CN108728267A - High-performance oil and stain removal detergent for kitchen - Google Patents
High-performance oil and stain removal detergent for kitchen Download PDFInfo
- Publication number
- CN108728267A CN108728267A CN201810722096.0A CN201810722096A CN108728267A CN 108728267 A CN108728267 A CN 108728267A CN 201810722096 A CN201810722096 A CN 201810722096A CN 108728267 A CN108728267 A CN 108728267A
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- China
- Prior art keywords
- detergent
- parts
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- performance
- surfactant
- Prior art date
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- 239000003599 detergent Substances 0.000 title claims abstract description 73
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000003755 preservative agent Substances 0.000 claims abstract description 38
- 230000002335 preservative effect Effects 0.000 claims abstract description 38
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 28
- 238000004140 cleaning Methods 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- 241001116389 Aloe Species 0.000 claims abstract description 16
- 235000011399 aloe vera Nutrition 0.000 claims abstract description 16
- 239000000872 buffer Substances 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 12
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims abstract description 11
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims abstract description 11
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims abstract description 11
- 229920001661 Chitosan Polymers 0.000 claims abstract description 6
- 230000003385 bacteriostatic effect Effects 0.000 claims abstract description 6
- 150000004676 glycans Chemical class 0.000 claims abstract description 6
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 6
- 239000005017 polysaccharide Substances 0.000 claims abstract description 6
- 108090000765 processed proteins & peptides Proteins 0.000 claims abstract description 6
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims abstract description 4
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims abstract description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 4
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 4
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 4
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 4
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004334 sorbic acid Substances 0.000 claims abstract description 3
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 3
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 230000001804 emulsifying effect Effects 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 21
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- -1 sodium alkyl sulfonates Chemical class 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 238000012545 processing Methods 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 10
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 claims description 10
- 229920002678 cellulose Polymers 0.000 claims description 10
- 239000001913 cellulose Substances 0.000 claims description 10
- 235000010980 cellulose Nutrition 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000013067 intermediate product Substances 0.000 claims description 10
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 10
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- 239000013049 sediment Substances 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 239000011856 silicon-based particle Substances 0.000 claims description 10
- 238000005245 sintering Methods 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 235000015424 sodium Nutrition 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 7
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 7
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000013081 microcrystal Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 5
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- JKGITWJSGDFJKO-UHFFFAOYSA-N ethoxy(trihydroxy)silane Chemical compound CCO[Si](O)(O)O JKGITWJSGDFJKO-UHFFFAOYSA-N 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 238000004108 freeze drying Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 239000013618 particulate matter Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 238000010926 purge Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 239000003643 water by type Substances 0.000 claims description 4
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- 235000019864 coconut oil Nutrition 0.000 claims description 3
- 239000003240 coconut oil Substances 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229930016911 cinnamic acid Natural products 0.000 claims 1
- 235000013985 cinnamic acid Nutrition 0.000 claims 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims 1
- 239000002068 microbial inoculum Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 230000001629 suppression Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 239000000126 substance Substances 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 abstract description 2
- 230000003588 decontaminative effect Effects 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract description 2
- 239000000022 bacteriostatic agent Substances 0.000 abstract 2
- 239000002131 composite material Substances 0.000 abstract 2
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 abstract 1
- 239000000686 essence Substances 0.000 description 12
- 239000002585 base Substances 0.000 description 5
- 230000003213 activating effect Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- CRPOUZQWHJYTMS-UHFFFAOYSA-N dialuminum;magnesium;disilicate Chemical compound [Mg+2].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] CRPOUZQWHJYTMS-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 244000089742 Citrus aurantifolia Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005227 alkyl sulfonate group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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Abstract
The invention relates to the technical field of daily chemical cleaning, in particular to a high-performance oil and stain removal detergent for kitchens. The components of the detergent comprise: surfactant, propylene glycol, preservative, cleaning reinforcing agent, essence, PH buffer, disodium ethylene diamine tetraacetate, sodium carboxymethylcellulose, aloe powder, composite bacteriostatic agent and deionized water. Wherein, the cleaning reinforcing agent is a high-hardness particle with selective adsorbability, has better grinding assisting effect, and also has the functions of foaming and foam homogenizing when being added into a detergent; the surfactant comprises anionic surfactant and nonionic surfactant, and the antiseptic is one of potassium sorbate, sorbic acid, methyl p-hydroxybenzoate and sodium benzoate; the composite bacteriostatic agent contains hydroxymethyl chitosan, algal polysaccharide and bacteriostatic peptide. The detergent has the characteristics of outstanding decontamination performance, easy rinsing and water resource saving.
Description
Technical field
The present invention relates to daily use chemicals cleaning technology fields, and in particular to a kind of high-performance deoiling detergent for kitchen use.
Background technology
Liquid detergent also known as kitchen detergent are a kind of detergent with good degreasing result, and this detergent is clean
Mildly, foam is soft and fine, decomposes greasy, fast decontaminating, degerming rapidly, and effectively thoroughly cleaning does not remain, and simple and elegant fruity is distributed when washing
Taste is washed rear pure white bright as new.When be often used and ensure household sanitation, avoid germina infection.The main component of liquid detergent is alkyl
Sodium sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizer, essence, water, pigment, preservative etc., sodium alkyl sulfonate and fatty alcohol
Ether sodium sulfate is all anion surfactant, is petroleum chemicals, to decontamination oil stain.
It is most important for degreasing, helping clean group to be divided into all types of surfactants in kitchen detergent, this
A little surfactants include anion surfactant, amphoteric surfactant and nonionic surfactant, surfactant
Degreasing can be generated, help cleaning action, be because the substance enables to the interface state of solution system that significant change occurs；
Surfactant usually has fixed hydrophilic lipophilic group, is aligned in the surface energy of solution.The molecule of surfactant
Structure has amphipathic：One end is hydrophilic radical, and the other end is hydrophobic grouping；Hydrophilic radical is often polar group, such as carboxylic acid, sulphur
Acid, sulfuric acid, amino or amido and its salt, hydroxyl, amide groups, ehter bond etc. also can be used as polar hydrophilic group；And hydrophobic grouping is normal
For nonpolar hydrocarbon chain, such as 8 above hydrocarbon chains of carbon atom.Therefore surfactant component can effectively adsorb greasy dirt, then flow
Under the flushing action of water, dirt is removed.
Scavenging effect of the detergent of this conventional constituents for most of oiliness pollutants and other organic contamination ingredients
It is more apparent, but the rinsing performance of surfactant type substance is poor, washing process needs first to consume a large amount of clear water；And it is right
In the cleaning action unobvious of the stronger spot of adhesive force, and need using foaming characteristics burnishers such as cleaning cotton, washing cloth
Cleaning is completed, detergent ingredients are also not strong enough for the adsorptivity of pollutant.The washing of detergent entirety, clean-up performance need
Reinforce.
Invention content
For problems of the prior art, the present invention provides a kind of high-performance deoiling detergent for kitchen use,
It is added to the cleaning reinforcing agent with good grinding effect, foaming effect and adsorptivity in the type detergent, improves detergent
Clean-up performance, and make detergent have easily rinsing, save water resource environmental-protecting performance.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of high-performance deoiling detergent for kitchen use, according to mass percent, the component of the detergent includes：Surface-active
Agent 30-35%, propylene glycol 5-7%, preservative 0.08-0.25% clean reinforcing agent 6-8%, essence 0.8-1.5%, PH buffer 1.5-
2.7%, disodium ethylene diamine tetraacetate 0.8-1.3%, sodium cellulose glycolate 0.2-0.4%, aloe powder 1-3%, compound preservative
1.2-2.4%, surplus are deionized water.
Preferably, according to mass percent, the component of the detergent includes：Surfactant 32-34%, propylene glycol 5.5-
6.8%, preservative 0.15-0.22% clean reinforcing agent 6.5-7.7%, essence 0.9-1.3%, PH buffer 1.9-2.2%, ethylenediamine
Tetraacethyl disodium 0.9-1.2%, sodium cellulose glycolate 0.25-0.35%, aloe powder 1.5-2.5%, compound preservative 1.5-
2.2%, surplus is deionized water.
It is further preferred that according to mass percent, the component of the type detergent includes：Surfactant 33%, propylene glycol
5.8%, preservative 0.19% cleans reinforcing agent 7.0%, essence 1.1%, PH buffers 2.1%, disodium ethylene diamine tetraacetate 1.0%, hydroxyl
Sodium carboxymethylcellulose pyce 0.3%, aloe powder 2.0%, compound preservative 1.7%, surplus are deionized water.
In the present invention, the preparation method for cleaning reinforcing agent is：
（1）According to mass fraction, the salpeter solution of 30 parts of 1.5mol/L is added into reaction kettle, then by 2 parts of sodium alkyl sulfonates
It is added in reaction kettle with 5 parts of polyvinyl alcohol, mixture is heated and stirred with 55-60 DEG C of temperature, then by 13 parts of positive silicic acid
Ethyl ester is added in reaction kettle, stirs to get sediment, after sediment is centrifuged, is filtered, washed, drying, with 750-800 DEG C
Temperature calcination 3-5h obtains active meso-porous titanium dioxide silicon particle；
（2）80 parts of active meso-porous titanium dioxide silicon particles are well-dispersed in enough cyclohexanone solvents, it is then molten to cyclohexanone
1.5 parts of chlorocarbon base silane coupling agents are added in agent, with 95-110 DEG C of temperature heating reaction 35-40min, the mixture that will be obtained
It is fully washed with alcohol solvent after filtering, then freeze-drying obtains intermediate product, and 8 parts of intermediate products and 20 parts of sodium azide add
Enter into enough n,N-Dimethylformamide solution, with 60-75 DEG C of temperature heating reaction 30-40min, mixture will be obtained
Modified manometer silicon dioxide is obtained after filtering, drying；
（3）According to mass fraction, by 30-35 parts of modified manometer silicon dioxides, 14-15 parts of Alpha-aluminas, 5-10 parts of nano concavo-convexes
Stick clay, 2-4 parts of microcrystalline celluloses, 1.3-1.6 parts of polyethylene glycol, 1.1-1.5 parts of acrylyl oxy-ethyl-trimethyl salmiacs and
20-25 parts of deionized waters are granulated after being mixed evenly, and particulate matter is sent in high temperature furnace and is sintered, sintering temperature 1150-
1250 DEG C, sintered particles are taken out in furnace cooling after the completion of sintering；
（4）Sintered particles are sent in planetary ball mill, it is 15-30 μm of pulvis to be ground into grain size, by pulvis with go from
The cycle of sequential purge 2-3 of sub- water-ethanol-deionized water, after then spray-dried, obtain needed for clean reinforcing agent.
Step（3）The middle microcrystalline cellulose used is by acrylic graft-modified nano micro crystal cellulose, and nanometer is micro-
The degree of polymerization of crystalline cellulose is 200-230.
Preferably, surfactant includes anion surfactant and nonionic surfactant, the mass ratio of the two
It is 3:2.
Preferably, anion surfactant includes but not limited to NaLS, fatty alcohol polyoxyethylene ether phosphoric acid
One kind in monoesters, alkylsulfonate, fatty alcohol polyoxyethylene ether sulfate and isomery alkyl poly glucoside carboxylate；Nonionic table
Face activating agent includes but not limited to lauric monoethanolamide, ethylene glycol stearate, coconut oil di-methylcarbinol amide and lauryl
One kind in glucosides.
Preferably, preservative is one kind in potassium sorbate, sorbic acid, methyl p-hydroxybenzoate and sodium benzoate.
The effect of preservative is that the microorganisms such as bacterium is avoided to infect or breed in kitchen detergent, to avoid kitchen from washing
It washs agent change confrontation kitchen tools to pollute, reduce the functional effect to kitchen detergent and preserves the influence in service life.
Preferably, carboxymethyl chitosan, algal polysaccharides and bacteriostatic peptide are contained in compound preservative.
Bacteriostat degerming ingredient there are many containing in compound preservative, can be purged a large amount of harmful bacterias on kitchen tools, protect
Clothing clean hygiene is held, injury of these microorganisms to human body is reduced.
The preparation method of detergent provided by the invention is：
Prepare raw material components according to mass percent, deionized water is added in emulsifying kettle, is heated to 65-70 DEG C, then will
Surfactant, disodium ethylene diamine tetraacetate and propylene glycol are added in emulsifying kettle, and the material in emulsifying kettle is fully dispersed
It is even, the temperature in emulsifying kettle is increased to 75-80 DEG C, is then added to cleaning reinforcing agent, aloe powder, PH buffers and essence
In emulsifying kettle, disperse and insulation reaction 16-20min, after reaction, by the temperature of charge in emulsifying kettle be reduced to 45 DEG C with
Under, preservative, compound preservative and sodium cellulose glycolate are added sequentially in emulsifying kettle, decentralized processing 10-12min, point
After the completion of dissipating processing, product is sent in aging reactor, 2-3d is aged naturally, obtains required detergent product.
The present invention has following advantageous effect：
Containing anion surfactant and nonionic surfactant in deoiling detergent for kitchen use in the present invention
Compound surface active ingredient there is good removal effect, wherein detergent also added most of organic dirt
A kind of special cleaning reinforcing agent ingredient, this cleaning reinforcing agent are a kind of synthesis particles.The hardness of the particle is high, corrosion resistance
Can be outstanding, therefore the grinding effect of detergent can be improved, contribute to detergent for the clear of the intractable spot of strong adhesive force
Clean effect.Micro-hole gap there are many containing in the structure of particle, material specific surface area is larger, therefore can generate blistering and even bubble
Effect, further increases the cleaning effect of detergent；The type particle also has very strong adsorptivity, can be tight by the spot of removing
Tight absorption, convenient for being rinsed to spot, reduces the water consumption of washing process.The type particle and is washed after special processing
The compatibility for washing agent bulk composition is preferable, can be stably dispersed in detergent component, it is not easy to sedimentation and aggtegation are generated,
The period of storage and service life of detergent can be improved.
The acid-base value of detergent can be adjusted in the PH buffers added in the type detergent, be surfactant and
Other components provide suitable acid or alkali environment, contribute to each analog assistant to play corresponding function, and can be with aloe powder component
Synergistic effect is generated, pro-skin, the skin effect of detergent is improved, reduces injury of the detergent to human skin.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of high-performance deoiling detergent for kitchen use, according to mass percent, the component of the detergent includes：Surface-active
Agent 30%, propylene glycol 5%, preservative 0.08% clean reinforcing agent 6%, essence 0.8%, PH buffers 1.5%, ethylenediamine tetra-acetic acid two
Sodium 0.8%, sodium cellulose glycolate 0.2%, aloe powder 1%, compound preservative 1.2%, surplus are deionized water.
In the present embodiment, the preparation method for cleaning reinforcing agent is：
（1）According to mass fraction, the salpeter solution of 30 parts of 1.5mol/L is added into reaction kettle, then by 2 parts of sodium alkyl sulfonates
It is added in reaction kettle with 5 parts of polyvinyl alcohol, mixture is heated and stirred with 55 DEG C of temperature, then by 13 parts of ethyl orthosilicates
It is added in reaction kettle, stirs to get sediment, after sediment is centrifuged, is filtered, washed, drying, with 750 DEG C of temperature calcination
3h obtains active meso-porous titanium dioxide silicon particle；
（2）80 parts of active meso-porous titanium dioxide silicon particles are well-dispersed in enough cyclohexanone solvents, it is then molten to cyclohexanone
1.5 parts of chlorocarbon base silane coupling agents are added in agent, with 95 DEG C of temperature heating reaction 35min, after obtained mixture is filtered
It is fully washed with alcohol solvent, then freeze-drying obtains intermediate product, and 8 parts of intermediate products and 20 parts of sodium azide are added to foot
In the n,N-Dimethylformamide solution of amount, with 60 DEG C of temperature heating reaction 30min, after mixture filtering, drying will be obtained
Obtain modified manometer silicon dioxide；
（3）According to mass fraction, by 30 parts of modified manometer silicon dioxides, 14 parts of Alpha-aluminas, 5 parts of nano attapulgite clays, 2 parts
Microcrystalline cellulose, 1.3 parts of polyethylene glycol, 1.1 parts of acrylyl oxy-ethyl-trimethyl salmiacs and 20 parts of deionized waters are mixed
It is granulated after uniformly, particulate matter is sent in high temperature furnace and is sintered, sintering temperature is 1150 DEG C, furnace cooling after the completion of sintering, will
Sintered particles take out；
（4）Sintered particles are sent in planetary ball mill, it is 15-30 μm of pulvis to be ground into grain size, by pulvis with go from
The cycle of sequential purge 2 of sub- water-ethanol-deionized water, after then spray-dried, obtain needed for clean reinforcing agent.
Step（3）The middle microcrystalline cellulose used is by acrylic graft-modified nano micro crystal cellulose, and nanometer is micro-
The degree of polymerization of crystalline cellulose is 200-230.
In detergent component, surfactant includes anion surfactant and nonionic surfactant, the two
Mass ratio is 3:2.Anion surfactant is NaLS；Nonionic surfactant is ethylene glycol stearate.
Preservative is potassium sorbate.
Contain carboxymethyl chitosan, algal polysaccharides and bacteriostatic peptide in compound preservative.
The preparation method of detergent provided by the invention is：
Prepare raw material components according to mass percent, deionized water is added in emulsifying kettle, is heated to 65 DEG C, then by surface
Activating agent, disodium ethylene diamine tetraacetate and propylene glycol are added in emulsifying kettle, and the material in emulsifying kettle is fully dispersed uniformly, will
Temperature in emulsifying kettle is increased to 75 DEG C, and cleaning reinforcing agent, aloe powder, PH buffers and essence are then added to emulsifying kettle
In, disperse and insulation reaction 16min, after reaction, by the temperature of charge in emulsifying kettle be reduced to 45 DEG C hereinafter, by anti-corrosion
Agent, compound preservative and sodium cellulose glycolate are added sequentially in emulsifying kettle, decentralized processing 10min, after the completion of decentralized processing,
Product is sent in aging reactor, 2d is aged naturally, obtains required detergent product.
Embodiment 2
A kind of high-performance deoiling detergent for kitchen use, according to mass percent, the component of the detergent includes：Surface-active
Agent 35%, propylene glycol 7%, preservative 0.25% clean reinforcing agent 8%, essence 1.5%, PH buffers 2.7%, ethylenediamine tetra-acetic acid two
Sodium 1.3%, sodium cellulose glycolate 0.4%, aloe powder 3%, compound preservative 2.4%, surplus are deionized water.
In the present embodiment, the preparation method for cleaning reinforcing agent is：
（1）According to mass fraction, the salpeter solution of 30 parts of 1.5mol/L is added into reaction kettle, then by 2 parts of sodium alkyl sulfonates
It is added in reaction kettle with 5 parts of polyvinyl alcohol, mixture is heated and stirred with 60 DEG C of temperature, then by 13 parts of ethyl orthosilicates
It is added in reaction kettle, stirs to get sediment, after sediment is centrifuged, is filtered, washed, drying, with 800 DEG C of temperature calcination
5h obtains active meso-porous titanium dioxide silicon particle；
（2）80 parts of active meso-porous titanium dioxide silicon particles are well-dispersed in enough cyclohexanone solvents, it is then molten to cyclohexanone
1.5 parts of chlorocarbon base silane coupling agents are added in agent, with 110 DEG C of temperature heating reaction 40min, after obtained mixture is filtered
It is fully washed with alcohol solvent, then freeze-drying obtains intermediate product, and 8 parts of intermediate products and 20 parts of sodium azide are added to foot
In the n,N-Dimethylformamide solution of amount, with 75 DEG C of temperature heating reaction 40min, after mixture filtering, drying will be obtained
Obtain modified manometer silicon dioxide；
（3）According to mass fraction, by 35 parts of modified manometer silicon dioxides, 15 parts of Alpha-aluminas, 10 parts of nano attapulgite clays,
4 parts of microcrystalline celluloses, 1.6 parts of polyethylene glycol, 1.5 parts of acrylyl oxy-ethyl-trimethyl salmiacs and 25 parts of deionized water mixing
It is granulated after stirring evenly, particulate matter is sent in high temperature furnace and is sintered, sintering temperature is 1250 DEG C, with furnace cooling after the completion of sintering
But, sintered particles are taken out；
（4）Sintered particles are sent in planetary ball mill, it is 15-30 μm of pulvis to be ground into grain size, by pulvis with go from
The cycle of sequential purge 3 of sub- water-ethanol-deionized water, after then spray-dried, obtain needed for clean reinforcing agent.
Step（3）The middle microcrystalline cellulose used is by acrylic graft-modified nano micro crystal cellulose, and nanometer is micro-
The degree of polymerization of crystalline cellulose is 200-230.
In detergent component, surfactant includes anion surfactant and nonionic surfactant, the two
Mass ratio is 3:2.Anion surfactant is fatty alcohol polyoxyethylene ether sulfate；Nonionic surfactant is coconut oil
Di-methylcarbinol amide.
Preservative is methyl p-hydroxybenzoate.
Contain carboxymethyl chitosan, algal polysaccharides and bacteriostatic peptide in compound preservative.
The preparation method of detergent provided by the invention is：
Prepare raw material components according to mass percent, deionized water is added in emulsifying kettle, is heated to 70 DEG C, then by surface
Activating agent, disodium ethylene diamine tetraacetate and propylene glycol are added in emulsifying kettle, and the material in emulsifying kettle is fully dispersed uniformly, will
Temperature in emulsifying kettle is increased to 80 DEG C, and cleaning reinforcing agent, aloe powder, PH buffers and essence are then added to emulsifying kettle
In, disperse and insulation reaction 20min, after reaction, by the temperature of charge in emulsifying kettle be reduced to 45 DEG C hereinafter, by anti-corrosion
Agent, compound preservative and sodium cellulose glycolate are added sequentially in emulsifying kettle, decentralized processing 12min, after the completion of decentralized processing,
Product is sent in aging reactor, 3d is aged naturally, obtains required detergent product.
Embodiment 3
A kind of high-performance deoiling detergent for kitchen use, according to mass percent, the component of the detergent includes：Surface-active
Agent 33%, propylene glycol 5.8%, preservative 0.19% clean reinforcing agent 7.0%, essence 1.1%, PH buffers 2.1%, ethylenediamine tetrem
Acid disodium 1.0%, sodium cellulose glycolate 0.3%, aloe powder 2.0%, compound preservative 1.7%, surplus are deionized water.
In the present embodiment, the preparation method for cleaning reinforcing agent is：
（1）According to mass fraction, the salpeter solution of 30 parts of 1.5mol/L is added into reaction kettle, then by 2 parts of sodium alkyl sulfonates
It is added in reaction kettle with 5 parts of polyvinyl alcohol, mixture is heated and stirred with 58 DEG C of temperature, then by 13 parts of ethyl orthosilicates
It is added in reaction kettle, stirs to get sediment, after sediment is centrifuged, is filtered, washed, drying, with 780 DEG C of temperature calcination
4h obtains active meso-porous titanium dioxide silicon particle；
（2）80 parts of active meso-porous titanium dioxide silicon particles are well-dispersed in enough cyclohexanone solvents, it is then molten to cyclohexanone
1.5 parts of chlorocarbon base silane coupling agents are added in agent, with 100 DEG C of temperature heating reaction 37min, after obtained mixture is filtered
It is fully washed with alcohol solvent, then freeze-drying obtains intermediate product, and 8 parts of intermediate products and 20 parts of sodium azide are added to foot
In the n,N-Dimethylformamide solution of amount, with 70 DEG C of temperature heating reaction 35min, after mixture filtering, drying will be obtained
Obtain modified manometer silicon dioxide；
（3）According to mass fraction, by 33 parts of modified manometer silicon dioxides, 14.5 parts of Alpha-aluminas, 7 parts of nano attapulgite clays, 3
Part microcrystalline cellulose, 1.5 parts of polyethylene glycol, 1.4 parts of acrylyl oxy-ethyl-trimethyl salmiacs and 23 parts of deionized waters mixing are stirred
It being granulated after mixing uniformly, particulate matter is sent in high temperature furnace and is sintered, sintering temperature is 1200 DEG C, furnace cooling after the completion of sintering,
Sintered particles are taken out；
（4）Sintered particles are sent in planetary ball mill, it is 15-30 μm of pulvis to be ground into grain size, by pulvis with go from
The cycle of sequential purge 2 of sub- water-ethanol-deionized water, after then spray-dried, obtain needed for clean reinforcing agent.
Step（3）The middle microcrystalline cellulose used is by acrylic graft-modified nano micro crystal cellulose, and nanometer is micro-
The degree of polymerization of crystalline cellulose is 200-230.
In detergent component, surfactant includes anion surfactant and nonionic surfactant, the two
Mass ratio is 3:2.Anion surfactant is alkylsulfonate；Nonionic surfactant is Plantacare APG 1200G.
Preservative is sodium benzoate.
Contain carboxymethyl chitosan, algal polysaccharides and bacteriostatic peptide in compound preservative.
The preparation method of detergent provided by the invention is：
Prepare raw material components according to mass percent, deionized water is added in emulsifying kettle, is heated to 68 DEG C, then by surface
Activating agent, disodium ethylene diamine tetraacetate and propylene glycol are added in emulsifying kettle, and the material in emulsifying kettle is fully dispersed uniformly, will
Temperature in emulsifying kettle is increased to 77 DEG C, and cleaning reinforcing agent, aloe powder, PH buffers and essence are then added to emulsifying kettle
In, disperse and insulation reaction 19min, after reaction, by the temperature of charge in emulsifying kettle be reduced to 45 DEG C hereinafter, by anti-corrosion
Agent, compound preservative and sodium cellulose glycolate are added sequentially in emulsifying kettle, decentralized processing 11min, after the completion of decentralized processing,
Product is sent in aging reactor, 2d is aged naturally, obtains required detergent product.
Performance test
Oil cut rate method is gone using GB9985-2000（Arbitration law）Mechanical greasy dirt is evenly affixed on test cloth, greasy dirt by test
Spot radius is 3cm；2 beakers are taken, the detergent 5mL for being separately added into embodiment 1-3 is added in the water of 200mL, will be tested
Cloth is placed in beaker, and different time is stirred with identical speed, removal effect of the detergent to dirt is observed, to purchase in the market
As a control group, experimental result see the table below " the vertical limette liquid detergent " bought.
Table 1：The degreasing clean-up performance of different detergent is tested
| Test event | Control group | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Soaking time | 5min | 5min | 5min | 5min |
| Stain radius after washing | 0.5cm | Nothing | 0.1cm | Nothing |
| Stain form after washing | It is high-visible | It is invisible | It is fuzzy visible | It is invisible |
It analyzes the above test result to find, detergent of the invention has good cleaning effect to greasy dirt, is highly suitable for
The cleaning and washing of kitchen heavy type greasy dirt articles for use.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (10)
1. a kind of high-performance deoiling detergent for kitchen use, it is characterised in that：According to mass percent, the group of the detergent
Divide and includes：Surfactant 30-35%, propylene glycol 5-7%, preservative 0.08-0.25% clean reinforcing agent 6-8%, essence 0.8-
1.5%, PH buffer 1.5-2.7%, disodium ethylene diamine tetraacetate 0.8-1.3%, sodium cellulose glycolate 0.2-0.4%, aloe powder
1-3%, compound preservative 1.2-2.4%, surplus are deionized water.
2. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：According to quality hundred
The component of score, the detergent includes：Surfactant 32-34%, propylene glycol 5.5-6.8%, preservative 0.15-0.22%, clearly
Clean reinforcing agent 6.5-7.7%, essence 0.9-1.3%, PH buffer 1.9-2.2%, disodium ethylene diamine tetraacetate 0.9-1.2%, hydroxyl first
Base sodium cellulosate 0.25-0.35%, aloe powder 1.5-2.5%, compound preservative 1.5-2.2%, surplus is deionized water.
3. a kind of high-performance deoiling detergent for kitchen use according to claim 2, it is characterised in that：According to quality hundred
The component of score, the detergent includes：Surfactant 33%, propylene glycol 5.8%, preservative 0.19% clean reinforcing agent
7.0%, essence 1.1%, PH buffers 2.1%, disodium ethylene diamine tetraacetate 1.0%, sodium cellulose glycolate 0.3%, aloe powder
2.0%, compound preservative 1.7%, surplus is deionized water.
4. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：The cleaning increases
The preparation method of agent is by force：
（1）According to mass fraction, the salpeter solution of 30 parts of 1.5mol/L is added into reaction kettle, then by 2 parts of sodium alkyl sulfonates
It is added in reaction kettle with 5 parts of polyvinyl alcohol, mixture is heated and stirred with 55-60 DEG C of temperature, then by 13 parts of positive silicic acid
Ethyl ester is added in reaction kettle, stirs to get sediment, after sediment is centrifuged, is filtered, washed, drying, with 750-800 DEG C
Temperature calcination 3-5h obtains active meso-porous titanium dioxide silicon particle；
（2）80 parts of active meso-porous titanium dioxide silicon particles are well-dispersed in enough cyclohexanone solvents, it is then molten to cyclohexanone
1.5 parts of chlorocarbon base silane coupling agents are added in agent, with 95-110 DEG C of temperature heating reaction 35-40min, the mixture that will be obtained
It is fully washed with alcohol solvent after filtering, then freeze-drying obtains intermediate product, and 8 parts of intermediate products and 20 parts of sodium azide add
Enter into enough n,N-Dimethylformamide solution, with 60-75 DEG C of temperature heating reaction 30-40min, mixture will be obtained
Modified manometer silicon dioxide is obtained after filtering, drying；
（3）According to mass fraction, by 30-35 parts of modified manometer silicon dioxides, 14-15 parts of Alpha-aluminas, 5-10 parts of nano concavo-convexes
Stick clay, 2-4 parts of microcrystalline celluloses, 1.3-1.6 parts of polyethylene glycol, 1.1-1.5 parts of acrylyl oxy-ethyl-trimethyl salmiacs and
20-25 parts of deionized waters are granulated after being mixed evenly, and particulate matter is sent in high temperature furnace and is sintered, sintering temperature 1150-
1250 DEG C, sintered particles are taken out in furnace cooling after the completion of sintering；
（4）Sintered particles are sent in planetary ball mill, it is 15-30 μm of pulvis to be ground into grain size, by pulvis with go from
The cycle of sequential purge 2-3 of sub- water-ethanol-deionized water, after then spray-dried, obtain needed for clean reinforcing agent.
5. a kind of high-performance deoiling detergent for kitchen use according to claim 4, it is characterised in that：The step
（3）The middle microcrystalline cellulose used is by acrylic graft-modified nano micro crystal cellulose, and nano micro crystal cellulose gathers
Right is 200-230.
6. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：It lives on the surface
Property agent include anion surfactant and nonionic surfactant, the mass ratio of the two is 3:2.
7. a kind of high-performance deoiling detergent for kitchen use according to claim 6, it is characterised in that：The anion
Surfactant includes but not limited to NaLS, fatty alcohol polyoxyethylene ether phosphate monoester, alkylsulfonate, fatty alcohol
One kind in polyoxyethylene ether sulfate and isomery alkyl poly glucoside carboxylate；Nonionic surfactant includes but not limited to the moon
One kind in cinnamic acid single ethanol amide, ethylene glycol stearate, coconut oil di-methylcarbinol amide and Plantacare APG 1200G.
8. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：The preservative
For one kind in potassium sorbate, sorbic acid, methyl p-hydroxybenzoate and sodium benzoate.
9. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：The compound suppression
Contain carboxymethyl chitosan, algal polysaccharides and bacteriostatic peptide in microbial inoculum.
10. a kind of high-performance deoiling detergent for kitchen use according to claim 1, it is characterised in that：The washing
The preparation method of agent is：
Prepare raw material components according to mass percent, deionized water is added in emulsifying kettle, is heated to 65-70 DEG C, then will
Surfactant, disodium ethylene diamine tetraacetate and propylene glycol are added in emulsifying kettle, and the material in emulsifying kettle is fully dispersed
It is even, the temperature in emulsifying kettle is increased to 75-80 DEG C, is then added to cleaning reinforcing agent, aloe powder, PH buffers and essence
In emulsifying kettle, disperse and insulation reaction 16-20min, after reaction, by the temperature of charge in emulsifying kettle be reduced to 45 DEG C with
Under, preservative, compound preservative and sodium cellulose glycolate are added sequentially in emulsifying kettle, decentralized processing 10-12min, point
After the completion of dissipating processing, product is sent in aging reactor, 2-3d is aged naturally, obtains required detergent product.
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| CN201810722096.0A CN108728267A (en) | 2018-07-04 | 2018-07-04 | High-performance oil and stain removal detergent for kitchen |
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| CN201810722096.0A CN108728267A (en) | 2018-07-04 | 2018-07-04 | High-performance oil and stain removal detergent for kitchen |
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| CN110003993A (en) * | 2019-05-17 | 2019-07-12 | 合肥市风达农业有限责任公司 | A kind of mulberries juice pigment spot special purpose detergent composition |
| CN110067002A (en) * | 2019-05-31 | 2019-07-30 | 深圳市润贝化工有限公司 | One kind being used for aircraft oven neutral cleaners |
| CN112521863A (en) * | 2020-12-07 | 2021-03-19 | 太仓市多多过滤材料有限公司 | Anti-blocking treatment process for inner hole of microporous plate |
| CN113166685A (en) * | 2018-12-07 | 2021-07-23 | 原子能与替代能源委员会 | Decontamination paste and method for decontaminating substrates made of solid material using said paste |
| CN113563983A (en) * | 2021-06-16 | 2021-10-29 | 江阴润玛电子材料股份有限公司 | Cleaning liquid for semiconductor integrated circuit and production process thereof |
| CN113680748A (en) * | 2021-08-26 | 2021-11-23 | 浙江工业大学 | Bio-based removal method for solid surface oil dirt |
| CN113980742A (en) * | 2021-11-12 | 2022-01-28 | 佛山市橙洁士洗涤剂有限公司 | Cleanser essence cream with strong oil removal property |
| TWI780716B (en) * | 2021-05-20 | 2022-10-11 | 黃文彬 | Environmentally friendly liquid and uses thereof |
| CN115678690A (en) * | 2022-12-14 | 2023-02-03 | 山东宙雨消防科技股份有限公司 | Magnesium hydroxide cleaning agent and preparation method thereof |
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| CN113166685A (en) * | 2018-12-07 | 2021-07-23 | 原子能与替代能源委员会 | Decontamination paste and method for decontaminating substrates made of solid material using said paste |
| CN110003993A (en) * | 2019-05-17 | 2019-07-12 | 合肥市风达农业有限责任公司 | A kind of mulberries juice pigment spot special purpose detergent composition |
| CN110067002A (en) * | 2019-05-31 | 2019-07-30 | 深圳市润贝化工有限公司 | One kind being used for aircraft oven neutral cleaners |
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| TWI780716B (en) * | 2021-05-20 | 2022-10-11 | 黃文彬 | Environmentally friendly liquid and uses thereof |
| CN113563983A (en) * | 2021-06-16 | 2021-10-29 | 江阴润玛电子材料股份有限公司 | Cleaning liquid for semiconductor integrated circuit and production process thereof |
| CN113680748A (en) * | 2021-08-26 | 2021-11-23 | 浙江工业大学 | Bio-based removal method for solid surface oil dirt |
| CN113980742A (en) * | 2021-11-12 | 2022-01-28 | 佛山市橙洁士洗涤剂有限公司 | Cleanser essence cream with strong oil removal property |
| CN115678690A (en) * | 2022-12-14 | 2023-02-03 | 山东宙雨消防科技股份有限公司 | Magnesium hydroxide cleaning agent and preparation method thereof |
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Application publication date: 20181102 |