DE4122470A1 - Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent - Google Patents
Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agentInfo
- Publication number
- DE4122470A1 DE4122470A1 DE4122470A DE4122470A DE4122470A1 DE 4122470 A1 DE4122470 A1 DE 4122470A1 DE 4122470 A DE4122470 A DE 4122470A DE 4122470 A DE4122470 A DE 4122470A DE 4122470 A1 DE4122470 A1 DE 4122470A1
- Authority
- DE
- Germany
- Prior art keywords
- cleaning
- weight
- glass
- hard surfaces
- reducing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 29
- 239000011521 glass Substances 0.000 title claims abstract description 10
- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 8
- 239000007800 oxidant agent Substances 0.000 title claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 title claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title abstract 2
- 239000010452 phosphate Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 title 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008096 xylene Substances 0.000 claims abstract description 9
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 6
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical group [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 6
- 239000012190 activator Substances 0.000 claims abstract description 4
- MLBKCFCDYTVXAN-UHFFFAOYSA-N C(C)(=O)C1(C(NNNC1=O)=O)C(C)=O Chemical compound C(C)(=O)C1(C(NNNC1=O)=O)C(C)=O MLBKCFCDYTVXAN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004744 fabric Substances 0.000 claims abstract description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 5
- JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 229960001922 sodium perborate Drugs 0.000 claims description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract description 6
- 239000011976 maleic acid Substances 0.000 abstract description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 239000002202 Polyethylene glycol Substances 0.000 description 12
- 229920001223 polyethylene glycol Polymers 0.000 description 12
- 239000000243 solution Substances 0.000 description 8
- 239000003599 detergent Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 5
- 235000019832 sodium triphosphate Nutrition 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003082 abrasive agent Substances 0.000 description 3
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 3
- 235000011837 pasties Nutrition 0.000 description 3
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- MPXCBQCUNKTGGN-UHFFFAOYSA-N CN(C)C.OP(=O)OP(O)=O Chemical compound CN(C)C.OP(=O)OP(O)=O MPXCBQCUNKTGGN-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0042—Reducing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0078—Compositions for cleaning contact lenses, spectacles or lenses
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft Reinigungspasten insbesondere zum schnellen Entfernen von Flecken aus Geweben, von Händen und harten Oberflächen.The invention relates in particular to cleaning pastes for rapid Remove stains from tissues, hands and hard surfaces.
Reinigungsmittel enthalten üblicherweise waschaktive Substanzen, Builder und Gerüststoffe. Je nach Einsatzgebiet können gezielt Lösungsmittel, Lösungsvermittler, Oxidations- und Reduktionsmittel oder Abrassivstoffe zugegeben werden.Detergents usually contain detergent substances, Builders and builders. Depending on the area of application can be targeted Solvents, solubilizers, oxidizing and reducing agents or abrasives are added.
Die DD-PS 1 20 046, DD-PS 2 31 799 und DD-PS 27 944 beschreiben Waschmittel, die ausschließlich waschaktive Substanzen und Gerüst stoffe wie Phosphate, Soda und Komplexbildner enthalten. Ihre Anwendung beschränkt sich ausschließlich auf den Einsatz als Textil waschmittel. Ein Kaltwaschmittel auf der Basis von Fettsäurealkyl estern und Benzinfraktionen wird in der DE-OS 35 37 619 beschrieben.The DD-PS 1 20 046, DD-PS 2 31 799 and DD-PS 27 944 describe Detergents that contain only washing-active substances and framework contain substances such as phosphates, soda and complexing agents. Your Application is limited to use as a textile laundry detergent. A cold detergent based on fatty acid alkyl esters and gasoline fractions are described in DE-OS 35 37 619.
In den DE-OS 17 92 066, DE-OS 22 08 348, DE-OS 29 13 049, DE-OS 30 04 835, DD-PS 2 24 082 und DD-PS 2 18 776 werden flüssige Mittel zur Reinigung harter Oberflächen beschrieben, die einen mehr oder weniger hohen Anteil an organischen Lösungsmitteln zur Entfernung insbesondere fetthaltiger Verschmutzungen aufweisen. Bei einer Anwendung als Fleckentfernungsmittel sind sie nur bedingt einsetz bar, da sie nur übliche Fett- und Pigmentverschmutzungen entfernen.In DE-OS 17 92 066, DE-OS 22 08 348, DE-OS 29 13 049, DE-OS 30 04 835, DD-PS 2 24 082 and DD-PS 2 18 776 become liquid assets described for cleaning hard surfaces that a more or less high proportion of organic solvents for removal especially greasy soiling. At a They are only of limited use as stain removers bar, as they only remove common grease and pigment contamination.
Reinigungsmittel die auch zur Entfernung von Blut- und Fettflecken geeignet sind, werden in den DD-PS 1 35 288 und DD-PS 2 40 563 be schrieben.Detergent also used to remove blood and grease stains are suitable, be in DD-PS 1 35 288 and DD-PS 2 40 563 wrote.
Diese Mittel enthalten neben Alkohol als Lösungsmittel den Komplex bildner Dimethylaminomethandiphosphonsäure. Diese Phosphonsäure ist biologisch nicht abbaubar.In addition to alcohol, these agents contain the complex as a solvent formers dimethylaminomethane diphosphonic acid. This phosphonic acid is not biodegradable.
Die in der DD-PS 86 457 beschriebenen pastösen Reinigungsmittel, die Alkohole, ethoxylierte Alkylphenole, aromatische substituierte Alkylhalogenide und quarternäre Ammoniumsalze sowie Tonerde enthalten sind zur Entfernung von Flecken aus Textilien wenig geeignet. The pasty cleaning agents described in DD-PS 86 457, the alcohols, ethoxylated alkylphenols, aromatic substituted Contain alkyl halides and quaternary ammonium salts and alumina are not very suitable for removing stains from textiles.
Pastöse Mittel für Hand- und Körperreinigung und Reinigung harter Oberflächen werden in den DD-PS 2 31 800 und DD-PS 2 65 160 beschrieben. Zur Verstärkung des Reinigungseffektes enthalten diese Mittel Abrassivstoffe. Diese Abrassive schließen eine Anwendung als Fleck entfernungsmittel für Textilien aus.Pasty agents for hand and body cleaning and hard cleaning Surfaces are described in DD-PS 2 31 800 and DD-PS 2 65 160. These contain agents to enhance the cleaning effect Abrasives. These abrasives exclude application as a stain removers for textiles.
Fleckentfernungsmittel werden in den DD-PS 40 860, DD-PS 41 252, DD-PS 47 987, DE-PS 35 09 266 und DE-OS 23 23 605 beschrieben.Stain removers are described in DD-PS 40 860, DD-PS 41 252, DD-PS 47 987, DE-PS 35 09 266 and DE-OS 23 23 605 described.
Diese Mittel enthalten Natriumhydrogensulfit, organische Säuren, Alkohol und/oder chlorierte Kohlenwasserstoffe. Diese Mittel sind ausschließlich zur Entfernung von Flecken aus Textilien geeignet. Mittel, die chlorierte Kohlenwasserstoffe enthalten nach dem Trock nen zur Randbildung. Insbesondere beim Einsatz von Perchlorethylen neigen die von den Textilien entfernten Verschmutzungen zur erneuten Ablagerung auf dem Textilgut und fördern damit eine verstärkte Vergrauung.These agents contain sodium bisulfite, organic acids, Alcohol and / or chlorinated hydrocarbons. These funds are only suitable for removing stains from textiles. Agents containing chlorinated hydrocarbons after drying edge formation. Especially when using perchlorethylene the dirt removed from the textiles tends to renew Deposition on the textile goods and thus promote an increased Graying.
Ein in der DE-PS 25 32 566 beschriebenes Mittel in pastöser Form enthält Cyclohexanol, Toluol, Dichlorethan, Trichlorethan und Parfüm, die in Gelatine eingeschlossen und auf einen pulverförmigen Feststoff aufgebracht sind.A medium described in DE-PS 25 32 566 in pasty form contains cyclohexanol, toluene, dichloroethane, trichloroethane and Perfume enclosed in gelatin and put on a powder Solid are applied.
Der Erfindung liegt die Aufgabe zu Grunde, Reinigungspasten zu entwickeln, die neben einer guten fleckentfernenden Wirkung auch gute Reinigungseffekte an harten Oberflächen und Händen besitzen.The invention is based on the object of cleaning pastes develop that in addition to a good stain-removing effect have good cleaning effects on hard surfaces and hands.
Erfindungsgemäß wurde die Aufgabe gelöst durch eine Kombination ausAccording to the invention, the object was achieved by a combination out
4,0 bis 15,0 Gew.-% anionisches Tensid
20,0 bis 40,0 Gew.-% nichtionogenes Tensid
0,5 bis 1,5% Gew.-% eines Maleinsäure-Acrylsäure-Copolymeres
2,0 bis 10,0 Gew.-% Phosphate
4,0 Bis 15,0 Gew.-% Testbenzin
10,0 bis 30,0 Gew.-% eines Reduktions- bzw. Oxidationsmittels4.0 to 15.0% by weight of anionic surfactant
20.0 to 40.0% by weight of nonionic surfactant
0.5 to 1.5% by weight of a maleic acid-acrylic acid copolymer
2.0 to 10.0% by weight of phosphates
4.0 to 15.0% by weight white spirit
10.0 to 30.0% by weight of a reducing or oxidizing agent
gegebenenfallspossibly
5,0 bis 13,0 Gew.-% Xylen
5,0 bis 15,0 Gew.-% eines Perborataktivators
0 bis 12,0 Gew.-% Natriumsulfat
0 bis 10,0 Gew.-% Soda
ad. 100 Gew.-% Wasser.5.0 to 13.0 wt% xylene
5.0 to 15.0% by weight of a perborate activator
0 to 12.0% by weight sodium sulfate
0 to 10.0% by weight of soda
ad. 100% by weight water.
Die erfindungsgemäßen Kombinationen verbessers je nach Einstellung die fleckentfernende Wirkung entscheidend und erlauben einen uni versellen Einsatz zur Reinigung von Händen, harten Oberflächen und Gläsern.The combinations according to the invention improve depending on the setting the stain-removing effect is crucial and allow a uni universal use for cleaning hands, hard surfaces and glasses.
Die fleckentfernende Wirkung wird entscheidend vom Anteil der Reduktions- bzw. Oxidationsmittel beeinflußt. Überraschend hat sich dabei gezeigt, daß die Zeitdauer der Reinigung entscheidend verringert werden kann, wenn das Verhältnis von Natriumhydrogen sulfit und Natriumdithionit 1 : 2,2 bis 1 : 4 beträgt. Eine Er höhung des Natriumdithionitanteils verlängert die Reinigungsdauer. Wird der Anteil an Natriumdithionit reduziert, kann es zu Entfär bungen und Stoffschädigungen kommen. Durch die Kombination von Tensiden und Lösungsmitteln konnte zur Entfernung von fetthaltigen Verschmutzungen auf chlorierte Kohlenwassserstoffe verzichtet werden.The stain-removing effect is determined by the proportion of Reducing or oxidizing agents influenced. Surprisingly it has been shown that the duration of cleaning is crucial can be reduced if the ratio of sodium hydrogen sulfite and sodium dithionite is 1: 2.2 to 1: 4. An he Increasing the sodium dithionite content extends the cleaning time. If the proportion of sodium dithionite is reduced, it can lead to decolorization exercises and material damage. By combining Surfactants and solvents could remove fatty ones Soiling of chlorinated hydrocarbons can be avoided.
Bei der Reinigung von Glasscheiben, Spiegeln und Brillengläsern wurde überraschenderweise gefunden, daß die erfindungsgemäßen Kombinationen eine sehr gute Antibeschlagwirkung aufweisen.When cleaning glass panes, mirrors and glasses was surprisingly found that the invention Combinations have a very good anti-fog effect.
In den nachfolgenden Ausführungsbeispielen sollen die Wirkungen näher erläutert werden.In the following examples, the effects are intended are explained in more detail.
Die aufgeführten Mittel werden in einer üblichen beheizbaren Rühr werksapparatur zusammengerührt und gemischt. Zweckmäßigerweise sollte die Rührgeschwindigkeit nicht höher als 700 U/min betragen. Das Vorhandensein einer Kühlung ist vorteilhaft. The listed agents are in a conventional heated stirrer factory equipment stirred and mixed. Conveniently the stirring speed should not exceed 700 rpm. The presence of cooling is advantageous.
In eine Rührwerksapparatur werdenBe in an agitator
6,0 kg Alkyl-C₁₅-sulfat, Na-Salz,
20,0 kg Alkyl-C16-18-polyethylenglykolether (70 EO)
14,0 kg Alkyl-C12-18-polyethylenglykol (11-EO)-polypropylenglykol
(2-PO)-ether,
2,3 kg einer 40%igen wäßrigen Lösung eines Maleinsäure-Acryl
säure-Copolymerisates
1,9 kg Wasser6.0 kg of alkyl C₁₅ sulfate, sodium salt,
20.0 kg of alkyl C 16-18 polyethylene glycol ether (70 EO)
14.0 kg alkyl C 12-18 polyethylene glycol (11-EO) polypropylene glycol (2-PO) ether,
2.3 kg of a 40% aqueous solution of a maleic acid-acrylic acid copolymer
1.9 kg of water
gegeben und unter Rühren auf etwa 60-70°C erwärmt und homogenisiert. Anschließend werden in beliebiger Reihenfolgegiven and heated to about 60-70 ° C with stirring and homogenized. Then, in any order
10,0 kg Natriumsulfat
7,8 kg Natriumtripolyphosphat und
18,0 kg Natriumdithionit10.0 kg sodium sulfate
7.8 kg sodium tripolyphosphate and
18.0 kg sodium dithionite
eingebracht und homogenisiert. Unter Rühren wird das Produkt auf ca. 30°C abgekühlt und anschließend werdenintroduced and homogenized. The product is stirred on cooled to approx. 30 ° C and then
6,7 kg Xylen und
13,3 kg Testbenzin6.7 kg of xylene and
13.3 kg white spirit
zugegeben. Bis zur vollständigen Homogenität wird weitergerührt.admitted. The mixture is stirred until completely homogeneous.
12,0 kg Alkylbenzolsulfonat, mittlerer Kettenlänge C₁₂, 50%iger
wäßrige Lösung
19,0 kg Alkyl-C₁₆-C₁₈-polyethylenglykolether (70 EO)
13,5 kg Alkyl-C₁₂-C₁₈-polyethylenglykol (11 EO)-polypropylenglykol
(2 PO)-ether und
2,2 kg einer 40%igen wäßrigen Maleinsäure-Acrylsäure-Copolymerisat
lösung12.0 kg of alkylbenzenesulfonate, medium chain length C₁₂, 50% aqueous solution
19.0 kg alkyl C₁₆ C₁₈ polyethylene glycol ether (70 EO)
13.5 kg of alkyl C₁₂-C₁₈ polyethylene glycol (11 EO) polypropylene glycol (2 PO) ether and
2.2 kg of a 40% aqueous maleic acid / acrylic acid copolymer solution
werden entsprechend Beispiel 1 homogenisiert. Anschließend werdenare homogenized according to Example 1. Then be
7,5 kg Natriumdithionit,
7,0 kg Natriumtripolyphosphat und
9,4 kg Soda, calc.7.5 kg sodium dithionite,
7.0 kg sodium tripolyphosphate and
9.4 kg soda, calc.
eingetragen. Nach Abkühlung auf ca. 30°C werdenregistered. After cooling to about 30 ° C
6,5 kg Xylen und
12,9 kg Testbenzin6.5 kg of xylene and
12.9 kg white spirit
eingerührt und homogenisiert.stirred in and homogenized.
Entsprechend Beispiel 1 werdenAccording to example 1
5,0 kg Alkyl-C₁₅-sulfat, Na-salz
20,0 kg Alkyl-C₁₆-C₁₈-polyethylenglykolether (70 EO)
12,0 kg Alkyl-C₁₂-C₁₈-polyethylenglykol (11 EO)-polypropylenglykol
(2 PO)-ether und
1,9 kg einer 40%igen wäßrigen Maleinsäure-Acrylsäure-Copolymerisat
lösung5.0 kg of alkyl C₁₅ sulfate, sodium salt
20.0 kg alkyl C₁₆ C₁₈ polyethylene glycol ether (70 EO)
12.0 kg of alkyl C₁₂-C₁₈ polyethylene glycol (11 EO) polypropylene glycol (2 PO) ether and
1.9 kg of a 40% aqueous maleic acid / acrylic acid copolymer solution
homogenisiert. Anschließend werdenhomogenized. Then be
6,2 kg Natriumtripolyphosphat
5,2 kg Natriumsulfat und
9,3 kg Diacetyl-dioxo-hexahydrotriazin6.2 kg sodium tripolyphosphate
5.2 kg of sodium sulfate and
9.3 kg diacetyl-dioxo-hexahydrotriazine
eingebracht. Nach Abkühlung auf 25°C werden erst 9,3 kg Natriumperborat und dannbrought in. After cooling to 25 ° C only 9.3 kg of sodium perborate and then
22,0 kg Xylen
11,0 kg Testbenzin22.0 kg xylene
11.0 kg white spirit
eingerührt und homogenisiert.stirred in and homogenized.
Diese Mittel sind zur Fleckentfernung aus farbigen Geweben gut geeignet.These agents are well suited for removing stains from colored fabrics.
In eine Rührwerksapparatur werdenBe in an agitator
17,1 kg Alkyl-C₁₆-C₁₈-polyethylenglykolether (70 EO)
12,8 kg Alkyl-C₁₂-C₁₈-polyethylenglykol (11 EO)-polypropylen
(2 PO)-ether und
2,0 kg einer 40%igen wäßrigen Maleinsäure-Acrylsäure-Copolymerisat
lösung17.1 kg alkyl-C₁₆-C₁₈ polyethylene glycol ether (70 EO)
12.8 kg of alkyl C₁₂-C₁₈ polyethylene glycol (11 EO) polypropylene (2 PO) ether and
2.0 kg of a 40% aqueous maleic acid / acrylic acid copolymer solution
gegeben.given.
In 13,8 kg einer 40%igen wäßrigen Natriumdrogensulfitlauge werden 5,1 kg Alkyl-C₁₅-sulfat, Na-Salz gelöst und diese Lösung zur Tensid mischung gegeben, die unter Rühren auf etwa 60-70°C erhitzt wird. Anschließend werdenIn 13.8 kg of a 40% aqueous sodium sulfite liquor 5.1 kg of alkyl C₁₅ sulfate, Na salt dissolved and this solution to the surfactant given mixture, which is heated to about 60-70 ° C with stirring. Then be
6,5 kg Natriumtripolyphosphat und
2,0 kg Natriumsulfat6.5 kg sodium tripolyphosphate and
2.0 kg sodium sulfate
dazugegeben. Nach Abkühlung auf etwa 30°C werdenadded. After cooling to about 30 ° C
10,6 kg Testbenzin
10,0 kg Xylen und
20,1 kg Natriumdithionit10.6 kg white spirit
10.0 kg xylene and
20.1 kg sodium dithionite
eingebracht und homogenisiert.introduced and homogenized.
Entsprechend Beispiel 4 werdenAccording to example 4
20,0 kg Alkyl-C₁₆-C₁₈-polyethylenglykolether (70 EO)
12,0 kg Alkyl-C₁₂-C₁₈-polyethylenglykol (11 EO)-polypropylenglykol
(2 PO)-ether
2,4 kg einer 40%igen wäßrigen Maleinsäure-Acryl-Copolymerisat
lösung
6,0 kg Alkyl-C₁₅-sulfat, Na-Salz
15,2 kg einer 40%igen Na-hydrogensulfitlauge
14,4 kg Natriumdithionit
7,6 kg Natriumtripolyphosphat
2,4 kg Natriumsulfat
10,0 kg Xylen und
10,0 kg Testbenzin20.0 kg alkyl C₁₆ C₁₈ polyethylene glycol ether (70 EO)
12.0 kg of alkyl C₁₂-C₁₈ polyethylene glycol (11 EO) polypropylene glycol (2 PO) ether
2.4 kg of a 40% aqueous maleic acid / acrylic copolymer solution
6.0 kg of alkyl C₁₅ sulfate, Na salt
15.2 kg of a 40% sodium hydrogen sulfite liquor
14.4 kg sodium dithionite
7.6 kg sodium tripolyphosphate
2.4 kg sodium sulfate
10.0 kg xylene and
10.0 kg white spirit
eingerührt und homogenisiert. stirred in and homogenized.
Diese Mittel sind universell einsetzbar als Fleckentfernungsmittel, Reiniger für harte Oberflächen und zur Reinigung stark verschmutzter Hände.These agents can be used universally as stain removers, Cleaner for hard surfaces and for cleaning heavily soiled Hands.
Entsprechend Beispiel 4 werden in einer RührwerksapparaturAccording to Example 4 are in an agitator
15,0 kg Alkyl-C₁₆-C₁₈-polyethylenglykolether (70 EO)
13,0 kg Alkyl-C₁₂-C₁₈-polyethylenglykol (11 EO)-polypropylenglykol
(2 PO)-ether
1,5 kg einer 40%igen wäßrigen Maleinsäure-Acrylsäure-Copolymerisat
lösung
6,8 kg Alkyl-C₁₅-sulfat, Na-Salz
3,0 kg Wasser
10,0 kg einer 40%igen Na-hydrogensulfitlauge
10,0 kg Natriumpyrophosphat
18,2 kg Natriumsulfat
7,5 kg Xylen und
15,0 kg Testbenzin15.0 kg of alkyl C₁₆ C₁ poly polyethylene glycol ether (70 EO)
13.0 kg of alkyl C₁₂-C₁₈ polyethylene glycol (11 EO) polypropylene glycol (2 PO) ether
1.5 kg of a 40% aqueous maleic acid / acrylic acid copolymer solution
6.8 kg of alkyl C₁₅ sulfate, sodium salt
3.0 kg of water
10.0 kg of a 40% sodium hydrogen sulfite liquor
10.0 kg sodium pyrophosphate
18.2 kg sodium sulfate
7.5 kg of xylene and
15.0 kg white spirit
eingerührt und homogenisiert.stirred in and homogenized.
Diese Kombination eigent sich hervorragend als Reinigungsmittel für harte Oberflächen und als Glasreiniger mit ausgezeichnetem Hydrophobierungseffekt.This combination is ideal as a cleaning agent for hard surfaces and as a glass cleaner with excellent Water repellent effect.
Zur Prüfung der Gebrauchseigenschaften wurden folgende Vergleichsbeispiele herangezogen:The following comparative examples were used to test the performance properties used:
Die Vergleichsbeispiele sind den Erfindungsbeschreibungen nach den DD-PS 2 40 563 (V1), DD-PS 2 18 776 (V2) und DD-PS 2 54 742 (V3) entnommen. Zusätzlich wurden handelsübliche Fleckentferner in die Testung aufgenommen.The comparative examples are the descriptions of the invention according to the DD-PS 2 40 563 (V1), DD-PS 2 18 776 (V2) and DD-PS 2 54 742 (V3). Commercial stain removers were also included in the test.
Die fleckentfernende Wirkung wurde bestimmt, in dem weiße Gewebestücken mit definierten Mengen Kaffee, Tee, Süßmost, Schweinefett, Eisen(III)chlorid lösung, Kakao und Tinte behandelt werden und nach dem Trocknen in die je weilige zu testende Reinigungslösung eingetaucht werden. Nach 30 Minuten werden die Testgewebe entnommen, unter fließendem kalten Leitungswasser abgespült und getrocknet. Als Maß für die Reinigungswirkung gilt das Ver hältnis der Reflexionswerte zwischen gereinigtem und unbeschmutztem Gewebe in Prozent. Die Reflexionswerte wurden mit einem Zeiss-Leukometer bestimmt.The stain-removing effect was determined in the white tissue pieces defined quantities of coffee, tea, sweet must, lard, iron (III) chloride solution, cocoa and ink are treated and after drying in each some cleaning solution to be tested can be immersed. After 30 minutes the test tissues are removed under running cold tap water rinsed and dried. Ver applies as a measure of the cleaning effect Ratio of the reflectance values between cleaned and unpolluted tissue in percent. The reflection values were determined with a Zeiss leukometer.
Die Reinigungswirkung an harten Oberflächen wurde an definiert verschmutzten Keramikplatten bestimmt. Die Platten wurden 15 Minuten in die Probeflüssig keit gelegt, mit einem durch Leitungswasser tiefnassen Schwamm fünfmal ab wechselnd durch Quer- und Längsstriche abgewischt und anschließend mit Lei tungswasser abgespült. Die Reinigungswirkung wurde visuell betrachtet.The cleaning effect on hard surfaces was defined on soiled Ceramics plates determined. The plates were placed in the sample for 15 minutes 5 times with a sponge soaked in tap water alternately wiped with horizontal and vertical lines and then with lei rinse water. The cleaning effect was viewed visually.
Die Reinigungswirkung an Glas wurde durch Reflexionswertbestimmungen an von definiert gereinigten und unbehandelten Petrischalen bestimmt. Als Maß gilt das Verhältnis der Reflexionswerte zwischen gereinigten und unbehandelten Petrischalen in Prozent.The cleaning effect on glass was determined by determining the reflectance value of defined cleaned and untreated petri dishes. As a measure the ratio of the reflection values between cleaned and untreated Petri dishes in percent.
Die hydrophobierende Wirkung wurde nach der in der DD-PS 2 54 742 beschrie benen Methode beurteilt. The hydrophobizing effect was assessed according to the method described in DD-PS 2 54 742.
Aus der Tabelle ist zu entnehmen, daß die erfindungsgemäßen Mittel in der Fleckentfernung alle nahezu die gleichen Ergebnisse erzielen, wie die einzelnen Spezialmittel. Dem multifunktionellen Fleckentferner sind sie überlegen. Gegenüber den Reinigungs- und Hydrophobierungs mittel können die erfidnungsgemäßen Mittel als qualitativ hochwer tiger eingeschätzt werden.The table shows that the agents according to the invention all achieve almost the same results in stain removal, like the individual special products. The multifunctional stain remover are you superior. Compared to cleaning and waterproofing means, the means according to the invention can be of high quality be assessed.
Claims (6)
20,0 bis 40,0 Gew.-% nichtionogenes Tensid
0,5 bis 1,5 Gew.-% eines Maleinsäure-Acrylsäure-Copolymeres
2,0 bis 10,0 Gew.-% Phosphate
4,0 bis 15,0 Gew.-% Testbenzin
10,0 bis 30,0 Gew.-% eines Reduktions- bzw. Oxidationsmittels
ad. 100 Gew.-% Wasserenthält.1. Cleaning paste based on surfactants and solvents, characterized in that it contains 4.0 to 15.0% by weight of anionic surfactant
20.0 to 40.0% by weight of nonionic surfactant
0.5 to 1.5% by weight of a maleic acid-acrylic acid copolymer
2.0 to 10.0% by weight of phosphates
4.0 to 15.0% by weight white spirit
10.0 to 30.0% by weight of a reducing or oxidizing agent
ad. Contains 100% by weight of water.
5,0 bis 15,0 Gew.-% eines Perborataktivators
0 bis 12,0 Gew.-% Natriumsulfat
0 bis 10,0 Gew.-% Sodaenthält.2. Cleaning paste according to claim 1, characterized in that it optionally additionally 5.0 to 13.0 wt .-% xylene
5.0 to 15.0% by weight of a perborate activator
0 to 12.0% by weight sodium sulfate
Contains 0 to 10.0 wt% soda.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4122470A DE4122470A1 (en) | 1991-07-06 | 1991-07-06 | Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4122470A DE4122470A1 (en) | 1991-07-06 | 1991-07-06 | Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4122470A1 true DE4122470A1 (en) | 1993-01-07 |
Family
ID=6435624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE4122470A Withdrawn DE4122470A1 (en) | 1991-07-06 | 1991-07-06 | Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE4122470A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999027062A1 (en) * | 1997-11-26 | 1999-06-03 | Henkel Kommanditgesellschaft Auf Aktien | Dish washing detergent with a specific viscosity profile |
| WO2009062537A1 (en) * | 2007-11-12 | 2009-05-22 | Pastaclean Gmbh | Cleaning paste |
| WO2010125050A2 (en) * | 2009-04-28 | 2010-11-04 | Pastaclean Gmbh | Cleaning paste |
| CN108300621A (en) * | 2018-02-08 | 2018-07-20 | 深圳天和圆实业有限公司 | A kind of household cleaning cream and preparation method thereof |
| WO2019030536A1 (en) * | 2017-08-10 | 2019-02-14 | Croda International Plc | Emulsifier system, personal care product, method and use |
-
1991
- 1991-07-06 DE DE4122470A patent/DE4122470A1/en not_active Withdrawn
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999027062A1 (en) * | 1997-11-26 | 1999-06-03 | Henkel Kommanditgesellschaft Auf Aktien | Dish washing detergent with a specific viscosity profile |
| WO2009062537A1 (en) * | 2007-11-12 | 2009-05-22 | Pastaclean Gmbh | Cleaning paste |
| WO2010125050A2 (en) * | 2009-04-28 | 2010-11-04 | Pastaclean Gmbh | Cleaning paste |
| WO2010125050A3 (en) * | 2009-04-28 | 2011-01-13 | Pastaclean Gmbh | Cleaning paste |
| WO2019030536A1 (en) * | 2017-08-10 | 2019-02-14 | Croda International Plc | Emulsifier system, personal care product, method and use |
| KR20200038479A (en) * | 2017-08-10 | 2020-04-13 | 크로다 인터내셔날 피엘씨 | Emulsifier system, personal care products, methods and uses |
| CN111163746A (en) * | 2017-08-10 | 2020-05-15 | 禾大国际股份公开有限公司 | Emulsifier system, personal care product, method and use |
| JP2020529460A (en) * | 2017-08-10 | 2020-10-08 | クローダ インターナショナル パブリック リミティド カンパニー | Emulsifiers, personal care products, methods and uses |
| KR102595060B1 (en) * | 2017-08-10 | 2023-10-31 | 크로다 인터내셔날 피엘씨 | Emulsifier systems, personal care products, methods and uses |
| CN108300621A (en) * | 2018-02-08 | 2018-07-20 | 深圳天和圆实业有限公司 | A kind of household cleaning cream and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0934382B1 (en) | The use of polycationic condensation products as an additive for detergents or detergent after treatment agents in order to inhibit running of colours and to reduce colour loss | |
| DE2857292C2 (en) | ||
| DE3344099C2 (en) | Liquid, fabric softening heavy-duty detergent and process for its preparation | |
| EP0272574B1 (en) | Mixtures of liquid non-ionic surfactants | |
| DE2813198A1 (en) | BLEACHING DETERGENT AND CLEANING AGENT AND METHOD FOR ITS APPLICATION | |
| DE69630577T2 (en) | Prewash stain remover composition with surfactant based on siloxane | |
| EP0054895A1 (en) | Mixture of surfactants for the cleaning of hard surfaces | |
| JPS6024221B2 (en) | How to wash textile products | |
| DE2343636A1 (en) | SOFTENING DETERGENT | |
| DE60026333T2 (en) | COMPOSITION TO TEXTILE CARE | |
| GB2204321A (en) | Biodegradable liquid detergent | |
| JPS5943099A (en) | Detergent | |
| DE2300658C2 (en) | Softener for textiles with a simultaneous dirt-releasing and antistatic effect | |
| DE1767426A1 (en) | Detergents, washing auxiliaries and cleaning agents containing antimicrobial agents | |
| DE4122470A1 (en) | Aq. cleaning paste for hands, hard surfaces and glass - contains surfactants, copolymer, phosphate, white spirit and reducing or oxidising agent | |
| DE2225250C3 (en) | ||
| CH619265A5 (en) | Liquid clear aqueous detergent and cleaner composition. | |
| DE19529587A1 (en) | Means for cleaning protective work clothing | |
| DE1957456A1 (en) | Building agent for a cleaning agent | |
| DE60105763T2 (en) | COMPOSITION TO TEXTILE CARE | |
| DE2637595A1 (en) | LIQUID DETERGENT | |
| DE4418487C2 (en) | Process for the production of a wet cleaning agent combination according to the modular system | |
| EP0427670A1 (en) | Liquid detergent | |
| DE3638459A1 (en) | DETERGENT COMPOSITION FOR REMOVING OILY DIRT | |
| DE4032126C2 (en) | Aqueous cleaners for hard surfaces |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8130 | Withdrawal |