CN106118896A - A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application - Google Patents
A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application Download PDFInfo
- Publication number
- CN106118896A CN106118896A CN201610417971.5A CN201610417971A CN106118896A CN 106118896 A CN106118896 A CN 106118896A CN 201610417971 A CN201610417971 A CN 201610417971A CN 106118896 A CN106118896 A CN 106118896A
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- China
- Prior art keywords
- heat exchanger
- type heat
- plate type
- washing agent
- complex cleaning
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Abstract
The present invention relates to the cleaning technique field of plate type heat exchanger, be specifically related to a kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application.Described abluent is made up of the raw material of following mass fraction: natural activity treatment fluid 2.5 5.7%, starch polyglycoside surfactants 1.2 2.5%, trihydroxy ethylamine oleate soap 0.25 0.75%, fatty alcohol-polyoxyethylene ether 1.2 1.5%, nicotinic acid 0.3 0.5%, glycerol type dendritic polyether 0.25 0.5%, tetraethyl ammonium hydroxide 0.5 1.2%, methyl carbonic acid ester quat 0.3 1.5%, surplus is water.The abluent safety and environmental protection that the present invention provides, cleansing power is strong.
Description
Technical field
The present invention relates to the cleaning technique field of plate type heat exchanger, be specifically related to a kind of plate type heat exchanger complex cleaning and washing agent and
Its preparation method and application.
Background technology
Plate type heat exchanger is widely used in the heat exchange between petroleum chemical industry water oil.It is substantial amounts of owing to water containing
The metal ion such as calcium, magnesium, is at high temperature readily formed calcium, the isoionic carbonate sediment of magnesium is attached to plate type heat exchanger
Side, opposite side then adheres to one layer of grease, and this makes the heat exchange efficiency of plate type heat exchanger reduce, so using certain time
After need plate type heat exchanger is carried out disassembly, cleaning.
Grease currently for oil transportation side panels surface is typically all carried out with chemical solvent or alkali liquor, then uses
Clear water rinses, then is carried out the incrustation scale acid solution on water delivery side panels surface.Human body is all hindered by chemical solvent or acid, aqueous slkali
Evil is relatively big, and this cleaning workload is big, and cleaning efficiency is low, and environmental pollution is serious.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of safety and environmental protection, the plate type heat exchanger that cleansing power is strong is multiple
Close abluent and its preparation method and application.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of plate type heat exchanger complex cleaning and washing agent, is made up of the raw material of following mass fraction: natural activity treatment fluid 2.5-
5.7%, starch polyglycoside surfactants 1.2-2.5%, trihydroxy ethylamine oleate soap 0.25-0.75%, fatty alcohol-polyoxyethylene ether
1.2-1.5%, nicotinic acid 0.3-0.5%, glycerol type dendritic polyether 0.25-0.5%, tetraethyl ammonium hydroxide 0.5-1.2%, first
Base carbonic ester quaternary ammonium salt 0.3-1.5%, surplus is water.
Further, described plate type heat exchanger complex cleaning and washing agent, it is made up of the raw material of following mass fraction: natural activity
Treatment fluid 3.8%, starch polyglycoside surfactants 2.1%, trihydroxy ethylamine oleate soap 0.57%, fatty alcohol-polyoxyethylene ether
1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid ester quat
1.2%, surplus is water.
Further, described natural activity treatment fluid includes following composition: peel 45-60%, sodium carbonate 1-5%, ice vinegar
Acid 1-5%, surplus is 75% ethanol.
Further, described peel is Pericarpium Citri junoris, Pericarpium Citri tangerinae, Fericarpium Citri Limoniae, pomelo peel, one in peel of Fructus Sapindi Mukouossi or one with
Upper compositions.
Further, the preparation method of described plate type heat exchanger complex cleaning and washing agent, comprise the steps:
S1, the preparation of natural activity treatment fluid: fresh peel is pulverized, first adds by the component ratio of natural activity treatment fluid
Enter sodium carbonate and glacial acetic acid, stir mixing 3-5min with the speed of 40-80r/min, then mixture is immersed in 75% ethanol,
Seal and soak more than one week, standby;
Prepared by S2, abluent: by each component ratio of abluent by each raw material mix homogeneously, obtain colourless transparent liquid.
The application in removing plate type heat exchanger surface smut of a kind of plate type heat exchanger complex cleaning and washing agent.
The invention have the benefit that
1, the present invention is combined compatibility in proportion by natural activity inorganic agent, surfactant, brightener, rust remover, water etc.
Forming, add a small amount of abluent, can clean up, oil removing and features high scale-removing effect, cleansing power is strong, and work efficiency is high;
2, the present invention selects peel and other chemical assistants to be raw material, and safety and environmental protection meets the requirement of environmental protection;And material
Expect cheap and easy to get, contribute to cost-effective;Sheet surface will not be caused corrosion by the cleanout fluid prepared.
3, preparation method provided by the present invention is simple, and production cost is low, good in economic efficiency.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the enforcement of the present invention
Example, is clearly and completely described the technical scheme in the embodiment of the present invention.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae
Skin, pomelo peel, one or more compositionss 52.5% in peel of Fructus Sapindi Mukouossi, sodium carbonate 4%, glacial acetic acid 2.8%, surplus
It is that the component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 60r/min, then mixture is soaked
Enter in 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 3.8% by mass fraction, starch polyglycoside surfactants
2.1%, trihydroxy ethylamine oleate soap 0.57%, fatty alcohol-polyoxyethylene ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether
0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid ester quat 1.2%, surplus is that the ratio of water is by equal for the mixing of each raw material
Even, obtain colourless transparent liquid.
Embodiment 2:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae
Skin, pomelo peel, one or more compositionss 45% in peel of Fructus Sapindi Mukouossi, sodium carbonate 5%, glacial acetic acid 1%, surplus is
The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 80r/min, is then immersed by mixture
In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 3.8% by mass fraction, starch polyglycoside surfactants
1.9%, trihydroxy ethylamine oleate soap 0.56%, fatty alcohol-polyoxyethylene ether 1.4%, nicotinic acid 0.4%, glycerol type dendritic polyether
0.3%, tetraethyl ammonium hydroxide 0.7%, methyl carbonic acid ester quat 1.2%, surplus is that the ratio of water is by equal for the mixing of each raw material
Even, obtain colourless transparent liquid.
Embodiment 3:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae
Skin, pomelo peel, one or more compositionss 60% in peel of Fructus Sapindi Mukouossi, sodium carbonate 1%, glacial acetic acid 5%, surplus is
The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 5min with the speed of 40r/min, is then immersed by mixture
In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 4.4% by mass fraction, starch polyglycoside surfactants
1.9%, trihydroxy ethylamine oleate soap 0.55%, fatty alcohol-polyoxyethylene ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether
0.4%, tetraethyl ammonium hydroxide 0.85%, methyl carbonic acid ester quat 0.6%, surplus is that the ratio of water is by equal for the mixing of each raw material
Even, obtain colourless transparent liquid.
Embodiment 4:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae
Skin, pomelo peel, one or more compositionss 55% in peel of Fructus Sapindi Mukouossi, sodium carbonate 2%, glacial acetic acid 4%, surplus is
The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 5min with the speed of 55r/min, is then immersed by mixture
In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 2.5% by mass fraction, starch polyglycoside surfactants
2.5%, trihydroxy ethylamine oleate soap 0.25%, fatty alcohol-polyoxyethylene ether 1.5%, nicotinic acid 0.3%, glycerol type dendritic polyether
0.5%, tetraethyl ammonium hydroxide 0.5%, methyl carbonic acid ester quat 1.5%, surplus is that the ratio of water is by equal for the mixing of each raw material
Even, obtain colourless transparent liquid.
Embodiment 5:
The preparation method of a kind of plate type heat exchanger complex cleaning and washing agent, comprises the steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, be first Pericarpium Citri junoris by mass fraction, Pericarpium Citri tangerinae, Fructus Citri Limoniae
Skin, pomelo peel, one or more compositionss 50% in peel of Fructus Sapindi Mukouossi, sodium carbonate 4%, glacial acetic acid 3%, surplus is
The component ratio of 75% ethanol is sequentially added into each component, stirs mixing 3min with the speed of 75r/min, is then immersed by mixture
In 75% ethanol, seal and soak more than one week, standby;
Prepared by S2, abluent: be natural activity treatment fluid 5.7% by mass fraction, starch polyglycoside surfactants
1.2%, trihydroxy ethylamine oleate soap 0.75%, fatty alcohol-polyoxyethylene ether 1.2%, nicotinic acid 0.5%, glycerol type dendritic polyether
0.25%, tetraethyl ammonium hydroxide 1.2%, methyl carbonic acid ester quat 0.3%, surplus is that the ratio of water is by equal for the mixing of each raw material
Even, obtain colourless transparent liquid.
The invention have the benefit that
1, the present invention is combined compatibility in proportion by natural activity inorganic agent, surfactant, brightener, rust remover, water etc.
Forming, add a small amount of abluent, can clean up, oil removing and features high scale-removing effect, cleansing power is strong, and work efficiency is high;
2, the present invention selects peel and other chemical assistants to be raw material, and safety and environmental protection meets the requirement of environmental protection;And material
Expect cheap and easy to get, contribute to cost-effective;Sheet surface will not be caused corrosion by the cleanout fluid prepared.
Preparation method provided by the present invention is simple, and production cost is low, good in economic efficiency.
Above example only in order to technical scheme to be described, is not intended to limit;Although with reference to previous embodiment
The present invention is described in detail, it will be understood by those within the art that: it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent;And these amendment or
Replace, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (6)
1. a plate type heat exchanger complex cleaning and washing agent, it is characterised in that be made up of the raw material of following mass fraction: at natural activity
Reason liquid 2.5-5.7%, starch polyglycoside surfactants 1.2-2.5%, trihydroxy ethylamine oleate soap 0.25-0.75%, poly alkyl alcohol
Oxygen vinyl Ether 1.2-1.5%, nicotinic acid 0.3-0.5%, glycerol type dendritic polyether 0.25-0.5%, tetraethyl ammonium hydroxide 0.5-
1.2%, methyl carbonic acid ester quat 0.3-1.5%, surplus is water.
2. plate type heat exchanger complex cleaning and washing agent as claimed in claim 1, it is characterised in that by the raw material group of following mass fraction
Become: natural activity treatment fluid 3.8%, starch polyglycoside surfactants 2.1%, trihydroxy ethylamine oleate soap 0.57%, poly alkyl alcohol
Oxygen vinyl Ether 1.3%, nicotinic acid 0.45%, glycerol type dendritic polyether 0.35%, tetraethyl ammonium hydroxide 0.9%, methyl carbonic acid
Ester quat 1.2%, surplus is water.
3. plate type heat exchanger complex cleaning and washing agent as claimed in claim 2, it is characterised in that described natural activity treatment fluid includes
Following composition: peel 45-60%, sodium carbonate 1-5%, glacial acetic acid 1-5%, surplus is 75% ethanol.
4. plate type heat exchanger complex cleaning and washing agent as claimed in claim 3, it is characterised in that described peel is Pericarpium Citri junoris, Pericarpium Citri tangerinae, lemon
Lemon skin, pomelo peel, one or more compositionss in peel of Fructus Sapindi Mukouossi.
5. the preparation method of the plate type heat exchanger complex cleaning and washing agent as according to any one of claim 1-4, it is characterised in that bag
Include following steps:
S1, the preparation of natural activity treatment fluid: pulverized by fresh peel, first add carbon by the component ratio of natural activity treatment fluid
Acid sodium and glacial acetic acid, stir mixing 3-5min with the speed of 40-80r/min, then immersed by mixture in 75% ethanol, seal
Soak more than one week, standby;
Prepared by S2, abluent: by each component ratio of abluent by each raw material mix homogeneously, obtain colourless transparent liquid.
6. the plate type heat exchanger complex cleaning and washing agent as according to any one of claim 1-4 is removing plate type heat exchanger surface
Application in dirt.
Priority Applications (1)
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CN201610417971.5A CN106118896A (en) | 2016-06-07 | 2016-06-07 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
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CN201610417971.5A CN106118896A (en) | 2016-06-07 | 2016-06-07 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
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Cited By (4)
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---|---|---|---|---|
CN106868491A (en) * | 2016-12-26 | 2017-06-20 | 安徽宝恒新材料科技有限公司 | A kind of method for strengthening steel surface snearing performance |
CN107090584A (en) * | 2017-04-26 | 2017-08-25 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger degreased cleaning agent and its preparation |
CN110734817A (en) * | 2019-10-30 | 2020-01-31 | 湖南金裕环保科技有限公司 | Scale remover for precision water system and preparation method thereof |
CN116410822A (en) * | 2023-03-31 | 2023-07-11 | 佛山市顺德区正泽精细化工有限公司 | Environment-friendly cleaning degreasing agent |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106868491A (en) * | 2016-12-26 | 2017-06-20 | 安徽宝恒新材料科技有限公司 | A kind of method for strengthening steel surface snearing performance |
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CN107090584A (en) * | 2017-04-26 | 2017-08-25 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger degreased cleaning agent and its preparation |
CN110734817A (en) * | 2019-10-30 | 2020-01-31 | 湖南金裕环保科技有限公司 | Scale remover for precision water system and preparation method thereof |
CN116410822A (en) * | 2023-03-31 | 2023-07-11 | 佛山市顺德区正泽精细化工有限公司 | Environment-friendly cleaning degreasing agent |
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