CN105368593A - Cleaning agent for petroleum machinery equipment and preparation method thereof - Google Patents
Cleaning agent for petroleum machinery equipment and preparation method thereof Download PDFInfo
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- CN105368593A CN105368593A CN201510806958.4A CN201510806958A CN105368593A CN 105368593 A CN105368593 A CN 105368593A CN 201510806958 A CN201510806958 A CN 201510806958A CN 105368593 A CN105368593 A CN 105368593A
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Abstract
The invention discloses a cleaning agent for petroleum machinery equipment and a preparation method thereof. The cleaning agent comprises the following raw materials by weight: 15-40 parts of Sapindus mukorossi pericarp extracted liquid, 13-28 parts of polyepoxysuccinic acid, 5-15 parts of polysorbate-80, and 3-8 parts of nonylphenol polyoxyethylene ether. The preparation method includes: subjecting Sapindus mukorossi pericarp to crushing, ultrasonic treatment and ethanol recovery to obtain Sapindus mukorossi pericarp extracted liquid; adding polysorbate-80 and nonylphenol polyoxyethylene ether into the Sapindus mukorossi pericarp extracted liquid, performing seal heating, then adding polyepoxysuccinic acid, and conducting cooling to room temperature, thus obtaining the cleaning agent for petroleum machinery equipment. The cleaning agent for petroleum machinery equipment provided by the invention has stable performance, is rust-proof and non-corrosive, and has a cleaning rate up to more than 98%. The cleaning agent provided by the invention not only has very strong cleaning, degreasing and derusting performance on the petroleum machinery equipment surface, but also has excellent surface polishing performance and surface protection performance, has significant cleaning effect on petroleum machinery equipment, and also has very strong practical value.
Description
Technical field
The present invention relates to a kind of device cleaning agent, specifically a kind of clean-out system for petroleum machinery equipment and preparation method thereof.
Background technology
The enterprises such as petroleum chemical plant, ethylene plant, oil recovery factory, oil transportation company, all need regularly to various equipment slightly being had the greasy dirt cleaning of viscosity.At present, clean-out system used is all extremely inflammable 93#, 97# or 120# gasoline, the easy presence of fire of execute-in-place, the serious harm person and property safety.
Summary of the invention
The object of the present invention is to provide a kind of stable performance, the clean-out system for petroleum machinery equipment that antirust, corrosion-free, cleaning rate is high and preparation method thereof, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
For a clean-out system for petroleum machinery equipment, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 15-40 part, poly-epoxy succinic acid 13-28 part, Tween-80 5-15 part, polyoxyethylene nonylphenol ether 3-8 part.
As the further scheme of the present invention: the described clean-out system for petroleum machinery equipment, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 25-35 part, poly-epoxy succinic acid 18-25 part, Tween-80 8-12 part, polyoxyethylene nonylphenol ether 4-7 part.
As the further scheme of the present invention: the described clean-out system for petroleum machinery equipment, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 30 parts, poly-epoxy succinic acid 22 parts, Tween-80 10 parts, polyoxyethylene nonylphenol ether 5 parts.
The preparation method of the described clean-out system for petroleum machinery equipment, is made up of following steps:
1) collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add its quality 5-10 ethanol doubly, then carry out supersound process, the condition of supersound process: ultrasonic frequency 100-150kHz, sonification power is 150-180W, and sonication treatment time is 30-50min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, filter residue quality 5-10 ethanol is doubly added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 40-50% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract;
2) Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 15-20min, Heating temperature is 55-60 DEG C, sealing is warming up to 80-82 DEG C again, add poly-epoxy succinic acid, and keep 5-10min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Amount of alcohol is the mass percent of ethanol in Seed of Chinese Soapberry Fruit peel extract.
The effect of each raw material in the present invention: Seed of Chinese Soapberry Fruit peel extract: Seed of Chinese Soapberry pericarp contains Seed of Chinese Soapberry Sesquiterpene glucoside (mukuroziside) I a, I b, II a, II b, sapindoside (mukurozisaponin) X, Y1, Y2, E, G etc.; For daily washing: tableware is clean, beauty treatment, hair washing, skin care etc.Poly-epoxy succinic acid (PESA) is a kind of without nitrogen, non-phosphorus organic compound, and have scale inhibitor double effects concurrently, biodegradability is got well and is applicable to high-alkali, high metal content water system, is a kind of green Water Treatment Chemicals.The deposition of PESA to calcium sulfate scale has threshold effect, and its scale inhibition performance increases along with the increase of chemical feeding quantity, and when arriving finite concentration, scale prevention ability no longer obviously increases.The effect that PESA hinders calcium carbonate scale is better than some conventional polycarboxylic acid, Sulfonates, polyphosphoric acid type Scale inhibitorss.Polysorbate 80 is nonionic surface active agent, has foreign odor, warm and micro-hardship.Be the O/W type emulsifying agent that a class is excellent, the change of high density ionogen and pH value is very little on the impact of its emulsifying capacity.Good emulsifying effect is all had to vegetables oil, mineral oil, animal grease etc.The nonionogenic tenside of condensation reaction under polyoxyethylene nonylphenol ether catalyst action.There is various different hydrophile-lipophile balance value (HLBvalue); Have been widely used at washing composition/printing and dyeing/chemical industry; There is good infiltration/emulsification/dispersion/antiacid/alkali resistant/anti-hard water/anti-reduction/resistance of oxidation.
Compared with prior art, the invention has the beneficial effects as follows:
Stable performance of the present invention, antirust, corrosion-free; Cleaning rate reaches more than 98%.The present invention not only has cleaning degreasing rust cleaning performance very by force to the surface of petroleum machinery equipment, also has preferably surface finish performance and surface protection performance, for the Be very effective of the cleaning of petroleum machinery equipment, has very strong practical value.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of clean-out system for petroleum machinery equipment, is made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 15 parts, poly-epoxy succinic acid 13 parts, Tween-80 5 parts, polyoxyethylene nonylphenol ether 3 parts.During preparation, collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add the ethanol of its quality 5 times, then carry out supersound process, the condition of supersound process: ultrasonic frequency 100kHz, sonification power is 150W, and sonication treatment time is 30min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, filter residue quality 5-10 ethanol is doubly added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 40% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract.Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 15min, Heating temperature is 55 DEG C, sealing is warming up to 80 DEG C again, add poly-epoxy succinic acid, and keep 5min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Embodiment 2
In the embodiment of the present invention, a kind of clean-out system for petroleum machinery equipment, is made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 40 parts, poly-epoxy succinic acid 28 parts, Tween-80 15 parts, polyoxyethylene nonylphenol ether 8 parts.During preparation, collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add the ethanol of its quality 10 times, then carry out supersound process, the condition of supersound process: ultrasonic frequency 150kHz, sonification power is 180W, and sonication treatment time is 50min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, the ethanol of filter residue quality 10 times is added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 50% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract.Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 20min, Heating temperature is 60 DEG C, sealing is warming up to 82 DEG C again, add poly-epoxy succinic acid, and keep 10min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Embodiment 3
In the embodiment of the present invention, a kind of clean-out system for petroleum machinery equipment, is made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 25 parts, poly-epoxy succinic acid 18 parts, Tween-80 8 parts, polyoxyethylene nonylphenol ether 4 parts.During preparation, collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add the ethanol of its quality 6 times, then carry out supersound process, the condition of supersound process: ultrasonic frequency 110kHz, sonification power is 160W, and sonication treatment time is 35min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, the ethanol of filter residue quality 6 times is added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 43% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract.Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 16min, Heating temperature is 56 DEG C, sealing is warming up to 81 DEG C again, add poly-epoxy succinic acid, and keep 6min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Embodiment 4
In the embodiment of the present invention, a kind of clean-out system for petroleum machinery equipment, is made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 35 parts, poly-epoxy succinic acid 25 parts, Tween-80 12 parts, polyoxyethylene nonylphenol ether 7 parts.During preparation, collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add the ethanol of its quality 9 times, then carry out supersound process, the condition of supersound process: ultrasonic frequency 140kHz, sonification power is 170W, and sonication treatment time is 45min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, the ethanol of filter residue quality 9 times is added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 48% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract.Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 19min, Heating temperature is 59 DEG C, sealing is warming up to 81 DEG C again, add poly-epoxy succinic acid, and keep 8min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Embodiment 5
In the embodiment of the present invention, a kind of clean-out system for petroleum machinery equipment, is made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 30 parts, poly-epoxy succinic acid 22 parts, Tween-80 10 parts, polyoxyethylene nonylphenol ether 5 parts.During preparation, collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add the ethanol of its quality 8 times, then carry out supersound process, the condition of supersound process: ultrasonic frequency 125kHz, sonification power is 165W, and sonication treatment time is 40min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, the ethanol of filter residue quality 7 times is added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 45% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract.Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 17min, Heating temperature is 57 DEG C, sealing is warming up to 81 DEG C again, add poly-epoxy succinic acid, and keep 7min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
Temperature of the present invention in use, need be risen to 40-45 DEG C and carry out cleaning petroleum machinery equipment again by the present invention.Use the clean-out system of above-described embodiment 1-5, indices such as cleaning rate, rust-preventing characteristic, stability, corrodibility etc. detect according to industry ordinary method, specific as follows:
Cleaning rate=wash greasy dirt weight/greasy dirt original weight amount.
Rust-preventing characteristic: first-surface is rustless, without the slight loss of gloss of considerable change; Secondary surface is without obviously becoming rusty or gently become rusty or light discolouration, uneven variable color; Three grades of surperficial big area corrosion phenomenas.
Stability: the composition of preparation is placed 4-6 and as a child observed solution delamination, stabilize to not stratified, not muddy, shakiness is decided to be layering or muddiness.
Corrodibility: carry out test after 24 hours, can not there is corrosion phenomenon in that tests exemplar.
Test through aforesaid method, use the clean-out system of above-described embodiment 1-5, degree of cleaning are as shown in table 1, and wherein comparative example is traditional clean-out system 93# gasoline.Concrete indices is as follows: outward appearance is homogeneous transparent liquid, without variable color layering, turbid phenomenon, low foam-non-foam; Cleaning rate is more than 98%, and rust-preventing characteristic is one-level, to equipment component non-corrosiveness.
Clean-out system for petroleum machinery equipment of the present invention; more traditional clean-out system; not only have the surface of petroleum machinery equipment and clean very by force degreasing rust cleaning performance; also there is preferably surface finish performance and surface protection performance; abandon conventional clean agent to the damage of petroleum machinery equipment surface or corrodibility; for the Be very effective of the cleaning of petroleum machinery equipment, there is very strong practical value.
Table 1
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. for a clean-out system for petroleum machinery equipment, it is characterized in that, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 15-40 part, poly-epoxy succinic acid 13-28 part, Tween-80 5-15 part, polyoxyethylene nonylphenol ether 3-8 part.
2. the clean-out system for petroleum machinery equipment according to claim 1, it is characterized in that, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 25-35 part, poly-epoxy succinic acid 18-25 part, Tween-80 8-12 part, polyoxyethylene nonylphenol ether 4-7 part.
3. the clean-out system for petroleum machinery equipment according to claim 2, it is characterized in that, be made up of the following raw material according to weight part: Seed of Chinese Soapberry Fruit peel extract 30 parts, poly-epoxy succinic acid 22 parts, Tween-80 10 parts, polyoxyethylene nonylphenol ether 5 parts.
4. a preparation method for the clean-out system for petroleum machinery equipment as described in as arbitrary in claim 1-3, is characterized in that, be made up of following steps:
1) collect Seed of Chinese Soapberry pericarp, clean rearmountedly to enter to pulverize in supper micron mill, cross 300 mesh sieves after pulverizing, obtained Seed of Chinese Soapberry powder; In Seed of Chinese Soapberry powder, add its quality 5-10 ethanol doubly, then carry out supersound process, the condition of supersound process: ultrasonic frequency 100-150kHz, sonification power is 150-180W, and sonication treatment time is 30-50min; Filter after supersound process for the first time, obtain filtrate and filter residue for the first time, filter residue quality 5-10 ethanol is doubly added in filter residue, carry out supersound process again, obtained second time filtrate after filtering, merge filtrate and second time filtrate for the first time, in vacuum tank, reclaiming ethanol to being 40-50% containing amount of alcohol, obtaining Seed of Chinese Soapberry Fruit peel extract;
2) Tween-80, polyoxyethylene nonylphenol ether are inserted in Seed of Chinese Soapberry Fruit peel extract, heated sealed stirs 15-20min, Heating temperature is 55-60 DEG C, sealing is warming up to 80-82 DEG C again, add poly-epoxy succinic acid, and keep 5-10min at this temperature, be then down to room temperature and namely obtain clean-out system for petroleum machinery equipment.
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| CN201510806958.4A CN105368593B (en) | 2015-11-22 | 2015-11-22 | A kind of cleaning agent and preparation method thereof for petroleum machinery equipment |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118896A (en) * | 2016-06-07 | 2016-11-16 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
| CN107164128A (en) * | 2017-05-08 | 2017-09-15 | 安徽海德石油化工有限公司 | A kind of petroleum-oil column cleaning agent |
| CN107858214A (en) * | 2017-11-29 | 2018-03-30 | 西安航空职业技术学院 | Degreasing cleaning agent for mechanical equipment and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632094A (en) * | 2004-11-10 | 2005-06-29 | 淄博西贝子化工有限公司 | Deoiling agent |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN104611162A (en) * | 2015-03-07 | 2015-05-13 | 孙华平 | Environment-friendly cleaning agent for mechanical equipment |
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2015
- 2015-11-22 CN CN201510806958.4A patent/CN105368593B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632094A (en) * | 2004-11-10 | 2005-06-29 | 淄博西贝子化工有限公司 | Deoiling agent |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN104611162A (en) * | 2015-03-07 | 2015-05-13 | 孙华平 | Environment-friendly cleaning agent for mechanical equipment |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106118896A (en) * | 2016-06-07 | 2016-11-16 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
| CN107164128A (en) * | 2017-05-08 | 2017-09-15 | 安徽海德石油化工有限公司 | A kind of petroleum-oil column cleaning agent |
| CN107858214A (en) * | 2017-11-29 | 2018-03-30 | 西安航空职业技术学院 | Degreasing cleaning agent for mechanical equipment and preparation method thereof |
| CN107858214B (en) * | 2017-11-29 | 2020-09-22 | 西安航空职业技术学院 | Degreasing cleaning agent for mechanical equipment and preparation method thereof |
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| CN105368593B (en) | 2018-07-27 |
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