CN105671583B - A kind of metal product cleaning agent - Google Patents
A kind of metal product cleaning agent Download PDFInfo
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- CN105671583B CN105671583B CN201610213083.1A CN201610213083A CN105671583B CN 105671583 B CN105671583 B CN 105671583B CN 201610213083 A CN201610213083 A CN 201610213083A CN 105671583 B CN105671583 B CN 105671583B
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- acid
- polyoxyethylene ether
- cleaning
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/06—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using emulsions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/024—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses a kind of metal product cleaning agents, including following component: ultralow interfacial tension surfactant, lactic acid, emulsifier, acidic cleaner, acid restrainer, bleeding agent, cocoanut fatty acid diethanolamide, isothiazolinone, tea oil tea seed powder, organic solvent and D-sorbite.The present invention provides a kind of mild acid wash agent, and the cleaning agent cleaning effect is good, still, can easily remove the blocked up greasy dirt such as animal oil, mineral oil, heavy engine oil, butter on metal surface, the workpiece after cleaning will form continuous moisture film；Without phosphorus, pollution-free, noresidue can satisfy environmentally friendly three wastes requirement discharge；Dissolubility is strong, and long-term place is not in layering and sediment, the high metal product cleaning agent of stability.
Description
Technical field
The present invention relates to a kind of cleaning agents, specifically, the present invention relates to a kind of metal product cleaning agents.
Background technique
The cleaning of the mechanized equipment indispensable work that is the component during being processed, being assembled, stored and repaired etc.
Skill link.The dirt for being attached to mechanical surface has various acid, alkali, salt, dust, cutting, hand perspiration, greasy dirt etc., these dirts are deposited
It can cause and accelerate metal erosion, reduce product quality, shorten the working life.In cleaning industry, it is desirable that practitioner exists
When selecting cleaning agent, cleaning ability is not only considered, it is also contemplated that Safety and Environmental Protection, reduces the pollution to environment as far as possible, prevent
The health of cleaning agent damage operator.Currently, still largely using strong basicity cleaning agent, organic solvent (petroleum in industrial production
Solvent, halogenated hydrocarbon solvent etc.) it is cleaned.Strong basicity cleaning agent main component is NaOH, Na2CO3、Na2SiO3、Na3PO4、
STPP etc., cleaning ability is poor, and part easily gets rusty after cleaning, commonly used in cleaning the slight greasy dirt of ferrous metal surface and inorganic
The dirts such as salt.Although solvent cleaner has very strong cleaning ability, it is easy to clean the dirt of metal surface, but most of easy
Combustion, it is volatile, mass energy is wasted, environmental pollution is caused, and have stronger irritation to the nervous centralis of human body, connects for a long time
Touching can cause the diseases such as neurasthenia, chapped skin.Aqueous cleaning agent based on surfactant can generate a large amount of foams,
Not easy-clear is unfavorable for subsequent operation.
Summary of the invention
The object of the present invention is to provide a kind of mild acid wash agent, and the cleaning agent cleaning effect is good, still, can easily will be golden
The blocked up greasy dirt such as animal oil, mineral oil, heavy engine oil, butter on metal surface removes, and the workpiece after cleaning will form continuous moisture film；
Without phosphorus, pollution-free, noresidue can satisfy environmentally friendly three wastes requirement discharge；Dissolubility is strong, and long-term place is not in be layered and sink
Starch, the high metal product cleaning agent of stability.
The technical solution adopted by the present invention be a kind of metal product cleaning agent, the component including following parts by weight:
Ultralow interfacial tension surfactant: 5~15 parts；Lactic acid: 0.2~2 part；
Emulsifier: 2~15 parts；Acidic cleaner: 7~25 parts；
Acid restrainer: 2~15 parts；Bleeding agent: 2~12 parts；
Cocoanut fatty acid diethanolamide: 3~8 parts；Isothiazolinone: 0.1~2 part；
Tea oil tea seed powder: 2~5 parts；Organic solvent: 5~30 parts；D-sorbite: 2~6 parts.
Preferably, the ultralow interfacial tension surfactant is carboxy betaine type amphoteric surfactant, HLB
Value is 12~14.
Preferably, the emulsifier component is fatty alcohol alkyl oxide, castor oil polyoxyethylene ether, succinic acid derive
One or more of object, ether carboxylic acid, fatty alcohol polyoxyethylene ether and monoethanolamine, diethanol amine, triethanolamine, diisopropanol
The mixture of one or more of amine, special hydramine.
Preferably, the bleeding agent ingredient is fatty alcohol polyoxyethylene ether, benzyl alcohol fatty alcohol polyoxyethylene ether, polyoxy
One or more of vinethene, isomery undecyl alcohol polyoxyethylene ether, alkyl polymer or block polyether.
Preferably, the acidic cleaner is Loprazolam or ethane sulfonic acid.
Preferably, the acid restrainer is imidazoline sebacic acid salt or imidazoline oleate.
Preferably, the organic solvent is D- limonene or propylene glycol.
The present invention is include at least the following beneficial effects:
(1) present invention uses the ultralow interfacial tension surfactant for main component, by matching with bleeding agent, emulsifier
It closes, can effectively improve the contact surface of cleaning agent and dirt, preferably dissolve dirt, it, can by the way that acidic cleaner is added
It, both can be with by the way that acid restrainer is added with rust staining, greasy dirt for effectively removing surface of metal product etc. relatively for the difficult dirt gone
Improve dirt-removing power of the cleaning agent under acidic environment, moreover it is possible to significantly improve to corrosion of metal inhibiting effect；
(2) present invention uses tea oil tea seed powder, has good emulsification, decomposes, frothing function, can degrease rapidly,
D-sorbite, which is added, can be enhanced the osmotic efficiency of cocoanut fatty acid diethanolamide, and isothiazole is added in the two synergistic effect
Quinoline ketone can keep chemical balance, reduce surface tension, prevent light, thermal decomposition or oxygenolysis.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technical effect can fully understand and implement.
Unless otherwise specified, the conventional hand that technological means employed in embodiment is well known to those skilled in the art
Section, used raw material is also available commercial.The various processes and method being not described in detail are as known in the art
Conventional method.
A kind of metal product cleaning agent, the component including following parts by weight:
Ultralow interfacial tension surfactant: 5~15 parts；Lactic acid: 0.2~2 part；
Emulsifier: 2~15 parts；Acidic cleaner: 7~25 parts；
Acid restrainer: 2~15 parts；Bleeding agent: 2~12 parts；
Cocoanut fatty acid diethanolamide: 3~8 parts；Isothiazolinone: 0.1~2 part；
Tea oil tea seed powder: 2~5 parts；Organic solvent: 5~30 parts；D-sorbite: 2~6 parts.
As a further improvement of that present invention, the ultralow interfacial tension surfactant is carboxy betaine type amphoteric surface
Activating agent, HLB value are 12~14, mainly improve the contact surface of dirt and cleaning agent, preferably dissolution dirt.
As a further improvement of that present invention, the emulsifier component is fatty alcohol alkyl oxide, castor oil polyoxyethylene
One or more of ether, succinic acid derivative, ether carboxylic acid, fatty alcohol polyoxyethylene ether and monoethanolamine, diethanol amine, three second
The mixture of one or more of hydramine, diisopropanolamine (DIPA), special hydramine, emulsifier have extremely strong affine with metal surface
Power forms one layer of only very thin fine and close protective film, effectively excludes metal surface so as to penetrate into inside metal pore
And moisture content and moisture inside pore.
As a further improvement of that present invention, the bleeding agent ingredient is fatty alcohol polyoxyethylene ether, benzyl alcohol poly alkyl alcohol
One or more of ethylene oxide ether, polyoxyethylene ether, isomery undecyl alcohol polyoxyethylene ether, alkyl polymer or block polyether.
As a further improvement of that present invention, the acidic cleaner is Loprazolam or ethane sulfonic acid, can effectively be removed
Iron rust, greasy dirt etc. are relatively the difficult dirt removed.
As a further improvement of that present invention, the acid restrainer be imidazoline sebacic acid salt or imidazoline oleate, can
To significantly improve under acidic environment to corrosion of metal inhibiting effect.
As a further improvement of that present invention, the organic solvent is D- limonene or propylene glycol, is had good molten
Xie Xing effectively dissolves a variety of surfactants and corrosion inhibiter, and furthermore itself also has good ability of cleaning greasy dirt, can remove
A variety of greasy dirts and iron rust.
Table 1 lists the concrete component and its content of different embodiment and comparative examples.
1 Examples 1 to 3 of table and the specific component of comparative example 1~4
Table 2 lists the test result of Examples 1 to 3 and comparative example 1~4.
The test result of table 2 Examples 1 to 3 and comparative example 1~4
Note: antirust time mensuration mode immerses the 45# steel disc closing of 4cm*4cm in the cleaning agent of embodiment and comparative example
10S, taking-up hang on interior, observe steel disc antirust time, rusty stain occur on steel disc, be denoted as end time.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (1)
1. a kind of metal product cleaning agent, which is characterized in that the component including following parts by weight:
Ultralow interfacial tension surfactant: 5~15 parts；Lactic acid: 0.2~2 part；
Emulsifier: 2~15 parts；Acidic cleaner: 7~25 parts；
Acid restrainer: 2~15 parts；Bleeding agent: 2~12 parts；
Cocoanut fatty acid diethanolamide: 3~8 parts；Isothiazolinone: 0.1~2 part；
Tea oil tea seed powder: 2~5 parts；Organic solvent: 5~30 parts；D-sorbite: 2~6 parts；
The ultralow interfacial tension surfactant is person's carboxy betaine type amphoteric surfactant, and HLB value is 12~14；
The emulsifier component is fatty alcohol alkyl oxide, castor oil polyoxyethylene ether, succinic acid derivative, ether carboxylic acid, rouge
One or more of fat alcohol polyoxyethylene ether and one of monoethanolamine, diethanol amine, triethanolamine, diisopropanolamine (DIPA) or
Several mixtures；
The bleeding agent ingredient is fatty alcohol polyoxyethylene ether, benzyl alcohol fatty alcohol polyoxyethylene ether, polyoxyethylene ether, isomery ten
One or more of one alcohol polyoxyethylene ether, alkyl polymer or block polyether；
The acidic cleaner is Loprazolam or ethane sulfonic acid；
The acid restrainer is imidazoline sebacic acid salt or imidazoline oleate；
The organic solvent is D- limonene or propylene glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610213083.1A CN105671583B (en) | 2016-04-07 | 2016-04-07 | A kind of metal product cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610213083.1A CN105671583B (en) | 2016-04-07 | 2016-04-07 | A kind of metal product cleaning agent |
Publications (2)
| Publication Number | Publication Date |
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| CN105671583A CN105671583A (en) | 2016-06-15 |
| CN105671583B true CN105671583B (en) | 2019-02-22 |
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| CN201610213083.1A Active CN105671583B (en) | 2016-04-07 | 2016-04-07 | A kind of metal product cleaning agent |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106191898A (en) * | 2016-08-11 | 2016-12-07 | 黄平县力星清洗剂生产有限公司 | A kind of abluent for cleaning dyeing apparatus surface smut |
| CN107326372B (en) * | 2017-06-17 | 2019-12-03 | 苏州元联科技创业园管理有限公司 | A kind of preparation method of wax removing agent |
| CN110157235A (en) * | 2019-06-13 | 2019-08-23 | 南京信息工程大学 | Environment-friendly type micro emulsion printing ink washing agent and preparation method |
| CN110512218A (en) * | 2019-08-07 | 2019-11-29 | 叶贵永 | A kind of preparation method of castor oil-base alkalinous metal degreaser |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7923425B2 (en) * | 2006-08-21 | 2011-04-12 | Henkel Ag & Co. Kgaa | Low-foaming, acidic low-temperature cleaner and process for cleaning surfaces |
| JP5969344B2 (en) * | 2012-09-27 | 2016-08-17 | トヨタ自動車株式会社 | Oil composition |
| CN103215611B (en) * | 2013-03-27 | 2016-06-22 | 沈阳帕卡濑精有限总公司 | A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals |
| CN104629924B (en) * | 2015-01-19 | 2017-11-14 | 桃江县慧辉生物科技有限公司 | A kind of pure natural stain removal bactericidal cleaning powder |
| CN104830548A (en) * | 2015-05-13 | 2015-08-12 | 吴江市震宇缝制设备有限公司 | Oil stain detergent for sewing machine overhauling |
| CN105132928B (en) * | 2015-09-08 | 2018-10-12 | 中国石油化工股份有限公司 | A kind of metal cleaner and its application |
| CN105088260A (en) * | 2015-09-12 | 2015-11-25 | 杭州萧山金润表面活性材料厂 | Deoiling cleaning agent for metal surface |
| CN105368595A (en) * | 2015-12-13 | 2016-03-02 | 青岛拓联信息技术有限公司 | Highly effective oil remover |
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Effective date of registration: 20230414 Address after: 1st Floor, Building 15, No. 588 Dongxi Road, Dongjing Town, Songjiang District, Shanghai, 200000 Patentee after: Shanghai Xipa Environmental Protection Technology Co.,Ltd. Address before: 215223 Tongxin Road 8, Hengfan Town Development Zone, Wujiang District, Suzhou, Jiangsu Patentee before: WUJIANG ZHENYU SEWING EQUIPMENT Co.,Ltd. |
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