CN102533477B - Non-corrosive heavy oil dirt remover and preparation method thereof - Google Patents
Non-corrosive heavy oil dirt remover and preparation method thereof Download PDFInfo
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- CN102533477B CN102533477B CN2011104566999A CN201110456699A CN102533477B CN 102533477 B CN102533477 B CN 102533477B CN 2011104566999 A CN2011104566999 A CN 2011104566999A CN 201110456699 A CN201110456699 A CN 201110456699A CN 102533477 B CN102533477 B CN 102533477B
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Abstract
The invention provides a non-corrosive heavy oil dirt remover and a preparation method thereof. The remover comprises fatty alcohol-polyoxyethylene ether sodium sulfate, fatty alcohol polyoxyethylene (7) ether, alkyl polyglucoside, sodium polyacrylate, 2-methyl-2,4-pentanediol, sodium hydroxide, potassium hydroxide, sodium metasilicate, monoethanol amine, essence and deionized water. The non-corrosive heavy oil dirt remover, provided by the invention, has the advantages of strong oil dirt removing capacity, environmental friendliness, and free corrosion about materials of metal, plastic, glass and the like in use.
Description
Technical field
The present invention relates to chemical field, particularly a kind of free from corrosion heavy oil stain remover and preparation method thereof.This free from corrosion heavy oil stain remover soil removability is strong, can effectively remove grease, and to nothing corrosion such as kitchen tools.
Background technology
At present, people clean kitchen range with the greasy dirt remover usually.And commercially available lampblack absorber and the kitchen range top are of a great variety, and the surfacing of lampblack absorber and the kitchen range top is complicated, the material that uses at present has stainless steel, baking vanish, toughened glass, synthetic glass, polymeric coating layer etc., and metal ingredient has Fe, Cr, Ni, Mn, Mo etc. in these materials.The sanitising agent of commonly using in the market generally focuses on the sanitising agent of the cleaning power of grease being selected alkaline system, and people use the phenomenon that kitchen tools surface discolouration or corrosion occur often.Therefore need to provide a kind of can effectively remove greasy dirt, can not cause to kitchen tools again the grease remover of corrosion.
Summary of the invention
The object of the present invention is to provide a kind of nothing corrosion heavy oil stain remover that can effectively remove grease.This utilizes mineral alkali and the organic bases that slow-release capability is arranged without corrosion heavy oil stain remover, and with the surfactant compound of strong soil removability, various raw materials synergies reach the strong and free from corrosion purpose of cleaning power again.
Another object of the present invention is to provide a kind of preparation method of free from corrosion heavy oil stain remover.
The objective of the invention is to be realized by following technical proposals:
A kind of free from corrosion heavy oil stain remover, contain polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 in the raw material of this remover, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine, essence, deionized water; The ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1 ~ 2
Aliphatic alcohol polyethenoxy (7) ether 5 ~ 7
Alkyl glycoside 1 ~ 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3 ~ 5
Sodium hydroxide 0.05～1.0
Potassium hydroxide 0.1～1.0
Starso 0.5～1.0
Monoethanolamine 1.5～2.5
Essence 0.1 ~ 0.4
Deionized water 77.5～87.15.
Another object of the present invention is achieved through the following technical solutions:
This preparation method's preparation process is as follows:
(1) 30 ~ 40% of described deionized water total amount is placed the material still, then add polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 according to said ratio while stirring, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine obtain mixed solution A to fully dissolving; This mixed solution A is formulated in the material still, need to stir successively when adding described each raw material;
(2) in mixed solution A, add essence, residue deionized water, stir, obtain mixing solutions B;
(3) mixing solutions B is carried out filtration treatment, can obtain described free from corrosion heavy oil stain remover.
The invention has the beneficial effects as follows:
1, feedstock fat polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether selected of the present invention all has good emulsification, soil removability, can peel off rapidly old grease with the strong alkyl glycoside of perviousness is composite, makes old grease be easy to remove; Raw material 2-methyl-2,4-pentanediol safety and environmental protection has good solubilising, soil removability, is beneficial to the greasy dirt dissolving, peels off; The raw material sodium polyacrylate has good chelating, dispersive ability; Feed hydrogen sodium oxide, potassium hydroxide can well dissolve and wipe oil, can make remover system slowly-releasing OH with monoethanolamine is composite
-, improve detersive power, reduce corrodibility; Starso is inhibiter, can reduce the remover system to the corrosion of kitchen tools surfacing, reaches free from corrosion purpose; Each raw material synergy both provided efficient greasy dirt cleaning power, reached simultaneously to the kitchen tools surface without corrosive effect.
2, the detersive power of free from corrosion heavy oil stain remover of the present invention is stronger, can rapid permeability, the emulsification greasy dirt, and outmoded greasy dirt is broken away from fast, be easy to remove.
3, free from corrosion heavy oil stain remover of the present invention adopts the Environmental Safety raw material, and is nontoxic, can be used for kitchen tackle.
4, with reference to the general water-base metal detergent of QB/T2117-1995, the mensuration of middle metal protection, free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment
The invention will be further described below in conjunction with embodiment.
Embodiment 1:
A kind of free from corrosion heavy oil stain remover, contain polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 in the raw material of this remover, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine, essence, deionized water; The ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1 ~ 2
Aliphatic alcohol polyethenoxy (7) ether 5 ~ 7
Alkyl glycoside 1 ~ 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3 ~ 5
Sodium hydroxide 0.05～1.0
Potassium hydroxide 0.1～1.0
Starso 0.5～1.0
Monoethanolamine 1.5～2.5
Essence 0.1 ~ 0.4
Deionized water 77.5～87.15.
The used weight unit of present embodiment is kilogram, also can be gram;
Essence described in the present embodiment is food grade essence, and all the other each raw materials are technical grade;
Each raw material described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each raw material in the described free from corrosion heavy oil stain remover can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Feedstock fat polyoxyethylenated alcohol sodium sulfate in the present embodiment, aliphatic alcohol polyethenoxy (7) ether all have good emulsification, soil removability, can peel off rapidly old grease with the strong alkyl glycoside of perviousness is composite, make old grease be easy to remove; Raw material 2-methyl-2,4-pentanediol safety and environmental protection has good solubilising, soil removability, is beneficial to the greasy dirt dissolving, peels off; Sodium polyacrylate has good chelating, dispersive ability; Feed hydrogen sodium oxide, potassium hydroxide can well dissolve and wipe oil, can make remover system slowly-releasing OH with monoethanolamine is composite
-, improve detersive power, reduce corrodibility; Starso is inhibiter, reduces the remover system to the corrosion of kitchen tools surfacing, reaches free from corrosion effect.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
The preparation method of described a kind of free from corrosion heavy oil stain remover, its preparation process is as follows:
(1) 30 ~ 40% of described deionized water total amount is placed the material still, then add polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 according to said ratio while stirring, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine obtain mixed solution A to fully dissolving; This mixed solution A is formulated in the material still, need to stir successively when adding described each raw material;
(2) in mixed solution A, add essence, residue deionized water, stir, obtain mixing solutions B;
(3) mixing solutions B is filtered with 200 order filtering nets, can obtain described free from corrosion heavy oil stain remover.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.5
Aliphatic alcohol polyethenoxy (7) ether 5
Alkyl glycoside 1
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 5
Sodium hydroxide 0.5
Potassium hydroxide 0.1
Starso 0.5
Monoethanolamine 2.0
Essence 0.1
Deionized water 83.7.
The heavy oil stain remover product that will meet industry standard is packed, vanning after the product outer packaging detects.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1
Aliphatic alcohol polyethenoxy (7) ether 7
Alkyl glycoside 1.5
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4
Sodium hydroxide 0.05
Potassium hydroxide 1
Starso 0.6
Monoethanolamine 1.5
Essence 0.2
Deionized water 82.55.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 2
Aliphatic alcohol polyethenoxy (7) ether 7
Alkyl glycoside 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3
Sodium hydroxide 0.05
Potassium hydroxide 1
Starso 0.8
Monoethanolamine 1.5
Essence 0.2
Deionized water 81.85.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.5
Aliphatic alcohol polyethenoxy (7) ether 6
Alkyl glycoside 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4.5
Sodium hydroxide 0.5
Potassium hydroxide 0.1
Starso 1.0
Monoethanolamine 1.8
Essence 0.3
Deionized water 81.7.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.8
Aliphatic alcohol polyethenoxy (7) ether 5.5
Alkyl glycoside 1.5
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4.5
Sodium hydroxide 1
Potassium hydroxide 0.1
Starso 0.8
Monoethanolamine 2.5
Essence 0.4
Deionized water 81.3.
The used weight unit of present embodiment is kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
With reference to the measuring method of metal protection among the QB/T2117-1995 " general water-base metal detergent ", free from corrosion heavy oil stain remover of the present invention to materials such as metal, plastics, glass without corrosion.
Embodiment 7:
Present embodiment is the preparation method of free from corrosion heavy oil stain remover.
A kind of preparation method of free from corrosion heavy oil stain remover, contain polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 in the raw material of this remover, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine, essence, deionized water; The ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1 ~ 2
Aliphatic alcohol polyethenoxy (7) ether 5 ~ 7
Alkyl glycoside 1 ~ 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3 ~ 5
Sodium hydroxide 0.05～1.0
Potassium hydroxide 0.1～1.0
Starso 0.5～1.0
Monoethanolamine 1.5～2.5
Essence 0.1 ~ 0.4
Deionized water 77.5～87.15
This preparation method's preparation process is as follows:
(1) 30 ~ 40% of described deionized water total amount is placed the material still, then add polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 according to said ratio while stirring, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine obtain mixed solution A to fully dissolving; This mixed solution A is formulated in the material still, need to stir successively when adding described each raw material;
(2) in mixed solution A, add essence, residue deionized water, stir, obtain mixing solutions B;
(3) mixing solutions B is carried out filtration treatment, can obtain described free from corrosion heavy oil stain remover, the equipment that adopts is 200 order filtering nets.
In above-mentioned process for preparation, should note whole clean operation environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can buy in market to obtain.
Claims (7)
1. free from corrosion heavy oil stain remover, it is characterized in that: the raw material of this remover is by polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2, and 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine, essence, deionized water form; The ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1 ~ 2
Aliphatic alcohol polyethenoxy (7) ether 5 ~ 7
Alkyl glycoside 1 ~ 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3 ~ 5
Sodium hydroxide 0.05～1.0
Potassium hydroxide 0.1～1.0
Starso 0.5～1.0
Monoethanolamine 1.5～2.5
Essence 0.1 ~ 0.4
Deionized water 77.5～87.15.
2. free from corrosion heavy oil stain remover according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.5
Aliphatic alcohol polyethenoxy (7) ether 5
Alkyl glycoside 1
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 5
Sodium hydroxide 0.5
Potassium hydroxide 0.1
Starso 0.5
Monoethanolamine 2.0
Essence 0.1
Deionized water 83.7.
3. free from corrosion heavy oil stain remover according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1
Aliphatic alcohol polyethenoxy (7) ether 7
Alkyl glycoside 1.5
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4
Sodium hydroxide 0.05
Potassium hydroxide 1
Starso 0.6
Monoethanolamine 1.5
Essence 0.2
Deionized water 82.55.
4. free from corrosion heavy oil stain remover according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 2
Aliphatic alcohol polyethenoxy (7) ether 7
Alkyl glycoside 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3
Sodium hydroxide 0.05
Potassium hydroxide 1
Starso 0.8
Monoethanolamine 1.5
Essence 0.2
Deionized water 81.85.
5. free from corrosion heavy oil stain remover according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.5
Aliphatic alcohol polyethenoxy (7) ether 6
Alkyl glycoside 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4.5
Sodium hydroxide 0.5
Potassium hydroxide 0.1
Starso 1.0
Monoethanolamine 1.8
Essence 0.3
Deionized water 81.7.
6. free from corrosion heavy oil stain remover according to claim 1, it is characterized in that: the ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1.8
Aliphatic alcohol polyethenoxy (7) ether 5.5
Alkyl glycoside 1.5
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 4.5
Sodium hydroxide 1
Potassium hydroxide 0.1
Starso 0.8
Monoethanolamine 2.5
Essence 0.4
Deionized water 81.3.
7. the preparation method of a free from corrosion heavy oil stain remover, it is characterized in that: contain polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 in the raw material of this remover, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine, essence, deionized water; The ratio of weight and number of each raw material of this remover is:
Polyoxyethylenated alcohol sodium sulfate 1 ~ 2
Aliphatic alcohol polyethenoxy (7) ether 5 ~ 7
Alkyl glycoside 1 ~ 2
Sodium polyacrylate 0.6
2-methyl-2,4-pentanediol 3 ~ 5
Sodium hydroxide 0.05～1.0
Potassium hydroxide 0.1～1.0
Starso 0.5～1.0
Monoethanolamine 1.5～2.5
Essence 0.1 ~ 0.4
Deionized water 77.5～87.15
This preparation method's preparation process is as follows:
(1) 30 ~ 40% of described deionized water total amount is placed the material still, then add polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (7) ether, alkyl glycoside, sodium polyacrylate, 2-methyl-2 according to said ratio while stirring, 4-pentanediol, sodium hydroxide, potassium hydroxide, Starso, monoethanolamine obtain mixed solution A to fully dissolving;
(2) in mixed solution A, add essence, residue deionized water, stir, obtain mixing solutions B;
(3) mixing solutions B is carried out filtration treatment, can obtain described free from corrosion heavy oil stain remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2011104566999A CN102533477B (en) | 2011-12-31 | 2011-12-31 | Non-corrosive heavy oil dirt remover and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104566999A CN102533477B (en) | 2011-12-31 | 2011-12-31 | Non-corrosive heavy oil dirt remover and preparation method thereof |
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| CN102533477A CN102533477A (en) | 2012-07-04 |
| CN102533477B true CN102533477B (en) | 2013-03-13 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074174A (en) * | 2012-12-29 | 2013-05-01 | 江苏飞拓界面工程科技有限公司 | Cleaning agent for heavy oil dirt |
| CN103060115A (en) * | 2013-01-07 | 2013-04-24 | 北京洛娃日化有限公司 | Heavy oil dirt cleaning gel |
| CN104048343A (en) * | 2014-07-02 | 2014-09-17 | 上海美力源环保科技有限公司 | Kitchen oil fume purification method and device |
| CN104048342B (en) * | 2014-07-02 | 2017-02-01 | 上海美力源环保科技有限公司 | Kitchen oil fume purification method and device |
| CN104048341A (en) * | 2014-07-02 | 2014-09-17 | 上海美力源环保科技有限公司 | Kitchen oil fume purification method and device |
| DE102015120614A1 (en) * | 2015-11-27 | 2017-06-01 | Bubbles & Beyond Gmbh | Cleaning composition and its use as a glass cleaner, screen cleaner and plastic surface cleaner |
| CN106635492A (en) * | 2016-12-05 | 2017-05-10 | 天津天狮生物发展有限公司 | Range hood cleaning agent and preparation method thereof |
| CN109206867A (en) * | 2018-08-28 | 2019-01-15 | 孙世华 | A kind of preparation method of stain resistant plastic package material |
| CN111411362B (en) * | 2020-06-02 | 2022-03-25 | 蓝思科技（长沙）有限公司 | Chemical nickel removing agent and method for iron matrix |
| CN111690471B (en) * | 2020-07-08 | 2022-01-11 | 中山榄菊日化实业有限公司 | High-concentration laundry detergent without gel and precipitation and preparation method thereof |
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| CN101220321A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Nontoxic carpet cleanser without water washing and special cleaning machine, and method for producing the same |
| CN101818105A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Washing agent with stain removal and softening functions and preparation method thereof |
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| CN101220321A (en) * | 2007-12-17 | 2008-07-16 | 北京绿伞化学有限公司 | Nontoxic carpet cleanser without water washing and special cleaning machine, and method for producing the same |
| CN101818105A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Washing agent with stain removal and softening functions and preparation method thereof |
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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co.,Ltd. Address before: Beijing green umbrella Chemical Co., Ltd., No. 3, Yongjie North Road, Yongfeng Industrial base, Haidian District, Beijing 100094 Patentee before: Beijing Lvsan Chemistry Co.,Ltd. |
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Effective date of registration: 20221206 Address after: No. 48, Pingwang Street, Xinggu Development Zone, Pinggu District, Beijing 101211 Patentee after: Beijing Xinggu Lvsan Technology Co.,Ltd. Address before: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee before: Beijing green umbrella Technology Co.,Ltd. |