CN102400163A - Cleaning agent for stainless steel hot-rolled member and preparation method thereof - Google Patents
Cleaning agent for stainless steel hot-rolled member and preparation method thereof Download PDFInfo
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- CN102400163A CN102400163A CN2011103826414A CN201110382641A CN102400163A CN 102400163 A CN102400163 A CN 102400163A CN 2011103826414 A CN2011103826414 A CN 2011103826414A CN 201110382641 A CN201110382641 A CN 201110382641A CN 102400163 A CN102400163 A CN 102400163A
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Abstract
The invention relates to the technical field of chemical cleaning, in particular to a cleaning agent applicable to a stainless steel hot-rolled member and a preparation method thereof. The cleaning agent for the stainless steel hot-rolled member is prepared by mixing the following raw materials in percentage by weight at a normal temperature: 36.8%-68.4% of water, 3.5%-7% of citric acid, 10%-20% of fatty alcohol polyoxyethylene ether, 5%-10% of tartaric acid, 5%-10% of triethanolamine, 0.1%-0.2% of sodium molybdate, 1.5%-3% of hydrochloric acid, 1%-2% of hydrofluoric acid, 5%-10% of oxalic acid and the balance of alkylphenol polyoxyethylene. The cleaning agent for the stainless steel hot-rolled member is simple and convenient in operation, novel in process, strong in cleaning capability and harmless in skin contact; the personal safety of an operator is effectively guaranteed; the warming is not needed; the cleaning effect is good; synchronously, the surface of stainless steel is not corroded; the glossiness of the stainless steel is maintained; furthermore, the cleaning agent for the stainless steel hot-rolled member can be used repeatedly and is low-carbon and environment-friendly; and the cost is saved.
Description
Technical field
The present invention relates to the chemical cleaning technique field, especially a kind of clean-out system that is applicable to the stainless steel hot rolled piece and preparation method thereof.
Background technology
At present, the stainless steel hot rolled piece is difficult to clean, and begins from making first procedure such as hollow billet, just need clean it, heats to 65 ℃ after nitric acid, hydrofluoric acid and water were mixed in 6: 3: 11 by weight percentage, and the workpiece that needs are handled is immersed in the clean-out system.For the stainless steel hot rolled piece of handling about 2 tons, the clean-out system treatment time that has just prepared is 1.5 hours, after use for some time; Treatment time then need extend to 6 hours, and the clean-out system of this moment must discharge fully, and this strong acid clean-out system also can corrode the surface of stainless steel hot rolled piece; Because nitric acid and hydrofluoric acid are through heating the generation acid mist; Human body there is great harm, and the severe contamination air, the discharging of waste acid water is the severe contamination water resources also.
Summary of the invention
The technical problem that the present invention will solve is: overcome the deficiency in the prior art, a kind of sinter that can clean stainless steel hot rolled piece erode metallic surfaces not again is provided, stainless steel hot rolled piece clean-out system harmless and free from environmental pollution and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of stainless steel hot rolled piece clean-out system is mixed and made into by following raw materials by weight percent:
Preferred stainless steel hot rolled piece clean-out system is a stainless steel hot rolled piece cleaning liquid, and described stainless steel hot rolled piece cleaning liquid is mixed and made into by following raw materials by weight percent:
After stainless steel hot rolled piece cleaning liquid used for some time, cleaning performance was not obvious, needed to add the stainless steel hot rolled piece this moment and cleaned annex solution, and described stainless steel hot rolled piece cleans annex solution and is mixed and made into by following raw materials by weight percent:
The preparation method of stainless steel hot rolled piece clean-out system of the present invention has following steps:
(1), under the normal temperature, in stirrer, adding weight percent is the water of 36.8%-68.4%;
(2), throw in the Hydrocerol A that weight percent is 3.5%-7% while stirring;
(3), throw in the AEO that weight percent is 10%-20% while stirring;
(4), throw in the tartrate that weight percent is 5%-10% while stirring;
(5), throw in the trolamine that weight percent is 5%-10% while stirring;
(6), throw in the Sodium orthomolybdate that weight percent is 0.1%-0.2% while stirring;
(7), throw in the hydrochloric acid that weight percent is 1.5%-3% while stirring;
(8), throw in the hydrofluoric acid that weight percent is 1%-2% while stirring;
(9), throwing in weight percent while stirring is 5%-10% oxalic acid;
(10), throw in the TX10 that weight percent is a surplus while stirring;
(11), all reinforced back restir that finishes was finished product in 20-30 minute.
Principle of work of the present invention is: TX10 has played fat abstraction, removes the grease on stainless steel hot rolled piece surface; Hydrocerol A can prolong the work-ing life of stainless steel hot rolled piece clean-out system, uses repeatedly, also can play the effect that hides flavor; The work-ing life that oxalic acid can prolong stainless steel hot rolled piece clean-out system again can the deposited iron ion; AEO can be attached to the obstinate oxide debris on stainless steel hot rolled piece surface, sinter, dirt, paraffin, heavy oil and heavy bull pine such as rust; Add that hydrochloric acid, hydrofluoric acid, Hydrocerol A, oxalic acid, this five acid of tartrate mix, make the bad thing on stainless steel hot rolled piece surface come off fast; Sodium orthomolybdate and trolamine are in the stainless steel hot rolled piece surface adsorption that cleans up and generate one deck passive film.
The invention has the beneficial effects as follows: the present invention is easy and simple to handle, and technology is novel, and cleaning force is strong; Skin exposure does not have injury, has ensured operator's personnel safety effectively, need not to heat; Cleaning performance is good, does not corrode stainless surface simultaneously, keeps stainless glossiness; And stainless steel hot rolled piece clean-out system can be reused low-carbon environment-friendly, saving cost.
Embodiment
In conjunction with the preferred embodiments the present invention is further described now, AEO is the JFC permeate agent among the embodiment, and TX10 is emulsifying agent 0P-10.
Embodiment 1
A kind of preparation method of stainless steel hot rolled piece clean-out system has following steps: under (1), the normal temperature, in stirrer, add 684 kilograms water; (2), throwing in content while stirring is 35 kilograms of 99.3% Hydrocerol As; (3), throw in 100 kilograms of JFC permeate agents while stirring; (4), throw in 50 kilograms in tartrate while stirring; (5), throwing in content while stirring is 50 kilograms of 85% trolamines; (6), throwing in content while stirring is 1 kilogram of 99% Sodium orthomolybdate; (7), throwing in content while stirring is 15 kilograms of 31% hydrochloric acid; (8), throwing in content while stirring is 10 kilograms in 90% hydrofluoric acid; (9), throwing in content while stirring is 50 kilograms of 0.5% oxalic acid; (10), throw in 5 kilograms of emulsifier op-10s while stirring; (11), all reinforced back restir that finishes was finished product in 20-30 minute.
Embodiment 2
A kind of preparation method of stainless steel hot rolled piece clean-out system has following steps: under (1), the normal temperature, in stirrer, add 521.5 kilograms water; (2), throwing in content while stirring is 50 kilograms of 99.3% Hydrocerol As; (3), throw in 150 kilograms of JFC permeate agents while stirring; (4), throw in 75 kilograms in tartrate while stirring; (5), throwing in content while stirring is 85 kilograms of 85% trolamines; (6), throwing in content while stirring is 1.5 kilograms of 99% Sodium orthomolybdates; (7), throwing in content while stirring is 20 kilograms of 31% hydrochloric acid; (8), throwing in content while stirring is 15 kilograms in 90% hydrofluoric acid; (9), throwing in content while stirring is 75 kilograms of 0.5% oxalic acid; (10), throw in 7 kilograms of emulsifier op-10s while stirring; (11), all reinforced back restir that finishes was finished product in 20-30 minute.
Embodiment 3
A kind of preparation method of stainless steel hot rolled piece clean-out system has following steps: under (1), the normal temperature, in stirrer, add 431 kilograms water; (2), throwing in content while stirring is 60 kilograms of 99.3% Hydrocerol As; (3), throw in 180 kilograms of JFC permeate agents while stirring; (4), throw in 90 kilograms in tartrate while stirring; (5), throwing in content while stirring is 90 kilograms of 85% trolamines; (6), throwing in content while stirring is 2 kilograms of 99% Sodium orthomolybdates; (7), throwing in content while stirring is 25 kilograms of 31% hydrochloric acid; (8), throwing in content while stirring is 18 kilograms in 90% hydrofluoric acid; (9), throwing in content while stirring is 95 kilograms of 0.5% oxalic acid; (10), throw in 9 kilograms of emulsifier op-10s while stirring; (11), all reinforced back restir that finishes was finished product in 20-30 minute.
Embodiment 4
A kind of preparation method of stainless steel hot rolled piece clean-out system has following steps: under (1), the normal temperature, in stirrer, add 368 kilograms water; (2), throwing in content while stirring is 70 kilograms of 99.3% Hydrocerol As; (3), throw in 200 kilograms of JFC permeate agents while stirring; (4), throw in 100 kilograms in tartrate while stirring; (5), throwing in content while stirring is 100 kilograms of 85% trolamines; (6), throwing in content while stirring is 2 kilograms of 99% Sodium orthomolybdates; (7), throwing in content while stirring is 30 kilograms of 31% hydrochloric acid; (8), throwing in content while stirring is 20 kilograms in 90% hydrofluoric acid; (9), throwing in content while stirring is 100 kilograms of 0.5% oxalic acid; (10), throw in 10 kilograms of emulsifier op-10s while stirring; (11), all reinforced back restir that finishes was finished product in 20-30 minute.
The finished product that embodiment 1 obtains is a stainless steel hot rolled piece cleaning liquid, and the finished product that embodiment 4 obtains cleans annex solution for the stainless steel hot rolled piece.During use, stainless steel hot rolled piece cleaning liquid is poured in the clean groove, soaked the workpiece of required processing, need not to heat; Rinse well with High Pressure Gun after totally going out groove when workpiece soaks, dry or oven drying at low temperature gets final product.After stainless steel hot rolled piece cleaning liquid uses for some time, must add the stainless steel hot rolled piece and clean annex solution.
The foregoing description only is explanation technical conceive of the present invention and characteristics; Its purpose is to let the personage that is familiar with this technology can understand content of the present invention and implements; Can not limit protection scope of the present invention with this; All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed in protection scope of the present invention.
Claims (4)
1. stainless steel hot rolled piece clean-out system, it is characterized in that: described stainless steel hot rolled piece clean-out system is mixed and made into by following raw materials by weight percent:
2. stainless steel hot rolled piece clean-out system according to claim 1 is characterized in that: described stainless steel hot rolled piece clean-out system is mixed and made into by following raw materials by weight percent:
3. stainless steel hot rolled piece clean-out system according to claim 1 is characterized in that: described stainless steel hot rolled piece clean-out system is mixed and made into by following raw materials by weight percent:
4. the preparation method of a stainless steel hot rolled piece clean-out system according to claim 1 is characterized in that: have following steps:
(1), under the normal temperature, in stirrer, adding weight percent is the water of 36.8%-68.4%;
(2), throw in the Hydrocerol A that weight percent is 3.5%-7% while stirring;
(3), throw in the AEO that weight percent is 10%-20% while stirring;
(4), throw in the tartrate that weight percent is 5%-10% while stirring;
(5), throw in the trolamine that weight percent is 5%-10% while stirring;
(6), throw in the Sodium orthomolybdate that weight percent is 0.1%-0.2% while stirring;
(7), throw in the hydrochloric acid that weight percent is 1.5%-3% while stirring;
(8), throw in the hydrofluoric acid that weight percent is 1%-2% while stirring;
(9), throwing in weight percent while stirring is 5%-10% oxalic acid;
(10), throw in the TX10 that weight percent is a surplus while stirring;
(11), all reinforced back restir that finishes was finished product in 20-30 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110382641.4A CN102400163B (en) | 2011-11-28 | 2011-11-28 | Cleaning agent for stainless steel hot-rolled member and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110382641.4A CN102400163B (en) | 2011-11-28 | 2011-11-28 | Cleaning agent for stainless steel hot-rolled member and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102400163A true CN102400163A (en) | 2012-04-04 |
| CN102400163B CN102400163B (en) | 2014-06-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201110382641.4A Active CN102400163B (en) | 2011-11-28 | 2011-11-28 | Cleaning agent for stainless steel hot-rolled member and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103014744A (en) * | 2012-10-17 | 2013-04-03 | 张志明 | Method for cleaning industrial metal plate |
| CN103849869A (en) * | 2014-03-13 | 2014-06-11 | 江苏省轻工业科学研究设计院有限公司 | Surface treatment solution for bicycle common carbon steel and preparation method of surface treatment solution |
| CN105112927A (en) * | 2015-09-14 | 2015-12-02 | 夏良文 | Novel aluminum product wax removing agent and preparation method thereof |
| CN107779882A (en) * | 2017-11-09 | 2018-03-09 | 合肥华清金属表面处理有限责任公司 | A kind of stainless steel oxidation skin is without three acid cleaners and its cleaning method |
| CN111926339A (en) * | 2020-07-29 | 2020-11-13 | 甘肃泰升化工科技有限公司 | Chemical stainless steel cleaning agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101135056A (en) * | 2007-09-29 | 2008-03-05 | 吴铭鑫 | Stainless steel cleaning agent |
-
2011
- 2011-11-28 CN CN201110382641.4A patent/CN102400163B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101135056A (en) * | 2007-09-29 | 2008-03-05 | 吴铭鑫 | Stainless steel cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 周宪民: "金属清洗剂SP-8310的研制与应用", 《汽车工艺与材料》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103014744A (en) * | 2012-10-17 | 2013-04-03 | 张志明 | Method for cleaning industrial metal plate |
| CN103014744B (en) * | 2012-10-17 | 2014-11-12 | 张志明 | Method for cleaning industrial metal plate |
| CN103849869A (en) * | 2014-03-13 | 2014-06-11 | 江苏省轻工业科学研究设计院有限公司 | Surface treatment solution for bicycle common carbon steel and preparation method of surface treatment solution |
| CN103849869B (en) * | 2014-03-13 | 2016-01-20 | 江苏省轻工业科学研究设计院有限公司 | A kind of bicycle use general carbon steel surface treatment liquid and preparation method thereof |
| CN105112927A (en) * | 2015-09-14 | 2015-12-02 | 夏良文 | Novel aluminum product wax removing agent and preparation method thereof |
| CN107779882A (en) * | 2017-11-09 | 2018-03-09 | 合肥华清金属表面处理有限责任公司 | A kind of stainless steel oxidation skin is without three acid cleaners and its cleaning method |
| CN111926339A (en) * | 2020-07-29 | 2020-11-13 | 甘肃泰升化工科技有限公司 | Chemical stainless steel cleaning agent and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102400163B (en) | 2014-06-18 |
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Owner name: CHANGZHOU WEIYI TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: CHANGZHOU KAINA ENVIRONMENTAL PROTECTION TECHNOLOGY CO., LTD. Effective date: 20140423 |
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Inventor after: Wang Tianyi Inventor before: Yang Xilong |
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Free format text: CORRECT: ADDRESS; FROM: 213000 CHANGZHOU, JIANGSU PROVINCE TO: 213159 CHANGZHOU, JIANGSU PROVINCE Free format text: CORRECT: INVENTOR; FROM: YANG XILONG TO: WANG TIANYI |
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Effective date of registration: 20140423 Address after: 213159 Hutang, Jiangsu, Wujin District, the town of Yan Zheng Road, No. 28, No. Applicant after: Changzhou Weiyi Technology Co., Ltd. Address before: 213000 Jiangsu province Changzhou City Zhonglou District Lotus Pond street xixinqiao Village No. 99 -1 Applicant before: Changzhou Kaina Environmental Protection Technology Co., Ltd. |
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Address after: 213172 Changzhou City, Jiangsu Province, former town, Wujin District, West Street, No. 60 Patentee after: Changzhou Weiyi Technology Co., Ltd. Address before: 213159 Hutang, Jiangsu, Wujin District, the town of Yan Zheng Road, No. 28, No. Patentee before: Changzhou Weiyi Technology Co., Ltd. |
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Effective date of registration: 20190826 Address after: 224600 South Side of Guanchao Third Road, Chenjiagang Coastal Economic Development Zone, Xiangshui County, Yancheng City, Jiangsu Province Patentee after: Xiangshui Defeng Metal Material Co., Ltd. Address before: 213172 Changzhou City, Jiangsu Province, former town, Wujin District, West Street, No. 60 Patentee before: Changzhou Weiyi Technology Co., Ltd. |