CN109536971A - A kind of water base metal cleaning agent - Google Patents
A kind of water base metal cleaning agent Download PDFInfo
- Publication number
- CN109536971A CN109536971A CN201811551009.6A CN201811551009A CN109536971A CN 109536971 A CN109536971 A CN 109536971A CN 201811551009 A CN201811551009 A CN 201811551009A CN 109536971 A CN109536971 A CN 109536971A
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- CN
- China
- Prior art keywords
- base metal
- water base
- cleaning agent
- metal cleaning
- sodium
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
Abstract
The invention discloses a kind of water base metal cleaning agents, according to mass percent meter, including following components anionic surfactant 2~25%, nonionic surfactant 2~30%, cleaning additive 0.5~10%, chelating agent 2~15%, dispersing agent 1~5%, defoaming agent 0.2~5%, antirust agent 2~8%, water surplus.Water base metal cleaning agent provided by the invention is free of highly basic and phosphorus, does not damage metal surface, free from environmental pollution；With excellent low bubble, soil dispersancy and cleaning ability.
Description
Technical field
The invention belongs to industrial cleaning field more particularly to a kind of water base metal cleaning agents.
Background technique
In the industrial production, metallic article is inevitably attached in processing, manufacture, assembly, storage and maintenance process
Dirt, including liquid or solids dirts such as various greases, lubricant, the salt of left after heat treatment, hand perspiration, dusts.These
Dirt not only will affect the following process of product, but also can cause abrasion or metal erosion, it is therefore desirable to use cleaning agent pair
Components start the cleaning processing.Currently, widely used metal cleaner is divided into solvent cleaner and aqueous cleaning agent.Solvent is clear
Although lotion has very strong dirt-removing power, its is inflammable, explosive, volatile, and there is potential insecurity factors, and cause
Environmental pollution.Aqueous cleaning agent is to take water as a solvent, and formed by various surfactants and additive compound, has price just
Preferably, the advantages that safe and environment-friendly, is gradually widely studied and applied.
107345302 A of Chinese patent CN discloses a kind of gold being made of surfactant, chelating agent, auxiliary agent and water
Belong to accurate bloom cleaning agent, cleaning ability is strong, does not influence metal surface gloss, and raw material easily biological-degradable is free of any nocuousness
Substance.
107779887 A of Chinese patent CN discloses a kind of living by potassium stearate, sodium hydroxide, imidazoline amophoteric surface
Property agent, hydroxy ethylidene-diphosphate, ethyl alcohol, butyl glycol ether and water composition metal polish derusting and cleaning agent, product not only may be used
With all kinds of greasy dirts ingredient accompanying by fast melt metal surface, make greasy dirt and metal surface generation separation, conducive to cleaning and clearly
It washes, and to metal and human body all without any damage.
107779892 A of Chinese patent CN discloses one kind by neopelex, disodium hydrogen phosphate, hydroxide
The environmentally-friendly water-based metal cleaner that sodium, polyethylene glycol, triethanolamine, defoaming agent and water form has excellent degreasing energy
Power, low bubble property and dispersibility, tasteless and nonirritant, safety and environmental protection.
107858696 A of Chinese patent CN discloses one kind by polypropylene glycol (PPG), fatty alcohol polyoxyethylene ether (EO-
9), the gold of sodium sulfate of polyethenoxy ether of fatty alcohol (AES), triethanolamine (TEA), butyl glycol ether, potassium hydroxide and water composition
Belong to greasy dirt detergent, product not only can quickly clean the spot of metal surface, effectively can also prevent metal surface from becoming rusty
The generation of spot, the effect of the metal cleaned is played long-term rust prevention and maintained.
On the one hand, current water base metal cleaning agent contains the harmful components such as highly basic and phosphate mostly, can be to metal watch
Face and environment all generate certain harm；On the other hand, water base metal cleaning agent be typically only capable to effectively to clear up liquid dirt or
Solids foul, the greasy dirt ingredient that can be cleaned are more single.Therefore, needing to develop a kind of all has cleaning effectiveness to most of dirts
Neutral Phosphorus-Free Water-Based Cleaning Agent for Metals.
Summary of the invention
The present invention is to solve the above-mentioned problems in the prior art, proposes a kind of water base metal cleaning agent.
To achieve the above object, the invention adopts the following technical scheme:
The present invention provides a kind of water base metal cleaning agent, by mass percentage, including following components:
Including following components further, by mass percentage:
It is further preferred that by mass percentage, including following components:
Further, the anionic surfactant is selected from neopelex, lauryl sodium sulfate, fat
One of alcohol polyoxyethylene ether ammonium sulfate or isomeric alcohol polyethenoxy ether sodium sulphate are a variety of.
Further, the nonionic surfactant is selected from fatty alcohol polyoxyethylene ether, alkyl polyglucoside or coconut
One of oily diglycollic amide is a variety of.
Further, the cleaning additive is triethanolamine.
Further, the chelating agent is selected from sodium citrate, sodium gluconate, disodium EDTA or ethylenediamine
One of tetraacethyl tetrasodium salt is a variety of.
Further, the dispersing agent is selected from one of naphthalenesulfonate formaldehyde condensation compound or polycarboxylate or a variety of.
Further, any one or more combination of the defoaming agent in polyethers or modified siloxane class.
Further, the antirust agent is selected from one of benzotriazole or sodium benzoate or a variety of.
The present invention by adopting the above technical scheme, compared with prior art, has the following technical effect that
Water base metal cleaning agent provided by the invention is free of highly basic and phosphorus, does not damage metal surface, free from environmental pollution；It adopts
It uses anionic surfactant and nonionic surfactant to compound as surfactant, and is equipped with cleaning additive, chela simultaneously
Mixture, dispersing agent and defoaming agent have excellent low bubble, soil dispersancy and cleaning ability.
Specific embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
Embodiment 1
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 4%；Isomeric alcohol polyethenoxy ether sodium sulphate 2%；Fatty alcohol polyoxyethylene ether 7%；Alkane
Base polyglucoside 2%；Coconut oil diethanol amide 2%；Triethanolamine 3%；Sodium citrate 2%；Tetrasodium salt of EDTA
2%；Naphthalenesulfonate formaldehyde condensation compound 2%；Modified siloxane defoaming agent 0.5%；Benzotriazole 1.5%；Sodium benzoate 3%；
Water 69%.
Embodiment 2
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 4%；Isomeric alcohol polyethenoxy ether sodium sulphate 2%；Fatty alcohol polyoxyethylene ether 7%；Alkane
Base polyglucoside 2%；Coconut oil diethanol amide 2%；Triethanolamine 3%；Sodium citrate 2%；Tetrasodium salt of EDTA
2%；Polycarboxylate 1%；Polyethers defoaming agent 1%；Benzotriazole 1%；Sodium benzoate 1%；Water 72%.
Embodiment 3
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 4%；Isomeric alcohol polyethenoxy ether sodium sulphate 2%；Fatty alcohol polyoxyethylene ether 7%；Alkane
Base polyglucoside 2%；Coconut oil diethanol amide 2%；Triethanolamine 1%；Sodium citrate 2%；Naphthalenesulfonate formaldehyde condensation compound
1%；Polyethers defoaming agent 1%；Benzotriazole 1%；Sodium benzoate 1%；Water 76%.
Embodiment 4
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 2%；Isomeric alcohol polyethenoxy ether sodium sulphate 2%；Fatty alcohol polyoxyethylene ether 5%；Alkane
Base polyglucoside 2%；Coconut oil diethanol amide 2%；Triethanolamine 1%；Sodium citrate 2%；Naphthalenesulfonate formaldehyde condensation compound
1%；Modified siloxane defoaming agent 1%；Benzotriazole 1%；Sodium benzoate 1%；Water 80%.
Embodiment 5
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 2%；Fatty alcohol polyoxyethylene ether 5%；Alkyl polyglucoside 2%；Coconut oil diethanol
Amide 2%；Triethanolamine 1%；Sodium citrate 2%；Polycarboxylate 1%；Modified siloxane defoaming agent 1%；Benzotriazole
1%；Sodium benzoate 1%；Water 82%.
Embodiment 6
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 2%；Lauryl sodium sulfate 2%；Fatty alcohol polyoxyethylene ether ammonium sulfate 2.5%；It is different
Structure alcohol polyethenoxy ether sodium sulfate 2%；Fatty alcohol polyoxyethylene ether 7%；Alkyl polyglucoside 2%；Coconut oil diethanol amide
2%；Triethanolamine 2%；Sodium citrate 1%；Sodium gluconate 1%；Naphthalenesulfonate formaldehyde condensation compound 1%；Modified siloxane disappears
Infusion 1%；Benzotriazole 1%；Sodium benzoate 1%；Water 72.5%.
Embodiment 7
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 4%；Lauryl sodium sulfate 4%；Fatty alcohol polyoxyethylene ether ammonium sulfate 5%；Isomery
Alcohol polyethenoxy ether sodium sulfate 4%；Fatty alcohol polyoxyethylene ether 9%；Alkyl polyglucoside 2%；Coconut oil diethanol amide
4%；Triethanolamine 1%；Sodium citrate 1%；Sodium gluconate 2%；Polycarboxylate 1%；Polyethers defoaming agent 1%；Benzo three
Nitrogen azoles 1%；Sodium benzoate 1%；Water 60%.
Embodiment 8
A kind of water base metal cleaning agent of the present embodiment, is formulated by the component of following mass percent:
Neopelex 4%；Lauryl sodium sulfate 5%；Fatty alcohol polyoxyethylene ether ammonium sulfate 8%；Fat
Alcohol polyoxyethylene ether 18%；Triethanolamine 1%；Sodium gluconate 2%；Polycarboxylate 1%；Polyethers defoaming agent 1%；Benzo three
Nitrogen azoles 1%；Sodium benzoate 2%；Water 57%.
Water base metal cleaning agent made from above-described embodiment 1~8 is carried out to the cleaning test of steel disc surface and oil contaminant, test knot
Fruit is shown in Table 1.
Table 1
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
| Cleaning rate (%) | 92.1 | 92.9 | 90.1 | 90.6 | 89.3 | 93.4 | 98.8 | 95.9 |
Specific embodiments of the present invention are described in detail above, but it is merely an example, the present invention is simultaneously unlimited
It is formed on particular embodiments described above.To those skilled in the art, any couple of present invention carries out equivalent modifications and
Substitution is also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention made by equal transformation and
Modification, all should be contained within the scope of the invention.
Claims (8)
1. a kind of water base metal cleaning agent, which is characterized in that by mass percentage, including following components:
2. water base metal cleaning agent according to claim 1, which is characterized in that the anionic surfactant is selected from ten
Dialkyl benzene sulfonic acids sodium, lauryl sodium sulfate, fatty alcohol polyoxyethylene ether ammonium sulfate or isomeric alcohol polyethenoxy ether sodium sulphate
One of or it is a variety of.
3. water base metal cleaning agent according to claim 1, which is characterized in that the nonionic surfactant is selected from rouge
One of fat alcohol polyoxyethylene ether, alkyl polyglucoside or coconut oil diethanol amide are a variety of.
4. water base metal cleaning agent according to claim 1, which is characterized in that the cleaning additive is triethanolamine.
5. water base metal cleaning agent according to claim 1, which is characterized in that the chelating agent is selected from sodium citrate, Portugal
One of grape sodium saccharate, disodium EDTA or tetrasodium salt of EDTA are a variety of.
6. water base metal cleaning agent according to claim 1, which is characterized in that the dispersing agent is selected from naphthalene sulphonate formaldehyde
One of condensation product or polycarboxylate are a variety of.
7. water base metal cleaning agent according to claim 1, which is characterized in that the defoaming agent is selected from polyethers or modification
The combination of any one or more in type siloxane.
8. water base metal cleaning agent according to claim 1, which is characterized in that the antirust agent be selected from benzotriazole or
One of sodium benzoate is a variety of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811551009.6A CN109536971A (en) | 2018-12-18 | 2018-12-18 | A kind of water base metal cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811551009.6A CN109536971A (en) | 2018-12-18 | 2018-12-18 | A kind of water base metal cleaning agent |
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| Publication Number | Publication Date |
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| CN109536971A true CN109536971A (en) | 2019-03-29 |
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| CN201811551009.6A Pending CN109536971A (en) | 2018-12-18 | 2018-12-18 | A kind of water base metal cleaning agent |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110257841A (en) * | 2019-08-01 | 2019-09-20 | 南京古田化工有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN110358639A (en) * | 2019-07-24 | 2019-10-22 | 义乌市中科院兰州化物所功能材料中心 | A kind of polishing device surface grease scavenger |
| CN110359056A (en) * | 2019-08-07 | 2019-10-22 | 郑州中原利达新材料有限公司 | A kind of high-speed rail powder metallurgy brake pad cleaning agent and preparation method thereof |
| CN111074285A (en) * | 2019-12-30 | 2020-04-28 | 广东省焊接技术研究所（广东省中乌研究院） | Metal degreasing agent and preparation method thereof |
| CN111472011A (en) * | 2020-04-29 | 2020-07-31 | 郑州中原利达新材料有限公司 | Copper-based powder alloy dust filter cup cleaning agent |
| CN111842379A (en) * | 2020-07-30 | 2020-10-30 | 天津绿展环保科技有限公司 | Iron drum renovates processing system |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112375629A (en) * | 2020-11-10 | 2021-02-19 | 武汉市诺思特电子科技有限公司 | Novel water-based cleaning agent |
| CN112813440A (en) * | 2020-12-31 | 2021-05-18 | 上海福岛新材料科技有限公司 | Water-based cleaning agent for improving coating adhesion force for coating pretreatment and preparation method thereof |
| CN114836764A (en) * | 2022-05-19 | 2022-08-02 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
| CN115198280A (en) * | 2022-06-14 | 2022-10-18 | 中核第四研究设计工程有限公司 | Cleaning agent for serial cleaning of stainless steel clean pipelines and preparation method thereof |
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| CN108070872A (en) * | 2017-11-30 | 2018-05-25 | 微普安全科技（徐州）股份有限公司 | A kind of Phosphorus-Free Water-Based Cleaning Agent for Metals |
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| CN102002722A (en) * | 2009-08-28 | 2011-04-06 | 比亚迪股份有限公司 | Stainless steel cleaner and stainless steel cleaning method |
| CN106868519A (en) * | 2017-03-07 | 2017-06-20 | 马鞍山拓锐金属表面技术有限公司 | Aqua type metal cleaner and preparation method thereof |
| CN107916429A (en) * | 2017-10-25 | 2018-04-17 | 成都圻坊生物科技有限公司 | Environment-friendly metal antirust high-efficiency water-base cleaning agent |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110358639A (en) * | 2019-07-24 | 2019-10-22 | 义乌市中科院兰州化物所功能材料中心 | A kind of polishing device surface grease scavenger |
| CN110257841A (en) * | 2019-08-01 | 2019-09-20 | 南京古田化工有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN110359056A (en) * | 2019-08-07 | 2019-10-22 | 郑州中原利达新材料有限公司 | A kind of high-speed rail powder metallurgy brake pad cleaning agent and preparation method thereof |
| CN111074285A (en) * | 2019-12-30 | 2020-04-28 | 广东省焊接技术研究所（广东省中乌研究院） | Metal degreasing agent and preparation method thereof |
| CN111472011A (en) * | 2020-04-29 | 2020-07-31 | 郑州中原利达新材料有限公司 | Copper-based powder alloy dust filter cup cleaning agent |
| CN111842379A (en) * | 2020-07-30 | 2020-10-30 | 天津绿展环保科技有限公司 | Iron drum renovates processing system |
| CN111961541A (en) * | 2020-08-24 | 2020-11-20 | 上海斯瑞文特种油品科技有限公司 | Environment-friendly metal surface cleaning agent and preparation method thereof |
| CN112375629A (en) * | 2020-11-10 | 2021-02-19 | 武汉市诺思特电子科技有限公司 | Novel water-based cleaning agent |
| CN112813440A (en) * | 2020-12-31 | 2021-05-18 | 上海福岛新材料科技有限公司 | Water-based cleaning agent for improving coating adhesion force for coating pretreatment and preparation method thereof |
| CN114836764A (en) * | 2022-05-19 | 2022-08-02 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
| CN114836764B (en) * | 2022-05-19 | 2023-11-24 | 宁波市旭一新材料有限公司 | Environment-friendly phosphorus-free water-based low-foam metal cleaning agent and preparation method thereof |
| CN115198280A (en) * | 2022-06-14 | 2022-10-18 | 中核第四研究设计工程有限公司 | Cleaning agent for serial cleaning of stainless steel clean pipelines and preparation method thereof |
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