the alkyl glycoside that contains weight percentage 50%, and the cocamidopropyl propyl amide amine oxide can be the product of the solution form of the cocamidopropyl propyl amide amine oxide that contains weight percentage 30%.
In this application, described " essence " can be this area essence commonly used, such as natural petit grain oil elite, sponge gourd volatile oil, lemon essential oil, ginger essence wet goods.
In this application, described " sanitas " can be this area sanitas commonly used, such as Kathon CG class sanitas, Sodium Benzoate, soluble propylhydroxybenzoate etc.
Simultaneously, person of skill in the art will appreciate that various materials used all can be preferably food grade in the above-mentioned liquid detergent of preparation, and described water can be preferably deionized water.
The application's another purpose is to provide a kind of method of the gentle liquid detergent for the preparation of stable viscosity.
Particularly, the application provides a kind of method for the preparation of aforementioned any liquid detergent, comprising:
Under heating and stirring, Xiang Shuizhong adds the described viscosity stabilizer of formula ratio, until described viscosity stabilizer dissolves fully, obtains the solution that transparent colloidal solution is viscosity stabilizer;
To the α olefin sulfonate, alkyl glycoside and the cocamidopropyl propyl amide amine oxide that add formula ratio in described transparent colloidal solution, stir and obtain homogeneous solution;
Continue stir and make system temperature be down to room temperature, then add disodium ethylene diamine tetraacetate, sanitas, essence, the citric acid of formula ratio and supply the water of surplus, obtain described liquid detergent.
In this application, described heating, stirring operation to dissolve described viscosity stabilizer can employing field any dissolving mixing means commonly used, after being heated to 38～42 ℃, add viscosity stabilizer, control stirring velocity 300～350rpm, stir 30～40min until described viscosity stabilizer dissolves fully and be transparence solution.
Wherein, in the step of the transparent colloidal solution of preparation, the amount of the water that uses can be 1/3～1/2 of the weight of the total water amount for preparing liquid detergent.Certainly, person of skill in the art will appreciate that, the amount of the water used in the step of the transparent colloidal solution of preparation also can adopt other amount, and condition is that water can dissolve viscosity stabilizer fully.
, to add in the step of α olefin sulfonate, alkyl glycoside and cocamidopropyl propyl amide amine oxide of formula ratio simultaneously, in order better stirring, can to add water, the amount of the water of adding be prepare liquid detergent the total water amount weight 1/4～1/3.
Wherein, in the gentle liquid detergent of the described stable viscosity of the application, the alkyl chain that α olefin sulfonate contains C16～18, and research shows that α olefin sulfonate is actual in accumulation in bodily tissue, safety non-toxic, to the skin gentleness, in physical environment, fully biodegradable in 5～7 days, do not pollute the environment, there is good wettability, emulsifying property, detersive power and whipability simultaneously, very easily water-soluble, easily rinse well; The alkyl chain that described alkyl glycoside contains C8～10, alkyl glycoside be a new generation adopt renewable natural matter, performance gentleness, safety non-toxic, and skin-friendliness is good, can quick and complete biodegradable " environmental protection " type nonionogenic tenside, have the characteristic of common nonionic and anion surfactant concurrently, there is good soil removability, without cloud point, gel-free phenomenon, can with the tensio-active agent synergy of any type, and the performance with thickening preferably and stabilising system, especially be applicable to being applied to liquid dishwashing detergent; Described cocamidopropyl propyl amide amine oxide belongs to oxidation amine tensio-active agent, there is good thickening, steady bubble, emulsification and the performance such as antistatic, good with the synergistic effect of negatively charged ion, positively charged ion and nonionogenic tenside, the effect that skin and hair is there is to softness, moisturizing and fungus and mildew resistance, having good biological degradability, is the tensio-active agent of a class performance gentleness; Described citric acid is natural organic acids; Described disodium ethylene diamine tetraacetate is the complexing of metal ion agent of widespread use in liquid washing agent.
Compared with prior art, the application has following beneficial effect:
(1) owing to having added the described viscosity stabilizer of the application in liquid detergent, the liquid detergent therefore made has stable viscosity, and its viscosity with temperature changes very little;
(2) in preparation the application's liquid detergent, there is no to use linear alkylbenzene sulphonic acid and polyoxyethylenated alcohol sodium sulfate commonly used at present, but use gentleness and the eco-friendly raw materials such as α olefin sulfonate, alkyl glycoside, cocamidopropyl propyl amide amine oxide, to the skin gentleness;
(3) the application's liquid detergent soil removability significantly is better than the soil removability of the liquid detergent on present market.
The accompanying drawing explanation
The schematic diagram that the viscosity with temperature that Fig. 1 is 7 liquid detergent samples changes.
Embodiment
Describe the application's embodiment below by embodiment, one of ordinary skill in the art appreciates that these specific embodiments only show the purpose in order to reach the application and the enforcement technical scheme selected is not the restriction to technical scheme.According to the application's instruction, in conjunction with prior art, to the improvement of present techniques scheme, be obvious, all belong to the scope of the application's protection.
Embodiment 1
A kind of gentle liquid detergent of stable viscosity, the following component of the meter of percentage ratio by weight that it comprises the gross weight based on described liquid detergent:
Wherein, the component in viscosity stabilizer (a) and component (b) be respectively purchased from U.S. Si Bikai can the food grade xanthan gum and purchased from the of a specified duration food grade sodium-chlor of large lightization limited liability company in Zhejiang, and the weight ratio of component (a) and component (b) is 7:3; α olefin sulfonate (AOS) is purchased from Zhejiang Zan Yu Science and Technology Ltd.; Alkyl glycoside (APG) is purchased from BASF; Cocamidopropyl propyl amide amine oxide (COA-30) is purchased from Guangzhou Xing Ye company limited; Citric acid is purchased from Weifang Ensign Industry Co., Ltd; Disodium ethylene diamine tetraacetate (EDTA-2Na) is purchased from Guangzhou day gram waffle work company limited; Sanitas is the Kathon CG purchased from the Shaanxi petrochemical industry; Essence is the natural petit grain oil purchased from Qi Huadun.
The preparation method is as follows:
Get 1/3 deionized water of the weight that accounts for the total water amount, after being heated to 40 ℃, slowly add described viscosity stabilizer under stirring, control stirring velocity 320rpm, stir 40min until dissolve fully, obtain the solution that transparent colloidal solution is viscosity stabilizer;
Add successively wherein α olefin sulfonate (AOS), alkyl glycoside (APG) and cocamidopropyl propyl amide amine oxide (COA-30) by formula ratio, and in order to stir better, add 1/4 deionized water of the weight that accounts for the total water amount and stir, obtaining homogeneous solution;
Continue stir and make system temperature be down to room temperature, then add successively disodium ethylene diamine tetraacetate (EDTA-2Na), sanitas, essence, citric acid and supply the water of surplus, obtain the gentle liquid detergent of the described stable viscosity of the present embodiment.
Embodiment 2:
A kind of gentle liquid detergent of stable viscosity comprises gross weight based on the described liquid detergent following component of percentage ratio meter by weight:
Wherein, the component in viscosity stabilizer (a) and component (b) be respectively purchased from U.S. Si Bikai can the food grade xanthan gum and purchased from the food grade Trisodium Citrate of Weifang Ensign Industry Co., Ltd,, and the weight ratio of component (a) and component (b) is 8:3; α olefin sulfonate (AOS), alkyl glycoside (APG), cocamidopropyl propyl amide amine oxide (COA-30), citric acid and disodium ethylene diamine tetraacetate (EDTA-2Na) are identical with embodiment 1; Sanitas is the Sodium Benzoate purchased from Guangzhou Yi Feng Chemical Industry Science Co., Ltd; Essence is the sponge gourd volatile oil purchased from Bowden.
The preparation method is as follows:
Get 1/3 deionized water of the weight that accounts for the total water amount, after being heated to 40 ℃, slowly add described viscosity stabilizer under stirring, control stirring velocity 320rpm, stir 37min until dissolve fully, obtain the solution that transparent colloidal solution is viscosity stabilizer;
Add wherein α olefin sulfonate (AOS), alkyl glycoside (APG) and cocamidopropyl propyl amide amine oxide (COA-30) by formula ratio, and in order to stir better, add 1/3 deionized water of the weight that accounts for the total water amount and stir, obtaining homogeneous solution;
Continue stir and make system temperature be down to room temperature, then add disodium ethylene diamine tetraacetate (EDTA-2Na), sanitas, essence, citric acid and supply the deionized water of surplus, obtain the gentle liquid detergent of the described stable viscosity of the present embodiment.
Embodiment 3
A kind of gentle liquid detergent of stable viscosity comprises gross weight based on the described liquid detergent following component of percentage ratio meter by weight:
Wherein, component in viscosity stabilizer (a) and component (b) are respectively purchased from the carboxymethyl cellulose of Hebei Mao Yuan chemical industry company limited with purchased from the Tripotassium Citrate of Shanghai Yi Mengsi Chemical Industry Science Co., Ltd, and the weight ratio of component (a) and component (b) is 6:4; α olefin sulfonate (AOS), alkyl glycoside (APG), cocamidopropyl propyl amide amine oxide (COA-30), citric acid and disodium ethylene diamine tetraacetate (EDTA-2Na) are identical with embodiment 1; Sanitas is the soluble propylhydroxybenzoate purchased from Henan Rong Shen chemical industry company limited; Essence is the lemon essential oil purchased from Qi Huadun.
The preparation method is as follows:
Get 1/3 deionized water of the weight that accounts for the total water amount, after being heated to 38 ℃, slowly add described viscosity stabilizer under stirring, control stirring velocity 300rpm, stir 30min until dissolve fully, obtain transparent colloidal solution;
Add wherein α olefin sulfonate (AOS), alkyl glycoside (APG) and cocamidopropyl propyl amide amine oxide (COA-30) by formula ratio, add 1/3 deionized water of the weight that accounts for the total water amount and stir, obtain homogeneous solution;
Continue stirring and make system temperature be down to room temperature, then add disodium ethylene diamine tetraacetate (EDTA-2Na), sanitas, essence, citric acid and supply the deionized water of surplus, obtain the gentle liquid detergent of the described stable viscosity of the present embodiment.
Embodiment 4
A kind of gentle liquid detergent of stable viscosity comprises gross weight based on the described liquid detergent following component of percentage ratio meter by weight:
Wherein, component in viscosity stabilizer (a) and component (b) are respectively purchased from the Natvosol of Xi'an Wan Chang bio tech ltd with purchased from the sodium sulfate of Jiangsu south wind chemical industry company limited, and the weight ratio of component (a) and component (b) is 10:1; α olefin sulfonate (AOS), alkyl glycoside (APG), cocamidopropyl propyl amide amine oxide (COA-30), citric acid and disodium ethylene diamine tetraacetate (EDTA-2Na) are identical with embodiment 1; Sanitas is the Sodium Benzoate purchased from Guangzhou Yi Feng Chemical Industry Science Co., Ltd; Essence is the ginger essential oil purchased from Qi Huadun.
The preparation method is as follows:
Get 1/2 deionized water of the weight that accounts for the total water amount, after being heated to 42 ℃, slowly add described viscosity stabilizer under stirring, control stirring velocity 350rpm, stir 40min until dissolve fully, obtain transparent colloidal solution;
Add wherein α olefin sulfonate (AOS), alkyl glycoside (APG) and cocamidopropyl propyl amide amine oxide (COA-30) by formula ratio, add 1/4 deionized water of the weight that accounts for the total water amount and stir, obtain homogeneous solution;
Continue stir and make system temperature be down to room temperature, then add disodium ethylene diamine tetraacetate (EDTA-2Na), sanitas, essence, citric acid and supply the deionized water of surplus, obtain the gentle liquid detergent of the described stable viscosity of the present embodiment.
Performance test:
One, viscosimetric analysis
According to GB/T10247-2008, with the NDJ-1B type rotational viscosimeter of Shanghai Changji Geological Instrument Co., Ltd., to be measured, specimen is A1, A2, A3, B1, B2, B3 and B4.A1, A2, A3 are commercially available liquid detergent product on domestic market.
Wherein, the main component of sample A1, A2 and A3 is: linear alkylbenzene sulphonic acid 9～12%; Polyoxyethylenated alcohol sodium sulfate 8～13%; Cocoanut fatty acid diethanolamide (6501) 1～2%; EDTA-2Na is appropriate; Sanitas is appropriate; Essence is appropriate; The deionized water surplus; And its preparation method is: get appropriate amount of deionized water, be heated to 50 ℃ of left and right, add appropriate sodium hydroxide and linear alkyl benzene sulphonic acid, stirring makes it neutralization fully, then being cooled to 40 ℃ of left and right adds polyoxyethylenated alcohol sodium sulfate and 6501 to stir successively, obtain homogeneous solution, continuing to stir makes system temperature be down to room temperature, at room temperature add successively disodium ethylene diamine tetraacetate (EDTA-2Na), sanitas, essence, sodium-chlor, then regulate pH to 8 left and right with citric acid or sodium hydroxide, the deionized water of supplying surplus gets final product.And B1, B2, B3 and B4 are the embodiment of the present application 1 to embodiment 4 prepared liquid detergent sample.
Test result as shown in Figure 1, from Fig. 1, can clearly find out, the viscosity with temperature rangeability of domestic market product (A1, A2 and A3) is very large, and the viscosity of the liquid detergent (B1 to B4) that the application provides is basicly stable, and the variation that viscosity with temperature of the application's liquid detergent changes is little.
Two, detersive power is measured
According to GB GB9985-2000 foam level method, sample A1, A2, A3, B1, B2, B3 and B4 are carried out to detersive power mensuration, the result obtained is as shown in table 1:
Table 1 detergency test data
Wherein, the composition of standard dish washing detergent and preparation method can be referring to the B1.4.3 in the mensuration of GB GB9985-2000 appendix B detersive power.
The detersive power of the liquid detergent that the application provides as can be seen from Table 1 significantly is better than the detersive power of standard dish washing detergent and domestic market product.
The application includes but not limited to above embodiment, and every any being equal to of carrying out under the principle of the application's spirit substitutes or local improvement, all will be considered as within the application's protection domain.
Claims (10)
1. a viscosity stabilizer, described viscosity stabilizer comprises at least one and the component (b) that component (a) is selected from carboxymethyl cellulose, Natvosol or xanthan gum and is selected from least one in Trisodium Citrate, Tripotassium Citrate, sodium-chlor or sodium sulfate; Preferably, described component (a) is xanthan gum; Preferably, described component (b) is Trisodium Citrate or sodium-chlor.
2. viscosity stabilizer according to claim 1, wherein, the weight ratio of described component (a) and described component (b) is 6:4～10:1.
3. the application of viscosity stabilizer as claimed in claim 1 in the preparation of liquid detergent, described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1, and the weight fraction of the gross weight of described viscosity stabilizer based on described liquid detergent is 0.1～0.3%.
4. the gentle liquid detergent of a stable viscosity, the following component of the meter of percentage ratio by weight that described liquid detergent comprises the gross weight based on described liquid detergent:
Wherein, described viscosity stabilizer is viscosity stabilizer claimed in claim 1, and the described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1.
5. liquid detergent according to claim 4, wherein, the weight percentage of the gross weight of described viscosity stabilizer based on described liquid detergent is 0.2%.
6. liquid detergent according to claim 4, wherein, the weight percentage of the gross weight of described α olefin sulfonate based on described liquid detergent is 30%; The alkyl chain that described α olefin sulfonate contains C16～18.
7. liquid detergent according to claim 4, wherein, the weight percentage of the gross weight of described alkyl glycoside based on described liquid detergent is 10%; The alkyl chain that described alkyl glycoside contains C8～10.
8. liquid detergent according to claim 4, wherein, the weight percentage of the gross weight of described cocamidopropyl propyl amide amine oxide based on described liquid detergent is 5%.
9. liquid detergent according to claim 4, wherein, the following component of the meter of percentage ratio by weight that described liquid detergent comprises the gross weight based on described liquid detergent:
Wherein, described viscosity stabilizer is viscosity stabilizer claimed in claim 1, and the described component (a) in wherein said viscosity stabilizer and the weight ratio of described component (b) are 6:4～10:1.
10. the method for the preparation of the described liquid detergent of any one in claim 4-9 comprises:
Under heating and stirring, Xiang Shuizhong adds the described viscosity stabilizer of formula ratio, until described viscosity stabilizer dissolves fully, obtains the solution that transparent colloidal solution is viscosity stabilizer;
To the α olefin sulfonate, alkyl glycoside and the cocamidopropyl propyl amide amine oxide that add formula ratio in described transparent colloidal solution, stir and obtain homogeneous solution;
Continue stir and make system temperature be down to room temperature, then add disodium ethylene diamine tetraacetate, sanitas, essence, the citric acid of formula ratio and supply the water of surplus, obtain described liquid detergent.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107603757A (en) * | 2017-05-15 | 2018-01-19 | 合肥普庆日化有限公司 | A kind of liquid detergent of viscosity stabilization and preparation method thereof |
| CN107619726A (en) * | 2017-05-15 | 2018-01-23 | 合肥普庆日化有限公司 | A kind of biodegradable liquid detergent |
| CN108795595A (en) * | 2018-07-11 | 2018-11-13 | 苏州华龙化工有限公司 | A kind of preparation method of high efficiency composition detergent |
| CN111073762A (en) * | 2019-12-27 | 2020-04-28 | 佛山市顺德区美的洗涤电器制造有限公司 | Liquid detergent composition suitable for automatic dosing in a dishwasher |
| CN112078958A (en) * | 2014-04-18 | 2020-12-15 | 宝洁公司 | Package assembly |
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| CN109135953A (en) * | 2018-09-21 | 2019-01-04 | 如皋市傲东化工有限公司 | A kind of dish washing liquid and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112078958A (en) * | 2014-04-18 | 2020-12-15 | 宝洁公司 | Package assembly |
| CN107603757A (en) * | 2017-05-15 | 2018-01-19 | 合肥普庆日化有限公司 | A kind of liquid detergent of viscosity stabilization and preparation method thereof |
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| CN103468427B (en) | 2015-04-15 |
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