CN108300621A - A kind of household cleaning cream and preparation method thereof - Google Patents

A kind of household cleaning cream and preparation method thereof Download PDF

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Publication number
CN108300621A
CN108300621A CN201810127178.0A CN201810127178A CN108300621A CN 108300621 A CN108300621 A CN 108300621A CN 201810127178 A CN201810127178 A CN 201810127178A CN 108300621 A CN108300621 A CN 108300621A
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China
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parts
household cleaning
water
cleaning cream
mixing
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Inventor
李成海
薛晓薇
赖泰阳
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Shenzhen Tianheyuan Industrial Co Ltd
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Shenzhen Tianheyuan Industrial Co Ltd
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Priority to CN201810127178.0A priority Critical patent/CN108300621A/en
Publication of CN108300621A publication Critical patent/CN108300621A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2024Monohydric alcohols cyclic; polycyclic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of household cleaning cream and preparation method thereof.The wherein described household cleaning cream includes 0.5 10 parts of xanthans;5 30 parts of water;50 100 parts of mineral salt;0.5 10 parts of grinding agent;1 20 parts of surfactant.Household cleaning cream provided by the present invention improves cleaning efficiency, clean and noresidue capable of washing, easy to carry, and reduce the mass production energy and resource uses and avoid waste, is that routine use brings huge convenience for production belt segment cost-saving.

Description

A kind of household cleaning cream and preparation method thereof
Technical field
The invention belongs to daily chemical product technical fields more particularly to a kind of household cleaning cream and preparation method thereof.
Background technology
Cleaning agent type is various, including inorganic cleaning and the organic washings agent of organic washing two major classes and inorganic cleaning agent Briefly, organic washing agent is exactly containing cleaning agent made of carbon compound, and inorganic clear numerous agent is exactly carbon-freeization for difference Cleaning agent made of object is closed, therefore they belong to inorganic matter.The sorting technique of cleaning agent is also very much, and each state is all not quite similar, I Generally fall into water system, half water system, non-water system cleaning agent three categories.
Liquid detergent is a kind of water-based detergent that people's frequent routine uses.Cleaning is mild, foam is soft and fine, rapid decomposition Greasy, fast decontaminating, degerming are effectively thoroughly cleaned, are not remained, distribute simple and elegant fruit flavor, wash rear pure white bright as new.Often make To ensure household sanitation, germina infection is avoided.The main component of liquid detergent is sodium alkyl sulfonate, fatty alcohol-ether sodium sulfate, bubble Foam agent, solubilizer, essence, water, pigment and preservative etc..Sodium alkyl sulfonate and fatty alcohol-ether sodium sulfate are all that anionic surface is lived Property agent, is petroleum chemicals, to decontamination oil stain.
Cleaning agent used in current market sales of people's daily life is liquid dosage form, as water type liquid, raw Produce preparation process in, need to feedstock composition be diluted dissolving become liquid, need expend compared with multiple-energy-source, resource and at This;When in use, since the liquid after dilution occupies larger volume, wherein water or other solvents occupies wherein larger quality, Cause to carry, is inconvenient to use, and water type liquid is when carrying out the cleaning to article, cannot clean up or volatilize completely and do Only, lead to abundant residues.In short, existing daily cleaning agent, since it is liquid dosage form, expend in production more multiple-energy-source, Resource improves production cost, and volume and quality in use are larger to be caused to carry and using extremely inconvenient;It is brought for production Cost wastes, and huge inconvenience is brought for routine use.
Invention content
To solve the above problems, the present invention provides a kind of household cleaning cream, include the component of following parts by weight:
0.5-10 parts of xanthans;
5-30 parts of water;
50-100 parts of mineral salt;
0.5-10 parts of grinding agent;
1-20 parts of surfactant.
Preferably, the household cleaning cream includes the component of following parts by weight:
1-5 parts of xanthans;
8-20 parts of water;
60-90 parts of mineral salt;
1-8 parts of grinding agent;
2-10 parts of surfactant.
Preferably, the household cleaning cream includes the component of following parts by weight:
1-3 parts of xanthans;
8-15 parts of water;
70-85 parts of mineral salt;
1-5 parts of grinding agent;
2-8 parts of surfactant.
Preferably, the household cleaning cream further includes the component of following parts by weight:
10-30 parts of rheum officinale;
1-5 parts of folium isatidis;
1-10 parts of folium artemisiae argyi;
20-50 parts of cordate houttuynia;
20-50 parts of Cortex Phellodendri;
10-30 parts of radix scrophulariae;
15-50 parts of Fructus Forsythiae;
30-50 parts of rhizoma anemarrhenae;
10-50 parts of borneol.
Preferably, the household cleaning cream includes the component of following parts by weight:20-30 parts of rheum officinale;
3-5 parts of folium isatidis;
5-10 parts of folium artemisiae argyi;
30-50 parts of cordate houttuynia;
40-50 parts of Cortex Phellodendri;
20-30 parts of radix scrophulariae;
30-50 parts of Fructus Forsythiae;
35-45 parts of rhizoma anemarrhenae;
20-50 parts of borneol.
Preferably, the household cleaning cream further includes the component of following parts by weight:20-30 parts of Artemisia capillaris;
10-30 parts of dandelion;
15-40 parts of the Chinese bulbul;
15-40 parts of Verbena officinalis.
Preferably, the household cleaning cream further includes the component of following parts by weight:
0.001-0.05 parts of solvent orange 7.
Preferably, the mineral salt is sodium bicarbonate;
The grinding agent is silica;
The surfactant is Cocoamidopropyl betaine;
The water is that conductivity is no more than 8us/cm, and pH value is the water of 5.5-7.5.
In addition, to solve the above problems, the present invention also provides a kind of preparation methods of household cleaning cream, including:
It takes 0.5-10 parts of xanthans to be mixed with 5-30 parts of water, is prepared into glue mixed liquor;
It takes 50-100 parts of mineral salt and 0.5-10 parts of grinding agent to be mixed, is prepared into dry-blend;
The glue mixed liquor is mixed 3-7 hours with the dry-blend, becomes mixing paste;
Take the mixing paste that 1-20 parts of surfactant is added, to get to household cleansing cream after mixing.
Preferably, described " taking 0.5-10 parts of xanthans to be mixed with 5-30 parts of water, to be prepared into glue mixed liquor " Including:
Take 20-30 parts of rheum officinale, 3-5 parts of folium isatidis, 5-10 parts of folium artemisiae argyi, 30-50 parts of cordate houttuynia, 40-50 parts of Cortex Phellodendri, radix scrophulariae 20-30 parts, 30-50 parts of Fructus Forsythiae, 35-45 parts of rhizoma anemarrhenae, 20-30 parts of Artemisia capillaris, 10-30 parts of dandelion, 15-40 parts of the Chinese bulbul, horse The water of the 15-40 parts of room temperature that 10 times of amounts are added of whip grass, impregnates 2 hours, is heated to decocting 60 minutes at 85-100 DEG C, 140 mesh Filtrate one is obtained by filtration;
Filter residue is added to the water of the room temperature of 6 times of amounts, is heated to decocting 30 minutes at 85-100 DEG C, filter is obtained by filtration in 140 mesh Liquid two;
The filtrate one and the filtrate two are merged, borneol mixing is added, it is dense that reduced vacuum is carried out at 70-85 DEG C Contracting obtains the Chinese medical concrete that density is 1.2-1.35;
0.5-10 parts of xanthans is added in the Chinese medical concrete to mix with 5-30 parts of water, is prepared into glue mixing Liquid;
" the mixing the glue mixed liquor 3-7 hours with the dry-blend, become mixing paste " includes:
The glue mixed liquor is taken, 0.1-1 parts of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
The mixing indicator solution is mixed 3-7 hours with the dry-blend, becomes mixing paste.
A kind of household cleaning cream of present invention offer and preparation method thereof, wherein the household cleaning cream includes xanthans 0.5- 10 parts;5-30 parts of water;50-100 parts of mineral salt;1-20 parts of 0.5-10 parts of grinding agent and surfactant.The present invention passes through xanthan Glue, water, mineral salt, grinding agent and surfactant prepare the quickly dissolving household cleaning cream as concentration, grinding agent therein Treat clean article with mineral salt and carry out friction cleaning, substantially increase cleaning efficiency, article to be cleaned can be cleaned up and Without any residual;In addition, cleaning agent provided by the present invention is household cleaning cream, it is concentrated type formula, quality is small and occupies body Product is small, convenient for the carrying and use in people's daily life;For producing preparation process, household cleaning cream need not carry out largely Dilution and dissolving, avoid the waste of the energy and resource, save great amount of cost.In short, household provided by the present invention is clear Clean cream improves cleaning efficiency, clean and noresidue capable of washing, easy to carry, and reduces making for the mass production energy and resource With with avoid waste, for production belt segment cost-saving, huge convenience is brought for routine use.
Specific implementation mode
Technical scheme of the present invention is described in further detail with reference to the mode of specific embodiment, but not structure At any limitation of the invention, the modification of anyone limited number of time made within the scope of the invention as claimed, still in this hair Within bright right.
The present invention provides a kind of household cleaning cream, includes the component of following parts by weight:
0.5-10 parts of xanthans;
5-30 parts of water;
50-100 parts of mineral salt;
0.5-10 parts of grinding agent;
1-20 parts of surfactant.
It is above-mentioned, it is to be understood that xanthans is also known as yellow glue, xanthan gum, and Xanthan Gum is one kind by false Xanthomonas campestris Belong to the monospore polysaccharide that fermentation generates, by cabbage black rot xanthomonas campestris using carbohydrate as primary raw material, through aerobic Fermentation bioengineering technology cuts off 1,6- glycosidic bonds, after opening branch, in a kind of acid born of the same parents for being bonded to straight chain composition by Isosorbide-5-Nitrae- Outer heteroglycan.Xanthans is to integrate thickening in the world at present, suspension, emulsify, be stable at the biogum that best performances are got over. The molecular side chain end of xanthans contains the number of pyruvic acid group, has a significant impact to its performance.Xanthans has long-chain high The general performance of molecule, but it contains more functional group than general macromolecule, can show special performance under given conditions.It Conformation in aqueous solution is various, and different characteristics is not showed under the conditions of.In the present invention, using it with good Water solubility, emulsibility, thickening property, ph stability and thermal stability, as household cleaning cream primary raw material.
Above-mentioned, water can be deionized water, or using other such as distilled water, multiple distilled water.
It is above-mentioned, it is to be understood that mineral salt is a kind of salt, wherein the mineral there are many containing, these mineral are beneficial to human body Health is easy to absorb, and the general name of the mineral containing silicate (SiO4) (also includes other siliceous salt, such as metasilicate, silicon ash Stone CaSiO3, that is, an example).Mineral salt can regard the combination of SiO2 and other oxides (being mostly metal oxide) as, and assistant Bao is helped Shellfish.
It is above-mentioned, it is to be understood that grinding agent refers to made of abrasive material, dispersant (also known as lapping liquid) and auxiliary material Intermixture is traditionally also classified as one kind of grinding tool.Grinding agent is for grinding and polish, and abrasive grain is in free state when use.Due to Dispersant and the ingredient and mixing ratio difference, grinding agent of auxiliary material have 3 kinds of liquid, paste and solid.In grinding agent Abrasive material plays shear action, and common abrasive material has corundum, silicon carbide, boron carbide and diamond etc..It is also used when lappingout and polishing Soft abrasiye, such as iron oxide, chromium oxide and cerium oxide.Dispersant makes abrasive material be dispersed in grinding agent, and plays dilution, lubrication The effects that with cooling, there are commonly kerosene, machine oil, animal oil, glycerine, alcohol and water etc..Auxiliary material mainly mixes fat, often It is made into, is being ground by the different materials in stearic acid, aliphatic acid, ethylene oxide, triethanolamine, paraffin, oleic acid and hexadecanol etc. Emulsification, lubrication and suction-operated are played in the process, and workpiece surface is promoted to generate chemical change, generate caducous oxidation film or sulphur Change film, so as to improving processing efficiency.
It is above-mentioned, include the frosted particle for playing frosted cleaning action in grinding agent, it is in the present invention, used Frosted particle is food grade materials, in use on the health of human body without influence.
In addition, also having colorant, preservative and aromatic etc. in auxiliary material.In the present invention, grinding agent, which plays, is in Occupy purpose of the grinding for pollutant to clean up in cleansing cream.
It is above-mentioned, it is to be understood that surfactant (surfactant) refers to being added that its solution system can be made on a small quantity The substance of significant change occurs for interface state.With fixed hydrophilic lipophilic group, aligned in the surface energy of solution.Surface The molecular structure of activating agent has amphipathic:One end is hydrophilic radical, and the other end is hydrophobic grouping;Hydrophilic radical is often polar group Group, such as carboxylic acid, sulfonic acid, sulfuric acid, amino or amido and its salt, hydroxyl, amide groups, ehter bond etc. also can be used as polar hydrophilic group; And hydrophobic grouping is often nonpolar hydrocarbon chain, such as 8 above hydrocarbon chains of carbon atom.Surfactant is divided into ionic surfactant (including cationic surfactant and anion surfactant), nonionic surface active agent, are answered at amphoteric surfactant With surfactant, other surfaces activating agent etc..In addition, in household cleaning cream provided by the present invention, it can also include enzyme, make For biological cleanser.It is to be appreciated that enzyme is that by what living cells generated there is catalytic activity and the special of high selectivity to have Machine object (protein, RNA, DNA), wherein most enzymes are protein.By the difference of its composition, protein enzyme is divided into list True protein and conjugated protein two major classes.For example, most of hydrolases belong to the enzyme being made of protein merely;Flavine monokaryon glycosides Sour enzyme then belongs to the binding protein enzyme being made of zymoprotein and confactor.Zymoprotein in conjugated protein is protein portion, Confactor is non-protein portion, and the two is combined into holoenzyme, and only holoenzyme just has catalytic activity.It in the present invention, can be abundant Using enzyme, the i.e. catalytic activity of ferment the cleaning of household cleaning cream is improved to assign the better dissolubility of product and episodic Ability.
The present invention prepares the quickly dissolving family as concentration by xanthans, water, mineral salt, grinding agent and surfactant Cleansing cream is occupied, grinding agent and mineral salt therein treat clean article and carry out friction cleaning, substantially increase cleaning efficiency, can incite somebody to action Article to be cleaned cleans up and without any residual;In addition, cleaning agent provided by the present invention is household cleaning cream, it is concentrated type Formula, quality is small and occupies small, to be convenient in people's daily life carrying and use;For producing preparation process, household Cleansing cream largely need not be diluted and be dissolved, and avoided the waste of the energy and resource, saved great amount of cost.In short, Household cleaning cream provided by the present invention improves cleaning efficiency, and clean and noresidue capable of washing is easy to carry, and reduces big The amount production energy and resource use and avoid waste, are that routine use brings huge side for production belt segment cost-saving Just.
In addition, the household cleaning cream provided in the present invention, compared with existing detergent (liquid detergent), effect is more, more It is easy to use, better, can be more broadly useful for, clean veterinary antibiotics;Remove pesticide residue, cleaning tableware, cleaning row Petticoat pipe, cleaning stove, the bathtub that clean toilet can also be washed, hand basin, closestool and floor ceramic tile etc.;To obstinate oil stain, dirt Dirt can be scrubbed with a little household cleaning cream provided by the present invention by corresponding wiper.Because lotion contains frosted Composition, and abrasive particle can be completely dissolved in wiping, be the household items of very safety and environmental protection.
In order to better illustrate household cleaning cream provided by the present invention, the application method of told household cleaning cream is listed in As described below:
(1) take all can cream apply wash bowl on remaining foam a little and be put into about 500ml clear water and got wet with foam and clean plate and bowl It is rinsed with clear water after wiping;
(2) it is cleaned i.e. within 5~10 minutes according to how much (per kilogram takes all-round 5 grams of cream, is dissolved in 3 kilograms of clear water) immersions of Fruit vegetables It can remove remains of pesticide;
(3) please be take when cleaning kitchen tools in right amount all-round cream be applied to velcro and release kitchen tools until cleaning with its sassafras;
(4) for the ground of the bathtub hand basin of toilet and ceramic tile take it is appropriate clean can looks it is for example new.
Preferably, the household cleaning cream includes the component of following parts by weight:
1-5 parts of xanthans;
8-20 parts of water;
60-90 parts of mineral salt;
1-8 parts of grinding agent;
2-10 parts of surfactant.
Preferably, the household cleaning cream includes the component of following parts by weight:
1-3 parts of xanthans;
8-15 parts of water;
70-85 parts of mineral salt;
1-5 parts of grinding agent;
2-8 parts of surfactant.
Preferably, the household cleaning cream further includes the component of following parts by weight:
10-30 parts of rheum officinale;
1-5 parts of folium isatidis;
1-10 parts of folium artemisiae argyi;
20-50 parts of cordate houttuynia;
20-50 parts of Cortex Phellodendri;
10-30 parts of radix scrophulariae;
15-50 parts of Fructus Forsythiae;
30-50 parts of rhizoma anemarrhenae;
10-50 parts of borneol.
It is above-mentioned, in the household cleaning cream provided in the present invention, add a certain amount of play in antibiotic effect Medicinal material, traditional Chinese medicine culture is of long standing and well established, and traditional Chinese medicine ingredients are added in formula as main component, plays and is treating clean article It carries out comprehensive cleaning simultaneously, the bacterium having on utensil is killed by traditional Chinese medicine ingredients.
Tableware after placing the long period, and if its surface do not clean completely, such as the extension of standing time There are a large amount of bacteriums, for example, staphylococcus aureus, staphylococcus albus, B-mode, α-hemolytic streptococcus, pneumococcus, Streptococcus hemolyticus, bacillus cloacae, aerobacteria, bloodthirsty Bacillus influenzae, Klebsiella pneumoniae, skin shape bacillus and gram-positive bacteria Etc..Rheum officinale, folium isatidis, folium artemisiae argyi, cordate houttuynia, Cortex Phellodendri, radix scrophulariae, Fructus Forsythiae are added in household cleaning cream provided in the present invention And rhizoma anemarrhenae, certain antibiotic effect to above-mentioned various bacteria can be played, antibacterial effect is played by traditional Chinese medicine ingredients to reach, keeps away The a large amount of harmful antimicrobial chemical ingredients of addition are exempted from.
It is above-mentioned, it is to be understood that borneol also known as piece brain, orange slices, L-Borneol, kapur, MEIHUA BINGPIAN, Dipterocarpus pilosus, plum Flower brain, borneol brain, Mei Bing etc. through steam distillation and are recrystallized by composite family Blumea balsamifera cauline leaf or canella borneol camphor tree branches and leaves And it obtains.In the present invention, refrigerant sense of the borneol raising to skin contact is added, makes have preferable user's body during user's use It tests.
Preferably, the household cleaning cream includes the component of following parts by weight:
20-30 parts of rheum officinale;
3-5 parts of folium isatidis;
5-10 parts of folium artemisiae argyi;
30-50 parts of cordate houttuynia;
40-50 parts of Cortex Phellodendri;
20-30 parts of radix scrophulariae;
30-50 parts of Fructus Forsythiae;
35-45 parts of rhizoma anemarrhenae;
20-50 parts of borneol.
Preferably, the household cleaning cream further includes the component of following parts by weight:
20-30 parts of Artemisia capillaris;
10-30 parts of dandelion;
15-40 parts of the Chinese bulbul;
15-40 parts of Verbena officinalis.
Above-mentioned, Artemisia capillaris, dandelion, the Chinese bulbul, Verbena officinalis are the traditional Chinese medicine ingredients for having certain antibiotic effect.
Preferably, the household cleaning cream further includes the component of following parts by weight:
0.001-0.05 parts of solvent orange 7.
Above-mentioned, solvent orange 7 is a kind of chemical staining agent, and brownish red shines acicular crystal or powder, biological stain, such as The fat stains of central nervous tissue.In the present invention, it is mainly useful for the coloration of oil substances.Specifically, During use, since there may be clean halfway situation, remained on surface in the utensils cleaning process such as tableware, pots and pans There is certain grease, such as hold the utensil of mutton sheep soup, the sheep oil on surface is not easy to clean up, and then causes mouldy, raw Phenomena such as worm, further brings huge security risk to people using the utensil.Household cleaning provided by the present invention In cream, due to adding micro solvent orange 7 as grease indicator, when in use, can and tool face to be cleaned grease Chromogenic reaction occurs, shows Chinese red, only needs cleanup crew to wash the coloring matter when to clean, you can realizing will All oil substances on article to be cleaned clean up.
Preferably, the mineral salt is sodium bicarbonate;
The grinding agent is silica;
The surfactant is Cocoamidopropyl betaine;
The water is that conductivity is no more than 8us/cm, and pH value is the water of 5.5-7.5.
Above-mentioned, the water in preparation process is deionized water, and control conductivity is no more than 8us/cm, pH value 5.5-7.5.
It is above-mentioned, it is to be understood that the entitled sodium bicarbonate of sodium bicarbonate chemistry.White fine crystals, solubility in water Less than sodium carbonate.It is also a kind of chemicals for industrial use, and 50 DEG C of solid or more, which starts gradually to decompose, generates sodium carbonate, carbon dioxide And water, 270 DEG C of whens, decompose completely.Sodium bicarbonate is the acid salt generated after highly basic is neutralized with weak acid, and weak base is presented when being dissolved in water Property.This characteristic can make it as the leavening agent in food product making process.Sodium bicarbonate can remain sodium carbonate after effect, use Mostly finished product can be made to have alkali taste.Because of the sodium bicarbonate containing high concentration in the present invention, itself has certain anti-corrosion effect, so not needing Additional addition preservative.
In addition, to solve the above problems, the present invention also provides a kind of preparation methods of household cleaning cream, including:
It takes 0.5-10 parts of xanthans to be mixed with 5-30 parts of water, is prepared into glue mixed liquor;
It is above-mentioned, xanthans and deionized water are pre-mixed, until being completely dissolved, support glue mixed liquor.
It takes 50-100 parts of mineral salt and 0.5-10 parts of grinding agent to be mixed, is prepared into dry-blend;
Mineral salt and grinding agent are sieved respectively, size controlling is 500-1000 mesh, then by mixing machine fully mix It closes, after mixing as dry-blend.Wherein, mixing machine can be that slot mixes machine, 2D mixing machines or 3D mixing machines etc..
The glue mixed liquor is mixed 3-7 hours with the dry-blend, becomes mixing paste;
The glue mixed liquor is mixed 3-7 hours with the dry-blend, 5 hours are preferably mixed, with specific reference to reality Inventory is configured incorporation time, and is carried out according to result of sampling inspection judging whether mixing is uniform, obtains mixing paste.
Take the mixing paste that 1-20 parts of surfactant is added, to get to household cleansing cream after mixing.
Surfactant is added in mixing paste to discharge, and obtain household cleaning cream.
After before discharging, a certain amount of sample detection need to be carried out, to whether household cleaning cream is uniformly mixed, whether content reaches Mark is tested.
Preferably, described " taking 0.5-10 parts of xanthans to be mixed with 5-30 parts of water, to be prepared into glue mixed liquor " Including:
Take 20-30 parts of rheum officinale, 3-5 parts of folium isatidis, 5-10 parts of folium artemisiae argyi, 30-50 parts of cordate houttuynia, 40-50 parts of Cortex Phellodendri, radix scrophulariae 20-30 parts, 30-50 parts of Fructus Forsythiae, 35-45 parts of rhizoma anemarrhenae, 20-30 parts of Artemisia capillaris, 10-30 parts of dandelion, 15-40 parts of the Chinese bulbul, horse The water of the 15-40 parts of room temperature that 10 times of amounts are added of whip grass, impregnates 2 hours, is heated to decocting 60 minutes at 85-100 DEG C, 140 mesh Filtrate one is obtained by filtration;
Filter residue is added to the water of the room temperature of 6 times of amounts, is heated to decocting 30 minutes at 85-100 DEG C, filter is obtained by filtration in 140 mesh Liquid two;
It is above-mentioned, 10 times of cold water soaks are carried out to dry Chinese medicine, are allowed to main component dissolution;And then at 85-100 DEG C of heating It decocts 60 minutes, temperature may be configured as 95 DEG C, keep fluidized state.Air pressure can be that normal pressure may be pressurised extraction, during which Dnockout cycle is constantly carried out, to achieve the purpose that feed liquid circulation mixing.When discharging, it is filtered to obtain filtrate by 140 mesh One, filter residue carries out second of extraction again, and the normal-temperature water measured by 6 times is extracted 30 minutes, filters 140 mesh, obtains filtrate two.
Wherein, vacuum extraction tank or high-pressure extracting tank can be used in extractor, to improve extraction efficiency.When feed liquid filters, It is overanxious that the sieved filter progress of concussion can be used.
The filtrate one and the filtrate two are merged, borneol mixing is added, it is dense that reduced vacuum is carried out at 70-85 DEG C Contracting obtains the Chinese medical concrete that density is 1.2-1.35;
Above-mentioned, reduced vacuum concentration can be used vacuum concentration pot and be concentrated, and density retinue test passes through densitometer pair Retinue sample is inspected by random samples, until density touches the mark.
0.5-10 parts of xanthans is added in the Chinese medical concrete to mix with 5-30 parts of water, is prepared into glue mixing Liquid;
" the mixing the glue mixed liquor 3-7 hours with the dry-blend, become mixing paste " includes:
The glue mixed liquor is taken, 0.1-1 parts of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
The mixing indicator solution is mixed 3-7 hours with the dry-blend, becomes mixing paste.
To facilitate the understanding of the present invention, the technical solution further illustrated the present invention with reference to embodiment.Applicant Statement, the present invention illustrate detailed process equipment and the technological process of the present invention, but the present invention not office by above-described embodiment It is limited to above-mentioned detailed process equipment and technological process, that is, does not mean that the present invention has to rely on above-mentioned detailed process equipment and technique Flow could be implemented.Person of ordinary skill in the field is each to product of the present invention it will be clearly understood that any improvement in the present invention The equivalence replacement of raw material and the addition of auxiliary element, the selection of concrete mode etc. all fall within protection scope of the present invention and openly Within the scope of.
Embodiment 1:
1, by 1 part of xanthans in liquid agitation pot:It is pre-mixed dissolving completely with 10 parts of ionized water is removed, glue is made Mixed liquor;
2, the grinding agent silica of 82 parts of mineral salt sodium bicarbonate and 2 parts is mixed into uniform powder in powder agitated kettle, made At dry-blend;
3, glue blended liquid phase and dry-blend are mixed into stirring 5 hours, are uniformly dispersed, at uniform lotion.
4,5 parts of surfactant Cocoamidopropyl betaine is added, is uniformly mixed, sample detection, after qualified It discharges filling.
Embodiment 2:
1, take 20 parts of rheum officinale, 3 parts of folium isatidis, 5 parts of folium artemisiae argyi, 30 parts of cordate houttuynia, 40 parts of Cortex Phellodendri, 20 parts of radix scrophulariae, 30 parts of Fructus Forsythiae, 15 parts of 35 parts of rhizoma anemarrhenae, 20 parts of Artemisia capillaris, 10 parts of dandelion, 15 parts of the Chinese bulbul, Verbena officinalis water that the room temperature that 10 times are measured is added, impregnate 2 hours are heated to decocting 60 minutes at 85 DEG C, and filtrate one is obtained by filtration in 140 mesh;
2, filter residue is added to the water of the room temperature of 6 times of amounts, be heated to decocting 30 minutes at 85 DEG C, filtrate is obtained by filtration in 140 mesh Two;
3, the filtrate one and the filtrate two are merged, borneol mixing are added, reduced vacuum concentration is carried out at 70 DEG C, Obtain the Chinese medical concrete that density is 1.2;
4,1 part of xanthans is added in the Chinese medical concrete to mix with 5 parts of water, is prepared into glue mixed liquor;
5, it takes 50 parts of mineral salt and 1 part of grinding agent to be mixed, is prepared into dry-blend;
6, the glue mixed liquor is taken, 0.1 part of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
7, the mixing indicator solution is mixed 3 hours with the dry-blend, becomes mixing paste.
8, take the mixing paste that 1 part of surfactant is added, to get to household cleansing cream after mixing, sample detection, It discharges after qualification filling.
Embodiment 3:
1, take 25 parts of rheum officinale, 4 parts of folium isatidis, 7 parts of folium artemisiae argyi, 40 parts of cordate houttuynia, 45 parts of Cortex Phellodendri, 25 parts of radix scrophulariae, 35 parts of Fructus Forsythiae, 30 parts of 40 parts of rhizoma anemarrhenae, 25 parts of Artemisia capillaris, 20 parts of dandelion, 30 parts of the Chinese bulbul, Verbena officinalis water that the room temperature that 10 times are measured is added, impregnate 2 hours are heated to decocting 60 minutes at 95 DEG C, and filtrate one is obtained by filtration in 140 mesh;
2, filter residue is added to the water of the room temperature of 6 times of amounts, be heated to decocting 30 minutes at 95 DEG C, filtrate is obtained by filtration in 140 mesh Two;
3, the filtrate one and the filtrate two are merged, borneol mixing are added, reduced vacuum concentration is carried out at 80 DEG C, Obtain the Chinese medical concrete that density is 1.3;
4,5 parts of xanthans is added in the Chinese medical concrete to mix with 20 parts of water, is prepared into glue mixed liquor;
5, it takes 70 parts of mineral salt and 5 parts of grinding agent to be mixed, is prepared into dry-blend;
6, the glue mixed liquor is taken, 0.5 part of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
7, the mixing indicator solution is mixed 5 hours with the dry-blend, becomes mixing paste.
8, take the mixing paste that 8 parts of surfactant is added, to get to household cleansing cream after mixing, sample detection, It discharges after qualification filling.
Embodiment 4:
1,30 parts of rheum officinale, 5 parts of folium isatidis, 10 parts of folium artemisiae argyi, 50 parts of cordate houttuynia, 50 parts of Cortex Phellodendri, 30 parts of radix scrophulariae, Fructus Forsythiae 50 are taken 40 parts of part, 45 parts of rhizoma anemarrhenae, 30 parts of Artemisia capillaris, 30 parts of dandelion, 40 parts of the Chinese bulbul, Verbena officinalis water that the room temperature that 10 times are measured is added, 2 hours are impregnated, are heated to decocting 60 minutes at 100 DEG C, filtrate one is obtained by filtration in 140 mesh;
2, filter residue is added to the water of the room temperature of 6 times of amounts, be heated to decocting 30 minutes at 100 DEG C, filtrate is obtained by filtration in 140 mesh Two;
3, the filtrate one and the filtrate two are merged, borneol mixing are added, reduced vacuum concentration is carried out at 85 DEG C, Obtain the Chinese medical concrete that density is 1.35;
4,10 parts of xanthans is added in the Chinese medical concrete to mix with 30 parts of water, is prepared into glue mixed liquor;
5, it takes 100 parts of mineral salt and 10 parts of grinding agent to be mixed, is prepared into dry-blend;
6, the glue mixed liquor is taken, 1 part of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
7, the mixing indicator solution is mixed 7 hours with the dry-blend, becomes mixing paste.
8, it takes the mixing paste that 20 parts of surfactant is added, to get to household cleansing cream after mixing, samples inspection It surveys, discharges after qualified filling.

Claims (10)

1. a kind of household cleaning cream, which is characterized in that include the component of following parts by weight:
0.5-10 parts of xanthans;
5-30 parts of water;
50-100 parts of mineral salt;
0.5-10 parts of grinding agent;
1-20 parts of surfactant.
2. household cleaning cream as described in claim 1, which is characterized in that the household cleaning cream includes the group of following parts by weight Point:
1-5 parts of xanthans;
8-20 parts of water;
60-90 parts of mineral salt;
1-8 parts of grinding agent;
2-10 parts of surfactant.
3. household cleaning cream as described in claim 1, which is characterized in that the household cleaning cream includes the group of following parts by weight Point:
1-3 parts of xanthans;
8-15 parts of water;
70-85 parts of mineral salt;
1-5 parts of grinding agent;
2-8 parts of surfactant.
4. household cleaning cream as described in claim 1, which is characterized in that the household cleaning cream further includes following parts by weight Component:
10-30 parts of rheum officinale;
1-5 parts of folium isatidis;
1-10 parts of folium artemisiae argyi;
20-50 parts of cordate houttuynia;
20-50 parts of Cortex Phellodendri;
10-30 parts of radix scrophulariae;
15-50 parts of Fructus Forsythiae;
30-50 parts of rhizoma anemarrhenae;
10-50 parts of borneol.
5. household cleaning cream as described in claim 1, which is characterized in that the household cleaning cream includes the group of following parts by weight Point:
20-30 parts of rheum officinale;
3-5 parts of folium isatidis;
5-10 parts of folium artemisiae argyi;
30-50 parts of cordate houttuynia;
40-50 parts of Cortex Phellodendri;
20-30 parts of radix scrophulariae;
30-50 parts of Fructus Forsythiae;
35-45 parts of rhizoma anemarrhenae;
20-50 parts of borneol.
6. household cleaning cream as claimed in claim 5, which is characterized in that the household cleaning cream further includes following parts by weight Component:
20-30 parts of Artemisia capillaris;
10-30 parts of dandelion;
15-40 parts of the Chinese bulbul;
15-40 parts of Verbena officinalis.
7. the household cleaning cream as described in claim any one of 1-6, which is characterized in that the household cleaning cream further includes following weight Measure the component of number:
0.001-0.05 parts of solvent orange 7.
8. the household cleaning cream as described in claim any one of 1-6, which is characterized in that the mineral salt is sodium bicarbonate;
The grinding agent is silica;
The surfactant is Cocoamidopropyl betaine;
The water is that conductivity is no more than 8us/cm, and pH value is the water of 5.5-7.5.
9. a kind of preparation method of household cleaning cream, which is characterized in that including:
It takes 0.5-10 parts of xanthans to be mixed with 5-30 parts of water, is prepared into glue mixed liquor;
It takes 50-100 parts of mineral salt and 0.5-10 parts of grinding agent to be mixed, is prepared into dry-blend;
The glue mixed liquor is mixed 3-7 hours with the dry-blend, becomes mixing paste;
Take the mixing paste that 1-20 parts of surfactant is added, to get to household cleansing cream after mixing.
10. the preparation method of household cleaning cream as claimed in claim 9, which is characterized in that described " to take 0.5-10 parts of xanthans Mixed with 5-30 parts of water, be prepared into glue mixed liquor " include:
Take 20-30 parts of rheum officinale, 3-5 parts of folium isatidis, 5-10 parts of folium artemisiae argyi, 30-50 parts of cordate houttuynia, 40-50 parts of Cortex Phellodendri, radix scrophulariae 20-30 Part, 30-50 parts of Fructus Forsythiae, 35-45 parts of rhizoma anemarrhenae, 20-30 parts of Artemisia capillaris, 10-30 parts of dandelion, 15-40 parts of the Chinese bulbul, Verbena officinalis The water of the 15-40 parts of room temperature that 10 times of amounts are added impregnates 2 hours, is heated to decocting 60 minutes at 85-100 DEG C, the filtering of 140 mesh Obtain filtrate one;
Filter residue is added to the water of the room temperature of 6 times of amounts, is heated to decocting 30 minutes at 85-100 DEG C, filtrate two is obtained by filtration in 140 mesh;
The filtrate one and the filtrate two are merged, borneol mixing is added, reduced vacuum concentration is carried out at 70-85 DEG C, is obtained To the Chinese medical concrete that density is 1.2-1.35;
0.5-10 parts of xanthans is added in the Chinese medical concrete to mix with 5-30 parts of water, is prepared into glue mixed liquor;
" the mixing the glue mixed liquor 3-7 hours with the dry-blend, become mixing paste " includes:
The glue mixed liquor is taken, 0.1-1 parts of solvent orange 7 is added and is mixed, obtains mixing indicator solution;
The mixing indicator solution is mixed 3-7 hours with the dry-blend, becomes mixing paste.
CN201810127178.0A 2018-02-08 2018-02-08 A kind of household cleaning cream and preparation method thereof Pending CN108300621A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109439456A (en) * 2018-11-28 2019-03-08 山东海天生物化工有限公司 A kind of sodium bicarbonate lotion dish washing detergent
CN109593615A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of preparation method of sodium bicarbonate detergent
CN109593614A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of fruits and vegetables cleaning agent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4122470A1 (en) * 1991-07-06 1993-01-07 Bitterfeld Wolfen Chemie Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent
CN1200759A (en) * 1995-09-19 1998-12-02 雷克特和科尔曼公司 Cleaning compositions with enhanced rheology
CN103013719A (en) * 2012-11-15 2013-04-03 隋丽梅 Room environmental cleaner and preparation method thereof
CN105695153A (en) * 2014-11-26 2016-06-22 天津普范科技开发有限公司 Chinese herbal medicinal furniture detergent
CN106701336A (en) * 2016-12-21 2017-05-24 上海皇宇科技发展有限公司 Multifunctional solid cleaning cream capable of high-efficiency decontamination and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4122470A1 (en) * 1991-07-06 1993-01-07 Bitterfeld Wolfen Chemie Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent
CN1200759A (en) * 1995-09-19 1998-12-02 雷克特和科尔曼公司 Cleaning compositions with enhanced rheology
CN103013719A (en) * 2012-11-15 2013-04-03 隋丽梅 Room environmental cleaner and preparation method thereof
CN105695153A (en) * 2014-11-26 2016-06-22 天津普范科技开发有限公司 Chinese herbal medicinal furniture detergent
CN106701336A (en) * 2016-12-21 2017-05-24 上海皇宇科技发展有限公司 Multifunctional solid cleaning cream capable of high-efficiency decontamination and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109439456A (en) * 2018-11-28 2019-03-08 山东海天生物化工有限公司 A kind of sodium bicarbonate lotion dish washing detergent
CN109593615A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of preparation method of sodium bicarbonate detergent
CN109593614A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of fruits and vegetables cleaning agent

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