CN110724607A - Shower room cleaning cream and preparation method thereof - Google Patents
Shower room cleaning cream and preparation method thereof Download PDFInfo
- Publication number
- CN110724607A CN110724607A CN201911119371.0A CN201911119371A CN110724607A CN 110724607 A CN110724607 A CN 110724607A CN 201911119371 A CN201911119371 A CN 201911119371A CN 110724607 A CN110724607 A CN 110724607A
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- China
- Prior art keywords
- shower room
- parts
- room cleaning
- stirring
- weight
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- 238000004140 cleaning Methods 0.000 title claims abstract description 102
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000006071 cream Substances 0.000 title claims description 13
- 239000000839 emulsion Substances 0.000 claims abstract description 60
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims abstract description 49
- 210000004080 milk Anatomy 0.000 claims abstract description 45
- 235000013336 milk Nutrition 0.000 claims abstract description 45
- 239000008267 milk Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 238000000227 grinding Methods 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 43
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 42
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 42
- 239000006185 dispersion Substances 0.000 claims description 38
- 239000003381 stabilizer Substances 0.000 claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 29
- 238000009775 high-speed stirring Methods 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 22
- 238000002156 mixing Methods 0.000 claims description 19
- 239000000377 silicon dioxide Substances 0.000 claims description 15
- 229920002125 Sokalan® Polymers 0.000 claims description 9
- 239000004584 polyacrylic acid Substances 0.000 claims description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims description 9
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 239000000176 sodium gluconate Substances 0.000 claims description 8
- 235000012207 sodium gluconate Nutrition 0.000 claims description 8
- 229940005574 sodium gluconate Drugs 0.000 claims description 8
- BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 claims description 7
- BEGBSFPALGFMJI-UHFFFAOYSA-N ethene;sodium Chemical group [Na].C=C BEGBSFPALGFMJI-UHFFFAOYSA-N 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- -1 isopropyl ammonium alkyl benzene Chemical class 0.000 claims description 3
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract description 24
- 239000011521 glass Substances 0.000 abstract description 13
- 235000006408 oxalic acid Nutrition 0.000 abstract description 8
- 239000012459 cleaning agent Substances 0.000 abstract description 6
- 230000035699 permeability Effects 0.000 abstract description 6
- 230000000149 penetrating effect Effects 0.000 abstract description 5
- 239000013043 chemical agent Substances 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 13
- 238000005202 decontamination Methods 0.000 description 6
- 230000003588 decontaminative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000005764 inhibitory process Effects 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- IQAIPUWCYPGRQL-UHFFFAOYSA-N 2-hydroxyacetic acid;hydrate Chemical compound O.OCC(O)=O IQAIPUWCYPGRQL-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The invention relates to the technical field of cleaning agents, in particular to a shower room cleaning emulsion and a preparation method thereof, wherein the shower room cleaning emulsion comprises the following raw materials in parts by weight: 15-30 parts of oxalic acid, 30-45 parts of glycolic acid, 15-30 parts of grinding agent, 5-15 parts of anionic surfactant, 5-15 parts of nonionic surfactant, 0.05-0.5 part of essence and 5-15 parts of deionized water. The shower room cleaning emulsion disclosed by the invention is fragrant in smell, free of pungent chemical agent smell, capable of removing alkaline water scales through acidity of oxalic acid and glycolic acid, and capable of penetrating a surfactant and an abrasive to the deep layer of dirt by utilizing the permeability of glycolic acid, capable of penetrating into the bottom of the glass stain and capable of breaking down various water scales and scales, strong in detergency, high in cleaning efficiency and high in storage stability. The preparation method of the shower room cleaning milk is simple to operate, convenient to control, low in production cost, high in product quality, stable in performance of the prepared cleaning milk, strong in detergency and capable of being used for large-scale production.
Description
Technical Field
The invention relates to the technical field of cleaning agents, and particularly relates to a shower room cleaning emulsion and a preparation method thereof.
Background
At present, the shower room glass has long time due to long-term contact with cold and hot water of a shower and cleaning agents such as shower gel shampoo and the like, and because scale soap scum (if a large amount of mineral substances exist in a hot spring place) and the like are continuously superposed, the dirt is difficult to completely remove, so that the attractiveness of the shower room and the pleasure of a user are seriously influenced.
The water scale in the shower room is an alkaline substance, but the traditional glass cleaning agent in the market at present is a neutral cleaning agent, the cleaning force is not enough, the cleaning agent is mainly liquid basically, stable milky viscous solution cannot be formed, the wall-hanging contact time with the glass is short, the detergency is reduced, and the cleaning effect is not obvious.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide the shower room cleaning milk which is fragrant in smell, free of pungent chemical agent smell, capable of penetrating into the bottom of glass stains to break down various scales and scales, strong in detergency, high in cleaning efficiency and high in storage stability.
The invention also aims to provide a preparation method of the shower room cleaning milk, which has the advantages of simple operation, convenient control, low production cost and high product quality, ensures that the prepared cleaning milk has stable performance and strong detergency and can be used for large-scale production.
The purpose of the invention is realized by the following technical scheme: a shower room cleaning emulsion comprises the following raw materials in parts by weight:
the cleaning milk prepared by the materials has fragrant smell and no pungent chemical agent smell, alkaline water scale is removed by acidity of oxalic acid and glycolic acid, the adopted glycolic acid has smaller molecular weight than oxalic acid and strong permeability, the surfactant and the grinding agent can permeate into the deep layer of the dirt while the dirt is removed by utilizing the acidity of the glycolic acid, the water scale and the scale deposit can be quickly disintegrated, and the decontamination efficiency is high; preferably, glycolic acid with the mass fraction of 60-70 wt% is adopted, so that the penetrability of the cleansing milk can be improved, the moisture content in the cleansing milk can be reduced, the stability of the cleansing milk is improved, the problem of few thickening agents suitable for neutral meta-acid emulsion in the application is solved, meanwhile, the emulsion containing high-concentration glycolic acid is easy to attach on dirt of glass, the using amount is less compared with the existing liquid-like cleansing agent, the sewage discharge after cleansing is reduced, and the environmental protection is facilitated.
The adopted anionic surfactant and the nonionic surfactant are compounded for use, so that the compatibility is good, the stability is high, the cleaning emulsion can have better wettability, emulsibility and cleaning performance after compounding, the adopted nonionic surfactant has good permeability and bactericidal performance, the effect of improving the penetration of the cleaning emulsion to deep dirt can be improved, the bactericidal effect can be achieved, and the better cleaning effect can be realized.
Preferably, the anionic surfactant is isopropyl ammonium alkyl benzene sulfonate; compared with the traditional dodecyl benzene sulfonate, the dodecyl benzene sulfonate has stronger cleaning power, is easier to wash for the second time by using clean water, is more suitable for the requirement of a shower room, is used by being compounded with a nonionic surfactant, and can improve the permeability and the cleaning strength of the cleaning emulsion.
Preferably, the nonionic surfactant is straight-chain fatty alcohol polyoxyethylene ether or isomeric alcohol polyoxyethylene ether.
Preferably, the linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
Preferably, the isomeric alcohol polyoxyethylene ether is isomeric tridecanol polyoxyethylene ether.
Preferably, the grinding agent is silicon dioxide with the mesh number of 100-400.
According to the invention, by adopting the silicon dioxide with a specific mesh number, the particle molecules of the silicon dioxide can effectively increase the friction force between the emulsion and the water scale, so that dirt can be effectively removed without damaging the glass, and the glass is bright as new after being cleaned; and the abrasive below 100 meshes is adopted, the risk of scraping glass is increased by 10%, the dirt removal rate can only reach 90%, the abrasive above 400 meshes can reach more than 99%, but the stability in the formula is low, the situation of serious layering of the cleaning milk product occurs within 1 hour, and when the mesh number is 400 meshes, the requirements of stability, cleaning power and the like can be simultaneously met, so that the viscosity of the cleaning milk at 25 ℃ can reach 50000mPa & s under the condition of no thickener.
Preferably, the shower room cleaning milk also comprises 3-8 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
the composite dispersion stabilizer prepared by adopting the materials has good compatibility and high stability, can be uniformly mixed and dispersed with other materials of the cleaning milk, and improves the dispersibility of the powdery grinding agent and other materials in the cleaning milk and the stability of the cleaning milk. The adopted polyacrylic acid has better dispersibility and scale inhibition performance, improves the scale inhibition performance of the cleaning milk, and delays the deposition of scale and other dirt on the glass again; the adopted sodium gluconate has excellent corrosion and scale inhibition effects, improves the decontamination and scale inhibition performance of the cleaning milk, delays the deposition of water scale and other dirt on glass again, and has better stability for the cleaning milk containing the deionized water component; the adopted sodium citrate can replace the traditional sodium tripolyphosphate to be used as an auxiliary agent of a non-toxic detergent, and can form a stable complex with dirt (especially calcium ions, magnesium ions and the like in scale dirt), so that the dirt is removed, and the dirt-removing capacity of the cleaning milk is improved; the adopted sodium ethylene diamine tetramethylene phosphonate has better stability and improves the decontamination stability of the cleaning milk; the adopted polyethylene glycol has good water solubility, has better compatibility with other materials, and can improve the wettability and the dispersibility of the cleaning milk; the MJ530 type complex dispersion stabilizer mainly contains organic fluorine ions and nano silicon-titanium ion ligands, has an interface wetting function and excellent dispersion stability, and improves the dispersibility and wettability of the cleaning emulsion.
Preferably, the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid and polyethylene glycol according to the parts by weight, then adding sodium gluconate and sodium ethylene diamine tetramethylene phosphonate, stirring for 8-15min under the condition that the ultrasonic frequency is 12000-18000Hz, finally adding MJ530 type complex dispersion stabilizer, and homogenizing for 3-10min to obtain the composite dispersion stabilizer.
According to the invention, the polyacrylic acid and the polyethylene glycol are mixed, the compatibility of the polyacrylic acid and the polyethylene glycol with other materials is high, the dispersibility and the mixing degree of the sodium gluconate and the sodium ethylene diamine tetramethylene phosphonate can be improved, the materials can be fully dispersed in a system by adopting an ultrasonic stirring mode, and finally the MJ530 type complex dispersion stabilizer is added and homogenized, so that the prepared composite dispersion stabilizer has good interface wettability and high dispersion stability.
The other purpose of the invention is realized by the following technical scheme: a preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
Preferably, in the step (1), the stirring speed when the grinding agent is added is 1500-2200rpm, and the grinding agent is added and then stirred for 30-50 min; in the step (2), the rotation speed of the high-speed stirring is 2000-2300 rpm.
The preparation method disclosed by the invention is simple to operate, convenient to control, low in production cost and high in product quality, so that the prepared cleaning milk is stable in performance and strong in detergency, and can be used for large-scale production; the method comprises the steps of adding glycolic acid into deionized water to form a system with high solubility and good permeability, adding an abrasive, promoting the dispersibility of the abrasive in the glycolic acid-water system under the high-speed stirring state to enable the abrasive to be in a white viscous emulsion A after being completely dispersed, and adding oxalic acid, an anionic surfactant, a nonionic surfactant and essence to improve the dispersibility of materials under the high-speed stirring state.
The invention has the beneficial effects that: the shower room cleaning milk disclosed by the invention is fragrant in smell, free of pungent chemical agent smell, capable of removing alkaline water scales through acidity of oxalic acid and glycolic acid, and capable of penetrating a surfactant and an abrasive to the deep layer of dirt by utilizing the permeability of glycolic acid, capable of penetrating into the bottom of the glass stain, capable of breaking down various water scales and scale deposits, strong in detergency, high in cleaning efficiency and high in storage stability, and suitable for cleaning heavy water scales and heavy soap scale articles in families, hotels, hot springs and other industries.
The preparation method of the shower room cleaning milk has the advantages of simple operation, convenient control, low production cost and high product quality, ensures that the prepared cleaning milk has stable performance and strong detergency, and can be used for large-scale production.
Detailed Description
The present invention will be further described with reference to the following examples for facilitating understanding of those skilled in the art, and the description of the embodiments is not intended to limit the present invention.
Example 1
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silicon dioxide with the mesh number of 100.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1500rpm when the grinding agent is added, and the grinding agent is added and stirred for 50 min; in the step (2), the rotation speed of high-speed stirring is 2000 rpm.
Example 2
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
Example 3
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silicon dioxide with the mesh number of 400.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 2200rpm when the grinding agent is added, and the grinding agent is added and stirred for 30 min; in the step (2), the rotation speed of high-speed stirring is 2300 rpm.
Example 4
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silicon dioxide with the mesh number of 100.
The shower room cleaning milk also comprises 3 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid and polyethylene glycol according to weight parts, adding sodium gluconate and sodium ethylene diamine tetramethylene phosphonate, stirring for 15min under the condition that the ultrasonic frequency is 12000Hz, finally adding MJ530 type complex dispersion stabilizer, and homogenizing for 3min to obtain the composite dispersion stabilizer.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1500rpm when the grinding agent is added, and the grinding agent is added and stirred for 50 min; in the step (2), the rotation speed of high-speed stirring is 2000 rpm.
Example 5
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
The shower room cleaning milk also comprises 5 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid and polyethylene glycol according to weight parts, adding sodium gluconate and sodium ethylene diamine tetramethylenephosphonate, stirring for 12min under the condition that the ultrasonic frequency is 15000Hz, finally adding MJ530 type complex dispersion stabilizer, and homogenizing for 6min to obtain the composite dispersion stabilizer.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
Example 6
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silicon dioxide with the mesh number of 400.
The shower room cleaning cream also comprises 8 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid and polyethylene glycol according to weight parts, adding sodium gluconate and sodium ethylene diamine tetramethylene phosphonate, stirring for 8min under the ultrasonic frequency of 18000Hz, finally adding MJ530 type complex dispersion stabilizer, and homogenizing for 10min to obtain the composite dispersion stabilizer.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 2200rpm when the grinding agent is added, and the grinding agent is added and stirred for 30 min; in the step (2), the rotation speed of high-speed stirring is 2300 rpm.
Comparative example 1
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
Comparative example 2
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
Comparative example 3
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
Comparative example 4
A shower room cleaning emulsion comprises the following raw materials in parts by weight:
the nonionic surfactant is straight-chain fatty alcohol-polyoxyethylene ether.
The linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
The grinding agent is silica with the mesh number of 250.
The shower room cleaning milk also comprises 5 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid, sodium hydroxide and water according to parts by weight, then adding sodium gluconate, sodium citrate and tetrasodium ethylene diamine tetraacetate, and stirring for 12min under the condition that the ultrasonic frequency is 15000Hz to prepare the composite dispersion stabilizer.
A preparation method of the shower room cleaning milk comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
In the step (1), the stirring speed is 1800rpm when the grinding agent is added, and the grinding agent is added and stirred for 40 min; in the step (2), the rotation speed of high-speed stirring is 2150 rpm.
The detergency of the cleaning milks obtained in examples 1 to 5 and comparative examples 1 to 4 was measured by the method of GB/T9985-2000 appendix B, and the detergency of mechanical cleaning of glass sheets for removing dirt was evaluated.
Wherein, the artificial dirt adopts the following formula:
| name (R) | Weight/g | Name (R) | Weight/g |
| Diammonium hydrogen phosphate | 15.0 | Milk powder | 15.0 |
| Sodium phosphate | 7.5 | Calcium stearate | 5.0 |
| Thiourea | 5.0 | Standard loess | 5.0 |
| Urea | 10.0 | 2500mg/kg hard water | 75.0 |
| Egg | 24.2 |
Wherein the standard loess comprises 54-72% of silicon dioxide, 10-14% of aluminum oxide, 4-9% of calcium oxide and 0.3-5.0% of ferric oxide; the hard water is composed of 16.7g of CaCl2And 24.7gMg2SO4·7H20, preparing 10L.
The test results are shown below:
| test items | Decontamination rate/%) |
| Example 1 | 92.8 |
| Example 2 | 93.2 |
| Example 3 | 92.4 |
| Example 4 | 96.5 |
| Example 5 | 98.1 |
| Example 5 | 96.8 |
| Comparative example 1 | 87.8 |
| Comparative example 2 | 88.2 |
| Comparative example 3 | 94.9 |
| Comparative example 4 | 96.1 |
The comparison of the data shows that the shower room cleaning emulsion has strong dirt-removing capacity and can break various water scales and dirt; compared with the cleaning milk prepared by the comparative example 1, the alkaline cleaning milk is formed by replacing formic acid and glycolic acid with the same amount of ammonium bicarbonate, and the cleaning capacity of the alkaline cleaning milk is obviously reduced. The comparative example 2 adopts the same amount of formic acid to replace oxalic acid, so that the cleaning capability is obviously reduced, and the invention can achieve better decontamination and cleaning effects by compounding the oxalic acid and the glycollic acid.
In contrast, the composite dispersion stabilizing dispersant in comparative example 3 is not added, the composite dispersion stabilizing dispersant in comparative example 4 is alkaline, and the cleaning ability of examples 3-4 is obviously reduced, which shows that the composite dispersion stabilizing dispersant compounded by the invention can improve the dispersibility and stability of the materials and the decontamination performance of the materials.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.
Claims (10)
1. A shower room cleaning cream is characterized in that: the feed comprises the following raw materials in parts by weight:
2. the shower room cleaning cream as claimed in claim 1, characterized in that: the anionic surfactant is isopropyl ammonium alkyl benzene sulfonate.
3. The shower room cleaning cream as claimed in claim 1, characterized in that: the nonionic surfactant is straight-chain fatty alcohol polyoxyethylene ether or isomeric alcohol polyoxyethylene ether.
4. The shower room cleaning cream as claimed in claim 3, characterized in that: the linear fatty alcohol-polyoxyethylene ether is AEO-7 type fatty alcohol-polyoxyethylene ether.
5. The shower room cleaning cream as claimed in claim 3, characterized in that: the isomeric alcohol polyoxyethylene ether is isomeric tridecanol polyoxyethylene ether.
6. The shower room cleaning cream as claimed in claim 1, characterized in that: the grinding agent is silicon dioxide with the mesh number of 100-400.
7. The shower room cleaning cream as claimed in claim 1, characterized in that: the shower room cleaning cream also comprises 3-8 parts of composite dispersion stabilizer, wherein each part of the composite dispersion stabilizer comprises the following raw materials in parts by weight:
8. the shower room cleaning cream as claimed in claim 7, characterized in that: the composite dispersion stabilizer is prepared by the following steps: mixing polyacrylic acid and polyethylene glycol according to the parts by weight, then adding sodium gluconate and sodium ethylene diamine tetramethylene phosphonate, stirring for 8-15min under the condition that the ultrasonic frequency is 12000-18000Hz, finally adding MJ530 type complex dispersion stabilizer, and homogenizing for 3-10min to obtain the composite dispersion stabilizer.
9. A method for preparing a shower room cleaning cream as claimed in any one of claims 1 to 8, characterized in that: the method comprises the following steps:
step (1): mixing deionized water and glycolic acid according to parts by weight, adding an abrasive under the condition of high-speed stirring, and continuously stirring and dispersing to obtain white viscous emulsion A;
step (2): adding the rest materials into the emulsion A prepared in the step (1) according to the parts by weight, and finally stirring and dispersing at a high speed to prepare the shower room cleaning emulsion.
10. The preparation method of the shower room cleaning milk according to claim 9, characterized in that: in the step (1), the stirring speed is 1500-; in the step (2), the rotation speed of the high-speed stirring is 2000-2300 rpm.
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| CN114480029A (en) * | 2021-12-22 | 2022-05-13 | 宁波小懒科技有限公司 | Cleaning agent |
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