CN116410822A - Environment-friendly cleaning degreasing agent - Google Patents
Environment-friendly cleaning degreasing agent Download PDFInfo
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- CN116410822A CN116410822A CN202310334185.9A CN202310334185A CN116410822A CN 116410822 A CN116410822 A CN 116410822A CN 202310334185 A CN202310334185 A CN 202310334185A CN 116410822 A CN116410822 A CN 116410822A
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- 238000005237 degreasing agent Methods 0.000 title claims abstract description 43
- 239000013527 degreasing agent Substances 0.000 title claims abstract description 36
- 238000004140 cleaning Methods 0.000 title claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 81
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 69
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003921 oil Substances 0.000 claims abstract description 21
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 19
- 244000131522 Citrus pyriformis Species 0.000 claims abstract description 19
- 239000010773 plant oil Substances 0.000 claims abstract description 19
- 239000002781 deodorant agent Substances 0.000 claims abstract description 16
- 240000000560 Citrus x paradisi Species 0.000 claims abstract description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 13
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 13
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 13
- 239000004334 sorbic acid Substances 0.000 claims abstract description 13
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims description 64
- 238000010438 heat treatment Methods 0.000 claims description 38
- 238000005303 weighing Methods 0.000 claims description 28
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 20
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 20
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 20
- 239000000052 vinegar Substances 0.000 claims description 20
- 235000021419 vinegar Nutrition 0.000 claims description 20
- 239000011259 mixed solution Substances 0.000 claims description 18
- 238000009835 boiling Methods 0.000 claims description 16
- 150000002191 fatty alcohols Chemical class 0.000 claims description 16
- 241000196324 Embryophyta Species 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 14
- -1 phospholipid compound Chemical class 0.000 claims description 11
- 239000006000 Garlic extract Substances 0.000 claims description 10
- 239000012459 cleaning agent Substances 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 230000004927 fusion Effects 0.000 claims description 10
- 235000020706 garlic extract Nutrition 0.000 claims description 10
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 10
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 239000003899 bactericide agent Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000341 volatile oil Substances 0.000 claims description 9
- 244000060011 Cocos nucifera Species 0.000 claims description 8
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000012875 nonionic emulsifier Substances 0.000 claims description 5
- 238000005238 degreasing Methods 0.000 claims description 4
- 239000012634 fragment Substances 0.000 claims description 3
- 239000008149 soap solution Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 10
- 238000000926 separation method Methods 0.000 abstract description 5
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000004519 grease Substances 0.000 abstract description 2
- 235000019198 oils Nutrition 0.000 abstract 1
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
- 239000008158 vegetable oil Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses an environment-friendly cleaning degreasing agent, which comprises the following components in parts by mass: and (2) a surfactant: 40-150 parts of pure water: 30-80 parts of an emulsifying agent: 10-50 parts of ethanol: 10-50 parts of auxiliary oil removal liquid: 20-50 parts of sodium percarbonate: 10-30 parts of deodorant: 10-40 parts of release liquid: 20-40 parts of plant oil removal liquid: 10-30 parts of grapefruit peel: 1-5 parts, the beneficial effects of the invention are as follows: through adding the vegetable oil removal liquid, realized extracting the vegetable liquid in orange peel, the lemon peel, further mix with citric acid and boil, carry out intensive mixing with citric acid, utilize the vegetable liquid to carry out the grease separation, improved the abluent efficiency of deoiling, through having added auxiliary liquid, realized utilizing triethanolamine, sorbic acid to carry out the deoiling operation, more environmental protection does not have the risk of corroding.
Description
Technical Field
The invention relates to the technical field of oil removal agents, in particular to an environment-friendly cleaning oil removal agent.
Background
The oil removing agent is a complex mixture of water-based organic and inorganic chemicals, and is a novel industrial oil removing agent developed by utilizing the principles of emulsification and saponification. The cleaning agent has wide application in the industrial fields of metal processing, food, textile, traffic, ships, buildings, electric appliances, medicines, chemical industry and the like, and the cleaning purpose is consistent although the cleaning surface matrixes are different, so that the cleanliness of the surfaces of the matrixes is recovered and the integrity of the surfaces of the matrixes is maintained, and the cleaning agent is classified according to the characteristics: 1. the solvent-based degreasing agent is usually a degreasing agent which is insoluble in water and cannot be diluted with water. Such as FRB-1.1, FRB-101, FRB-111, FRB-121, FRB-122, FRB-1.1, F, FRB-662, FRB-663, which are full of industrial substitutes for trichloroethylene; conventionally used kerosene, diesel oil, gasoline, trichloroethylene, trichloroethane, white oil and the like belong to solvent degreasing agents; 2. the water-based degreasing agent is soluble in water and can be diluted by adding water. For example, the water-based degreasing agents comprise a high-efficiency water-based degreasing agent WP-751, a neutral degreasing agent WHC-1, a weak alkaline degreasing agent WHC-2, an alkaline degreasing agent WHC-5, an acidic degreasing agent WP-20 and the like. 2. Classifying 1 according to pH value, and an acidic degreasing agent, namely a degreasing agent with the pH value lower than 7; 2. neutral degreasing agent, which means a degreasing agent having a pH of about 7; 3. the alkaline degreasing agent is a degreasing agent with the PH value being more than 7;
in the existing cleaning degreasing agents, most of the degreasing agents contain organic acids, the organic acids are easy to cause corrosion of equipment, the degreasing effect is not good when the cleaning degreasing agents are used, the cleaning degreasing agents are not environment-friendly, and corrosion damage is large when the cleaning degreasing agents are used for a long time.
Disclosure of Invention
The invention aims to provide an environment-friendly cleaning degreasing agent for solving the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions: an environment-friendly cleaning degreasing agent comprises the following components in parts by mass: and (2) a surfactant: 40-150 parts of pure water: 30-80 parts of an emulsifying agent: 10-50 parts of ethanol: 10-50 parts of auxiliary oil removal liquid: 20-50 parts of sodium percarbonate: 10-30 parts of deodorant: 10-40 parts of release liquid: 20-40 parts of plant oil removal liquid: 10-30 parts of grapefruit peel: 1-5 parts of auxiliary liquid: 5-9 parts of bactericide: 1-8 parts.
Preferably, the surfactant is a mixture of fatty alcohol polyoxyethylene ether and coco diethanolamide.
Preferably, the emulsifier is one of a phospholipid compound and a nonionic emulsifier, and the auxiliary oil removal liquid is one of essential oil and soap solution.
Preferably, the deodorant is a natural plant deodorant, and the bactericide is garlic extract.
Preferably, the preparation method of the surfactant specifically comprises the following steps:
a1, weighing fatty alcohol polyoxyethylene ether and coco diethanolamide, heating the fatty alcohol polyoxyethylene ether to 50-75 ℃, and then cooling to 30-40 ℃;
and A2, adding coconut diethanolamide into the cooled fatty alcohol-polyoxyethylene ether, uniformly stirring, heating to 50-65 ℃, and cooling to room temperature to obtain the surfactant.
Preferably, the preparation method of the release liquid specifically comprises the following steps:
b1, weighing white vinegar and baking soda, pouring half of the white vinegar into a container, and adding the baking soda into the container to mix with the white vinegar to obtain a first mixed solution;
and B2, heating the first mixed solution to the temperature of 60-80 ℃, directly adding the rest white vinegar after the temperature is reached, and stopping heating and stirring for 20-40min to obtain the release liquid.
Preferably, the preparation method of the plant oil removal liquid specifically comprises the following steps:
c1, weighing orange peel, lemon peel and citric acid, wherein the ratio of the orange peel to the lemon peel to the citric acid liquid is 1:1:2, crushing the orange peel and the lemon slices to 20-40 meshes to obtain crushed lumps:
and C2, adding the fragments into citric acid liquid for boiling, filtering impurities after boiling for 10-30min to obtain the plant oil removal liquid.
Preferably, the grapefruit peel is subjected to washing, sun drying and crushing treatment.
Preferably, the preparation method of the auxiliary liquid specifically comprises the following steps:
d1, weighing triethanolamine, sorbic acid and deionized water, adding the triethanolamine into the deionized water, and stirring by a stirring kettle, wherein the rotating speed of the stirring kettle is 500-800rpm, and the stirring time is 20-40min;
d2, adding sorbic acid into the stirring kettle after stirring is completed, wherein the rotating speed of the stirring kettle is 300-700rpm, and the stirring time is 10-40min, so as to obtain a fusion solution;
and D3, heating and stirring the fusion solution at the heating temperature of 50-70 ℃ for 1-2 hours to obtain auxiliary liquid.
Preferably, the ratio of the emulsifier to the ethanol is 1:1.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the disclosure.
Compared with the prior art, the invention has the beneficial effects that: through adding plant deoiling liquid, realized extracting the vegetable liquid in orange peel, the lemon peel, further mix boiling with citric acid, carry out intensive mixing with citric acid, utilize vegetable liquid to carry out the grease separation, the abluent efficiency of deoiling has been improved, through having added auxiliary liquid, realized utilizing triethanolamine, sorbic acid to carry out the deoiling operation, more environmental protection, there is not the risk of corroding, through having added the emulsifier, the emulsifier is one of phospholipid compound and nonionic emulsifier, carry out emulsification treatment to the surface greasy dirt, be convenient for break away from to the greasy dirt better, deoiling stability has been improved.
Detailed Description
Example 1:
the environment-friendly cleaning degreasing agent provided by the embodiment of the invention comprises the following components in parts by mass: and (2) a surfactant: 40-150 parts of pure water: 30-80 parts of an emulsifying agent: 10-50 parts of ethanol: 10-50 parts of auxiliary oil removal liquid: 20-50 parts of sodium percarbonate: 10-30 parts of deodorant: 10-40 parts of release liquid: 20-40 parts of plant oil removal liquid: 10-30 parts of grapefruit peel: 1-5 parts of auxiliary liquid: 5-9 parts of bactericide: 1-8 parts of plant oil removal liquid is added, so that plant liquid in orange peel and lemon peel is extracted, further mixed with citric acid for boiling, fully mixed with citric acid, and oil and fat separation is performed by using the plant liquid, and the oil removal cleaning efficiency is improved.
Example 2:
the surfactant is a mixture of fatty alcohol polyoxyethylene ether and coco diethanolamide, and the fatty alcohol polyoxyethylene ether and coco diethanolamide are added to reduce the adsorptivity of oil stains, facilitate the separation of the oil stains and improve the oil removal efficiency.
Wherein, the emulsifier is one of phospholipid compound and nonionic emulsifier, and auxiliary degreasing liquid is one of essential oil and soap solution, and the emulsifier is one of phospholipid compound and nonionic emulsifier, and the surface greasy dirt is emulsified, is convenient for break away from better to the greasy dirt, has improved deoiling stability.
Wherein the deodorant is natural plant deodorant, the bactericide is garlic extract, and the bactericide is garlic extract by adding the bactericide, and the bactericide is sterilized when the deoiling agent is used.
The preparation method of the surfactant specifically comprises the following steps:
a1, weighing fatty alcohol polyoxyethylene ether and coco diethanolamide, heating the fatty alcohol polyoxyethylene ether to 50-75 ℃, and then cooling to 30-40 ℃;
a2, adding coconut diethanolamide into the cooled fatty alcohol-polyoxyethylene ether, uniformly stirring, heating to 50-65 ℃, and cooling to room temperature to obtain a surfactant, wherein the adsorbability of oil stains is reduced by adding the fatty alcohol-polyoxyethylene ether and the coconut diethanolamide, so that the oil stains are conveniently separated, and the oil removal efficiency is improved.
The preparation method of the release liquid specifically comprises the following steps:
b1, weighing white vinegar and baking soda, pouring half of the white vinegar into a container, and adding the baking soda into the container to mix with the white vinegar to obtain a first mixed solution;
and B2, heating the first mixed solution to the temperature of 60-80 ℃, directly adding the rest white vinegar after the temperature is reached, and stopping heating and stirring for 20-40min to obtain the release liquid.
The preparation method of the plant oil removal liquid specifically comprises the following steps:
c1, weighing orange peel, lemon peel and citric acid, wherein the ratio of the orange peel to the lemon peel to the citric acid liquid is 1:1:2, crushing the orange peel and the lemon slices to 20-40 meshes to obtain crushed lumps:
c2, adding the fragments into citric acid liquid for boiling, filtering impurities after boiling for 10-30min to obtain plant oil removal liquid, and adding the plant oil removal liquid to extract the plant liquid in orange peel and lemon peel, further mixing with the citric acid for boiling, fully mixing with the citric acid, and utilizing the plant liquid for oil separation, thereby improving the oil removal cleaning efficiency.
Wherein, the grapefruit peel is subjected to washing, sun drying and crushing treatment.
The preparation method of the auxiliary liquid specifically comprises the following steps:
d1, weighing triethanolamine, sorbic acid and deionized water, adding the triethanolamine into the deionized water, and stirring by a stirring kettle, wherein the rotating speed of the stirring kettle is 500-800rpm, and the stirring time is 20-40min;
d2, adding sorbic acid into the stirring kettle after stirring is completed, wherein the rotating speed of the stirring kettle is 300-700rpm, and the stirring time is 10-40min, so as to obtain a fusion solution;
and D3, heating and stirring the fusion solution, wherein the heating temperature is 50-70 ℃, stirring for 1-2 hours to obtain auxiliary liquid, and adding the auxiliary liquid to realize oil removal operation by using triethanolamine and sorbic acid, so that the method is more environment-friendly and has no corrosion risk.
Wherein, the ratio of the emulsifier to the ethanol is 1:1, which is convenient for better matching with the ethanol and improves the stability.
Example 3:
an environment-friendly cleaning degreasing agent comprises the following components in parts by mass: and (2) a surfactant: 40 parts of pure water: 30 parts of a phospholipid compound: 10 parts of ethanol: 10 parts of essential oil: 20 parts of sodium percarbonate: 10 parts of natural plant deodorant: 10 parts of release liquid: 20 parts of plant oil removal liquid: 10 parts of grapefruit peel: 1 part of auxiliary liquid: 5 parts of garlic extract: 1 part.
The preparation method of the environment-friendly cleaning degreasing agent specifically comprises the following steps:
s1, weighing fatty alcohol polyoxyethylene ether and cocoanut acid diethanolamide, heating the fatty alcohol polyoxyethylene ether to 50 ℃, then cooling to 30 ℃, adding cocoanut acid diethanolamide into the cooled fatty alcohol polyoxyethylene ether, uniformly stirring, heating to 50 ℃, then cooling to room temperature to obtain a surfactant, weighing the surfactant, pure water and a phospholipid compound, mixing the surfactant and the pure water, adding the phospholipid compound, heating to 50 ℃ during mixing, and obtaining a first mixed solution;
s2, weighing white vinegar and baking soda, pouring half of the white vinegar into a container, adding the baking soda into the container to mix with the white vinegar to obtain a first mixed solution, heating the first mixed solution to the temperature of 60 ℃, directly adding the rest white vinegar after reaching the temperature, stopping heating and stirring for 20 min to obtain a release liquid, weighing essential oil, sodium percarbonate and the release liquid, mixing the essential oil with the release liquid, heating to the temperature of 50 ℃, immediately cooling to the temperature of 35 ℃ after reaching the heating temperature, adding sodium percarbonate, continuously stirring uniformly, and adding into the first mixed solution to obtain a second mixed solution;
s3, weighing orange peel, lemon peel and citric acid, wherein the ratio of the orange peel to the lemon peel to the citric acid liquid is 1:1:2, crushing the orange peel and the lemon slices to 20 meshes to obtain crushed blocks, adding the crushed blocks into the citric acid liquid for boiling, filtering impurities after boiling for 10 min to remove the impurities to obtain plant oil removal liquid, weighing the plant oil removal liquid and the grapefruit peel, cleaning, sun drying and crushing the grapefruit peel, pouring the grapefruit peel into the plant oil removal liquid for boiling, cooling at room temperature after boiling, adding the second mixed liquid into the third mixed liquid, and uniformly stirring to obtain the third mixed liquid;
s4, weighing triethanolamine, sorbic acid and deionized water, adding the triethanolamine into the deionized water, stirring the mixture through a stirring kettle, wherein the rotation speed of the stirring kettle is 500rpm, the stirring time is 20 min, adding the sorbic acid into the stirring kettle after stirring is completed, the rotation speed of the stirring kettle is 300rpm, the stirring time is 10 min, obtaining a fusion solution, heating and stirring the fusion solution, the heating temperature is 50 ℃, stirring for 1h to obtain an auxiliary solution, weighing ethanol, a natural plant deodorant, the auxiliary solution and a garlic extract, adding the ethanol, the natural plant deodorant and the auxiliary solution into the third mixed solution, heating the mixture to 60 ℃, keeping the temperature for 1h, adding the garlic extract, and uniformly stirring to obtain the environment-friendly cleaning degreasing agent.
Example 4:
an environment-friendly cleaning degreasing agent comprises the following components in parts by mass: and (2) a surfactant: 150 parts of pure water: 80 parts of a phospholipid compound: 50 parts of ethanol: 50 parts of essential oil: 50 parts of sodium percarbonate: 30 parts of natural plant deodorant: 40 parts of release liquid: 40 parts of plant oil removal liquid: 30 parts of grapefruit peel: 5 parts of auxiliary liquid: 9 parts of garlic extract: 8 parts.
The preparation method of the environment-friendly cleaning degreasing agent specifically comprises the following steps:
s1, weighing fatty alcohol polyoxyethylene ether and cocoanut acid diethanolamide, heating the fatty alcohol polyoxyethylene ether to 75 ℃, then cooling to 40 ℃, adding cocoanut acid diethanolamide into the cooled fatty alcohol polyoxyethylene ether, uniformly stirring, heating to 65 ℃, cooling to room temperature to obtain a surfactant, weighing the surfactant, pure water and a phospholipid compound, mixing the surfactant and the pure water, adding the phospholipid compound, heating to 80 ℃ during mixing, and obtaining a first mixed solution;
s2, weighing white vinegar and baking soda, pouring half of the white vinegar into a container, adding the baking soda into the container to mix with the white vinegar to obtain a first mixed solution, heating the first mixed solution to 80 ℃, directly adding the rest white vinegar after reaching the temperature, stopping heating and stirring for 40min to obtain a release solution, weighing essential oil, sodium percarbonate and the release solution, mixing the essential oil with the release solution, heating to 75 ℃, immediately cooling to 45 ℃ after reaching the heating temperature, adding sodium percarbonate, continuously stirring uniformly, and adding into the first mixed solution to obtain a second mixed solution;
s3, weighing orange peel, lemon peel and citric acid, wherein the ratio of the orange peel to the lemon peel to the citric acid liquid is 1:1:2, crushing the orange peel and the lemon slices to 40 meshes to obtain crushed blocks, adding the crushed blocks into the citric acid liquid for boiling, filtering impurities after boiling for 30min to remove the impurities to obtain plant oil removal liquid, weighing the plant oil removal liquid and the grapefruit peel, cleaning, sun drying and crushing the grapefruit peel, pouring the grapefruit peel into the plant oil removal liquid for boiling, cooling at room temperature after boiling, adding the second mixed liquid, and uniformly stirring to obtain a third mixed liquid;
s4, weighing triethanolamine, sorbic acid and deionized water, adding the triethanolamine into the deionized water, stirring the mixture through a stirring kettle, wherein the rotation speed of the stirring kettle is 800rpm, the stirring time is 40min, adding the sorbic acid into the stirring kettle after stirring is completed, the rotation speed of the stirring kettle is 700rpm, the stirring time is 40min, obtaining a fusion solution, heating and stirring the fusion solution, the heating temperature is 70 ℃, stirring for 2 hours to obtain an auxiliary solution, weighing ethanol, a natural plant deodorant, the auxiliary solution and a garlic extract, adding the ethanol, the natural plant deodorant and the auxiliary solution into the third mixed solution, heating the mixture to 90 ℃, keeping the temperature for 2 hours, adding the garlic extract, and uniformly stirring to obtain the environment-friendly cleaning degreasing agent.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Other embodiments of the disclosure will be apparent to those skilled in the art from consideration of the specification and practice of the disclosure disclosed herein. This application is intended to cover any adaptations, uses, or adaptations of the disclosure following, in general, the principles of the disclosure and including such departures from the present disclosure as come within known or customary practice within the art to which the disclosure pertains. It is intended that the specification and examples be considered as exemplary only, with a true scope of the disclosure being indicated by the following claims.
Claims (10)
1. The environment-friendly cleaning degreasing agent is characterized by comprising the following components in parts by mass: and (2) a surfactant: 40-150 parts of pure water: 30-80 parts of an emulsifying agent: 10-50 parts of ethanol: 10-50 parts of auxiliary oil removal liquid: 20-50 parts of sodium percarbonate: 10-30 parts of deodorant: 10-40 parts of release liquid: 20-40 parts of plant oil removal liquid: 10-30 parts of grapefruit peel: 1-5 parts of auxiliary liquid: 5-9 parts of bactericide: 1-8 parts.
2. The environment-friendly cleaning and degreasing agent according to claim 1, wherein the surfactant is a mixture of fatty alcohol polyoxyethylene ether and coco diethanolamide.
3. The environment-friendly cleaning and degreasing agent according to claim 2, wherein the emulsifier is one of a phospholipid compound and a nonionic emulsifier, and the auxiliary degreasing liquid is one of essential oil and soap solution.
4. An environment-friendly cleaning and degreasing agent according to claim 3, wherein the deodorant is a natural plant deodorant, and the bactericide is garlic extract.
5. The environment-friendly cleaning and degreasing agent as claimed in claim 4, wherein the preparation method of the surfactant comprises the following steps:
a1, weighing fatty alcohol polyoxyethylene ether and coco diethanolamide, heating the fatty alcohol polyoxyethylene ether to 50-75 ℃, and then cooling to 30-40 ℃;
and A2, adding coconut diethanolamide into the cooled fatty alcohol-polyoxyethylene ether, uniformly stirring, heating to 50-65 ℃, and cooling to room temperature to obtain the surfactant.
6. The environment-friendly cleaning and degreasing agent as claimed in claim 5, wherein the preparation method of the release liquid comprises the following steps:
b1, weighing white vinegar and baking soda, pouring half of the white vinegar into a container, and adding the baking soda into the container to mix with the white vinegar to obtain a first mixed solution;
and B2, heating the first mixed solution to the temperature of 60-80 ℃, directly adding the rest white vinegar after the temperature is reached, and stopping heating and stirring for 20-40min to obtain the release liquid.
7. The environment-friendly cleaning and degreasing agent as claimed in claim 6, wherein the preparation method of the plant degreasing liquid comprises the following steps:
c1, weighing orange peel, lemon peel and citric acid, wherein the ratio of the orange peel to the lemon peel to the citric acid liquid is 1:1:2, crushing the orange peel and the lemon slices to 20-40 meshes to obtain crushed lumps:
and C2, adding the fragments into citric acid liquid for boiling for 10-30min, and filtering impurities to remove the impurities to obtain the plant oil removal liquid.
8. The environment-friendly cleaning and degreasing agent according to claim 7, wherein the grapefruit peel is subjected to cleaning, sun drying and crushing treatment.
9. The environment-friendly cleaning degreasing agent as claimed in claim 8, wherein the preparation method of the auxiliary liquid comprises the following steps:
d1, weighing triethanolamine, sorbic acid and deionized water, adding the triethanolamine into the deionized water, and stirring by a stirring kettle, wherein the rotating speed of the stirring kettle is 500-800rpm, and the stirring time is 20-40min;
d2, adding sorbic acid into the stirring kettle after stirring is completed, wherein the rotating speed of the stirring kettle is 300-700rpm, and the stirring time is 10-40min, so as to obtain a fusion solution;
and D3, heating and stirring the fusion solution at the heating temperature of 50-70 ℃ for 1-2 hours to obtain auxiliary liquid.
10. The environment-friendly cleaning and degreasing agent according to claim 9, wherein the ratio of the emulsifier to the ethanol is 1:1.
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| CN202310334185.9A CN116410822A (en) | 2023-03-31 | 2023-03-31 | Environment-friendly cleaning degreasing agent |
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| CN202310334185.9A CN116410822A (en) | 2023-03-31 | 2023-03-31 | Environment-friendly cleaning degreasing agent |
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| CN106893653A (en) * | 2015-12-17 | 2017-06-27 | 天津微都市科技有限公司 | A kind of environmentally friendly degreaser |
| CN107964667A (en) * | 2017-12-17 | 2018-04-27 | 柳州市晟铂贸易有限公司 | A kind of environmental protective metal degreaser |
| CN113214915A (en) * | 2021-04-26 | 2021-08-06 | 深圳市恒享表面处理技术有限公司 | Oil removing agent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106893653A (en) * | 2015-12-17 | 2017-06-27 | 天津微都市科技有限公司 | A kind of environmentally friendly degreaser |
| CN106118896A (en) * | 2016-06-07 | 2016-11-16 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
| CN107964667A (en) * | 2017-12-17 | 2018-04-27 | 柳州市晟铂贸易有限公司 | A kind of environmental protective metal degreaser |
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