CN106118896A - A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application - Google Patents

A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application Download PDF

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Publication number
CN106118896A
CN106118896A CN201610417971.5A CN201610417971A CN106118896A CN 106118896 A CN106118896 A CN 106118896A CN 201610417971 A CN201610417971 A CN 201610417971A CN 106118896 A CN106118896 A CN 106118896A
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China
Prior art keywords
heat exchanger
type heat
plate type
washing agent
complex cleaning
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Pending
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CN201610417971.5A
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Chinese (zh)
Inventor
张凌霞
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Anhui Pu Ruipule Heat Transfer Technology Co Ltd
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Anhui Pu Ruipule Heat Transfer Technology Co Ltd
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Priority to CN201610417971.5A priority Critical patent/CN106118896A/en
Publication of CN106118896A publication Critical patent/CN106118896A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

Abstract

The present invention relates to the cleaning technique field of plate type heat exchanger, be specifically related to a kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application.Described abluent is made up of the raw material of following mass fraction: natural activity treatment fluid 2.5 5.7%, starch polyglycoside surfactants 1.2 2.5%, trihydroxy ethylamine oleate soap 0.25 0.75%, fatty alcohol-polyoxyethylene ether 1.2 1.5%, nicotinic acid 0.3 0.5%, glycerol type dendritic polyether 0.25 0.5%, tetraethyl ammonium hydroxide 0.5 1.2%, methyl carbonic acid ester quat 0.3 1.5%, surplus is water.The abluent safety and environmental protection that the present invention provides, cleansing power is strong.

Description

A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application
Technical field
The present invention relates to the cleaning technique field of plate type heat exchanger, be specifically related to a kind of plate type heat exchanger complex cleaning and washing agent and Its preparation method and application.
Background technology
Plate type heat exchanger is widely used in the heat exchange between petroleum chemical industry water oil.It is substantial amounts of owing to water containing The metal ion such as calcium, magnesium, is at high temperature readily formed calcium, the isoionic carbonate sediment of magnesium is attached to plate type heat exchanger Side, opposite side then adheres to one layer of grease, and this makes the heat exchange efficiency of plate type heat exchanger reduce, so using certain time After need plate type heat exchanger is carried out disassembly, cleaning.
Grease currently for oil transportation side panels surface is typically all carried out with chemical solvent or alkali liquor, then uses Clear water rinses, then is carried out the incrustation scale acid solution on water delivery side panels surface.Human body is all hindered by chemical solvent or acid, aqueous slkali Evil is relatively big, and this cleaning workload is big, and cleaning efficiency is low, and environmental pollution is serious.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of safety and environmental protection, the plate type heat exchanger that cleansing power is strong is multiple Close abluent and its preparation method and application.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of plate type heat exchanger complex cleaning and washing agent, is made up of the raw material of following mass fraction: natural activity treatment fluid 2.5- 5.7%, starch polyglycoside surfactants 1.2-2.5%, trihydroxy ethylamine oleate soap 0.25-0.75%, fatty alcohol-polyoxyethylene ether 1.2-1.5%, nicotinic acid 0.3-0.5%, glycerol type dendritic polyether 0.25-0.5%, tetraethyl ammonium hydroxide 0.5-1.2%, first Base carbonic ester quaternary ammonium salt 0.3-1.5%, surplus is water.
Further, described plate type heat exchanger complex cleaning and washing agent, it is made up of the raw material of following mass fraction: natural activity Treatment fluid 3.8%, starch polyglycoside surfactants 2.1%, trihydroxy ethylamine oleate soap 0.57%, fatty alcohol-polyoxyethylene ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid ester quat 1.2%, surplus is water.
Further, described natural activity treatment fluid includes following composition: peel 45-60%, sodium carbonate 1-5%, ice vinegar Acid 1-5%, surplus is 75% ethanol.
Further, described peel is Pericarpium Citri junoris, Pericarpium Citri tangerinae, Fericarpium Citri Limoniae, pomelo peel, one in peel of Fructus Sapindi Mukouossi or one with Upper compositions.
Further, the preparation method of described plate type heat exchanger complex cleaning and washing agent, comprise the steps:
S1, the preparation of natural activity treatment fluid: fresh peel is pulverized, first adds by the component ratio of natural activity treatment fluid Enter sodium carbonate and glacial acetic acid, stir mixing 3-5min with the speed of 40-80r/min, then mixture is immersed in 75% ethanol, Seal and soak more than one week, standby;
Prepared by S2, abluent: by each component ratio of abluent by each raw material mix homogeneously, obtain colourless transparent liquid.
The application in removing plate type heat exchanger surface smut of a kind of plate type heat exchanger complex cleaning and washing agent.
The invention have the benefit that
1, the present invention is combined compatibility in proportion by natural activity inorganic agent, surfactant, brightener, rust remover, water etc. Forming, add a small amount of abluent, can clean up, oil removing and features high scale-removing effect, cleansing power is strong, and work efficiency is high;
2, the present invention selects peel and other chemical assistants to be raw material, and safety and environmental protection meets the requirement of environmental protection;And material Expect cheap and easy to get, contribute to cost-effective;Sheet surface will not be caused corrosion by the cleanout fluid prepared.
3, preparation method provided by the present invention is simple, and production cost is low, good in economic efficiency.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the enforcement of the present invention Example, is clearly and completely described the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection Scope.
Embodiment 1:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae Skin, pomelo peel, one or more compositionss 52.5% in peel of Fructus Sapindi Mukouossi, sodium carbonate 4%, glacial acetic acid 2.8%, surplus It is that the component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 60r/min, then mixture is soaked Enter in 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 3.8% by mass fraction, starch polyglycoside surfactants 2.1%, trihydroxy ethylamine oleate soap 0.57%, fatty alcohol-polyoxyethylene ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid ester quat 1.2%, surplus is that the ratio of water is by equal for the mixing of each raw material Even, obtain colourless transparent liquid.
Embodiment 2:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae Skin, pomelo peel, one or more compositionss 45% in peel of Fructus Sapindi Mukouossi, sodium carbonate 5%, glacial acetic acid 1%, surplus is The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 80r/min, is then immersed by mixture In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 3.8% by mass fraction, starch polyglycoside surfactants 1.9%, trihydroxy ethylamine oleate soap 0.56%, fatty alcohol-polyoxyethylene ether 1.4%, nicotinic acid 0.4%, glycerol type dendritic polyether 0.3%, tetraethyl ammonium hydroxide 0.7%, methyl carbonic acid ester quat 1.2%, surplus is that the ratio of water is by equal for the mixing of each raw material Even, obtain colourless transparent liquid.
Embodiment 3:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae Skin, pomelo peel, one or more compositionss 60% in peel of Fructus Sapindi Mukouossi, sodium carbonate 1%, glacial acetic acid 5%, surplus is The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 5min with the speed of 40r/min, is then immersed by mixture In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 4.4% by mass fraction, starch polyglycoside surfactants 1.9%, trihydroxy ethylamine oleate soap 0.55%, fatty alcohol-polyoxyethylene ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.4%, tetraethyl ammonium hydroxide 0.85%, methyl carbonic acid ester quat 0.6%, surplus is that the ratio of water is by equal for the mixing of each raw material Even, obtain colourless transparent liquid.
Embodiment 4:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae Skin, pomelo peel, one or more compositionss 55% in peel of Fructus Sapindi Mukouossi, sodium carbonate 2%, glacial acetic acid 4%, surplus is The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 5min with the speed of 55r/min, is then immersed by mixture In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 2.5% by mass fraction, starch polyglycoside surfactants 2.5%, trihydroxy ethylamine oleate soap 0.25%, fatty alcohol-polyoxyethylene ether 1.5%, nicotinic acid 0.3%, glycerol type dendritic polyether 0.5%, tetraethyl ammonium hydroxide 0.5%, methyl carbonic acid ester quat 1.5%, surplus is that the ratio of water is by equal for the mixing of each raw material Even, obtain colourless transparent liquid.
Embodiment 5:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae Skin, pomelo peel, one or more compositionss 50% in peel of Fructus Sapindi Mukouossi, sodium carbonate 4%, glacial acetic acid 3%, surplus is The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 75r/min, is then immersed by mixture In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 5.7% by mass fraction, starch polyglycoside surfactants 1.2%, trihydroxy ethylamine oleate soap 0.75%, fatty alcohol-polyoxyethylene ether 1.2%, nicotinic acid 0.5%, glycerol type dendritic polyether 0.25%, tetraethyl ammonium hydroxide 1.2%, methyl carbonic acid ester quat 0.3%, surplus is that the ratio of water is by equal for the mixing of each raw material Even, obtain colourless transparent liquid.
The invention have the benefit that
1, the present invention is combined compatibility in proportion by natural activity inorganic agent, surfactant, brightener, rust remover, water etc. Forming, add a small amount of abluent, can clean up, oil removing and features high scale-removing effect, cleansing power is strong, and work efficiency is high;
2, the present invention selects peel and other chemical assistants to be raw material, and safety and environmental protection meets the requirement of environmental protection;And material Expect cheap and easy to get, contribute to cost-effective;Sheet surface will not be caused corrosion by the cleanout fluid prepared.
Preparation method provided by the present invention is simple, and production cost is low, good in economic efficiency.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a plate type heat exchanger complex cleaning and washing agent, it is characterised in that be made up of the raw material of following mass fraction: at natural activity Reason liquid 2.5-5.7%, starch polyglycoside surfactants 1.2-2.5%, trihydroxy ethylamine oleate soap 0.25-0.75%, poly alkyl alcohol Oxygen vinyl Ether 1.2-1.5%, nicotinic acid 0.3-0.5%, glycerol type dendritic polyether 0.25-0.5%, tetraethyl ammonium hydroxide 0.5- 1.2%, methyl carbonic acid ester quat 0.3-1.5%, surplus is water.
2. plate type heat exchanger complex cleaning and washing agent as claimed in claim 1, it is characterised in that by the raw material group of following mass fraction Become: natural activity treatment fluid 3.8%, starch polyglycoside surfactants 2.1%, trihydroxy ethylamine oleate soap 0.57%, poly alkyl alcohol Oxygen vinyl Ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid Ester quat 1.2%, surplus is water.
3. plate type heat exchanger complex cleaning and washing agent as claimed in claim 2, it is characterised in that described natural activity treatment fluid includes Following composition: peel 45-60%, sodium carbonate 1-5%, glacial acetic acid 1-5%, surplus is 75% ethanol.
4. plate type heat exchanger complex cleaning and washing agent as claimed in claim 3, it is characterised in that described peel is Pericarpium Citri junoris, Pericarpium Citri tangerinae, lemon Lemon skin, pomelo peel, one or more compositionss in peel of Fructus Sapindi Mukouossi.
5. the preparation method of the plate type heat exchanger complex cleaning and washing agent as according to any one of claim 1-4, it is characterised in that bag Include following steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, first add carbon by the component ratio of natural activity treatment fluid Acid sodium and glacial acetic acid, stir mixing 3-5min with the speed of 40-80r/min, then immersed by mixture in 75% ethanol, seal Soak more than one week, standby;
Prepared by S2, abluent: by each component ratio of abluent by each raw material mix homogeneously, obtain colourless transparent liquid.
6. the plate type heat exchanger complex cleaning and washing agent as according to any one of claim 1-4 is removing plate type heat exchanger surface Application in dirt.
CN201610417971.5A 2016-06-07 2016-06-07 A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application Pending CN106118896A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN106868491A (en) * 2016-12-26 2017-06-20 安徽宝恒新材料科技有限公司 A kind of method for strengthening steel surface snearing performance
CN107090584A (en) * 2017-04-26 2017-08-25 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger degreased cleaning agent and its preparation
CN110734817A (en) * 2019-10-30 2020-01-31 湖南金裕环保科技有限公司 Scale remover for precision water system and preparation method thereof
CN116410822A (en) * 2023-03-31 2023-07-11 佛山市顺德区正泽精细化工有限公司 Environment-friendly cleaning degreasing agent

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106868491A (en) * 2016-12-26 2017-06-20 安徽宝恒新材料科技有限公司 A kind of method for strengthening steel surface snearing performance
CN106868491B (en) * 2016-12-26 2019-02-01 安徽宝恒新材料科技有限公司 A method of enhancing steel surface snearing performance
CN107090584A (en) * 2017-04-26 2017-08-25 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger degreased cleaning agent and its preparation
CN110734817A (en) * 2019-10-30 2020-01-31 湖南金裕环保科技有限公司 Scale remover for precision water system and preparation method thereof
CN116410822A (en) * 2023-03-31 2023-07-11 佛山市顺德区正泽精细化工有限公司 Environment-friendly cleaning degreasing agent

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