CN110734817A - Scale remover for precision water system and preparation method thereof - Google Patents

Scale remover for precision water system and preparation method thereof Download PDF

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Publication number
CN110734817A
CN110734817A CN201911047447.3A CN201911047447A CN110734817A CN 110734817 A CN110734817 A CN 110734817A CN 201911047447 A CN201911047447 A CN 201911047447A CN 110734817 A CN110734817 A CN 110734817A
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China
Prior art keywords
water system
precision water
scale
scale remover
preparation
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Pending
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CN201911047447.3A
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Chinese (zh)
Inventor
桂成方
桂林
刘春花
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Hunan Jinyu Environment Protection Technology Co Ltd
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Hunan Jinyu Environment Protection Technology Co Ltd
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Priority to CN201911047447.3A priority Critical patent/CN110734817A/en
Publication of CN110734817A publication Critical patent/CN110734817A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3281Heterocyclic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses precision water system scale removers, which comprise, by weight, 13.3-16.8% of nicotinic acid, 8.0-10.3% of glacial acetic acid, 6.6-9.1% of ammonium bifluoride, 1.8-2.8% of sodium gluconate and the balance of water.

Description

Scale remover for precision water system and preparation method thereof
Technical Field
The invention belongs to the technical field of water treatment, and particularly relates to precision water system scale remover and a preparation method thereof.
Background
After the water cannot be boiled in daily life, equipment of a plurality of factories, restaurants and hotels also needs water, such as various common precision water systems of heat exchangers, cooling water towers, air conditioners, condensers and the like, after periods of operation and use, because impurities and microorganisms in the water are heated and deposited and adsorbed on heat exchange surfaces, the deposits are called scale, the composition of the scale is complex and generally consists of substances such as compounds, algae, silt and the like, after the scale is generated, the heat exchange efficiency of the equipment is reduced, and statistically, when the thickness of the scale reaches 0.1mm in the precision water systems of , the heat efficiency is reduced by about 5 percent, so the normal use of the equipment is directly influenced after the scale is generated, therefore, a plurality of methods are adopted to remove the scale, the manual scale removal is , but the manual scale removal is ineffective for the equipment with complex shape, while the chemical cleaning method of , which adopts common chemical cleaning agents, can remove the scale, needs professional knowledge, severely corrodes the equipment with thinner walls, and the is necessary for research and development of precision water systems.
Chinese patent CN 201010100925.5 discloses high-efficiency cooling system cleaning agents with spectrums, which comprise, by mass, 1-5% of organic acid, 0.5-3% of metal ion chelating agents, 0.5-2% of cleaning accelerators, 0.1-1% of corrosion and scale inhibition dispersing agents, 0.3-5% of degreasing agents and the balance of water, wherein the cleaning agents are safe to use, the cleaning time is 1-2 hours, the descaling rate is more than 90%, corrosion damage to a cooling system is greatly reduced, the organic acid is or two mixtures of sulfamic acid, citric acid, glycolic acid, oxalic acid and tartaric acid, the chelating agents are mixtures of ethylenediamine tetraacetic acid and diethylenetriaminepentaacetic acid, the cleaning accelerators are or two mixtures of ammonium bifluoride, sodium fluoride and potassium fluoride, and the corrosion and scale inhibition dispersing agents are composed of sodium gluconate, acrylic acid-methyl acrylate and styrene sulfonic acid-maleic anhydride.
Disclosure of Invention
In order to overcome the defects of the prior art, of the invention aims to provide kinds of precision water system descaling agents, which do not corrode equipment, have no odor, have a descaling rate of more than 96 percent, do not corrode a human body and have high descaling speed.
The second object of the present invention is to provide a method for preparing the above-mentioned scale remover for precision water system.
The descaling agent for the precision water system comprises the following components in percentage by weight:
the scale remover for the precision water system can also be added with 5.6 to 7.6 percent of hydrogen peroxide, and the concentration is 25 percent.
The precise water system scale remover is prepared from the following components in percentage by weight:
Figure BDA0002254479280000012
Figure BDA0002254479280000021
the invention utilizes hydrogen ions provided by glacial acetic acid and nicotinic acid to remove scale, ammonium bifluoride provides fluoride ions, and the sodium gluconate belongs to the effects of corrosion inhibitors and complexing agents and has strong permeability.
The invention discloses a preparation method of a precise water system scale remover, which comprises the following steps: weighing the components, blending, stirring and dissolving uniformly.
The application method of the precision water system scale remover comprises the following steps: and soaking the equipment to be descaled in the descaler of the precision water system, taking out the equipment after the dirt completely falls off, and washing the equipment by using clear water.
The descaling agent for the precision water system has the following beneficial effects: the scale removing agent does not corrode equipment, has no odor, has the scale removing rate of more than 96 percent, does not corrode a human body, and has high scale removing speed.
Detailed Description
The invention is further illustrated by examples which are not intended to be limiting.
Table 1 shows the formulations of examples 1 to 4 and comparative examples 1 to 2 in wt%.
TABLE 1 formulations of examples 1-4, comparative examples 1-2
Figure BDA0002254479280000022
The preparation method of the descaling agent for the precision water system comprises the following steps: the components are weighed, blended, stirred and dissolved uniformly.
The application method of the scale remover for the precision water system comprises the following steps: soaking equipment (boiler) to be descaled in the descaler of the precision water system, taking out after all the dirt falls off, and washing the equipment with clean water.
The use effects of the above examples and comparative examples are as follows:
Figure BDA0002254479280000031

Claims (4)

1, kinds of precision water system scale remover, which is characterized by comprising the following components by weight percentage:
Figure FDA0002254479270000011
2. the descaling agent for precision water systems as claimed in claim 1, wherein 5.6-7.6% of hydrogen peroxide is further added, and the concentration is 25%.
3. The descaling agent for precision water systems as claimed in claim 2, wherein the descaling agent is prepared from the following components:
Figure FDA0002254479270000012
4. the method for preparing the scale remover for the precision water system as claimed in claim 1, which comprises the following steps: weighing the components, blending, stirring and dissolving uniformly.
CN201911047447.3A 2019-10-30 2019-10-30 Scale remover for precision water system and preparation method thereof Pending CN110734817A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201911047447.3A CN110734817A (en) 2019-10-30 2019-10-30 Scale remover for precision water system and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201911047447.3A CN110734817A (en) 2019-10-30 2019-10-30 Scale remover for precision water system and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110734817A true CN110734817A (en) 2020-01-31

Family

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Country Status (1)

Country Link
CN (1) CN110734817A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1177977A (en) * 1995-02-01 1998-04-01 雷克特和科尔曼产品有限公司 Bleaning process and composition
CN101768529A (en) * 2010-01-25 2010-07-07 蓝星环境工程有限公司 Broad-spectrum and efficient cleaning agent for cooling system
CN105483718A (en) * 2016-01-19 2016-04-13 博罗县东明化工有限公司 Wash-whitening and descaling liquid and die-casting aluminum alloy pretreatment method
CN106118896A (en) * 2016-06-07 2016-11-16 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application
CN107321669A (en) * 2017-06-29 2017-11-07 杭州和家环境科技有限公司 A kind of central air conditioning water system cleaning method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1177977A (en) * 1995-02-01 1998-04-01 雷克特和科尔曼产品有限公司 Bleaning process and composition
CN101768529A (en) * 2010-01-25 2010-07-07 蓝星环境工程有限公司 Broad-spectrum and efficient cleaning agent for cooling system
CN105483718A (en) * 2016-01-19 2016-04-13 博罗县东明化工有限公司 Wash-whitening and descaling liquid and die-casting aluminum alloy pretreatment method
CN106118896A (en) * 2016-06-07 2016-11-16 安徽普瑞普勒传热技术有限公司 A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application
CN107321669A (en) * 2017-06-29 2017-11-07 杭州和家环境科技有限公司 A kind of central air conditioning water system cleaning method

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Application publication date: 20200131