CN107916429A - Environment-friendly metal antirust high-efficiency water-base cleaning agent - Google Patents
Environment-friendly metal antirust high-efficiency water-base cleaning agent Download PDFInfo
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- CN107916429A CN107916429A CN201711016046.2A CN201711016046A CN107916429A CN 107916429 A CN107916429 A CN 107916429A CN 201711016046 A CN201711016046 A CN 201711016046A CN 107916429 A CN107916429 A CN 107916429A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
- C23G1/061—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
Abstract
Environment-friendly metal antirust high-efficiency water-base cleaning agent provided by the invention, includes 1 ~ 2 part of 8 ~ 16 parts of 8 ~ 16 parts of 1 ~ 2 part of base cationic surfactant, anion surfactant, nonionic surfactant, chelating agent, the Na CP of following parts by weight4 0.4 ~ 0.8 part, 0.2 ~ 0.4 part of sodium metasilicate, 0.2 ~ 0.4 part of defoamer, 0.3 ~ 0.5 part of corrosion inhibiter, 50 ~ 62 parts of water, 0.4 ~ 0.6 part of additive.Environment-friendly metal antirust high-efficiency water-base cleaning agent provided by the invention is used as surfactant using cationic surfactant, anion surfactant and nonionic surfactant compounding, its cleaning ability is strong, solubility is big in water, and stability is good, is not easy to form precipitation or flocculation suspended things.The present invention uses Na CP at the same time4 With sodium metasilicate as builder, there is good cooperative effect with surfactant, energy softening of water, there is pH value cushioning effect to stablize, soil dispersancy and anti-dirt redeposition ability are strong；Also using amino acid as corrosion inhibiter, its corrosion inhibition is good, environmentally safe, is a kind of green corrosion inhibitor.
Description
Technical field
The present invention relates to metal cleaner field, and in particular to environment-friendly metal antirust high-efficiency water-base cleaning agent.
Background technology
In mechanical industry production, either part process and assemble, or bag is sealed up for safekeeping in heat treatment, plating and product
When dress and unpacking, metal surface will be cleaned.Being attached to the dirt of metal surface has various acid, alkali, salt, dust, throwing
The solids fouls such as light cream, cutting fluid, hand perspiration, various greases or liquid dirt.These dirts have water miscible, also there is oil-soluble
, if not cleaning up, being smoothed out for each manufacturing procedure of metal is not only influenced, but also can cause or accelerate metal erosion,
Reduce product quality, reduction of service life.
Metal surface cleaning agent has aqueous cleaning agent, solvent cleaner, alkaline cleaner.It is molten that solvent cleaner is divided into oil
Agent cleaning agent and chlorinated hydrocarbon solvent cleaning agent.Petroleum solvent cleaning agent has very strong dirt-removing power, it is easy to cleans metal surface
Dirt, it is but inflammable and explosive, it is volatile, have stronger irritation to human central nervous, and easily make metal rusting.Meanwhile wave
Take mass energy, cause environmental pollution.Chlorinated hydrocarbon solvent cleaning agent cleaning ability is extremely strong, it is easy to cleans the oiliness of metal surface
Dirt, but this kind of solvent toxicity is big, it is harmful, commonly used in closed cleaning.
Aqueous cleaning agent is the characteristics of using water being good polar solvent, then the wetting and infiltration for passing through surfactant
Effect, weakens adhesive force of the pollutant in metal surface, then aids in cleaning means pollutant is faster departed from metal surface, reaches
To the effect of decontamination.Aqueous cleaning agent is safe and environment-friendly, cheap, and required chemical composition is all easier to obtain, because
This, is the metal cleaner being widely popularized at present.
The main component of water base metal cleaning agent is surfactant and inorganic assistant；To avoid metal in cleaning process
Corrosion occurs with during the storage after cleaning, need to add inhibition antirust agent, common corrosion inhibiter have inorganic oxide-film corrosion inhibiter,
Inorganic precipitation film corrosion inhibiter and organic adsorption film corrosion inhibiter.Inorganic oxide film corrosion inhibiter, inorganic precipitation film corrosion inhibiter are to use
Inorganic metal ion forms film in metal surface, is attached to metal surface, reaches the effect of inhibition, but if metal ion density
The change of too small or pH value, easily forms micro cell in metal surface breakage, has aggravated the corrosion of metal surface on the contrary.
All the time, the most frequently used, most effective builder in STTP detergents, its energy softening of water, can promote dirt grain
Son is scattered, can provide alkalescence, promotes dirt saponification, emulsification, dissolving, its wash-aid effect is good, cheap.But contain in STTP
Phosphorus, easily causes body eutrophication, pollutes environment.
The content of the invention
For the prior art, the purpose of the invention is to provide a kind of environment-friendly type environmentally friendly, dirt-removing power is strong
Metal rust preventing high-efficiency water-base cleaning agent.
In order to solve the above technical problems, the present invention provides environment-friendly metal antirust high-efficiency water-base cleaning agent, the material bag
Include the raw material of following parts by weight：1~2 part of cationic surfactant, 8~16 parts of anion surfactant, non-ionic surface
8~16 parts of activating agent, 1~2 part of chelating agent, Na-CP40.4~0.8 part, 0.2~0.4 part of sodium metasilicate, defoamer 0.2~0.4
Part, 0.3~0.5 part of corrosion inhibiter, 50~62 parts of water, 0.4~0.6 part of additive.
The cationic surfactant is M550, dodecyl benzyl dimethyl ammonium chloride, cetyl trimethyl bromine
Change ammonium, hexadecylpyridinium chloride, octadecyl ammonium hydrochloride, dioctadecylamine hydrochloride, N, N- dimethylamino octadecylammoniums
One kind in hydrochloride.
The anion surfactant is enuatrol, triethanolamine oleate, fatty alcohol-ether sodium sulfate, the stupid sulphur of dodecyl
One kind in sour sodium, lauryl sodium sulfate, methoxyl group fatty acyl acid Sodium p-aminobenzene sulfonat.
The nonionic surfactant is oleamide, fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, 12
One kind in alkyl diethanolamide, alkanolamide, alkyl glycosides.
The chelating agent for carboxyl acetic acid salt, malate, tartrate, succinate, one kind in malonate or
Two kinds.Carboxyl acids, carboxylic acid quasi-chelate compound are readily biodegradable mostly, free from environmental pollution, at the same time it can also be used as scale inhibition
Agent, reduces the use of anti-deposition agent.
Na-CP4There is good cooperative effect with surfactant, energy softening of water, there is pH value cushioning effect to stablize, dirty
The excellent auxiliary cleaning actions such as dirty dispersibility and anti-dirt redeposition ability are strong, meanwhile, Na-CP4Also there is certain gold
Belong to slow-release capability.
The mass ratio of the cationic surfactant, anion surfactant and nonionic surfactant is：1:
8:8.Anion surfactant produces strong electrical function, because making table together with being compounded with cationic surfactant
Face activity greatly improves, but when anion surfactant and cationic surfactant compounding use, easily occur precipitation or
Cotton-shaped suspension, therefore, its ratio accuracy requirement are higher.When anion surfactant and cationic surfactant compound,
A small amount of nonionic surfactant is added, not only contributes to the increase of compound system solubility, improves anion surface active
Agent and the stability of cationic surfactant compounding, can also strengthen cleaning performance.
The Na-CP4Preparation method be：Add water to stir maleic anhydride, sodium hydrogensulfite, and be heated to 65~70
DEG C, make its dissolving complete, add acrylic acid, stirring reaction 2h, is then cooled to 65~70 DEG C at 80~85 DEG C, and hydrogen is added dropwise
Sodium hydroxide solution to pH value is 7.0~7.5, adds absolute ethyl alcohol and is precipitated, filtered, dry, ground 200 mesh sieve, obtains
Na-CP4。
It is 1 that the additive, which includes mass ratio,:1:0.5 anti-deposition agent, solubilized thinner and sodium acid carbonate.
The corrosion inhibiter is poly-aspartate, cysteine, sulfenyl alanine, histidine, glycine, tryptophane, dried meat
One or more in propylhomoserin, methionine.
The auxiliary agent includes defoamer, stabilizer, water-reducing agent, its mass ratio is 0.5:3:1.5.
Further, the environment-friendly metal antirust high-efficiency water-base cleaning agent, includes the raw material of following parts by weight：Including
The raw material of following parts by weight：1.6 parts of cationic surfactant, 10.8 parts of anion surfactant, non-ionic surface active
10.8 parts of agent, 1.2 parts of chelating agent, 0.6 part of Na-CP4,0.4 part of sodium metasilicate, 0.3 part of defoamer, 0.4 part of corrosion inhibiter, 58 parts of water,
0.2 part of anti-deposition agent, solubilized 0.2 part of thinner, 0.1 part of sodium acid carbonate.
Environment-friendly metal antirust high-efficiency water-base cleaning agent provided by the invention, has the advantages that：
(1) environment-friendly metal antirust high-efficiency water-base cleaning agent provided by the invention using cationic surfactant, it is cloudy from
Sub- surfactant and nonionic surfactant compounding is used as surfactant, its cleaning ability is strong, and solubility is big in water,
Stability is good, is not easy to form precipitation or flocculation suspended things.
(2) environment-friendly metal antirust high-efficiency water-base cleaning agent provided by the invention uses Na-CP4It is used as to help with sodium metasilicate and washes
Agent, has good cooperative effect, energy softening of water, there is pH value cushioning effect to stablize, soil dispersancy with surfactant
It is strong with anti-dirt redeposition ability；At the same time also using amino acid as corrosion inhibiter, its corrosion inhibition is good, environmentally safe, is
A kind of green corrosion inhibitor.
Embodiment
The present invention is further described below.
Embodiment 1：
The environment-friendly metal antirust high-efficiency water-base cleaning agent, includes the raw material of following parts by weight：Dimethyl
1 part of base benzyl ammonium chloride, 8 parts of triethanolamine oleate, 8 parts of fatty alcohol polyoxyethylene ether, 1 part of carboxylic acid sodium acetate, Na-CP4 0.4
Part, 0.3 part of sodium metasilicate, 0.2 part of defoamer, 0.5 part of poly-aspartate, 50 parts of water, 0.16 part of anti-deposition agent, solubilized thinner
0.16 part, 0.8 part of sodium acid carbonate.
Embodiment 2：
The environment-friendly metal antirust high-efficiency water-base cleaning agent, includes the raw material of following parts by weight：Cetyl front three
2 parts of base ammonium bromide, 16 parts of fatty alcohol-ether sodium sulfate, 16 parts of nonylphenol polyoxyethylene ether, 2 parts of natrium malicum, Na-CP40.8 part,
0.2 part of sodium metasilicate, 0.4 part of defoamer, 0.3 part of histidine, 62 parts of water, 0.24 part of anti-deposition agent, solubilized 0.24 part of thinner,
0.12 part of sodium acid carbonate.
Embodiment 3
The environment-friendly metal antirust high-efficiency water-base cleaning agent, includes the raw material of following parts by weight：M5501.6 parts, first
10.8 parts of epoxide fatty acyl acid Sodium p-aminobenzene sulfonat, 10.8 parts of lauryl diethanolamide, 1.2 parts of sodium succinate, Na-CP4
0.6 part, 0.4 part of sodium metasilicate, 0.3 part of defoamer, 0.2 part of cysteine, 0.2 part of sulfenyl alanine, 58 parts of water, anti-deposition agent
0.2 part, solubilized 0.2 part of thinner, 0.1 part of sodium acid carbonate.
According to the recipe configuration cleaning agent 1 of above-described embodiment, cleaning agent 2 and cleaning agent 3 and 10 times of dilution, cleaning agent is obtained
3 dilution of 1 dilution, 2 dilution of cleaning agent and cleaning agent, cleans the metal for being covered with greasy dirt with ultrasonic washing instrument at normal temperatures
Surface, and observe metal surface in one month and whether produce new rusty stain.Using the efficient cleaner case as a comparison of in the market
Example, is not added with cleaning agent ultrasonic cleaning and is used as blank case, after test cleaning, the cleaning degree of metal surface, and its result such as institute of table 1
Show.
Table 1
The present invention is not limited to above-mentioned preferred forms, anyone can show that other are various under the enlightenment of the present invention
The product of form, however, make any change in its shape or structure, it is every that there is skill identical or similar to the present application
Art scheme, is within the scope of the present invention.
Claims (9)
1. environment-friendly metal antirust high-efficiency water-base cleaning agent, it is characterised in that：Include the raw material of following parts by weight：Cationic surface
1 ~ 2 part of activating agent, 8 ~ 16 parts of anion surfactant, 8 ~ 16 parts of nonionic surfactant, 1 ~ 2 part of chelating agent, Na-CP4
0.4 ~ 0.8 part, 0.2 ~ 0.4 part of sodium metasilicate, 0.2 ~ 0.4 part of defoamer, 0.3 ~ 0.5 part of corrosion inhibiter, 50 ~ 62 parts of water, additive 0.4
~ 0.6 part.
2. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The cation form
Face activating agent is M550, dodecyl benzyl dimethyl ammonium chloride, cetyl trimethylammonium bromide, cetyl chloride pyrrole
Pyridine, octadecyl ammonium hydrochloride, dioctadecylamine hydrochloride, N, one kind in N- dimethylamino octadecylammonium hydrochlorides.
3. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The anion table
Face activating agent for enuatrol, triethanolamine oleate, fatty alcohol-ether sodium sulfate, sodium dodecylbenzenesulfonate, lauryl sodium sulfate,
One kind in methoxyl group fatty acyl acid Sodium p-aminobenzene sulfonat.
4. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The nonionic table
Face activating agent is oleamide, fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, lauryl diethanolamide, alkanol
One kind in acid amides, alkyl glycosides.
5. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The chelating agent is
One or both of carboxyl acetic acid salt, malate, tartrate, succinate, malonate.
6. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The additive bag
Mass ratio is included as 1:1:0.5 anti-deposition agent, solubilized thinner and sodium acid carbonate.
7. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 1, it is characterised in that：The corrosion inhibiter is
Poly-aspartate, cysteine, sulfenyl alanine, histidine, glycine, tryptophane, proline, one kind in methionine or
It is a variety of.
8. according to claim 1 ~ 7 any one of them environment-friendly metal antirust high-efficiency water-base cleaning agent, it is characterised in that：It is described
The mass ratio of cationic surfactant, anion surfactant and nonionic surfactant is：1:8:8.
9. environment-friendly metal antirust high-efficiency water-base cleaning agent according to claim 8, it is characterised in that：Including following weight
The raw material of part：1.6 parts of cationic surfactant, 10.8 parts of anion surfactant, 10.8 parts of nonionic surfactant,
1.2 parts of chelating agent, Na-CP40.6 part, 0.4 part of sodium metasilicate, 0.3 part of defoamer, 0.4 part of corrosion inhibiter, 58 parts of water, anti-deposition agent
0.2 part, solubilized 0.2 part of thinner, 0.1 part of sodium acid carbonate.
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| CN201711016046.2A CN107916429A (en) | 2017-10-25 | 2017-10-25 | Environment-friendly metal antirust high-efficiency water-base cleaning agent |
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| CN201711016046.2A CN107916429A (en) | 2017-10-25 | 2017-10-25 | Environment-friendly metal antirust high-efficiency water-base cleaning agent |
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|---|---|---|---|---|
| CN108866560A (en) * | 2018-08-27 | 2018-11-23 | 合肥绿洁环保科技有限公司 | A kind of environment-friendly antirust metal cleaner |
| CN109023404A (en) * | 2018-08-27 | 2018-12-18 | 合肥绿洁环保科技有限公司 | A kind of antirust low foam metal cleaner |
| CN109136952A (en) * | 2018-09-21 | 2019-01-04 | 苏州经贸职业技术学院 | A kind of noresidue metal cleaner and preparation method thereof |
| CN109355667A (en) * | 2018-12-05 | 2019-02-19 | 西安庄信新材料科技有限公司 | A kind of titanium surface acid washing lotion and acid cleaning process |
| CN109536971A (en) * | 2018-12-18 | 2019-03-29 | 北美防锈技术（上海）有限公司 | A kind of water base metal cleaning agent |
| CN110106035A (en) * | 2019-06-17 | 2019-08-09 | 北京洁禹通环保科技有限公司 | A kind of electronic air cleaning device module environment-friendly water-based cleaning agent and its preparation process |
| CN110387550A (en) * | 2019-08-29 | 2019-10-29 | 马鞍山拓锐金属表面技术有限公司 | A kind of preparation process of environmentally-friendly water-based metal cleaner |
| CN111074286A (en) * | 2018-10-18 | 2020-04-28 | 沧州华润化工有限公司 | Preparation method of biological degreasing agent |
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| CN111549351A (en) * | 2020-06-15 | 2020-08-18 | 南通科星化工有限公司 | High-cleaning-ability environment-friendly metal surface oil stain cleaning agent and preparation method thereof |
| CN112175756A (en) * | 2020-11-05 | 2021-01-05 | 河北工业大学 | Cleaning solution for removing surface residues after CMP of multi-layer copper interconnection barrier layer |
| CN113025444A (en) * | 2021-04-12 | 2021-06-25 | 合肥朗逸表面处理有限公司 | Environment-friendly water-soluble cleaning agent for electronic and precision parts |
| CN114457344A (en) * | 2021-09-26 | 2022-05-10 | 中海油(天津)油田化工有限公司 | Water-based cleaning agent for cleaning offshore oil well pipe column and preparation method thereof |
| CN114507573A (en) * | 2022-02-25 | 2022-05-17 | 中铁伟业（北京）新技术有限公司 | Environment-friendly water-based cleaning agent special for rubber windshield of motor train unit and preparation method of cleaning agent |
| CN114686898A (en) * | 2022-04-27 | 2022-07-01 | 广州市盛邦化工科技有限公司 | Lubricating grease cleaning agent and preparation method and application thereof |
| CN114941141A (en) * | 2022-05-13 | 2022-08-26 | 成都航利装备科技有限公司 | Engine airflow channel cleaning solvent and preparation method thereof |
| CN115747816A (en) * | 2022-12-05 | 2023-03-07 | 中国工程物理研究院材料研究所 | Application of glycol ether in cleaning of active metal, non-water-based cleaning agent and cleaning method of active metal |
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| CN108866560A (en) * | 2018-08-27 | 2018-11-23 | 合肥绿洁环保科技有限公司 | A kind of environment-friendly antirust metal cleaner |
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| CN112175756A (en) * | 2020-11-05 | 2021-01-05 | 河北工业大学 | Cleaning solution for removing surface residues after CMP of multi-layer copper interconnection barrier layer |
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| CN114686898B (en) * | 2022-04-27 | 2024-02-23 | 广州市盛邦化工科技有限公司 | Grease cleaning agent and preparation method and application thereof |
| CN114941141A (en) * | 2022-05-13 | 2022-08-26 | 成都航利装备科技有限公司 | Engine airflow channel cleaning solvent and preparation method thereof |
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| CN115747816A (en) * | 2022-12-05 | 2023-03-07 | 中国工程物理研究院材料研究所 | Application of glycol ether in cleaning of active metal, non-water-based cleaning agent and cleaning method of active metal |
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