CN104630781A - Bronze ware cleaning brightener - Google Patents
Bronze ware cleaning brightener Download PDFInfo
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- CN104630781A CN104630781A CN201510075478.5A CN201510075478A CN104630781A CN 104630781 A CN104630781 A CN 104630781A CN 201510075478 A CN201510075478 A CN 201510075478A CN 104630781 A CN104630781 A CN 104630781A
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- bronze
- oxalic acid
- diatomite
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Abstract
The invention discloses a bronze ware cleaning brightener and belongs to the technical field of daily cleaning product processing. The bronze ware cleaning brightener is prepared from the raw materials of oxalic acid, reduced glutathione, ethanol, parolin oil, silicone oil, diatomite, defoamer L62, and lauroylmonoethanolamide. The bronze ware cleaning brightener not only can eliminate the dirt, but also can brighten the bronze ware like before. The reduced glutathione added in the bronze ware cleaning brightener is able to remove the toxic harmful substances generated by oxidation of the old bronze ware, relieve the toxicity of the oxalic acid and greatly reduce the side effect after being detoxified and restored. The product is simple, convenient and practical and is able to remove the dirt, the rust and the spot and does not corrode the bronze; the powdered diatomite is used for scrubbing the bronze ware so that the surface of the bronze ware is smooth, delicate and bright.
Description
Technical field
The invention belongs to the processing technique field of daily cleaning articles for use, particularly relate to a kind of bronze, brass or copper ware cleaning and smoothing agent.
Background technology
At all times, people know that copper has the effect of preventing and curing diseases to human body.In recent years, bronze, brass or copper ware daily necessities have progressed into family and food and beverage enterprise.But brass work is oxidizable, meets easy to change the spots such as acid, alkali, salt, tarnish.A kind of bronze, brass or copper ware cleaning and smoothing agent of the application solves the problem of copper blackspot, greasy dirt.
Summary of the invention
A kind of bronze, brass or copper ware cleaning and smoothing agent, adopts oxalic acid, reduced glutathion, ethanol, paraffin oil, water-soluble silicon oil, diatomite, defoamer L62, lauric monoethanolamide etc. to be prepared from.Not only can clean removal dirt, also make its light as new, this product is after removing toxic substances reduction, and side effect reduces greatly.
The technical measures that the present invention takes
A kind of bronze, brass or copper ware cleaning and smoothing agent, takes raw material by weight: oxalic acid 3.5-10 part, reduced glutathion 12-36 part, ethanol 12-36 part, paraffin oil 2.5-8 part, water-soluble silicon oil 2-6 part, diatomite 6-18 part, defoamer L620.8-2.5 part, lauric monoethanolamide 2-6 part, water 100-300 part.
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil oxalic acid mixed solution and water-soluble silicon oil and mix thoroughly, add defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully to mix thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
Compared with prior art, the present invention has following beneficial effect:
1, present invention adds reduced glutathion, can remove the harmful and noxious substance that the oxidation of old bronze, brass or copper ware produces, alleviate the toxicity of oxalic acid, after removing toxic substances reduction, side effect reduces greatly.
2, not only can clean oily matter, the look rust staining of bronze, brass or copper ware, blackspot, stain spot can also be cleaned.Add the gloss brightness that water-soluble silicon oil increases bronze, brass or copper ware, make bronze, brass or copper ware light as new, keep the metalluster on copper surface.
3, the simple and convenient practicality of product, decontamination dirt derusts spot, corrosion-free to copper, and the diatomite of powdery cleans bronze, brass or copper ware, and make its copper surface more smooth careful glittering, product washing function is comprehensive.
Embodiment:
A kind of bronze, brass or copper ware cleaning and smoothing agent, it comprises: take raw material by weight: oxalic acid 3.5-10 part, reduced glutathion 12-36 part, ethanol 12-36 part, paraffin oil 2.5-8 part, water-soluble silicon oil 2-6 part, diatomite 6-18 part, defoamer L620.8-2.5 part, lauric monoethanolamide 2-6 part, water 100-300 part.
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil, oxalic acid mixed solution and water-soluble silicon oil are mixed thoroughly, added defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully mixes thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
Embodiment 1
A kind of bronze, brass or copper ware cleaning and smoothing agent, takes raw material by weight: oxalic acid 3.5 parts, reduced glutathion 12 parts, ethanol 12 parts, paraffin oil 2.5 parts, water-soluble silicon oil 2 parts, 6 parts, diatomite, defoamer L620.8 part, lauric monoethanolamide 2 parts, 100 parts, water.
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil, oxalic acid mixed solution and water-soluble silicon oil are mixed thoroughly, added defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully mixes thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
Embodiment 2
A kind of bronze, brass or copper ware cleaning and smoothing agent, takes raw material by weight: oxalic acid 10 parts, reduced glutathion 36 parts, ethanol 36 parts, paraffin oil 8 parts, water-soluble silicon oil 6 parts, 18 parts, diatomite, defoamer L622.5 part, lauric monoethanolamide 6 parts, 300 parts, water.
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil, oxalic acid mixed solution and water-soluble silicon oil are mixed thoroughly, added defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully mixes thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
Embodiment 3
A kind of bronze, brass or copper ware cleaning and smoothing agent, takes raw material by weight: oxalic acid 7 parts, reduced glutathion 24 parts, ethanol 24 parts, paraffin oil 5 parts, water-soluble silicon oil 4 parts, 12 parts, diatomite, defoamer L621.6 part, lauric monoethanolamide 4 parts, 200 parts, water.
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil, oxalic acid mixed solution and water-soluble silicon oil are mixed thoroughly, added defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully mixes thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
Using method: both hands wear Rubber gloves, shakes up this product, pours out and on one piece of wet cloth, cleans bronze, brass or copper ware on a small quantity, and the spot spot of brass work disappears for a moment, and rinse well with clear water, clean dry cloth is dried, and namely gloss becomes clear, bright yellow as new bronze, brass or copper ware.
Note: the water of employing is pure water or distilled water.
Wherein, the physico-chemical property of each raw material and purposes as follows:
Oxalic acid: have another name called oxalic acid, dicarboxylic acid.The simplest di-carboxylic acid, is present in natural plant with calcium salt forms, water white transparency xln or white powder.Taste acid, normal containing two molecular crystal water.Anhydrous oxalic acid is water white transparency crystallization, has two kinds of crystal habits, i.e. α type (rhombus) and β type (monoclinic form).Relative density, α type: 1.900 (17 DEG C); β type: 1.895 (17 DEG C).Fusing point α type: 189.5 DEG C; β type: 182 DEG C.The relative density 1.653 (20 DEG C) of oxalic acid dihydrate, fusing point 101.5 DEG C.When being heated to 100 DEG C, then losing crystal water and form anhydride, to 165 DEG C, then part distillation, a part resolves into formic acid and carbonic acid gas, or the resolvent of formic acid.Water-soluble and ethanol, the solubility with temperature in water raises and increases, and is slightly soluble in ether, is insoluble to benzene, chloroform and sherwood oil.Be acid the strongest in binary carboxylic, except there is the character of general carboxylic, also there is strong reducing property.Ferric iron back can be also ferrous iron by oxalic acid, because ferrous iron is soluble in water, therefore can by the iron rust removing on clothing.Also can with much metal oxalic salt, except divalent iron salt and an alkali metal salt, all the other oxalate are all insoluble in water.Oxalic acid is poisonous, the irritant and corrosive nature to skin, mucous membrane, easily by epidermis, mucosal absorption and cause poisoning.Here oxalic acid is used as bronze, brass or copper ware metal except verdigris patina and bate pits agent, sequestrant.
Reduced glutathion: white crystals, general merchandise is pale yellow powder, water-soluble, Diluted Alcohol liquid.Fusing point 195 DEG C, [α] D25-18.9 ° (4.5%), [α] D27-21 ° (2.7%).Gsh, through oxidation deoxidation, makes two molecule gsh be combined into Sleep-promoting factor B (GSSG; Relative molecular mass 612.64).GSSG, without physiological function, is still (reduced form) gsh after reduction.Only has reduced glutathion competence exertion physiological action.Detoxification is had to protect body from the murder by poisoning of heavy metal and epoxy compounds.All there is certain detoxification to the poisoning of CO, heavy metal, organic solvent, carcinogenic substance etc., excrete after combining with it.Play a protective role to by symptoms such as radioactive rays, radiopharmaceuticals or the oligoleukocythemia that causes due to antitumor drug.Here reduced form toxinicide is used as.
Ethanol: i.e. alcohol, colourless transparent liquid, inflammable, volatile, can mix arbitrarily with water ether, chloroform, glycerine etc., multiple organic compound and some mineral compound can be dissolved, reactionless with rare acids, bases, salt, generate aldehyde and acetic acid during oxidation, have weak hormesis to eyes.Here solvent is used as.
Paraffin oil: have another name called whiteruss, white oil, Dormant oils, be colourless, odorless viscous liquid, after heating, slightly oil is smelly, and to acid, heat, light is all very stable, in neutral conditions not react with, does not have fluorescence.Relative density 0.86 ~ 0.91.Water insoluble, glycerine, cold ethanol.Be dissolved in hot ethanol, dithiocarbonic anhydride, ether, ester, chloroform, benzene, sherwood oil.Except Viscotrol C, can mix with many greases and wax.Here copper metal detergency builder is used as.
Water-soluble silicon oil: have another name called silicone oil, colourless yellowish transparent oily liquid.Relative density 0.96 ~ 1.02.Can dissolve each other with any ratio with water.Belong to non-ionic type, surface tension is very low, has emulsification lubrication.Here smooth, the gloss effect that increase bronze, brass or copper ware is used as.
Diatomite: a kind of biogenic white or slight yellow powdery siliceous rock, be made up of amorphous SiO2, and containing a small amount of Fe2O3, CaO, MgO, Al2O3 and organic impurity.Light weight and soft, easy grinding powder, vesicular, porosity reaches about 90%.There is very strong adsorptive power, the water of himself weight 1.5 ~ 4.0 times can be absorbed, also have good filterableness, Bleachability, chemical stability and thermal insulation.Here be used as decontamination, decolouring, deodorizing, deacidify and polish effect.
Defoamer L62: another name SYNPERONIC PE/F68, pale yellowish oil liquid, water-soluble, the organic solvents such as easy molten ethanol, nontoxic, non-corrosiveness, the washing that tool is good and froth breaking effect.
Lauric monoethanolamide: there is good surfactivity, dispersion of calcium soap, emulsifying power, foam power and detersive power.Here cleaning detergent is used as.
Claims (4)
1. a bronze, brass or copper ware cleaning and smoothing agent, it is characterized in that: take raw material by weight, oxalic acid 3.5-10 part, reduced glutathion 12-36 part, ethanol 12-36 part, paraffin oil 2.5-8 part, water-soluble silicon oil 2-6 part, diatomite 6-18 part, defoamer L620.8-2.5 part, lauric monoethanolamide 2-6 part, water 100-300 part;
First diatomite was dried be ground into again end stand-by, pour in paraffin oil after ethanol is heated in boiling water to dissolve and add oxalic acid again and mix thoroughly stand-by, water is put into mixing vessel, add reduced glutathion to mix thoroughly, add ethanol and paraffin oil, oxalic acid mixed solution and water-soluble silicon oil are mixed thoroughly, added defoamer L62 and lauric monoethanolamide is mixed thoroughly, finally add diatomite powder fully to mix thoroughly, after sub-bottle packaging is good, namely become a kind of bronze, brass or copper ware cleaning and smoothing agent.
2. a kind of bronze, brass or copper ware cleaning and smoothing agent according to claim 1, it is characterized in that: take raw material by weight, oxalic acid 3.5 parts, reduced glutathion 12 parts, ethanol 12 parts, paraffin oil 2.5 parts, water-soluble silicon oil 2 parts, 6 parts, diatomite, defoamer L620.8 part, lauric monoethanolamide 2 parts, 100 parts, water.
3. a kind of bronze, brass or copper ware cleaning and smoothing agent according to claim 1, it is characterized in that: take raw material by weight, oxalic acid 10 parts, reduced glutathion 36 parts, ethanol 36 parts, paraffin oil 8 parts, water-soluble silicon oil 6 parts, 18 parts, diatomite, defoamer L622.5 part, lauric monoethanolamide 6 parts, 300 parts, water.
4. a kind of bronze, brass or copper ware cleaning and smoothing agent according to claim 1, it is characterized in that: take raw material by weight, oxalic acid 7 parts, reduced glutathion 24 parts, ethanol 24 parts, paraffin oil 5 parts, water-soluble silicon oil 4 parts, 12 parts, diatomite, defoamer L621.6 part, lauric monoethanolamide 4 parts, 200 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510075478.5A CN104630781A (en) | 2015-02-11 | 2015-02-11 | Bronze ware cleaning brightener |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510075478.5A CN104630781A (en) | 2015-02-11 | 2015-02-11 | Bronze ware cleaning brightener |
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| CN104630781A true CN104630781A (en) | 2015-05-20 |
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| CN201510075478.5A Pending CN104630781A (en) | 2015-02-11 | 2015-02-11 | Bronze ware cleaning brightener |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105441954A (en) * | 2015-12-22 | 2016-03-30 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Metal surface brightener material combination and metal surface brightener |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102943274A (en) * | 2012-11-27 | 2013-02-27 | 李蓉 | Metal kitchenware cleaning agent |
| CN103469236A (en) * | 2013-09-22 | 2013-12-25 | 西北机器有限公司 | Copper base material cleaning agent and preparation method thereof |
| CN103740517A (en) * | 2014-02-12 | 2014-04-23 | 北京戴斯科技有限公司 | Sand cylinder cleaning agent |
-
2015
- 2015-02-11 CN CN201510075478.5A patent/CN104630781A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102943274A (en) * | 2012-11-27 | 2013-02-27 | 李蓉 | Metal kitchenware cleaning agent |
| CN103469236A (en) * | 2013-09-22 | 2013-12-25 | 西北机器有限公司 | Copper base material cleaning agent and preparation method thereof |
| CN103740517A (en) * | 2014-02-12 | 2014-04-23 | 北京戴斯科技有限公司 | Sand cylinder cleaning agent |
Non-Patent Citations (3)
| Title |
|---|
| 凌关庭: "《抗氧化食品与健康》", 30 April 2004, 化学工业出版社 * |
| 刘云: "《日用化学品原材料技术手册》", 31 October 2003, 化学工业出版社 * |
| 张英: "《精细化学品配方大全 下》", 31 May 2001, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105441954A (en) * | 2015-12-22 | 2016-03-30 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | Metal surface brightener material combination and metal surface brightener |
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Application publication date: 20150520 |